J. Appl. Geophys., Vol. 3, No. 2, September 2004, 177-187 PALEOMAGNETISM OF THE UPPER CRETAEOUS BAHARIYA FORMATION, BAHARIYA OASIS, WESTERN DESERT, EGYPT By Hatem Odah National Research Institute of Astronomy and Geophysics, 11722 Helwan, Cairo, Egypt ABSTRACT A total of 70 samples were collected at 14 sites from the Upper Cretaceous Nubia Sandstones of Gebel El Dist, Bahariya Formation, Bahariya Oasis, Western Desert for paleomagnetic and rock magnetic studies. Rock magnetic measurements indicated that the main magnetic carrier is hematite. Magnetite and goethite are also present as subordinate constituents. Careful thermal demagnetization was applied to the samples because of the existance of the high coercive minerals. Most of these samples carry a weak but stable remanant magnetization. The demagnetization yielded a mean magnetization of Dec = 197º and Inc = -32º (α95 = 7.1ο), corresponding to a pole position of Lat. = 71ο N and Long. = 151ο E. The obtained pole position is inconsistent with the Upper Cretaceous African reference pole, but falls closer to the Eocene (40 Ma age) pole indicating that the studied rocks could have suffered a complete remagnetization during the late Eocene time. these rocks became magnetized. The interpretation of the magnetic record of these sediments depends critically on when and how the natural remnant magnetization (NRM) was acquired and what postdepositional sort of modifications occurred. In this study, the Bahariya Formation, Bahariya Oasis, Western Desert is subjected to paleomagnetic and rock magnetic investigations. Despite the assigning Lower Cenomanian age for the Bahariya Formation by many authors (e. g. Morsy, 1987; Hanafy et al., 1996; Abdel-Monem et al., 2003), the age of this formation and the postdepositional processes affected it still a matter of controversy. Therefore, the purpose of this study is to use paleomagnetism in INTRODUCTION The Nubia Sandstones have been intensively used in paleomagnetic investigations for their high content of magnetic minerals and measurable magnetism. The first paleomagnetic investigation on the Egyptian Nubia Sandstones was carried out by El Shazly and Krs (1970) who examined some Nubia Sandstones from Wadi Natash in the Eastern Desert. Later, the Nubia Sandstones were studied in several localities, ex. El Shazly and Krs (1973); Hussain et al. (1976); Schult et al. (1978, 1981); Hussain and Aziz (1983); Ibrahim (1993); Kafafy et al. (1995) and Ibrahim et al. (1998). Despite such investigations, the paleomagnetic data of the Nubia Sandstones of Egypt remain a subject of controversy due to the incomplete understanding of the processes by which dating and analysis of post depositional magnetization, hence dating the 177 178 Hatem Odah postdepositional diagenetic processes affected this formation. In addition, the tectonic movements affected the sampling area is also tested as the Bahariya Oasis lies on the hingline between the stable and unstable shelves (Said, 1962) and has been subjected to subsequent phases of folding and faulting (Morsy, 1987; El Agami, 1989). GEOLOGIC SETTING The term Nubia Sandstone is well established in the stratigraphic column of Egypt and is used to describe the extensive sandy formations (clastic series) overlying the Precambrian basement rocks and those conformably underlies the marine sequence of Upper Cretaceous variegated shale. Similar formations of the Nubia Sandstones are also known in some surrounded countries in North Africa and Middle East. Because fossils are generally absent or rare in these rocks, it is difficult to assign them definite ages. The questions of the age of the Nubia Sandstones and their environments of deposition have been discussed in several publications (Said, 1962; Pomeyrol, 1968; Soliman, 1971; El Shazly and Krs, 1973; Klitzsch et al. 1979; Ward and McDonald 1979; Van Houten et al., 1984; El Khoriby, 2003). The age of the Nubia Sandstone of the Eastern Desert according to Van Houten et al. (1984) ranges from Early Cretaceous to Late TuronianConiacian time. The studied Bahariya Formation, Bahariya Oasis, Western Desert is assigned a Cretaceous age (Cenomanian) by many authors (e.g. Morsy, 1987; Hanafy et al., 1996, and Abdel-Monem et al., 2003). This Cenomanian age ranges from 98 to 93 Ma according to the Geological Time Scale for the Phanerozoic (Gradstein and Ogg, 1996). Amer (1973), Khalifa (1977) and Franks (1982) assumed that the tectonism in the Bahariya Oasis was essentially due to the Syrian arc belt deformations which continued in the post Upper Cretaceous and pre-Lower Eocene. The most important tectonic event occurred during the late Cretaceous and early Tertiary was probably related to the movement of North Africa plate towards Europe. This resulted in the elevation