AP Chemistry - Problem Drill 17: Chemical Reactions Question No. 1 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 1. A chemical reaction is the process of bond forming and breaking between atoms. All reactions can be classified into six types. What type is the following reaction: H2CO3 (aq) + Ca(OH)2 (aq) CaCO3 (aq) + 2 H2O (l)? Question (A) Composition (B) Decomposition (C) Single Replacement (D) Acid-base A. Incorrect! Composition is more than one compound forming one compound. B. Incorrect! Decomposition is one compound breaking apart into multiple compounds. C. Incorrect! Single displacement reactions involve a compound and an element as reactants. Feedback D. Correct! This is the reaction of carbonic acid and calcium hydroxide. This is an acid and base reacting to give a salt and water. It is an acid-base or neutralization reaction. H2CO3 is an acid and Ca(OH)2 is a base. The products (CaCO3 and H2O) are a salt and water. This is an acid-base reaction or neutralization reaction, a special type of double displacement. The correct answer is (D). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 2 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 2. Most of the binary acid (HX or H2S) can be produced by their element gases (H2 and X2). Determine the type of reaction for the production of HCl gas from its elements. Question (A) Single displacement (B) Acid-base (C) Composition (D) Decomposition A. Incorrect! This reaction is H2 + Cl2 2HCl. The single displacement is A + BC AC + B. The production of HCl gas from its elements is not a single displacement type. B. Incorrect! Although HCl is a strong acid, there is no base to reaction with. This reaction is H 2 + Cl2 2HCl. It is not a neutralization reaction or acid-base reaction with a general form HA + BOH AD + CB. Feedback C. Correct! Good job! This reaction H2 + Cl2 2HCl is a composition reaction or synthesis reaction with a general form of A + B AB. D. Incorrect! This reaction is H2 + Cl2 2HCl. This is the reversed type of decomposition reaction. Write the balanced reaction and match the general form of a reaction type. This reaction H2 + Cl2 2HCl is a composition reaction or synthesis reaction with a general form of A + B AB. The correct answer is (C). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 3 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 3. Reduction is a half-reaction in redox. It is defined as a decrease in oxidation number with a gain of electrons. Which of the following is a reduction reaction? I. II. Question Sr2+ + 2 e- Sr 2 Cl- Cl2 + 2 e- (A) I (B) II (C) I and II (D) Neither I nor II A. Correct! Good job! Reduction reduces the charge by the gain of electrons. Strontium is going from +2 to 0, which is a reduction in charge. B. Incorrect! Reduction reduces the charge. Chloride is going from -1 to 0, which is not reduction. Feedback C. Incorrect! Reduction reduces the charge. Although strontium is being reduced from +2 to 0, the chloride is being oxidized from -1 to 0. D. Incorrect! Look closely—one of them is a reduction reaction. Reduction is the gain of electrons to reduce the charge of the species. Strontium is being reduced from +2 to 0. The second half reaction is an oxidation reaction since the chlorine is being oxidized to a higher charge (-1 to 0). The correct answer is (A). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 4 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 4. The knowledge of solubility rules is essential in predicting whether a reaction might involve the formation of a precipitate, i.e. an insoluble compound. Which of the following is insoluble in water? Question (A) NaOH (B) K3PO4 (C) Ba(OH)2 (D) CaSO4 A. Incorrect! Sodium is soluble with most anions. B. Incorrect! Potassium is soluble with most anions. C. Incorrect! Hydroxide is soluble with barium. Feedback D. Correct! Sulfate is not soluble with calcium. Most sulfate compounds are soluble except: Ag+, Pb2+, Ba2+, Sr2+, and Ca2+. Use the solubility rules. Look up the anion and determine if it is soluble or insoluble with the particular cation. All these choice are soluble except calcium sulfate. The correct answer is (D). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 5 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 5. Predicting products is a difficult task with some exceptions. One of them is the double displacement reaction. What would the products of the following reaction be? CaCl2 (aq) + Na2SO4 (aq) ? Question (A) CaSO4 (B) CaSO4 (C) CaSO4 (D) CaNa2 (aq) + 2 NaCl (aq) (s) + 2 NaCl (aq) (s) + Na2Cl2 (aq) (aq) + Cl2SO4 (aq) A. Incorrect! You have the correct products, but one of them is insoluble. Exchange the two cations and write out the state of each species. B. Correct! Good job! This is a double displacement reaction and calcium sulfate is not soluble. Exchange the two cations and write out the state of each species. Feedback C. Incorrect! Your formula for sodium chloride is incorrect. Exchange the two cations and write out the state of each species. D. Incorrect! Do not combine two cations and two anions. Cations only bond to anions. Exchange the two cations and write out the state of each species. This is a double displacement reaction. The cation of the first compound combines with the anion of the second to form an insoluble CaSO4. Ca is +2 and SO4 is -2 so the compound is neutral as written. The cation of the second combines with the anion of the first to form NaCl, which is neutral as written. Use solubility rules to determine if one is insoluble. NaCl is soluble, but CaSO 4 is not. The correct answer is (B). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 6 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 6. Sodium hypochlorite is commonly known as liquid bleach. It emits oxygen when it degrades with another byproduct NaCl. Write out the reaction and determine the type of reaction. Question (A) 2NaClO(aq) 2NaCl(aq) + O2(g) … Single Displacement Reaction (B) NaClO + O2 NaClO3 … Composition Reaction (C) 2NaClO(aq) 2NaCl(aq) + O2(g) … Decomposition Reaction (D) 2NaClO3 NaCl + O2 … Composition Reaction A. Incorrect! The reaction is correctly written and balanced. However, this is not a single displacement reaction. B. Incorrect! The reaction emits oxygen. This means that one of the products is O2. Oxygen should not be the reactant in this case. Feedback C. Correct! Good job! The single reactant is NaClO and the two products are NaCl and O2. Write it out and balance it. It is a decomposition reaction. D. Incorrect! The reactant is sodium hypochlorite (NaClO), not sodium chlorate (NaClO3). The single reactant is NaClO and the two products are NaCl and O2. Write it out and balance it. Specify the state of each species. It is a decomposition reaction. 2NaClO(aq) 2NaCl(aq) + O2(g) … Decomposition Reaction The correct answer is (C). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 7 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 7. Redox reactions are a family of reactions with the transfer of electrons between species. Each redox has two half-reactions. Oxidation refers to the loss of electrons while reduction refers to the gain of electrons. An example of an oxidation reaction is? Question (A) Na+ + e- Na (B) Cu2+ + e- Cu+ (C) Cu2+ + 2 e- Cu (D) Cu+ Cu2+ + eA. Incorrect! Oxidation reactions have an increase in charge due to the loss of electrons. Sodium is reduced from +1 to 0 - this is a reduction reaction. B. Incorrect! Oxidation reactions have an increase in charge due to the loss of electrons. Copper is going from +2 to +1 - this is a reduction reaction. Feedback C. Incorrect! Oxidation reactions have an increase in charge due to the loss of electrons. Copper is going from +2 to 0 - this is a reduction reaction. D. Correct! Good job! Oxidation reactions have an increase in charge due to the loss of electrons. Copper’s charge is going from +1 to +2 - this is an oxidation reaction. Oxidation is the release of an electron with an increase in oxidation number (i.e. higher charge). The above reactions are called “half reactions” because they only show half of the story. The overall reactions must include both the reduction and oxidation half reactions. Cu+ Cu2+ + eThis half-reaction proceeds forward to a higher charge in loss of an electron. It is an oxidation reaction. The correct answer is (D). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 8 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 8. There are six main types of reactions: Composition or Synthesis Reactions; Decomposition Reactions; Single Displacement Reactions; Double Displacement Reactions; Neutralization (Acid-Base) Reactions and Redox Reactions (Combustion). What type of reaction is the following? 