8519 - 1 - Page 1 Name: ____________________________________________ 1) Radioactive cobalt-60 is used in radiation therapy treatment. Cobalt-60 undergoes beta decay. This type of nuclear reaction is called A) B) C) D) 2) 7) Approximately what fraction of an original Co-60 sample remains after 21 years? B) A) nuclear fusion artificial transmutation nuclear fission natural transmutation 4) increases as it loses electrons decreases as it loses electrons increases as it gains electrons decreases as it gains electrons 5) D) C) neutron D) alpha Which of the following types of radiation has the greatest penetrating power? A) gamma B) alpha 6) C) Which of the following particles has the greatest mass? A) beta B) positron When a neutral atom undergoes oxidation, the atom's oxidation state A) B) C) D) 3) C) beta D) positron Which formula represents a molecule of a saturated hydrocarbon? A) C6 H6 C) C4 H10 B) C5 H8 D) C2 H2 Given the structural formulas for two organic compounds: The differences in their physical and chemical properties are primarily due to their different A) number of carbon atoms B) number of hydrogen atoms 8) 9) Which equation shows conservation of charge? A) Fe + 2e- ‚ Fe3+ C) Fe ‚ Fe2+ + 2e- B) Fe ‚ Fe2+ + e- D) Fe + 2e- ‚ Fe2+ Molecules of 2-methyl butane and 2,2-dimethyl propane have different A) B) C) D) 10) C) molecular masses D) functional groups numbers of carbon atoms molecular formulas structural formulas numbers of covalent bonds A voltaic cell spontaneously converts A) B) C) D) chemical energy to electrical energy electrical energy to chemical energy nuclear energy to electrical energy electrical energy to nuclear energy 11) Given the incomplete equation representing an organic addition reaction: X(g) + Cl2 (g) ‚ XCl2 (g) Which compound could be represented by X? A) C3 H8 C) C4 H10 B) C2 H4 D) CH4 8519 - 1 - Page 2 12) Given the incomplete reaction: 16) Which structural formula represents a molecule that is not an isomer of pentane? A) Which compound is represented by X? 13) 14) A) C) B) D) A) 16 N C) 32 P B) 14 C D) 37 K The amount of energy released from a fission reaction is much greater than the energy released from a chemical reaction because in a fission reaction A) B) C) D) 15) B) Which isotope is most commonly used in the radioactive dating of the remains of organic materials? C) energy is converted into mass ionic bonds are broken mass is converted into energy covalent bonds are broken The diagram below shows a key being plated with copper in an electrolytic cell. D) 17) Which formula represents an unsaturated hydrocarbon? A) C) B) D) Given the reduction reaction for this cell: Cu 2+(aq) + 2e- ‚ Cu(s) This reduction occurs at A) B) C) D) B, which is A, which is B, which is A, which is the anode the anode the cathode the cathode 18) What is the IUPAC name of the compound having the following structural formula? A) 2-pentene B) 3-pentyne C) 2-pentyne D) 3-pentene 8519 - 1 - Page 3 19) Which structural formula represents 2-pentyne? 22) Given the formula: A) This compound is classified as A) an amine B) a ketone 23) C) an aldehyde D) an amide Given the structural formula: B) C) This structural formula represents a molecule of A) a ketone B) an aldehyde 24) D) Given the balanced equation with an unknown compound represented by X: C16 H12 O6 (aq) 20) 21) A) CH3 OH(aq) B) CH2 OHCH2 OH(aq) C) butanol D) propanal C) CH3 CH2 OH(aq) D) CH2 (OH)4 (aq) Which structural formula represents an ether? 25) A) The process of joining many small molecules into larger molecules is called A) saponification B) substitution 26) B) C) neutralization D) polymerization What is the oxidation number of chromium in K2 Cr2 O7 ? A) +6 B) +12 27) C) 2X + 2CO2 (g) Which compound is represented by X? What is the IUPAC name for the compound that has the condensed structural formula CH3 CH2 CH2 CHO? A) butanal B) propanol C) an ester D) an amino acid C) +2 D) +7 Given the reaction: Mg(s) + 2H+(aq) + 2Cl-(aq) ‚ Mg 2+(aq) + 2Cl-(aq) + H2 (g) Which species undergoes oxidation? D) A) H2 (g) C) H+(aq) B) Mg(s) D) Cl-(aq) 8519 - 1 - Page 4 28) 34) Given the reaction: 2Al(s) + Fe2 O3 (s) Mg + CuSO4 ‚ MgSO4 + Cu Al2 O3 (s) + 2Fe(s) Which equation represents the oxidation that takes place? Which species undergoes reduction? 