Review Part 4: The Periodic Table Chemistry Spring 2011 Vocabulary: List 4 43. 44. 45. 46. 47. reactant: starting material consumed in a reaction product: finishing material formed in a reaction mole: 6.02x1023 of anything Avogadro’s number: 6.02x1023 molar mass: mass of one mole of a substance 1 Vocabulary: List 4 cont. 48. 49. 50. 51. 52. 53. kinetic molecular theory: molecules are in constant random motion pressure: caused by collisions of molecules with container walls temperature: average kinetic energy of molecules volume: space occupied diffusion: spread of particles STP: standard temperature and pressure; 1 atm and 0º 0ºC Periodic Table Ordered by increasing atomic number 2 Valence Electrons Number of electrons in outermost shell Based on group # in PT Octet Rule Atoms want to have 8 valence electrons!!! 3 Gaining/Losing Electrons If an atom gains electrons, it becomes negatively charged. • i.e.: O + 2e- O2- If an atom loses electrons, it becomes positively charged. • i.e.: Al Al3+ + 3e- How many lost or gained? So that it follows octet rule Charges of Groups 4 Combining Atoms Atoms combine in ratios such that positive and negative charges cancel out Example: What would the formula be for a compound combining Li and S? • Li is +1 (Li+). S is -2 (S2-). • Need two Li+ to cancel out one S2• Formula is Li2S. Periodic Trends: Ionization Energy 5 Periodic Trends: Electronegativity ***Exception: Noble gases have LOW electronegativity Periodic Trends: Atomic Radius 6 Atomic Radii: Cations/Anions Cations (+) have fewer e’s and are smaller Anions (-) have more e’s and are bigger Atomic Mass Average value of the mass of an element i.e.: Chlorine has an atomic mass of 35.45 g/mol because there is mostly chlorine-35 but also some chlorine37. 7 Calculating Molar Mass Sum up the atomic masses of the atoms making up a molecule. Example: What is the molar mass of C2HF3? • molar • molar • molar • molar mass mass mass mass = = = = 2 x m C + 1 x m H + 3 x mF 2 x 12 + 1 x 1 + 3 x 19 24 + 1 + 57 82 g/mol Sample Question 1 A neutral atom contains 12 neutrons and 11 electrons. The number of protons in this atom is A 1 B 11 C 12 D 23 8 Sample Question 2 What determines the order of placement of the elements on the modern periodic table? A atomic number B atomic mass C the number of neutrons, only D the number of neutrons and protons Sample Question 3 Which of the lists below has the elements arranged in order of increasing atomic mass? A Cl, K, Ar B Fe, Co, Ni C Te, I, Xe D Ne, F, Na 9 Sample Question 4 When a lithium atom forms an Li+ ion, the lithium atom A gains a proton B gains an electron C loses a proton D loses an electron Sample Question 5 What is the total number of electrons in a Cr3+ ion? A 18 B 21 C 24 D 27 10 Sample Question 6 Hydrogen has three isotopes with mass numbers of 1, 2, and 3 and has an average atomic mass of 1.00794 amu. amu. This information indicates that A equal numbers of each isotope are present B more isotopes have an atomic mass of 2 or 3 than of 1 C more isotopes have an atomic mass of 1 than of 2 or 3 D isotopes have only an atomic mass of 1 Sample Question 7 An unknown element X can form a compound with the formula XBr3. In which group on the periodic table would element X be found? A 1 B 2 C 13 D 14 11 Sample Question 8 What occurs when an atom of chlorine forms a chloride ion? A The chlorine atom gains an electron, and its radius becomes smaller. B The chlorine atom gains an electron, and its radius becomes larger. C The chlorine atom loses an electron, and its radius becomes smaller D The chlorine atom loses an electron, and its radius becomes larger. Sample Question 9 Which list of elements from group 2 on the periodic table is arranged in order of increasing atomic radius? A Be, Mg, Ca B Ca, Mg, Be C Ba, Ra, Sr D Sr, Ra, Ba 12 Sample Question 10 The A B C D molar mass of Ba(OH)2 is 154.3 g 155.3 g 171.3 g 308.6 g 13
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