Mud Volcanoes and Dome-Like Structures at the Eastern Mediterranean Ridge G. ÇİFÇİ 1, A. LIMONOV 2, L. DIMITROV 3 and V. GAINANOV 2 1 Dokuz Eylül University, Eng. Faculty, Dept. of Geophysics, 35100 Bornova-İzmir, Turkey Moscow State University, Faculty of Geology, Russian Federation 3 Institute of Oceanography, Bulgarian Academy of Sciences, 9000 Varna, Bulgaria 2 (Received 8 April 1997; accepted 19 November 1997) Key words: Mediterranean ridge, United Nation rise, mud diapirs, mud volcanoes, dome-like structures Abstract. The Mediterranean Ridge is interpreted as a large accretionary complex, which originated due to the northern subduction of the African lithosphere below the Eurasian one and the partial collision of those two continents; more precisely, between the African and Aegean Microplates. The main goals of the UNESCOTTR 5 (Training Through Research) cruise, carried out by several methods including high resolution seismic profiling, included the investigations of mud volcanoes, the distribution of the Messinian evaporites, and mapping the seafloor structures. The high resolution seismic data were confirmed with other geoacoustic methods as sidescan sonars (short-ORETECH and long-range OKEAN) and subbottom sampling. The area of investigation is designed to run parallel to the Mediterranean Ridge on the eastern end towards the Florence Rise, and is situated between the northern and southern deformation fronts of the ridge. The seismic data were preprocessed onboard (band pass filtering, horizontal stack and attenuation level) and predictive deconvolution. New mud volcanoes and structures were discovered at the western part of the target area, named ‘United Nations (UN) Rise’ to celebrate the fiftieth anniversary of the United Nations. With respect to fluid expulsion, three mud volcanoes were imaged, all of which show different backscattering characteristics. The investigated area shows complex structures and the UN area within the inner deformation front of the Mediterranean Ridge, is much more complicated. Some features are similar to mud volcanoes, but with some important differences. The typical characteristics of these features are a positive (up-doming) structure on the seafloor relief, no acoustically transparent zone, a strong low-frequency reflector (M-reflector?) down-bent near this object and some of these features are symmetrical. The Mud volcanism can exhibit itself only where the evaporitic layer is thin or absent. The mud volcanism on the Mediterranean Ridge reflects the general tectonic evolution of the accretionary complex presently progressing. 1. Introduction Main objectives of the UNESCO scientific and educational program (TREDMAR) later called TrainingMarine Geophysical Researches 19: 421–438, 1997. Ó 1997 Kluwer Academic Publishers. Printed in the Netherlands. Through-Research (TTR-5) 1995 cruise, in the eastern Mediterranean were to investigate the characteristics of mud volcanoes with high resolution seismic profiling, the distribution of the Messinian evaporites, and to map the salient seafloor structures at the eastern part of the Mediterranean Ridge. It is important to define the Messinian evaporite distribution in the area, because this layer of plastic evaporites strongly influences the distribution of mud volcanoes and in many respects determines the tectonic style and the seafloor morphology on the Mediterranean Ridge. The high-resolution seismic data were combined with long-range sidescan sonar (OKEAN) and deep-tow high resolution sidescan sonar/subbottom profiling data. Features which looked interesting on the long range OKEAN data, were subsequently checked with high-resolution sidescan sonar/ subbotom profiler deep-tow system (ORETECH), sampled with gravity corer and observed with TV grab. The seismic lines shot in the target area during the fifth TTR cruise extend from 150 km southeast of Crete to 50 km south of the Anaximander Mountains (Figure 1). The area of investigation runs parallel to the Mediterranean Ridge, between its northern and southern deformation fronts, which are related to a set of N and S verging thrusts. Water depths in the study area vary from about 1800 to 3000 m. Two air guns with volumes of 1.5 and 2.1 liters, respectively were used for high-resolution profiling at a depth of between 4 and 7 m and were towed at a distance of 25 m from the stern. Shot was every 10 sec. The streamer has 2 receiving sections, each having 50 m active sections with 6 channels. Streamer offsets were changed for different profiles due to variable noise level of the seismic data. The data were preprocessed onboard (band pass filtering: 30–150 Hz, horizontal stack and attenuation level). Predictive deconvolution was successfully applied on some of the seismic sections. 