MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 1 / 13
Version: 7.0
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1 Product identifier
Trade name:
Description:
Feropur, Feropur P, Feropur H
reaction mass of disodium oxide and sodium hydride and
sodium hydroxide
Registration number:
01-2119491178-29-0000
1.2 Relevant identified uses of the substance or mixture and uses advised against
Intended or recommended use of
Products for industrial using - for the pre-pickling of high-quality
the substance:
steels. Material for the descaling steels.
Uses advised against:
No such uses were defined.
1.3 Details of the supplier of the safety data sheet
Manufacturer trade name:
BOCHEMIE a.s.
Manufacturer address:
Lidická 326, 735 81 Bohumín, Czech Republic
Company ID:
293 96 824
Phone number / Fax:
+420 596 091 111 / +420 596 013 462
e-mail:
[email protected]
e-mail of the person responsible
for MSDS:
[email protected]
1.4 Emergency telephone number
224 91 92 93; 224 91 54 02; 224 91 45 71
Toxikologické informační středisko, Na Bojišti 1, 128 08 Praha 2, Czech Republic
SECTION 2: HAZARDS IDENTIFICATION
This product is classified according to Regulation No 1272/2008/EC.
2.1 Classification of the substance or mixture
Classification according to Regulation
Water react. 1, H261; Ox. Sol. 1, H272; Met. Corr. 1, H290; Skin
No. 1272/2008/EC
Corr.1A, H314
For the full wording of hazard statements see Section 16.
The most important adverse physicochemical, human health and environmental effects: Causes severe skin burns
and eye damage. Hydrogen generation at contact with water – explosion hazard.
2.2 Label elements
2.2.1
Labelling according to Regulation (EC) No 1272/2008 (CLP/GHS)
Hazard pictograms:
Signal word:
Hazard statements:
Precautionary statements:
Danger
H290
May be corrosive to metals.
H314
Causes severe skin burns and eye damage.
H261
In contact with water releases flammable gases.
H272
May intensify fire; oxidizer.
P223
Do not allow contact with water.
P370+P378 In case of fire: Use dry sand, powder extinguishing agents for
extinguishing light metals, inert gases; avoid the air access for
extinction.
P280
Wear protective rubber gloves/protective clothing/eye
protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 2 / 13
Version: 7.0
P402+P404 Store in a dry place. Store in a closed container.
2.3 Other hazards
The product does not meet the PBT/vPvB criteria according to REACH, annex XIII.
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
3.1 Substances
3.1.1
Main constituent
Hazardous
components
Percentage
(%)
Sodium hydroxide
≤ 79
Sodium hydride
≤ 17
Disodium oxide
5 - 15
Sodium carbonate
4-6
3.1.2
CAS
EC
Index No.
REACH No.
1310-73-2
215-185-5
011-002-00-6
01-2119457892-27
7646-69-7
231-587-3
001-003-00-X
1313-59-3
215-208-9
497-19-8
207-838-8
011-005-00-2
01-2119485498-19
Classification acc. to Regulation No.
1272/2008/ES
Skin Corr. 1A; H314, Met. Corr. 1A; H290
Water react. 1; H260
Skin Corr. 1B;
H314, EUH014
Eye Irrit. 2; H319
Impurity, stabilising additive, or individual constituent
Hazardous components
None
Percentage (%)
--
For the full text of sentences see section 16.
3.2 Mixtures
Not relevant.
SECTION 4: FIRST AID MEASURES
4.1 Description of first aid measures
In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible).
− Inhalation: shut off source of exposure, if possible. Bring the victim to the fresh air; keep at rest (avoid even
walking) if necessary, seek medical attention.
− Skin contact: take off contaminated clothing and shoes. Wash thoroughly with water and soap. Seek medical
attention. In case of extensive burns, hospitalise.
− Eye contact: flush immediately with large amounts of fresh water at least 10 minutes; seek medical attention.
− Ingestion: rinse mouth with potable water and leave victim to drink 0.5 L of water if the subject is conscious. Do
not induce vomiting, seek medical aid.