29) A) Fe C) Al B) Al3+ D) Fe3+ Which change in oxidation number indicates oxidation? A) -1 to -2 B) +2 to -3 30) electrical energy, spontaneously nuclear energy, spontaneously nuclear energy, nonspontaneously electrical energy, nonspontaneously C) Mg 2+ + 2e- ‚ Mg B) Cu ‚ Cu 2+ + 2e- D) Cu 2+ + 2e- ‚ Cu Which type of organic compound is represented by the structural formula shown below? A) ether B) alcohol 36) the gain of electrons the loss of electrons the gain of protons the loss of protons What is the purpose of the salt bridge in a voltaic cell? A) B) C) D) 33) C) -1 to +2 D) +3 to +2 Which process occurs at the anode in an electrochemical cell? A) B) C) D) 32) 35) A) Mg ‚ Mg 2+ + 2e- In a voltaic cell, chemical energy is converted to A) B) C) D) 31) Given the reaction: It is a path for the flow of positive and negative ions. It is a path for the flow of electrons. It blocks the flow of electrons. It blocks the flow of positive and negative ions. A diagram of a chemical cell and an equation are shown below. When the switch is closed, electrons will flow from A) the Pb 2+(aq) to the Pb(s) B) the Pb(s) to the Cu(s) C) the Cu 2+(aq) to the Cu(s) D) the Cu(s) to the Pb(s) According to the Activity Series chemistry reference table, which of these metals will react most readily with 1.0 M HCl to produce H2 (g)? A) Ca B) Mg 37) C) ester D) aldehyde C) K D) Zn In which compound does chlorine have the highest oxidation number? A) NaClO C) NaClO3 B) NaClO4 D) NaClO2 8519 - 1 - Page 5 38) Based on the Selected Radioisotopes chemistry reference table, what is the fraction of a sample of potassium-42 that will remain unchanged after 62.0 hours? 39) (a) State one possible advantage of using nuclear power instead of burning fossil fuels. 40) Given the nuclear equation: What nuclear particle is represented by X? (b) State one possible risk of using nuclear power. (c) If animals feed on plants that have taken up Sr-90, the Sr-90 can find its way into their bone structure. Explain one danger to the animals. Questions 41 through 44 refer to the following: The graphic below shows the numbers of neutrons and protons for specific nuclides of C, N, Ne, and S. 8519 - 1 - Page 6 41) Using the point plotted on the given graph for neon, complete the table below. 42) Explain, in terms of atomic particles, why the S-32 nuclide shown in the graph is stable. 43) Using the point plotted on the graph for nitrogen, what is the neutron-to-proton ratio of this nuclide? 44) Based on the Selected Radioisotopes chemistry reference table, complete the decay equation for N-16. ‚ _______________ + _______________ 45) Given the reaction: 4Al(s) + 3O2 (g) ‚ 2Al2 O3 (s) (a) Write the balanced oxidation half-reaction for this oxidation-reduction reaction. 47) Given the ester: ethyl butanoate (a) In the box below, draw the structural formula for this ester. (b) What is the oxidation number of oxygen in Al2 O3 ? 46) Given the balanced equation for an organic reaction between butane and chlorine that takes place at 300.DC and 101.3 kilopascals: C4 H10 + Cl2 ‚ C4 H9 Cl + HCl Identify the type of organic reaction shown. (b) Determine the gram formula mass of this ester. 8519 - 1 - Page 7 48) Given the structural formula for butane: Questions 49 through 51 refer to the following: The diagram below represents a voltaic cell and a balanced ionic equation. In the box below, draw the structural formula of an isomer of butane. 49) What is the total number of moles of electrons needed to completely reduce 6.0 moles of Ni2+(aq) ions in the ionic equation shown? 50) Identify one metal from the Activity Series chemistry reference table that is more easily oxidized than Mg(s). 51) Explain the function of the salt bridge in the voltaic cell shown.
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