UOP XCeedTM Bioreactor Technology: Specialty Chemicals Application UOP’s XCeed bioreactor technology is an enabling process for bulk treatment of contaminants in a variety of applications and diverse waste streams. Specialty chemical wastewater streams are plagued with residual organics, including aromatics, amines and various derivatives. UOP’s XCeed bioreactor technology can be employed for bulk treatment as well as in polishing and reuse applications. The system’s compartmentalized plug-flow design and sophisticated biological population lead to highly efficient treatment with low sludge generation, low operational and maintenance costs, and low component replacement costs. UOP’s XCeed bioreactor technology has been incorporated in several specialty chemical applications to meet regulatory discharge requirements. Customer Challenge: A specialty chemicals plant in Castanea, Pennsylvania manufactures a wide-range of chemicals, including: • Dye intermediates • Phenol derivatives • Aniline • Chlorobenzene Key Features • Low energy demand resulting in lower operating and maintenance costs than alternative systems • Generates 70-80% less waste solids relative to membrane bioreactors (MBRs), and up to 60-70% less waste solids than moving bed bioreactors • Nitrobenzene • Nitriles • Aromatic amines (MBBRs) • High effluent quality with low sludge generation • Sophisticated lab and analytical capabil- Due to the batch nature of the production of these chemicals, the wastewater generated by the plant varies considerably not only in the biological oxygen demand (BOD) strength ities to ensure efficient and effective process design for customer solutions of the wastewater, but also in the organic composition that contributes to the BOD. • Modular system design offers The local sewer authority implemented a surcharge requiring the facility to pay a fee when BOD levels in the discharged wastewater were greater than 300 mg/L. Due to the variability of the plant's specialty chemicals production, the facility's wastewater BOD concentration could measure upwards of >10,000 mg/L. Given these conditions, the plant faced prohibitively high surcharges for disposing of their wastewater to the local sewer and needed to find a more economical solution. Solution The customer conducted an extensive on-site pilot of UOP's XCeed bioreactor technology, treating actual wastewater generated from the site over a period of months. During this pilot study, UOP’s XCeed bioreactor system was able to tolerate the wide variability of organics composition and concentration in the plant's wastewater while maintaining a final BOD measurement of <300 mg/L. mechanical simplicity, compact size and flexible configuration Results As a result of the successful pilot study, the customer implemented a full-scale XCeed bioreactor treatment system at this site, including up-front equalization tanks and two bioreactor modules, which operated in parallel to treat the plant's wastewater. The combination of equalization tanks and the unique plug-flow characteristics of UOP’s XCeed bioreactor technology resulted in consistently meeting the BOD surcharge limit and lowering specific toxic organic constituents such as chloro-benzene, toluene, phenol and acrylonitrile below the level of detection. UOP LLC, A Honeywell Company 25 East Algonquin Road Des Plaines, IL 60017-5017, U.S.A. Tel: +1-847-391-2000 www.uop.com © 2015 UOP LLC. All rights reserved. This information is not to be taken as a warranty or representation for which UOP assumes legal responsibility nor as permission or recommendation to practice any patented invention without a license. It is offered solely for your consideration. UOP6144-4a March 2015
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