4.2 Most important symptoms and effects, both acute and delayed
Corrosive and irritant effect on skin and eyes are predominant.
4.3 Indication of any immediate medical attention and special treatment needed
In case of to eyes contact, ingestion and in the development of burns ensure medical aid.
SECTION 5: FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable: dry sand, powder extinguishing agents for extinguishing light metals (e.g. Totalit), inert gases (nitrogen),
avoid the air (oxygen) access.
Unsuitable: water, aqueous extinguishing agents, wet sand.
5.2 Special hazards arising from the substance or mixture
Hydrogen generation at contact with water – explosion hazard.
5.3 Advice for fire fighters
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 3 / 13
Version: 7.0
In case fires wear a overall, a suitable respiratory system protection. If the product escapes into the sewerage, the
product should be sufficiently diluted with water, while keeping preventive measures against the explosion of hydrogen
and fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1
For non-emergency personnel
Wear suitable personal protective equipment. Avoid contact with skin and eyes. Do not use the substance in the closed
area.
6.1.2
For emergency responders
Wear suitable personal protective equipment. Avoid contact with skin and eyes. Do not eat food, drink and smoke,
when is manipulated with product.
6.2 Environmental precautions
Avoid release to the sewers, water courses, soil or environment. In case of accidental discharge of large amount of the
concentrated product to the surface water, ground water or waste water, notify local authorities according to local
regulations (e.g. fire brigade, police, rescue police, water course administrator).
6.3 Methods and material for containment and cleaning up
Wear suitable personal protective equipment. Avoid contact with skin and eyes. In case spill the product, use suitable
absorbents (special absorbents for aggressive materials or universal absorbents) and put into the labelled lockable
container. Avoid accidental discharge into sewers or water courses. The hydroxyl ion can be neutralized by acids.
6.4 Reference to other sections
See section 8 and 13.
SECTION 7: HANDLING AND STORAGE
7.1 Precautions for safe handling
Store in vented, closed, clean, noncorrosive containers in a cool dry location, away direct sunlight and not adjacent to
chemicals which may react with the bleach if spillage occurs. If closed containers become heated, the containers should
be vented to release decomposition products (mainly oxygen under normal conditions). Avoid excessive contamination
of environment. Avoid release to the environment.
Important information is provided by instructions on the label or on the www pages by company – Bochemie a. s.
(www.bochemie.cz).
7.2 Conditions for safe storage, including any incompatibilities
Store in original containers. Keep away from food, drink, fresh water and feed. Protect against direct sunlight. Provide
impermeable floor. Keep away from combustible material. Avoid the access of unauthorized personnel. Storage
temperature from -30 to + 50°C.
7.3 Specific and use(s)
Important information is provided by material data safety sheet, by instructions on the label or on the company web
pages www.bochemie.cz. Only for industrial use.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
More information see Annex – exposure scenario.
8.1 Control parameters
8.1.1
National exposure limit values
Substance
Sodium hydroxide
Sodium carbonate
PEL
(mg/m3)
1
5
8.1.2
Information monitoring procedures
Exposure limit values and/or biological limit values according to national legislation.
8.1.3
Air monitoring procedures
Exposure limit values for air pollution according to national legislation.
8.1.4
DNEL and PNEC values
DNEL long-term inhalation = 0.93 mg of substance/m3 (local and systemic effects)
PNEC STP microorganisms = 0.93 mg/l
NPK-P
(mg/m3)
2
10
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 4 / 13
Version: 7.0
PNEC Water: 0.93 mg/l
PNEC Sediment: 3.35 mg /kgdwt
PNEC Soil: 0.124 mg/kgdwt
8.2 Exposure controls
8.2.1
Appropriate engineering controls
Provide sufficient ventilation. Ensure that a man handling/working with the product makes use of personal protective
equipment, is aware of substance characteristics, and knows instructions for use and conditions of personal protection
and protection of environment. Personal protective equipment should be kept in a faultless conditions and damaged
equipment should be replaced immediately. Observe rules of personal hygiene, particularly do not eat, drink, and
smoke, when working. Before eating and after work wash your hands with warm water and soap.