422 g. çi̇fçi̇ et al. Fig. 1. Schematic map showing the study area in the general position of the Mediterranean Ridge and mud volcano areas in the Eastern Mediterranean. The Mediterranean Ridge mud volcano belt is hatched. 1. Cobblestone-3 area; 2. Pan di Zucchero area; 3. Prometheus 2 area; 4. Olimpi area; 5. The United Nation Rise. Lines with solid and open triangles indicate the outer and inner deformation fronts of the Ridge, respectively. M.A.P.>Messina Abyssal Plain; S.A.P.>Syrte Abyssal Plain; H.A.P.>Herodotus Abyssal Plain; P.T.>Pliny Trench; S.T.>Strabo Trench; A.M.>Anaximander Mountains; F.R.>Florance Rise (Compiled by M. K. Ivanov, J. P. Foucher and A. F. Limonov, UNESCO, 1996). 2. Geological Setting of the Mediterranean Ridge The Mediterranean Ridge is interpreted as a large accretionary complex, which originated due to the northern subduction of the African lithosphere below the Eurasian one and partial collision of those two continents, more precisely between the African and the Aegean Microplate. The Mediterranean Ridge is undergoing a very strong compressional deformation, and its structure is dominated by thrusts reverse faults and strike-slipe faults with numerous compressional folds. The edges of some thrust sheets are seen on sidescan sonar sonographs as curvilinear escarpments (Kenyon et al., 1982; Limonov et al., 1995). Judging from the age and composition of the rock fragments found in the mud breccia from mud volcanoes in western and central parts of the Mediterranean Ridge (Cobblestone 3 and Olimpi areas), it is made up of a wide variety of lithological rock types, ranging in the age at least from the Middle Cretaceous to Holocene (Limonov and Ivanov, 1996). The average depth of the Mediterranean Ridge is about 2100–2200 m, varying between 1200 m and more than 3000 m. Its topography is characterized by small closely spaced depressions and ridges (with a relief 50–100 m and a wavelength of 0.5–2 km) oriented mostly parallel to the general trend of the ridge. Such a pattern produces a ‘hummocky’ hyperbolic acoustic reflection configuration. This special character of the Mediterranean Ridge relates to the presence of Messinian evaporites at a shallow (100–400 m) depth below the seafloor; they strongly influence the interstitial fluid migration, pore water composition, and the pattern of structural deformation of the ridge (Cita and Camerlenghi, 1990). The relationship between the development of the Mediterranean Ridge mud volcanoes and the tectonic structure needs to be defined. The presence of mud volcanoes in different areas on the Mediterranean Ridge accretionary complex was initially documented by Italian expeditions. Four mud diapir and mud volcano areas have been documented before the TTR-3 cruise: the Cobblestone (or Prome- mud volcanoes and dome-like structures at the eastern mediterranean ridge theus), the Pan di Zucchero, the Prometheus 2 and the Olimpi areas (Figure 1). All of them are located in the crestal zone of the Mediterranean Ridge (Camerlenghi et al., 1992). The Olimpi and Prometheus 2 areas constitute a single zone. It is suggested that other known areas (Cobblestone and Pan di Zucchero areas) belong to the same zone which is referred to as ‘The Mediterranean Mud Diapiric Belt’. The phenomenon of the mud volcanism is rather the rule than exception for the Mediterranean Ridge accretionary complex as for other similar tectonic features such as the Nankai Trough accretionary prism (Taira et al., 1992) or the Barbados accretionary complex (Le Pichon et al., 1990). The dimensions of the mud volcanoes and the depth of their roots seem to increase generally southward, from the inner deformation front to the Mediterranean Ridge crest. Two contrasting mud dome structures in the Olimpi mud diapir field have been drilled to test two hypotheses: 1. whether they formed as mud diapirs (i.e. intrusion), or 2. as mud volcanoes (i.e. extrusion). Some new seismic data and the results of scientific drilling has