PROBLEM SET Carbohydrates These questions and activities come from a variety of sources: your textbook, other books that I have, study guides, and old homeworks, labs, and exams. They are provided to give you an idea of the types of questions you can expect to see on exams. These are not to be turned in for a grade, though I am happy to go over your answers with you. Important Vocabulary Terms: Write out definitions for each of the following terms: a. carbohydrate b. monosaccharide c. pentose d. hexose e. disaccharide f. glycosidic bond g. oligosaccharide h. polysaccharide i. starch j. glycogen k. cellulose l. chitin Multiple Choice: Select the best answer from the choices provided: 1. What structural difference accounts for the functional differences between starch and cellulose? A. Starch can be digested by animal enzymes, whereas cellulose cannot. B. Starch is a polymer of glucose, whereas cellulose is a polymer of fructose. C. Starch and cellulose differ in the glycosidic linkages between their glucose monomers. 2. Which of the following categories includes all others in the list? A. starch B. polysaccharide C. disaccharide D. monosaccharide E. carbohydrate 3. The molecular formula for glucose is C6H12O6. What would be the molecular formula for a polymer made by linking ten glucose molecules together by dehydration reactions? A. C60H102O51 B. C60H102O51 C. C6H12O6 D. C60H120O60 E. C60H100O50 Additional problems: Write your answers in the spaces provided. 1. Match the following carbohydrate-related terms with the number of monomers found in each. ____ oligosaccharide A. 1 ____ monosaccharide B. 2 ____ polysaccharide C. 3-20 ____ disaccharide D. more than 20 2. Write the chemical formula for a monosaccharide that has three carbons. ________________ 3. In the space below, draw β-glucose in its ring form. When you are finished, number the carbon atoms. On your structure, circle and label the hydroxyl group on carbon-2. 4. How would you alter this chemical structure to show α-glucose? 5. Write out the chemical reaction in which glucose and fructose form sucrose. • What are the reactants of this reaction? • What type of reaction is this (i.e., what is its name)? • What are the products of this reaction? (Note: there are two products.) 6. A dehydration reaction joins two glucose molecules to form maltose. The formula for glucose is C6H12O6. What is the chemical formula for maltose? 7. Circle the atoms of these two glucose molecules that will be removed by a dehydration reaction. Then draw the resulting maltose molecule below. 8. In the figure above (Fig. 5.5, p. 71, in your textbook), number all of the carbons that are present. Show how the numbering is consistent with the name of the glycosidic linkage in each disaccharide. 9. Compare the composition, structure, and function of starch and cellulose. What role do starch and cellulose play in the human body? 10. Complete the table below for the four main classes of carbohydrates. Class # Monomers General Function(s) Example 11. Take the following list of carbohydrates and classify them as either monosaccharides, disaccharides, or polysaccharides: a. galactose _______________________ b. glucose _______________________ c. cellulose _______________________ d. sucrose _______________________ e. fructose _______________________ f. glycogen _______________________ g. maltose _______________________ h. chitin _______________________ i. galactose _______________________ j. _______________________ starch and and and examples examples general formula called function as called examples to form found in function as called found in examples Classified by # of monosaccharides linked together by composed of CARBOHYDRATES differ due to function as called examples 12. Use the terms that were introduced in lecture to complete this concept map. An answer key can be found in the Carbohydrates folder in the Files section of Canvas.
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