8.2.2
Individual protection measures, such as personal protective equipment
Eye protection to EN 166, designed to protect against dusts.
Eye/face protection:
Use the working clothes.
Skin protection:
Rubber gloves
Hand protection:
In case of insufficient ventilation, wear suitable respiratory equipment.
Respiratory protection:
8.2.3
Environmental exposure controls
Observe instructions for handling and storage, particularly ensure provisions preventing spill of concentrated substance
into watercourses, soil and sewerage (for further information see Handling Conditions according to Act No 254/2001 of
Czech Act Coll., on Waters).
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance (at 20°C; 101.3 kPa):
solid
Colour:
white to yellowish-grey
Odour:
odourless
pH (1% solution at 20°C):
very alkaline
Melting point:
347°C
Boiling point:
not relevant
Flash point:
not relevant
Evaporation rate:
not determinate.
Flammability (solid, gas):
incombustible in dry condition by the temperature of 270°C;
contact with water liberates highly flammable gases
Upper/lower flammability or explosive limits:
the substance does not flammable
Vapour pressure (°C):
does not need to be performed
Vapour density:
not determinate.
Relative density (20°C):
2.05
Water solubility:
not possible
Partition coefficient: n-octanol/water:
not needed
Auto-ignition temperature;
not applicable
Decomposition temperature:
not determinate
Viscosity:
not relevant
Explosive properties:
non-explosive
Oxidising properties:
does have oxidising properties.
9.2 Other information
Not known.
SECTION 10: STABILITY AND REACTIVITY
If the originals container is tightly closed, the product is stable.
10.1 Reactivity
Substance is high reactive with water to form hydrogen gas - self-ignition and/or explosion hazard.
10.2 Chemical stability
Product is stable when stored in the intact packaging in the warehouse without changing of atmospheric conditions and
is prevented against humidity (including atmospheric humidity).
10.3 Possibility of hazardous reactions
Not known.
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 5 / 13
Version: 7.0
10.4 Conditions to avoid
Avoid increased humidity (product devaluation, hydrogen generation), raised temperature, long-lasting direct exposure
to sun.
10.5 Incompatible materials
Strong oxidising agents, acids, water.
10.6 Hazardous decomposition products
Hydrogen is generated at reaction with water, caustic alkali (sodium hydroxide).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
a)
acute toxicity
b)
skin corrosion/irritation:
c)
serious eye damage/irritation:
d)
respiratory or skin sensitisation:
e)
germ cell mutagenicity:
f)
carcinogenicity:
g)
reproductive toxicity:
h)
i)
j)
STOT-single exposure:
STOT-repeated exposure:
aspiration hazard:
Corrosive substance, no tested
Corrosive substance
Corrosive substance, causes eye damage
not sensitising
Not classified as mutagenic, NaOH is not expected to be systemically
available in the body under normal handling and use (EU RAR of sodium
hydroxide (2007), section 4.1.2.6)
Not classified, NaOH is not expected to be systemically available in the
body under normal handling and use (EU RAR of sodium hydroxide
(2007), section 4.1.2.7)
Not classified, NaOH is not expected to be systemically available in the
body under normal handling and use (EU RAR of sodium hydroxide
(2007), section 4.1.2.8)
not determined
not expected to occur
Corrosive substance
SECTION 12: ECOLOGICAL INFORMATION
12.1 Toxicity
NaOH is a strong alkaline substance that dissociates completely in water to Na+ and OH-.
Sodium hydroxide:
- LC50 96 hours for fish (mg.l-1):
35-189
acute toxicity
- EC50 48 hours for freshwat. inverte. (mg.l-1):
40
PNEC
NaOH is a strong alkaline substance that dissociates completely in water to Na+ and OH-.
12.2 Persistence and degradability
Abiotic degradation: NaOH is a strong alkaline substance that dissociates completely in water to Na+ and OH-.
Atmospheric emissions as aerosols are rapidly neutralized by carbon dioxide and the salts will be washed out by rain.
