Chemistry 2202 Review for Unit 1 Test 1 For questions involving calculations, show all work and give the correct number of significant digits and units in your answer. 1. Complete the table: Isotope name Isotope notation Atomic # Mass # # protons #neutrons 38 90 95 82 87 230 241 208 38 90 95 82 49 140 146 126 Strontium-87 Thorium-230 Americium-241 Lead-208 2. Bromine exists as two naturally occurring isotopes: Bromine-79 (78.91 u) and Bromine-81 (80.92 u). These isotopes have isotopic abundances of 50.69 % and 49.31 % respectively. Calculate the average atomic mass of bromine. WAM = (78.91 u x 0.5069) + (80.92u x 0.4931) = 39.9995 u + 39.9017 u =79.90 u 3. The average atomic mass of silicon is 28.090 u. Silicon-28 has a mass of 27.977 u and relative abundance of 92.23 %. Silicon-29 has a mass of 28.976 u and relative abundance of 4.67 %. Find the mass of the silicon-30 isotope. Abundance silicon-30: LET x = mass of silicon-30 = 100.00% – 92.23%-4.67% = 3.10% WAM = 28.090 u = (27.977 u x 0.9223) + (28.976 u x 0.0467 ) + (0.0310x) 28.090 u = 25.803 u + 1.3532 u + 0.0310x 28.090 u = 27.1563 u + 0.0310x 28.090 u - 27.1563 u =0.0310x 0.9337 u = 0.0310x X=30.12 u 4. Match the following symbol to the quantity (Write the letter in the space provided) a. Mass a m b. Amount (in moles) e M c. Volume f MVSTP d. Avagadro’s number b n e. Molar mass d NA f. Molar volume c v 5. Who developed the concept of the mole? Avagadro 6. Calculate the molar mass for each of the following: No need to show workings for this question only. a. Water MH2O = 18.02 g/mol b. CO2(g) MCO2 = 44.01 g/mol c. Ca(CH3COO)2(s) M Ca(CH3COO)2 = 158.18 g/mol d. Glucose MC6H12O6 = 180.18 g/mol 7. How many decimal places should you include in molar masses calculated from the periodic table? You should always include two places past the decimal ex. MNaOH= 40.00 g/mol 8. Rearrange the formula for the quantity indicated: 9. Convert the following: a. 6.000 x 1024 particles of H2O to amount(in moles) Answer: b. 0.125 mol of N2(g) to number of particles Answer: c. 450 g of NaCl(s) to amount (in moles) Answer: d. 1.345 mol CO2(g) to mass Answer: e. 25.0 L at STP of ammonia to amount(in moles) Answer: f. 14.2 mmol of H2S(g) to volume at STP Answer: 10. These questions involve the application of more than one of the “mole” formulas. a. What mass of propane, C3H8(g) would be found in 25.0 L of the gas at STP? Answer: b. How many molecules of water would be in a 36.0 kg sample?
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