supported the hypothesis of an eruptive origin of the mud volcano deposits, although the source of the mud is still debatable (Kopf et al., 1996). The easternmost portion of the Mediterranean Ridge has been crossed by some single- and multichannel seismic reflection profiles (Finetti and Morelli, 1973; Morelli, 1975; Ross and Uchipi, 1977; Woodside and Williams, 1977) and by a few deep seismic refraction profiles (Lort, 1973; Malovitsky et al., 1975), French PRISMED Program (Mascle et al., 1994; Chaumillon and Mascle, 1995) and GLORIA mosaic compiled by Kenyon et al. (1982). However, the eastern part of the Mediterranean Ridge has been poorly investigated. The tectonic transpression is partially accommodated by a strike-slip motion. Many linear topographic features could be related to compressional deformations with a left lateral strike-slip sense. The deep structure of the ridge in the study area remains almost unknown. Deep seismic profiles normally show a sharp transition from the stratified, slightly disturbed seismic sequences on the Herodotus Abyssal Plain to the highly-deformed sedimentary cover on the ridge at the western part of the study area, provisionally distinguished the A and B reflectors (at the top and bottom of the Messinian evaporites, respectively). Malovitsky et al. (1975) had determined the sedimentary sequence from Paleozoic platform formations through Mesozoic to Quaternary sediments, with a thickness of about 15 km. However, the oldest fragments of rock clasts 423 so far found among the mud breccia from mud volcanoes are no older than mid-Cretaceous (Limonov and Ivanov, 1996). 3. Interpretation of the Seismic Profiles Across the Eastern Mediterranean Ridge Fifteen lines (PS-154 to PS-168) of high resolution seismic survey were carried out along the Mediterranean Ridge from the Olimpi Area in the west to the Florence Rise in the east (Figure 2). Most of lines were concentrated in the southwestern part of the area where some new mud volcanoes were discovered for detailed observations. PS-157 follows the axis of the Mediterranean Ridge and shows a wide area of cobblestone structures. PS-159 and PS-160 are situated north of PS-157 along the Strabo Trench which is a major sinistral strike slip fault subparallel to the Hellenic Trench and the Mediterranean Ridge. The zone between the two main profiles (PS-157 and PS-159–160), is most probably the ‘backstop’ of the accretionary complex of the Hellenic subduction zone. PS-158 represents the eastern border of the area and links the profiles PS-157 and PS-159. PS-155 profile line connects the Olimpi mud volcano field to the main investigated area of this study. The line crosses the Napoli dome (Figure 3), which is the most prominent tectonic feature. We expected to obtain a typical seismic image of a mud volcano that could serve for calibration of similar features observed on the other seismic sections. The relief along the line is rather smooth, and the mud volcano is seen as a large dome with a symmetric cross-section, surrounded by a round zone of depression. The body of the mud volcano is characterized by an acoustically transparent seismic reflection pattern, and the seismic reflectors nearby the feeder channel bend down beneath the mud volcano. The characteristic M-reflector, interpreted as the top of the Messinian evaporites which is very pronounced away from the mud volcanoes (Figure 4), is absent around the Napoli dome for an area and more than 10 km across. The presence of Messinian layers at a distance from the mud volcano seems to be related to faults. At the very end of the profile, the Messinian probably pinches out again. The average thickness of the evaporites can be estimated to be around 100–150 ms, although the bottom is not clearly detected, due to multiple diffractions. The regional seismic line PS-156, is oriented from E–SE to W–NW and cuts across the northern part of the UN Rise area which is called this site as a discrete area of mud volcanism and to call this ‘United Nation Fig. 2. Location of the Seismic profiles (PS-156–157, 160–162, 168), OKEAN lines in the study area. Also sampling sites are shown outside the United Nation Rise. Bathymetry after IOC-UNESCO (1981). 424 g. çi̇fçi̇ et al. mud volcanoes and dome-like structures at the eastern mediterranean ridge 425 Fig. 3. Seismic Test Profile across the Napoli mud volcano from Olimpi mud volcano field to the investigation area. The shape of the dome and body of the mud volcano is generally symmetrical, although there is no symmetry in the surrounding structures – the sediments are very much deformed by faults and folds. Rise’ in celebration of the fiftieth anniversary of this organization in 1995. A V-shaped valley 1.7 km wide is observed as well as on the PS-161 line. Its northern wall marks as a high backscattering line, parallel to the seismic line on its ORETECH records (Figure 4). The section of profile 156 crossing the northern part of the UN, displays a very complex seafloor topography including a relief up to 300 m. The inner structure appears also complex, and it is often impossible to discriminate between the Plio-Quaternary (Pl-Q) sediments and the underlying reflectors. The Pl-Q layer appears generally very thin, below the resolution of the seismic section, and that strongly deformed bedrocks (Messinian or older strata) are almost outcropping. A very strong M-reflector as well as the seabottom topography appear almost horizontal along Line 156 (right part of Figure 4a) and chaotic reflections are observed and the topography is characterized by cobblestone structures. Such seafloor topography produces hummocky, hyperbolic acoustic reflections, masking all reflections from the deeper part of the seismic sections (Limonov et al., 1994). An unknown feature (Figure 4a) corresponds to a large flat-topped dome showing an internal acoustic window. The feature has a more than 100-m thick cover of the Pl-Q sediments, and well-stratified low frequency reflectors are recorded downsection. This structure may have some connection with the buried mud volcano on the ORETECH line. The profiler data indicate a dome-like shape for this volcano that is nearly 2 km across. It has a marked circular shape in plain view (Figure 4b). The PS-159 seismic line is subparallel and close to the Strabo Trench but in the cobblestone area. Here the two standard units referred to the Messinian are replaced in a short distance by a single low-frequency unit with high-amplitude reflectors. This profile illustrates alternates between intensively deformed zones and weakly disturbed sections. The characteristic feature of this line is the abundance of thrust features of potential ‘reverse flower structures’ (Figure 5a), which are evidence for strike-slip displacements. We believe this is probably due to the proximity of the Strabo shear zone. Transcurrent faults are also seen on OKEAN records from this area (Figure 5b). There are some drastic changes in the struc- Fig. 4a. V-shaped valley and a flat-topped dome of an unknown nature (may be assumed to be a mud dome) and the transition from accretionary complex passing through the SW edge of the Strabo Trench in PS-156. 426 g. çi̇fçi̇ et al. Fig. 4b. Top: Probable buried mud volcano on the northern slope of the United Nation Rise. Bottom: 6.5-kHz profiler record. mud volcanoes and dome-like structures at the eastern mediterranean ridge 427 Fig. 5a. The Reverse Flower Structure in seismic profile-159. 428 g. çi̇fçi̇ et al. Fig. 5b. Some drastic changes in the structural trends are seen, which are probably caused by transcurrent strike-slip faults. mud volcanoes and dome-like structures at the eastern mediterranean ridge 429 Fig. 6a. Top: ORETECH image of the Stoke-on-Trent mud volcano and one main flow. Bottom: 6.5-kHz profiler record. 430 g. çi̇fçi̇ et al. Fig. 6b. Top: ORETECH image of the Dublin mud volcano (arrow) and one main flow. Bottom: 6.5-kHz profiler record. mud volcanoes and dome-like structures at the eastern mediterranean ridge 431 Fig. 6c. Discovered Dublin and Stoke-on-Trent mud volcanoes in PS-160. In its middle a column of strong reflections appears which is overlain by high-frequency reflections. They sometimes show the M-reflector, which is louvered by a system of conjugated faults. This is covered by a layer of low-frequency chaotic reflections. 432 g. çi̇fçi̇ et al. Fig. 7. Two huge intrusions which gives some signs of a mud diapirism (dome-like structures). mud volcanoes and dome-like structures at the eastern mediterranean ridge 433 Fig. 8a. Geological overview of the new mud volcano area of the United Nation Rise at the Eastern Mediterranean Ridge. (D): cobblestone areas, SMV: Stoke-on-Trent mud volcano, DMV: Dublin mud volcano, (1): inner deformation front, (2): high backscattering spots on OKEAN data, (3): SW edge of high seafloor deformations area>‘United Nation Rise’, (V): V-shaped valley. 434 g. çi̇fçi̇ et al. Fig. 8b. General geological interpretation of the main seismic profiles (PS-156, 160–162 and 164) in the study area of the United Nation Rise at the Eastern Mediterranean. The difference between the area of high seafloor deformation and the area with typical cobblestone seafloor topography is seen. Some dome-like structures (?!) and discovered Dublin (MVD) and Stoke-on-Trent (MVS) mud volcanoes are marked. mud volcanoes and dome-like structures at the eastern mediterranean ridge 435 436 g. çi̇fçi̇ et al. tural trends, which could be related to the presence of large transcurrent faults (Limonov et al., 1996). Sometimes we observe a combination of both deformations. The positive flower structure resembles to some extent the mud volcanoes or Agas domes (following the terminology of Hovland and Judd, 1988), but without acoustic masking, normally seen below such structures as consequences of gas saturation. They show an average width of 2–4 km and represent positive topographic features on the seafloor topography. The seabottom topography in the PS-160 line is rather rough and induces a chaotic seismic facies; M-reflector is hardly detectible. Two mud domes however were recognized on this line. They mark on the ORETECH record as isometric black spots and display an internal seismic structure similar to the domelike structures. The Stoke-on-Trent mud volcano and one of its main mudflows extends along the profile, over a distance of 2.4 km (Figure 6a). A large mudflow can be observed spreading in a northwestern direction. The volcano and its mudflow appear as an area of markedly high backscattering, which is related to the presence of mud breccia virtually uncovered by pelagic mud on the seafloor. The Stoke-on-Trent mud system is characterized by a strong reflection shown on the subbottom profiler. Its surface is flat to gently domed. The Dublin mud volcano is characterized by high backscattering and is narrow, only 300 m, but a much larger area of the seafloor is highly reflective, as shown by subbottom profiler (Figure 6b). The low backscatter may indicate substantial coverage with pelagic mud and thus appears as an older eruptive event rather than one thought tobe more recent, responsible for the high backscattering spot at the center of the Dublin mud volcano. This area of low backscattering but high reflectivity on the subbottom profiler record is gently domed (Foucher et al., 1996). These two features were sampled by gravity cores. The Stoke-on-Trent mud volcano is characterized by a symmetric dome of about 7.5 km in width. They contain in the central part of an area by strong reflections, and are overlain with high-frequency reflections. Reflectors appear to bend down due to a system of conjugate faults; in some areas the M-reflector can be seen. The feature is underlain by low frequency chaotic reflections (Figure 6c). Two wide features which can be reported as mud diaprisms, are seen in Figure 7. They look like domelike structures having heights of about 170 m and 280 m, respectively. On the OKEAN data, they mark as isometric black spots. These features may correspond to large mud volcanoes. The inner seismic structures of domelike features are very similar to mud volcanoes. Many diffraction patterns seen in the cobblestone area have no correlation and coherency among their reflections. Below a high reflection zone (thickness of approximately 130–135 msec) a few strong low-frequency reflections are detected. Such a pattern can be observed as a consequence of intervening events at the wall of the mud channel which contains gas and pull-down effects. 4. Discussion The geological interpretation of seismic profiles PS-156, 160–162 and 164 in the area show some differences between the area of high seafloor deformation and the area with typical cobblestone seafloor topography (Figure 8a and b). The UN Rise complex structure is particularly evident in the highly dissected seafloor topography with sharp, variable relief and sudden changes of the structural trends. This can be explained by a combination of the tectonic compression caused by the motion northwards of the African Plate and a probable tectonic escape from the west, where Africa and Europe are in direct collision (Cita and Camerlenghi, 1992). The rise is characterized by recent, active tectonic movements. The general tectonic pattern there is dictated by the presence of a system of major sinistral strike-slip faults, which is parallel to the fault system of the Strabo Trench. These faults are very young and are clearly displayed in seafloor relief as steep escarpments. In fact, mud volcanoes are also related to these large faults and these are covered by unconsolidated sediment. Although there is evidence for the presence of mud volcanism east of the Olimpi area, this phenomenon is not as widespread as in the central and western parts of the Mediterranean Ridge. The main reasons for this are thought to be: (i) the presence of a relatively thick layer of the plastic Messinian evaporites, which prevent the breakthrough of mud brecia onto seafloor and (ii) a weaker compressional tectonic stress, affecting the accretionary prism in this part of the Mediterranean Ridge (Limonov et al., 1996). There is a relationship between the Mediterranean Sea to world climate and potential of mud volcanoes to release greenhouse gases like methane and disturb the Mediterranean water circulation. The information provided by the mud breccia is important for several reasons. Little is known about the deep geology of the Mediterranean Ridge because of difficulties below the rough surface and ambiguous Messinian salt using geophysical methods. The eruptive products of the mud volcanoes provide information about the rocks at the lower depths. They may also give information mud volcanoes and dome-like structures at the eastern mediterranean ridge about hydrocarbon potential in the deeper part of the accretionary prism. Whether the mud volcanoes are an environmental or social hazard is also important and should be investigated. If mud volcanoes are as violent in eruption in the deep sea as they have been observed on land (in cases where large craters are created with diameters in the area of 1 kilometer ), they could cause tsunamis (J. F. Woodside, pers. commun.). 437 Muhsin Köktaş, Eolco Felser and Rachel Huber for cooperation and thanks also go to Jean Paul Foucher for helpful discussions. Also we would like to express our great thanks to the people who were involved in the acquisition of the seismic data and to the scientists Leonid Akentiev and Sergey Kraskovsky. Without their hard work it would not have been possible to obtain the data. We thank the Joint Editor, J.-C. Sibuet and the reviewers for their suggestions to improve the manuscript. 5. Conclusions References Interpretation of the high resolution seismic lines of the Eastern Mediterranean was carried out using images as an acoustic characteristic of mud volcanoes. New mud volcanoes, and probably mud domes were discovered in the UN area which rises from 250 to more than 700 m above the surrounding seafloor. The complex structure can also be explained by the general setting of the UN area. It is situated just in the kink point, west of which we observe a strong lateral south-north compression of the accretionary prism. To the east, there is more strike-slip motion due to a combination of the effect of the mutual displacements of the African Plate and Aegean Microplate and probably tectonic escape from the west Several features, observed in the study area may also correspond to some mud volcano structures. They are characterized as dome-shaped seafloor features, most of them marked as high backscattering spots on the sidescan OKEAN records. Some dome-like structures are also observed showing similar reflection characteristics to mud volcanoes. These structures also mark as a near circular high backscattering spot on sidescan lines. The internal parts of those features are quite similar and are characterized by the following: no good reflections below the seabottom; such acoustically transparent layers are then followed by high-frequency reflections and a series of very strong low-frequency reflections. A pull-down effect can be detected in some places near the border of the structure. The same seismic characteristics were found as several seafloor dome structures including discovered mud volcanoes. We suspect that such a picture may be produced by interference events between the wall of the mud volcano and by the presence of gas-rich sediments. 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