Biotic degradation: Sodium persists indefinitely in the environment. The hydroxyl ion can be neutralized by acids, it
can form complexes or it can be precipitated.
NaOH does not fulfil the Persistence criterion.
12.3 Bioaccumulative potential
Considering its high water solubility, NaOH is not expected to bioconcentrate in organisms. Log Pow is not applicable
for an inorganic compound.
12.4 Mobility in soil
NaOH is highly soluble in water. During movement through soil, some ion exchange will occur.
12.5 Results of PBT and vPvB assessment
The product does not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6 Other adverse effects
No known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
a) Recommended Methods of Substance and Contaminated Packaging Disposal:
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 6 / 13
Version: 7.0
According to Waste Catalogue, it could be dangerous waste. Substance waste shall be handled as hazardous waste and
removed by licensed waste removal company. Contaminated packaging is a dangerous waste.
b) Waste Legal Regulations:
Act No 185/2001 of Czech Act Coll., on Wastes in last wording. If this substance and its packaging become waste,
the last user has to assign relevant waste code according to Decree No 381/2001 of Czech Act Coll., in last wording.
Act No. 477/2001 Coll. on waste as amended.
c) Suggestion of waste classification:
Subgroup
16 03
Deficient batches and unusable products – waste
16 03 03* Inorganic wastes containing hazardous substances
Or:
11 01
Wastes from chemical surface treatment and coating of metals and other materials
11 01 07 Pickling bases
d) Suggestion of waste container classification:
Containers with residues of the substance: 15 01 10* Containers with residues of hazardous substances or polluted with
such substances
More information is in an annex – exposure scenario.
SECTION 14: TRANSPORT INFORMATION
(ADR/RID/GGVSE)
IMDG
14.1 UN number:
UN 3131
UN 3131
14.2 UN proper shipping name:
WATER-REACTIVE SOLID,
CORROSIVE, N.O.S. (Sodium
hydroxide, Sodium hydride)
WATER-REACTIVE SOLID,
CORROSIVE, N.O.S. (Sodium
hydroxide, Sodium hydride)
14.3 Transport hazard class(es):
4.3, 8
4.3, 8
14.4 Packing group:
II
II
14.5 Environmental hazards
NO
NO
14.6 Special precautions for user:
--
--
14.7 Transport in bulk according
to Annex II of MARPOL and
the IBC Code.
--
--
Danger code (Kemler): 482
Danger code (Kemler): 482
Limited quantities (LQ): 500g
Limited quantities (LQ): none
Other information:
SECTION 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Legislation regulating individual issues of the environmental protection and occupational hygiene conditions.
Regulation No. 1907/2006 (REACH).
Regulation No 1272/2008/EC (CLP)
Directive No. 98/24/EC on safety and health protection of employees from risks connected with chemical agents used at
work.
15.2 Chemical safety assessment
A Chemical Safety Assessment was carried out for the substances.
SECTION 16: OTHER INFORMATION
a)
Changes during Revision of the MSDS
The changed sections are indicated with bold line:
b)
A key or legend to abbreviations and acronyms used
Substance or mixture corrosive to metals
Met. Corr. 1
Skin corrosion category 1A
Skin Corr. 1A
Substance or mixture which in contact with water emits flammable gas.
Water react. 1
Eye irritation
Eye Irrit. 2
Oxidising solid cat.1
Ox. Sol. 1
Predicted No Effect Concentration
PNEC
Derived No Effect Level
DNEL
Permissible Exposure Limit
PEL
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 7 / 13
Version: 7.0
Maximum Permissible Concentration
NPK-P
Persistent, Bioaccumulative and Toxic
PBT
Very Persistent and Very Bioaccumulative
vPvB
Lethal dose, 50 percent
LD50
Lethal concentration, 50 percent
LC50
c)
Key literature references and sources for data
Information contained herein is based on our best knowledge and current legislation, according to Regulation
1272/2008/EC. Further, this Material Safety Data Sheet was elaborated on grounds of information provided by suppliers
of particular components. The MSDS contains information needed for security of safety and occupational health
protection and the environmental protection. The mentioned information refers to present state of knowledge and
experience and is in accordance with legislation in force. It cannot be considered warrantee of suitability or usability of
the product for particular application.
d)
List of hazard statements
In contact with water releases flammable gases which may ignite spontaneously.