2 C2H6 + 7 O2 4 CO2 + 6 H2O Question (A) Composition (B) Decomposition (C) Double displacement (D) Combustion A. Incorrect! Composition reactions combine more than one compound into one compound. This is a typical combustion reaction of hydrocarbons – a reaction with oxygen gas to generate carbon dioxide and water. B. Incorrect! Decomposition reactions have one compound breaking down into more than one compound. This is a typical combustion reaction of hydrocarbons – a reaction with oxygen gas to generate carbon dioxide and water. Feedback C. Incorrect! Double displacement reactions involve two compounds switching anions. This is a typical combustion reaction of hydrocarbons – a reaction with oxygen gas to generate carbon dioxide and water. D. Correct! This is a combustion reaction because of the reaction with O2. It is also a redox as oxygen is reduced from 0 to -2 and carbon is oxidized from -3 to +4. All combustion reactions are redox. This is a typical combustion reaction, also a redox. Oxygen is changing charge from 0 to -2 and carbon is changing charge from -3 to +4. This is an oxidation-reduction reaction. A typical combustion reaction of hydrocarbons reacts with O2 to give CO2 and H2O. The correct answer is (D). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 9 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 9. Which reaction below does NOT form a precipitate as a product when the two ionic compounds are mixed in a solution? Question (A) Ba(NO3)2 + Na2SO4 (B) KCl + AgNO3 (C) Cu(NO3)2 + Na2S (D) Zn(NO3)2 + SnCl2 A. Incorrect! According to the solubility rule for SO42-, there are five cations that form precipitates with the sulfate anion. The completed reaction is: Ba(NO3)2(aq) + Na2SO4(aq) BaSO4(s) + 2NaNO3(aq) with BaSO4 as a precipitate. B. Incorrect! According to the solubility rule for Cl-, only cations Ag+, Pb2+ and Hg22+ form insoluble compounds with Cl-. The completed reaction is: KCl(aq) + AgNO3(aq) AgCl(s) + KNO3(aq). AgCl is a well known precipitate. Feedback C. Incorrect! According to the solubility rule for S2-, all cations except group IA and IIA form precipitates with S2-. The completed reaction is Cu(NO3)2(aq) + Na2S(aq) CuS(s) + 2NaNO3(aq). CuS is a precipitate. D. Correct! Good job! This is the one with no precipitate formed as a product. All NO3compounds are soluble. The complete reaction is Zn(NO3)2(aq) + SnCl2(aq) Sn(NO3)2(aq) +ZnCl2(aq). There is no precipitate in this reaction. Solubility rules are the key to solve many chemistry reaction problems. Try to learn and master them. Follow each anion’s solubility rule and identify the insolubility for each product species. The first four reactions all have precipitates as products. The last one has no precipitate. This is the one with no precipitate formed as a product. All NO3- compounds are soluble. Zn(NO3)2(aq) + SnCl2(aq) Sn(NO3)2(aq) +ZnCl2(aq). There is no precipitate in this reaction. Solution The correct answer is (D). RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved Question No. 10 of 10 Instructions: (1) Read the problem and answer choices carefully (2) Work the problems on paper as needed (3) Pick the answer (4) Go back to review the core concept tutorial as needed. 10. Write out the reaction between hydrochloric acid and calcium metal with the release of H2 gas. Also indicate the type of reaction. Question (A) 2HCl(aq) + Ca(s) CaCl2(aq) + H2(g) … Single displacement (B) 2HClO(aq) + Ca(s) CaCl2(aq) + H2(g) + O2(g) … Double displacement (C) 2HCl(aq) + Ca(s) Ca(OH)2(aq) + Cl2(g) … Single displacement (D) 2HCl(aq) + Ca(s) CaCl2(aq) + H2(g) … Composition A. Correct! Good job! The HCl and Ca metal react to give H 2 and CaCl2. This is a typical single displacement. B. Incorrect! Hydrochloric acid is HCl not HClO. It is also a wrong reaction. Feedback C. Incorrect! This reaction does give H2 as a product, not Cl2, as stated in the problem statement. D. Incorrect! The reaction is written correctly. However, this is not a composition reaction. In a single displacement reaction (also called substitution reaction), one element is being displaced from a compound by another element, with a general form: A + BC AC + B The HCl and Ca metal react to give H2 and CaCl2. This is a typical single displacement. 2HCl(aq) + Ca(s) CaCl2(aq) + H2(g) … Single displacement The correct answer is (A). Solution RapidLearningCenter.com Rapid Learning Inc. All Rights Reserved
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