and folding of the north Western Desert along ENE and WSW and development of faults. Moreover, by end of the Oligocene, the Bahariya Oasis underwent faulting by ruptures producing E –W fractures and conjugate shear fractures. Among these fractures, thermal and volcanic activities took place (Morsy, 1987). Issawi et al. (1999) stated that there were periods of heavy rain fall and activity of surface water during Oligocene. Therefore, after the NE – SW anticline of the Bahariya Oasis has formed and fractured by faults, both running water and wind excavated the center of this anticline to form a great anticlinal depression (reverse topography, El Agami, 1989). The Cenomanian Bahariya Formation at the Bahariya Oasis was therefore subjected to diagenetic changes by meteoric water and thermal activity after their deposition and until the Miocene. One of these diagenetic phases occurred during the Late Eocene and Early Oligocene. The Bahariya Formation forms most of the cliffs and slops surrounding the Bahariya depression in the Western Desert. It also forms the southern and northern parts of depression floor and covers most of Farafra depression (Morsy, 1987). The stratigraphy and structure of this formation have been discussed by several authors (e.g. Ball and Beadnell, 1903; Morsy, 1987). The lithostratigraphic section of Bahariya Formation given by most authors is nearly similar where the section of Gabal El Dist is considered as the type locality of this formation. In general, the formation consists of cross-bedded, variegated sandstone alternating with clay and shale and could be P a le o m a g n e tis m o f T h e U p p e r Cr e ta e o u s B a h a r iy a F o r m a tio n subdivided into two members, from base to top, the Mandisha Member and El Dist Member (Morsy, 1987). SAMPLING AND METHODOLOGY In this study, 70 specimens out of 14 sites were obtained from Bahariya Formation at Gebel El Dist. The sampling site (lat. 28º 55´ N and long. 28º 25´ E) is located to the west of El Gidida mine (Fig. 1). All samples were collected as hand samples that were oriented using a magnetic compass. 28° 40' 28° 50' 29° 00' 29° 10' 29° 20' Study area El Gidida Mine 28° 30' Sampling Section G. El Dist 0 5 10 Km. Quaternary Dep. Qatrani Fm. El Heiz Fm. Iron ore Dep. Eocene Dep. Bahariya Fm. Haddadin Basalt Duwi Fm. Sabaya Fm. 28° 20' Fig. 1. Location map showing the sampling locality. Cores of 2.5 cm diameters were later drilled in the laboratory and sliced into specimens of 2.2 cm length to suite paleomagnetic measurements. The structural attitude of the studied formation was carefully measured and was found to be strike/dip = 270/25 for the structural correction of the magnetic vectors back to their pre-tilting position. All the magnetic measurements were carried out at the Paleomagnetic Laboratory of the Department of Earth and Planetary Science, University of Tokyo, Japan. The natural remnant magnetization was measured using the fully shielded 2GSQUID Cryogenic magnetometer. The present geomagnetic field direction at the 179 study area is Dec.= 2.863° and Inc.= + 41.867° calculated using the 9th generation of the International Geomagnetic Reference Field program (http://www.geomag.bgs.ac. uk / gifs / igrf_form.shtml). ROCK MAGNETISM The Fe oxides which contribute to the NRM are identified using blocking temperature spectra (Irving and Opdyke, 1964), and isothermal remnant magnetization IRM (Dunlop, 1972). The timing of the NRM acquision of the studied rocks was obtained by comparing the obtained pole position with the previously published pole positions. Some pilot samples representing the fourteen sampled sites were subjected to rock magnetic measurements to identify the main magnetic carriers using a vibrating sample magnetometer (VSM, MicroMag 3900) of Princeton Measurements Corporation. Thermomagnetic curves (Js-T curves) of the pilot samples were measured in helium atmosphere (using the MicroMag). Figure 2a is an example of the Js-T curves showing three Curie temperatures at about 216 οC, that may reveal the presence of goethite, at about 575 οC, indicating the presence of magnetite, and at 700 οC at the end of the experiment indicating the presence of hematite. Hysteresis loops of the studied samples show wasp tail shape without saturation even in field of 800 mT. Figure 2b shows an example of the studied hysteresis loops indicating the presence of low coercivity phase (“magnetite-like” phase) and high coercivity phase (“hematite-like” phase) and/or (“goethite-like” phase) confirming the results of the thermomagnetic curves. The calculated mean hysteresis parameters are: the saturation magnetization Ms = 1.34 Am2/kg; the saturation remanence Mrs = 2.15 Am2 /kg; the ratio of Mrs / Ms = 1.6 and the coercive force Hc = 180.38 mT. 180 Hatem Odah 14 6 A 12 4 10 Ms = 1 34 * Mrs = 2 15 * Mrs / Ms = Hc = 180 4 B -2 -2 2 8 0 6 - 4 - 2 0 0 100 200 300 400 Temperature ( 500 o 600 700 800 C) - - 0 Applied Field 400 800 Fig. 2: Rock magnetic measurements of the studied samples: a) Thermomagnetic curve of sample 1 from site 3 with Curie temperatures showing the presence of hematite, magnetite and goethite, and b) Hysteresis loop of sample 1 from site 3 shows the presence of hematite. PALEOMAGNETISM All the studied samples showed weak magnetization with initial NRM intensities ranging from 0.5 to 0.9 mA/m, which was well above the noise of the squid. It was noticed that the intensity of magnetization for the studied sandstone is directly related to the degree of red pigmentation i.e. the more reddish the sample, the higher its intensity. In order to isolate the characteristic remnant magnetization, all the collected samples were subjected to a full range of thermal demagnetization in steps up to 690 OC. Thermal demagnetization was effective and yielded well resolved paleomagnetic components. Most of the treated samples showed erratic behavior during the beginning of the demagnetzation that was explained by the removal of a soft overprint that may be carried by goethite. This soft component was removed after heating to about 100 OC in most of the samples. Direction and intensity of the demagnetization data were plotted on the orthogonal projection (Zijderveld, 1967) and the linear segment was selected to perform the principle component analysis (Kirschvink, 1980) which is based on the determination of the demagnetization trajectories heading towards the origin. Typical examples of the magnetic behavior during the thermal demagnetization are shown in Figure 3. Most samples showed stable magnetization, intensity decreasing continuously and directions changed apart from the first few steps, linearly heading toward the origin of the orthogonal plot. Most of the NRM intensity was lost by 600 οC (Fig. 3). The unit weigh is given to each site and the site mean directions were calculated and combined together for calculating the overall mean direction using Fisher statistics (Fisher, 1953). The obtained results before and after bedding correction are listed in Table 1 and plotted in Figure 4 (a and b). DISCUSSION AND CONCLUSIONS All sites show negative inclination with consistent directions, except sites 8 and 14 with a small deviation (Table 1; Fig. 4). The calculated overall mean direction after the bedding correction (Dec = 197º and Inc = -32º) differs from the direction of the present Earth's magnetic field at the study area (Dec. = 2.863°, Inc. = 41.867°) i.e. the magnetization is not related to the present Earth’s magnetic field. P a le o m a g n e tis m o f T h e U p p e r Cr e ta e o u s B a h a r iy a F o r m a tio n 181 N, UP 2 A 1.5 NRM 1 575 0.5 0 NRM 0 100 200 300 400 500 600 700 o Temperature ( C) N, UP 8 7 B 6 5 4 W, W 3 550 2 1 NRM 0 0 100 200 300 400 500 600 700 o Temperature ( C) N, UP 2 C 1.5 1 W, W 550 0.5 NRM 0 0 100 200 300 400 500 600 700 o Temperature ( C) Fig 3. Characteristic examples of the thermal demagnetization and intensity behaviour of the samples. 182 Hatem Odah Table 1. Site-mean directions of the studied sandstone samples with the overall mean direction. Site No. α95 (ο) Directions Paleomag. Pole Inc. (ο) Dec. (ο) Lat. (°N) Long. (°E) 1 5.4 197 -17 65 166 2 4.8 201 -23 64 155 3 6.0 204 -20 61 153 4 5.3 220 -32 52 127 5 5.0 215 -33 57 129 6 6.2 202 -15 61 161 7 4.3 217 -21 51 138 8 8.1 239 -14 31 128 9 4.5 203 -24 64 152 10 5.3 197 -13 63 170 11 6.2 218 -21 51 138 12 6.2 208 -16 57 151 13 5.1 204 -16 60 157 14 7.9 199 -47 73 116 BBC 7.1 209 -23 58 145 Mean ABC 7.1 197 -32 71 151 α95 = radius of the cone of the 95% confidence; Dec and Inc. = declination and inclination, respectively; Lat. = north latitude; Long. = east longitude. BBC, ABC = Mean before and after bedding correction respectively. N N Fig. 4. Site mean directions with the overall mean of the sites before and after bedding correction. P a le o m a g n e tis m o f T h e U p p e r Cr e ta e o u s B a h a r iy a F o r m a tio n The obtained paleomagnetic pole position from this study after bedding correction lies at Lat. = 71° N and long. = 151° E (α95 = 7.1ο). Unfortunately, a fold test could not be applied in the present study as the sampled formation tilts homogeneously in the same direction. The resultant pole still deviates from the poles of 90 - 100 Ma of the Cretaceous African reference poles of Besse and Courtillot (2002). These data were extracted from the computerized Global Paleomagnetic Database (GPMD V3.3) of McElhinny and Lock (1995). On the other side, the resultant pole shows a good consistency with pole positions of age window 30 – 50 Ma (Fig. 5). This inconsistency between the resultant pole and Cretaceous African reference pole (90 Ma) may refer to a tectonic movement that could have affected the sampling area. A trial was done to calculate the amount of rotation with respect to the 90 Ma reference pole of Africa of Besse and Courtillot (2002). The mean of pole positions for the ages from 82 -111 of GPMD V3.3 of McElhinny and Lock (1995) is calculated to lie at Lat. = 66.4° N and long. = 247.2° E (α95 = 6.3ο). The calculated rotation value is found to be 16.3ο ± 6ο (Rot-flat program). This rotation angle is too large to be expected in this area and has no geological explanation. Therefore, such tectonic interpretation of this inconsistency is excluded. Therefore, another interpretation for this inconsistency of the resultant pole with the pole positions of 90 - 100 Ma and its consistency with the pole positions of 30 – 50 Ma (Fig. 5) is that these sediments have suffered post depositional remagnetization that affected the Bahariya Formation and at the age of 30 – 50 Ma. Abdeldayem (1999) has constructed a Cenozoic APWP for Africa. He has computed the mean poles for the appropriated time windows and plotted them 183 together with the 62 Ma pole of Besse and Courtillot (1991). It was therefore decided to plot the resultant pole against the recently Cenozoic APWA of Abdeldayem (1999) to try to test the date of this magnetization. As Figure 6 shows, the present pole coincides with the 40 Ma (Late Eocene) pole. 180 74 90 44 BNS 34 89 30 82 50 72 37 60 93 270 24 90 80 0 Fig. 5. Comparison between the obtained Bahariya pole position with the African reference poles from 24 - 90 Ma age of Besse and Courtilliot (2002) extracted from the GPMD V3.3 Database of McElhinny and Lock (1995). 180 BNS 62 40 18 30 9 270 60 90 0 Fig. 6. Comparison between the obtained Bahariya pole position with the APWP of the African Cenozoic of Abdeldayem (1999). 184 Hatem Odah To confirm this age, the resultant pole was further plotted with some selected genuine poles representing the Eocene age for Egypt (Fig. 7 and Table 2). As Figure 7 shows, there is a clear consistency between the resultant pole and the other poles of the Mokattam and Maadi limestone of Kafafy et al., (1995) and Mokattam limestone of Abdeldayem (1999). 180 4 1 3 2 60 270 90 0 Fig. 7. Comparison between the present studied pole position with some selected Eocene poles from Egypt. All these results confirm that the studied formation was remagnetized postdepositionally, most probably of 40 Ma age. The hypothesis of the remagne-tization processes for the studied rocks is more accepted and came combatable with the available geologic information which indicates that the studied formation has been subjected to subsequent of folding, faulting and diagenetic changes by the act of meteoric water and thermal activity (El Kammar and El Kammar, 2002). One of these phases of diagenetic changes, which occurred during the Late Eocene and Early Oligocene caused the oxidation and dissolution of the primary iron bearing minerals (magnetite and pyrite) and precipitated the iron in the form of hematite and goethite. In addition, the climate during most of the Tertiary was humid, implying that ample runoff water was available (Bown et al., 1982). Moreover, Issawi et al. (1999) stated that there were periods of heavy rain fall and activity of surface water during Oligocene that could led to addition and precipitation of secondary magnetic minerals, more probably hematite. This is in agreement with the rock magnetic results that indicate that hematite is the main carrier of the magnetization. The studied formation has therefore acquired a secondary chemical remnant magnetization CRM that replaced all pre-existing magnetization and therefore bears no relationship to the depositional age of the rock. The remagnetization hypothesis is therefore more acceptable and more realistic as it was assumed by similar paleomagnetic studies carried out on Nubia sandstones from other areas (e.g., Kafafy et al., 1996; Ibrahim et al., 1998) which proposed a regional remagnetization due to their porous nature that allowed secondary minerals to be deposited between and around the rock grains diagenetically. Additionally, El Khoriby (2003) stated that the high porosity of the Nubia Sandstones allowed the passage of groundwater that made these rocks more susceptible to extensive alteration. The calculated mean inclination indicates that the magnetization was acquired when the studied rock and the sampling locality were at a paleo-latitude of 17.3ο north the equator (near equatorial environment), confirming the warm and arid weather which led to the deposition of the hematite during the prevailing diagenetic process. 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