H260
In contact with water releases flammable gas.
H261
May intensify fire; oxidizer.
H272
May be corrosive to metals.
H290
Causes severe skin burns and eye damage
H314
Causes serious eye irritation
H319
e)
Instructions for Training
Personnel handling the substance must be instructed about manipulation risks and on requirements for health and
environmental protection (relevant provisions of the Labor Code as amended) and further, they must be demonstrably
familiarized with dangerous properties, occupational health and environmental protection principles and first aid
measures (Act No. 258/2000 Coll. on public health protection as amended).
f)
Recommended Use Limitations
The substance should not be used for any other purpose than determined (see Section 1.2). As specific conditions of use
of the substance are beyond control of the supplier, the user is the only responsible to adapt the information and
warnings contained herein to local legislation and regulations. The safety information describes the product from
perspective of its safety and it cannot be deemed technical specifications of the product.
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
ANNEX
Page: 8 / 13
Version: 7.0
EXPOSURE SCENARIO
Scenario 1: Formulation of Feropur (FP-F)
This scenario is described by the following combinations of use descriptors. The corresponding contributing scenarios
are described in the respective subchapters.
ERC
PROC
PC
ERC2
PROC 3
PC 14
Exposure Scenario
An overall exposure scenario may be described by a number of contributing scenarios which may be subdivided into
environmental exposure, worker exposure and consumer exposure. The following scenarios contribute to the scenario
Formulation of Feropur (FP-F).
The corresponding release to the environment, exposure of workers and consumers resulting from these contributing
scenarios is summarized in chapter 10.1 ff.
Contributing Scenario (1) controlling environmental exposure for ERC2
Formulation of Feropur (FP-F)
Amounts used
2,000 to per year
Release times per year
220
Environmental factors not influenced by risk
management
River flow rate: 18000 m3/day
Other given operational conditions affecting
environmental exposure
Release to: air: 0%, water: 0.001%, soil: 0%; fraction used at main
source: 100%; fraction tonnage to region: 100%
Technical onsite conditions and measures to
reduce or limit discharges, air emissions and
releases to soil
spERC: Formulation of Ferropur (spERC related to ERC 1).
Notes:
Release times per year:
Discharge if waste water is every working day, i.e. 220 days per
year.
Fraction Main Source:
1 = 100% = One point source in Europe
0.1 = 10% = Wide dispersive use
1 = worst case was selected
Release to air:
0% - Rationale: Feropur is not volatile (RMM efficacy: 100%)
Release to fresh or marine water:
0.3% - According to EU 2003, TGD on Risk Assessment Part II
Appendix 1 A Tables A2.1 (RMM efficacy 99.7%)
Release to soil:
0.01% - Assumption: Caustic sludge or solid caustic are collected by
a professional contractor and discharged by landfill after treatment
(neutralization) (RMM efficacy: 99.9%).
Landfill after treatment ( neutralization) of caustic sludge or caustic
solids; RMM effectivity: 100% (air), 99.9% (soil), 99.7% (water)
Conditions and measures related to municipal
Municipal sewage treatment plant discharge: 2000000 L/day
sewage treatment plant
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 3, Annex I.3 and Annex II.2.
Contributing Scenario (2) controlling industrial worker exposure for PROC 3
Formulation of Feropur (FP-F)
Product characteristics
solid
Duration of activity
1 - 4 hours
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
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Version: 7.0
Other given operational conditions affecting
workers exposure
Work is carried out indoors; dustiness during process: high
Technical conditions and measures to control
dispersion and exposure
Local exhaust ventilation
Conditions and measures related to personal
protection, hygiene and health evaluation
Respiratory protection: 90%; protective gloves: 99%, burst-time: >4
hours (default)
Gloves (EN 374) to prevent skin effects from powders. Use, storage,
maintenance and replacement advice followed.
