South Pasadena • Chemistry Name Period Date 5 · Chemical Reactions STOICHIOMETRY WORKSHEET 1. Nitrogen gas reacts with hydrogen gas, forming ammonia gas. (a) Write the balanced equation for the reaction. N2 (g) + 3 H2 (g) 2 NH3 (g) (b) Find the molar masses of the substances in the reaction. N2: H2: 2(14.01) = 28.02 g/mol 2(1.008) = 2.016 g/mol (c) NH3: 1(14.01) + 3(1.008) = 17.03 g/mol Find the moles of NH3 (g) formed when 5.00 moles of H2 (g) reacts. GIVEN: 5.0 mol H2 DESIRED: WORK: ANSWER: 2 mol NH3 5.0 mol H2 3 mol H2 = 3.3 mol NH3 3.3 mol NH3 ? mol NH3 (d) Find the moles of H2 (g) required when 3.5 grams of N2 (g) reacts. GIVEN: WORK: ANSWER: 3.5 g N2 1 mol N2 3 mol H2 3.5 g N2 28.02 g N2 1 mol N2 = 0.37 mol H2 0.37 mol H2 DESIRED: ? mol H2 (e) Find the grams of H2 (g) needed to form 21.1 grams of NH3 (g). GIVEN: WORK: ANSWER: 21.1 g NH3 1 mol NH3 3 mol H2 2.016 g H2 21.1 g NH3 17.03 g NH3 2 mol NH3 1 mol H2 = 3.75 g H2 3.75 g H2 DESIRED: ? g H2 (f) Find the liters of NH3 (g) produced at STP when 9.62 grams of N2 (g) is used. GIVEN: WORK: ANSWER: 9.62 g N2 1 mol N2 2 mol NH3 22.4 L NH3 9.62 g N2 28.02 g N2 1 mol N2 1 mol NH3 = 15.4 L NH3 15.4 L NH3 DESIRED: ? L NH3 2. Solid potassium chlorate decomposes to form solid potassium chloride and oxygen gas. (a) Write the balanced equation for the reaction. 2 KClO3 (s) 2 KCl (s) + 3 O2 (g) (b) Find the molar masses of the substances in the reaction. KClO3: KCl: O2: 1(39.10) + 1(35.45) + 3(16.00) 1(39.10) + 1(35.45 = 74.55 g/mol 2(16.00) = 32.00 g/mol = 122.55 g/mol Find the mass of KCl (s) produced when 42.0 grams of KClO3 (s) decomposes. (c) GIVEN: WORK: ANSWER: 42.0 g KClO3 1 mol KClO3 2 mol KCl 74.55 g KCl 42.0 g KClO3 122.55 g KClO3 2 mol KClO3 1 mol KCl 25.5 g KCl DESIRED: ? g KCl = 25.5 g KCl (d) Find the volume of O2 (g) produced at STP when 42.0 grams of KClO3 (s) decomposes. GIVEN: WORK: ANSWER: 42.0 g KClO3 1 mol KClO3 3 mol O2 22.4 L O2 42.0 g KClO3 122.55 g KClO3 2 mol KClO3 1 mol O2 11.5 L O2 DESIRED: ? L O2 = 11.5 L O2 3. Zinc metal is placed in a solution of hydrochloric acid to form hydrogen gas and aqueous zinc chloride. (a) Write the balanced equation for the reaction. Zn (s) + 2 HCl (aq) H2 (g) + ZnCl2 (aq) MM: 65.38 (b) 36.46 2.016 136.28 Find the mass of Zn (s) required to produce 12.6 L of H2 (g) at STP. GIVEN: WORK: ANSWER: 12.6 L H2 1 mol H2 1 mol Zn 65.38 g Zn 12.6 L H2 22.4 L H2 1 mol H2 1 mol Zn = 36.8 g Zn 36.8 g Zn DESIRED: ? g Zn (c) Calculate the moles of HCl (aq) required to produce 12.6 L of H2 (g) a STP. GIVEN: WORK: ANSWER: 12.6 L H2 1 mol H2 2 mol HCl 12.6 L H2 22.4 L H2 1 mol H2 = 1.13 mol HCl 1.13 mol HCl DESIRED: ? mol HCl (d) If the volume of HCl (aq) in part (c) is 1.20 L, calculate the concentration of the HCl solution. VARIABLES: WORK: ANSWER: n = 1.13 mol V = 1.20 L M=? n 1.13 mol M= = = 0.938 M V 1.20 L 0.938 M 4. A solution of lead acetate is combined with a solution of hydrochloric acid forming a lead chloride precipitate and acetic acid. (a) Write the balanced equation for the reaction. