A Tale of Four Electrons Using creative writing to learn about chemical bonding Paul Burgmayer ne sweltering summer afternoon, four electrons sat on a river bank, restless and with nothing to do. On the left was Crystal, a sodium electron. Crystal [was] often… lonely because she was the only electron in her atom’s outer shell. “Once upon a time, in a land far, far away…” began the chemistry teacher, “each of these electrons began in single atoms. Eventually, they bonded with other atoms, following one of three fates: ionic, covalent, or metallic bonding to form chemical bonds…Bonding is a sort of rite of passage that changed the lives of these electrons forever.” Here ye, here ye to all who dare: The King of Periodicity henceforth proclaims his desire for four brave and noble electron knights to join the famed “Knights of the Periodic Table.” Those electrons of atoms of noble birth will face challenges unlike any other. “And in the news today, Bonding, Inc., is looking for new electrons to begin careers for the large bonding firm. Electrons interested…” Mike’s mother interrupted the news report: “Mike, do you want to eat? We have Proton Pebbles, Fluorine Flakes, and—” “Not now! They’re talking about the new jobs!” Mike turned up the TV. February 2011 53 So begin four student essays for “A Tale of Four Electrons,” a creative writing assignment I use with my 10th-grade Honors Chemistry students. The project helps students consolidate their learning about bonding—an important unifying theme in chemistry—and answer questions such as How are ionic, metallic, and covalent bonds related? How do variations in electron configuration across a period alter expected bonding? and How do intermolecular forces depend on bond polarity? uu uu uu words (Figure 2) in ways that demonstrate their understanding. (Students are also given the option to create a multipage, hyperlinked PowerPoint to explain chemical bonding, but the story option is encouraged.) To simplify the grading process, I provide students with a story line consisting of four parts (Figure 3, p. 56): uu uu I have found that most students are enthusiastic about this assignment. I am also amazed by their ability to intertwine creative stories with bonding concepts and vocabulary words. This article describes the assignment, and the processes I use to grade students’ tales. The assignment I begin by giving students a copy of the assignment and a grading sheet (see “On the web”). Students must incorporate all 14 bonding concepts (Figure 1) and 35 of 44 bonding vocabulary uu In Part 1, students describe the “life” of each electron in an unbonded atom, including a name, a description of the atom, and the orbital configuration. In Part 2, they must form one of the four bonds (i.e., ionic, metallic, polar covalent, or pure molecular/ network covalent) with an appropriate atom and describe the electron’s bonding experience. In Part 3, students explain the bonding results on a molecular and everyday level, including expected physical properties and any intermolecular forces that arise. This dual view of the world (particulate vs. macroscopic) is a major theme throughout my course and an important part of the National Science Education Standards (NRC 1996; Content Standard B). Figure 1 Bonding concepts. uu uu uu uu uu uu uu uu 54 Most atoms are chemically bonded to other atoms. The three major types of chemical bonding are ionic, covalent, and metallic. In general, atoms of metals bond ionically with atoms of nonmetals, atoms of metals bond metallically with each other, and atoms of nonmetals bond covalently with each other. Atoms in molecules are joined by covalent bonds. The bond length between two atoms in a molecule is the distance at which the potential energy of the bonded atoms is minimized. The octet rule states that many chemical compounds tend to form bonds so that each atom—by gaining, losing, or sharing electrons—shares or has eight electrons in its highest occupied energy level. A single bond is a covalent bond in which a pair of electrons is shared between two atoms. Covalent bonds with more than one pair of shared electrons are called multiple bonds. Bonding within many molecules and ions can be indicated by a Lewis structure (or what is sometimes called an electron dot diagram). The Lewis structure for water, for example, looks like this: The Science Teacher Molecules or ions that cannot be correctly represented by a single Lewis structure are represented by resonance structures. uu An ionic compound is a three-dimensional network of positive and negative ions mutually attracted to one another. uu Because of the strong attraction between positive and negative ions, ionic compounds tend to be harder and more brittle and have higher boiling points than materials containing only covalently bonded atoms. uu Polyatomic ions are charged groups of atoms held together by covalent bonds. uu Metallic bonding is a type of chemical bonding that results from the attraction between metal atoms and mobile electrons floating in a conduction band between metal atoms. uu In metallic bonding, the lack of a band gap between valence and conduction bands gives metals their properties of high electrical conductivity, malleability, ductility, and luster. uu Intermolecular forces—such as dipole-dipole forces and London dispersion forces—exist between certain types of molecules. Hydrogen bonding is a special case of dipole-dipole forces. A Tale of Four Electrons uu In Part 4, students describe their four electrons meeting for coffee and comparing and contrasting their experiences. The covalently bonded electron claims that all bonding is really covalent in nature. The other electrons either agree or disagree and defend their reasoning. Students have four weeks to complete the project— including two class periods and four “homework-free” nights. After we discuss the assignment as a class, students are asked to come prepared to try out their stories with their classmates the following day. During their first in-class workday, as students discuss their plots with a partner and match them with chemical concepts, they discover that the assignment is more difficult than they thought. I rotate around the room, discussing any uncovered misconceptions. Because students use chemistry concepts to create their own “world,” they review the concepts in a highly interactive and engaged way. Students then have two weeks to create a draft outline of their stories with incorporated concepts. Once submitted, I review the outlines to make sure students follow the story line and demonstrate understanding of the concepts. They receive a preliminary grade based on correct concept inclusions, cohesiveness of the story, and creativity. I also suggest ways to improve stories for those with low scores. Students then have two more weeks and three more homework-free nights to work on their tales. During the second in-class workday, two weeks after the first, there is less discussion; students spend most of their time incorporating missing concepts. I wander around the room—looking over students’ shoulders, asking about their plots, and trying to catch any misconceptions. As the assignment deadline nears, I begin to overhear students discussing their plots and characters. Although some groan about the workload, students are clearly proud of their final creations. G ra d i n g As expected with an assignment covering so much material, grading is a major task. This is where the grading sheet (see “On the web”) comes in handy. I also have students submit Extensions. Figure 2 This assignment could be used for any difficult or complex science concept. The biology curriculum at my school includes a similar exercise, in which students write a two-act play about the steps of photosynthesis. This year, I tried a similar approach in a lower-level chemistry class to assess students’ understanding of the law of conservation of matter in a “copper cycle” lab, in which copper is reacted with a series of reagents. This forms different copper salts and eventually transforms the copper back to the metallic state. Beginning students often do not understand that the same copper atoms are carried through the sequential reactions. Asking students to describe themselves as a copper atom moving through the cycle allows me to see how they view the transformation on a submicroscopic, particulate level. For many years, my wife, Sharon Burgmayer, a professor at Bryn Mawr College, has given students the option of writing an “elemental profile” in lieu of an in-class exam. The goal of this profile is to develop a “personality” for the element, what she describes as “literary character development” in the form of a letter to the student’s family describing a new friend. Grading is based on creativity, the number of connections made between chemical behavior and “personality,” writing quality, and the accuracy of the chemistry described. Chemical bonding vocabulary. Introduction uu uu uu uu uu uu uu chemical bond covalent bonding ionic bonding metallic bonding nonpolar covalent bonding polarity polar-covalent bonding Covalent bonding u bond energy uu bond length uu uu uu uu uu uu uu uu uu uu uu uu uu uu uu chemical formula diatomic molecule double bond electron dot notation Lewis structure lone pair electrons molecular compound molecular formula molecule octet rule resonance single bond structural formula triple bond unpaired electrons Ionic uu formula unit uu ionic compound uu lattice energy uu polyatomic ion Metallic uu band gap uu conduction band uu ductility uu electrical conductivity uu heat of vaporization uu luster uu malleability uu thermal conductivity uu valence band Intermolecular forces uu dipole uu hydrogen bonding uu instantaneous dipole-dipole attraction uu intermolecular force uu London dispersion force uu molecular polarity uu permanent dipole-dipole attraction February 2011 55 Figure 3 Story line. Overview: To consolidate your understanding of basic bonding principles, write a story about four electrons that start their lives in individual atoms, but end up in ionic, metallic, polar covalent, and nonpolar covalent compounds. There should be four parts to your story. Part 1: Life before bonding 1. Name each electron. The name should creatively reflect the bond type that electron will experience. 2. To start, each electron should reside on an atom appropriate for its eventual bonding. 3. For each electron, briefly describe its atom using atomic theory (include Effective Nuclear Charge [ENC]) and describe the electron itself (which should be a valence electron) with an electron configuration. their stories electronically (see “On the web”) to eliminate paper handling and check for plagiarism. To simplify the grading process, I ask students to submit their work using Microsoft Word’s “bookmark” feature to highlight and bookmark all sentences related to a concept or vocabulary word. That way I can skim each story, checking for the requested concepts and vocabulary bookmarks, and review their understanding. An internet-based system such as Google Docs (see “On the web”) can also be used, but I prefer Microsoft Word because the bookmark feature allows for explicit naming. Stories missing vocabulary, concepts, or both are returned for revision. For this assignment, students earn points in four areas: uu uu uu Part 2: The bonding experience 1. Pick an appropriate atom to bond with your electron-containing atom to form an ionic, metallic, polar covalent, or nonpolar covalent bond. 2. For each bond type, describe the bond-forming process. Describe what your electron experiences as the bond is formed. You may use illustrations from the Bonding Images file I have provided, but the illustrations cannot be the primary way used to describe the bonding process. Part 3: Results of bonding 1. Have your electron describe (in his or her own words) the results of the bonding on both a molecular and everyday level. Make sure you describe the expected physical properties for each type of bond. Also describe any intermolecular forces that the electron might experience. Part 4: Discussion 1. Imagine your four electrons meet for coffee at a local diner. Create a conversation comparing and contrasting their experiences. As part of the conversation, include a claim by the covalently bonded electron that “all bonding is really just different forms of covalent bonding.” Have the other electrons respond to that claim. Please be aware that there is no right answer when it comes to the idea that all bonding is really covalent in nature. Both metallic bonding and ionic bonding can be viewed as either an extension of covalent bonding or different and unique types of bonding. I am looking for evidence-based reasoning that is incorporated into your characters’ coffee shop discussions. 56 The Science Teacher uu correct use of vocabulary words (35%), correct explanation of bonding concepts (30%), story line (20%), and creativity (15%). As I read each story, I tally misused vocabulary words and review each of the 14 bonding concepts. This is easier than it might seem, since certain words are commonly misunderstood. Though almost all students include the 14 concepts in some way, some simply list the concept, which gets them no credit. The grading sheet clearly states that full credit is only given if students incorporate the concept into their story in a way that demonstrates understanding. I pay special attention to the coffee shop discussion in Part 4, in which students are asked to think critically about bonding. There is no right answer when it comes to the idea that all bonding is really covalent in nature. Both metallic bonding and ionic bonding can be viewed as either an extension of covalent bonding or a different and unique type of bonding. So I look for evidence-based reasoning and how it is incorporated into their coffee shop discussions. Figure 4 is an example from one student’s story. Reflection I have used this assignment for two years. Students admit that this is one of the most difficult assignments in my class. The sheer number of concepts and vocabulary words that must be knit together into a cohesive story is daunting. Yet most students are proud of their achievements, and rightly so—many demonstrate a sophisticated and nuanced understanding of the types of bonding and their relationships. Because students are using concepts to create their own “world,” they learn and review concepts in a way that is interactive and engaging. It is clear when a student does not understand a concept or vocabulary word because he or she uses it perfunctorily, rather than tightly integrating it into the narrative or character descriptions. I also have fun reading the stories. Compared to test essays, reading these is pleasurable, and even makes me laugh. A Tale of Four Electrons Figure 4 A d d re s s i n g t h e S t a n d a rd s . Part 4 of one student’s tale. The following National Science Education Standards (NRC 1996) are addressed in this project: Below is part of the coffee shop discussion from one student’s tale; the full conversation is available online (see “On the web”). (Note: Crystal is a valence electron from a sodium atom; Frost is from an oxygen atom; Roger is from nitrogen; and Nemo is from a gold atom.) Science Content Standard: Physical Science (p. 176) Structure of atoms uu Chemical reactions uu Assessment Standard B (p. 79) Achievement and opportunity to learn science must be assessed. uu The four electrons met again at the local coffee shop to compare their bonding experiences… “You’re absolutely wrong, Frost!” Crystal exclaimed. “Covalent bonds don’t experience more interactions than ionic bonds. It’s just that my sodium was attracted to chlorine, and the chlorine was attracted back. Ionic bonding isn’t a one-sided affair!” “I suppose,” Frost replied. “But if you think about it, our bonds are similar. Sure, your bond didn’t have any molecules or polarity, but in the end it’s all about filling up that outer shell with the octet rule.” “Absolutely,” Roger said. “You know, our bonding is basically the same. Our atoms both attracted other atoms. When we bonded, we share[d] electrons.” “We were sort of similar too, Roger,” Crystal added. “After all, it’s all about filling that outer shell any way you can.” “I feel so out of the loop here!” Nemo whined. “My bonding was so much different [than] all of yours! Was anything the same?” They all thought for a moment. “Well, sure!” Crystal said. “Both of our bonded structures were in some type of network; everyone relied on everyone else. Ionic bonds work in big lattices, and metallic bonds work in big structures, too.” “You’re right!” said Frost… Though it is a lot of work for both students and the teacher, the payoff is an emotional engagement with what can otherwise be a dry subject. To many students, chemistry is a daunting tower of vocabulary, math, and concepts that does not typically draw on their creative talents. Those who like to write or are mathematically challenged love the assignment. They see it as a way to demonstrate chemical understanding with words, not numbers. After completing the assignment, one student wrote, “I am interested in creative writing a lot, so I was ecstatic when I found out about the story option for the project.” G o i n g fo r wa rd Looking to the future, I wonder about distributing this assignment over the entire bonding unit. Students might write Part 1 (life before bonding) as the class starts the bonding unit, and Parts 2, 3, and 4 after it is completed—allowing more time to build concepts into their stories. The benefit of this staged ap- Assessment Standard D (p. 85) uu Assessment practices must be fair. proach might be that as students work through the unit, they can imagine their four elemental electrons moving through the processes of bonding—making the unit less abstract. I also wonder about devoting one period to sharing completed stories, particularly the coffee shop conversations. Since the relationship of covalent bonding to other bonding forms is not clear-cut, discussion about the coffee shop conversation could open the topic up in a way that a straight “chemistry” discussion might not. To many students, the topic of bonding is abstract, filled with foreign vocabulary and bizarre concepts—far from their experience of the “real world.” This assignment attempts to concretize bonding by having students create their own world—one that they can more closely identify with and use to demonstrate their chemical understanding. n Paul Burgmayer ([email protected]) is a chemistry teacher at Great Valley High School in Malvern, Pennsylvania. Author’s note Though I believe there are many advantages to this more rightbrained approach to assessing bonding, personifying atoms as characters in a story does not sit well with some. However, I would argue that the dual role of assessing students’ understanding and engaging students in their own learning is worth the trade-off. High school students are sophisticated enough to understand that this is a creative writing exercise, not a rigorous scientific explanation of fundamental forces—a distinction that I emphasize throughout the project. On the web A Tale of Four Electrons assignment, grading sheet, and full coffee shop conversation: www.nsta.org/highschool/connections.aspx Electronic story submission: http://turnitin.com Google docs: http://docs.google.com Reference National Research Council (NRC). 1996. National science education standards. Washington, DC: National Academies Press. February 2011 57
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