Protective clothes and eye protection (EN 166) RMMs: 99% Eye
protection to EN 166, designed to protect against dusts.
Engineering controls and half mask respirator (EN 519), RMMs:
99% Engineering controls are used to keep exposures below the
OEL (DNEL). If these are not sufficient, then additional use of a
half-mask respirator to EN 519.)
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 2.1, Annex I.2.1 and Annex II.1.1.
Scenario 2: Industrial end-use: Topping of molten salt (400°C) PROC 13 (FP-EUI-1)
This scenario is described by the following combinations of use descriptors. The corresponding contributing scenarios
are described in the respective subchapters.
ERC
PROC
PC
ERC8B
PROC 13
PC 14
Exposure Scenario
An overall exposure scenario may be described by a number of contributing scenarios which may be subdivided into
environmental exposure, worker exposure and consumer exposure. The following scenarios contribute to the scenario
Industrial end-use: Topping of molten salt (400°C) PROC 13 (FP-EUI-1).
The corresponding release to the environment, exposure of workers and consumers resulting from these contributing
scenarios is summarized in chapter 10.2 ff.
Contributing Scenario (1) controlling environmental exposure for ERC8B
Industrial end-use: Topping of molten salt (400°C) PROC 13 (FP-EUI-1)
Amounts used
2,000 to per year
Release times per year
365
Environmental factors not influenced by risk
management
River flow rate: 18000 m3/day
Other given operational conditions affecting
environmental exposure
Release to: air: 0.1%, water: 2%, soil: 0%; fraction used at main
source: 0.2%; fraction tonnage to region: 10%
Technical onsite conditions and measures to
reduce or limit discharges, air emissions and
releases to soil
NA
Conditions and measures related to municipal
Municipal sewage treatment plant discharge: 2000000 L/day
sewage treatment plant
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 3, Annex I.3 and Annex II.2.
Contributing Scenario (2) controlling industrial worker exposure for PROC 13
Industrial end-use: Topping of molten salt (400°C) PROC 13 (FP-EUI-1)
Product characteristics
Solid; substance (inhalation): 25%
Duration of activity
15 min/day (justification: Realistic worst case duration of activity as
provided by the end user.)
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 10 / 13
Version: 7.0
Other given operational conditions affecting
workers exposure
Work is carried out indoors; dustiness during process: high;
substance (inhalation): 25% (justification: Definitive concentration
in substance.)
Technical conditions and measures to control
dispersion and exposure
Local exhaust ventilation
Conditions and measures related to personal
protection, hygiene and health evaluation
Respiratory protection: 90%; protective gloves: 99%, burst-time: >4
hours (default)
Gloves (EN 374
Protective clothes and eye protection (EN 166), RMMs: 99% Eye
protection to EN 166,
Engineering controls and half mask respirator (EN 519), RMMs:
99% (keep exposures below the OEL (DNEL). If these are not
sufficient, half-mask respirator to EN 519.)
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 2.1, Annex I.2.1 and Annex II.1.1.
Scenario 3: Industrial end-use: Topping of molten salt (400°C) PROC 23a (FP-EUI-2)
This scenario is described by the following combinations of use descriptors. The corresponding contributing scenarios
are described in the respective subchapters.
ERC
PROC
PC
ERC8B
PROC 23A
PC 14
Exposure Scenario
An overall exposure scenario may be described by a number of contributing scenarios which may be subdivided into
environmental exposure, worker exposure and consumer exposure. The following scenarios contribute to the scenario
Industrial end-use: Topping of molten salt (400°C) PROC 23a (FP-EUI-2).
The corresponding release to the environment, exposure of workers and consumers resulting from these contributing
scenarios is summarized in chapter 10.3 ff.
Contributing Scenario (1) controlling environmental exposure for ERC8B
Industrial end-use: Topping of molten salt (400°C) PROC 23a (FP-EUI-2)
Amounts used
2,000 to per year
Release times per year
365
Environmental factors not influenced by risk
management
River flow rate: 18000 m3/day
Other given operational conditions affecting
environmental exposure
Release to: air: 0.1%, water: 2%, soil: 0%; fraction used at main
source: 0.2%; fraction tonnage to region: 10%
Technical onsite conditions and measures to
reduce or limit discharges, air emissions and
releases to soil
NA
Conditions and measures related to municipal
Municipal sewage treatment plant discharge: 2000000 L/day
sewage treatment plant
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 3, Annex I.3 and Annex II.2.
Contributing Scenario (2) controlling industrial worker exposure for PROC 23A
Industrial end-use: Topping of molten salt (400°C) PROC 23a (FP-EUI-2)
Product characteristics
Solid; substance (inhalation): 25%
Duration of activity
>4 hours (default)
Other given operational conditions affecting
workers exposure
Work is carried out indoors; dustiness during process: high;
substance (inhalation): 25% (justification: Definitive concentration
in substance.)
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 11 / 13
Version: 7.0
Technical conditions and measures to control
dispersion and exposure
Local exhaust ventilation
Conditions and measures related to personal
protection, hygiene and health evaluation
Respiratory protection: 90%; protective gloves: 99%, burst-time: >4
hours (default) Gloves (EN 374) to prevent skin effects from
powders. Use, storage, maintenance and replacement advice
followed.
Protective clothes and eye protection (EN 166), S-phrase RMMs:
99% Eye protection to EN 166, designed to protect against dusts.
Engineering controls and half mask respirator (EN 519), S-phrase
RMMs: 99% (keep exposures below the OEL (DNEL). If these are
not sufficient, half-mask respirator to EN 519.)
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 2.1, Annex I.2.1 and Annex II.1.1.
Scenario 4: Industrial end-use: Topping of molten salt (400°C) PROC 25a (FP-EUI-3)
This scenario is described by the following combinations of use descriptors. The corresponding contributing scenarios
are described in the respective subchapters.
ERC
PROC
PC
ERC8B
PROC 25A
PC 14
Exposure Scenario
An overall exposure scenario may be described by a number of contributing scenarios which may be subdivided into
environmental exposure, worker exposure and consumer exposure. The following scenarios contribute to the scenario
Industrial end-use: Topping of molten salt (400°C) PROC 25a (FP-EUI-3).
The corresponding release to the environment, exposure of workers and consumers resulting from these contributing
scenarios is summarized in chapter 10.4 ff.
Contributing Scenario (1) controlling environmental exposure for ERC8B
Industrial end-use: Topping of molten salt (400°C) PROC 25a (FP-EUI-3)
Amounts used
2,000 to per year
Release times per year
365
Environmental factors not influenced by risk
management
River flow rate: 18000 m3/day
Other given operational conditions affecting
environmental exposure
Release to: air: 0.1%, water: 2%, soil: 0%; fraction used at main
source: 0.2%; fraction tonnage to region: 10%
Technical onsite conditions and measures to
reduce or limit discharges, air emissions and
releases to soil
NA
Conditions and measures related to municipal
Municipal sewage treatment plant discharge: 2000000 L/day
sewage treatment plant
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 3, Annex I.3 and Annex II.2.
Contributing Scenario (2) controlling industrial worker exposure for PROC 25A
Industrial end-use: Topping of molten salt (400°C) PROC 25a (FP-EUI-3)
Product characteristics
Solid; substance (inhalation): 25%
Duration of activity
>4 hours (default)
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Page: 12 / 13
Version: 7.0
Other given operational conditions affecting
workers exposure
Work is carried out indoors; dustiness during process: high;
substance (inhalation): 25% (justification: Definitive concentration
in substance.)
Technical conditions and measures to control
dispersion and exposure
Local exhaust ventilation
Conditions and measures related to personal
protection, hygiene and health evaluation
Respiratory protection: 90%; protective gloves: 99%, burst-time: >4
hours (default) Gloves (EN 374) to prevent skin effects from
powders. Use, storage, maintenance and replacement advice
followed.
Protective clothes and eye protection (EN 166), S-phrase RMMs:
99% Eye protection to EN 166, designed to protect against dusts.
Engineering controls and half mask respirator (EN 519), S-phrase
RMMs: 99% (keep exposures below the OEL (DNEL). If these are
not sufficient, half-mask respirator to EN 519.)
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 2.1, Annex I.2.1 and Annex II.1.1.
Scenario 5: Manufacturing of Feropur (FP-M)
This scenario is described by the following combinations of use descriptors. The corresponding contributing scenarios
are described in the respective subchapters.
ERC
PROC
PC
ERC1
PROC 1
PC 14
Exposure Scenario
An overall exposure scenario may be described by a number of contributing scenarios which may be subdivided into
environmental exposure, worker exposure and consumer exposure. The following scenarios contribute to the scenario
Manufacturing of Feropur (FP-M).
The corresponding release to the environment, exposure of workers and consumers resulting from these contributing
scenarios is summarized in chapter 10.5 ff.
Contributing Scenario (1) controlling environmental exposure for ERC1
Manufacturing of Feropur (FP-M)
Amounts used
2,000 to per year
Release times per year
220
Environmental factors not influenced by risk
management
River flow rate: 18000 m3/day
Other given operational conditions affecting
environmental exposure
Release to: air: 0%, water: 0.001%, soil: 0%; fraction used at main
source: 100%; fraction tonnage to region: 100%
MATERIAL SAFETY DATA SHEET
(according to Regulation (EC) No 1907/2006 of the European Parliament as amended by Regulation (EC)No 830/2015)
Date of issue: 11th November 2002
Date of revision: 1 October 2015
Previous date: 21 November 2014
Product name:
FEROPUR
Technical onsite conditions and measures to
reduce or limit discharges, air emissions and
releases to soil
Page: 13 / 13
Version: 7.0
spERC: Manufacturing of Ferropur (spERC related to ERC 1).
Notes:
Release times per year:
According to specific data of particular manufacturing sites, as
provided by the manufacturer.
Fraction Main Source:
1 = 100% = One point source in Europe
0.1 = 10% = Wide dispersive use
1 = worst case was selected
Release to air:
0% - Rationale: Feropur is not volatile (RMM efficacy: 100%)
Release to fresh or marine water:
0.3% - According to EU 2003, TGD on Risk Assessment Part II
Appendix 1 A Tables A1.1 (RMM efficacy 99.7%)
Release to soil:
0.01% - Assumption: Caustic sludge or solid caustic are collected by
a professional contractor and discharged by landfill after treatment
(neutralisation) (RMM efficacy: 99.9%)
Landfill after treatment ( neutralisation) of caustic sludge or caustic
solids; RMM effectivity: 100% (air), 99.9% (soil), 99.7% (water)
Conditions and measures related to municipal
Municipal sewage treatment plant discharge: 2000000 L/day
sewage treatment plant
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 3, Annex I.3 and Annex II.2.
Contributing Scenario (2) controlling industrial worker exposure for PROC 1
Manufacturing of Feropur (FP-M)
Product characteristics
solid
Duration of activity
1 - 4 hours
Other given operational conditions affecting
workers exposure
Work is carried out indoors; dustiness during process: high
Technical conditions and measures to control
dispersion and exposure
Local exhaust ventilation
Conditions and measures related to personal
protection, hygiene and health evaluation
Respiratory protection: 90%; protective gloves: 99%, burst-time: >4
hours (default) Gloves (EN 374) to prevent skin effects from
powders. Use, storage, maintenance and replacement advice
followed.
Protective clothes and eye protection (EN 166), S-phrase RMMs:
99% Eye protection to EN 166, designed to protect against dusts.
Engineering controls and half mask respirator (EN 519), S-phrase
RMMs: 99% (keep exposures below the OEL(DNEL). If these are
not sufficient, half-mask respirator to EN 519.)
More details on the individual use conditions, applied algorithms and default values of this scenario are summarized in
the attached EasyTRA report under chapters 2.1, Annex I.2.1 and Annex II.1.1.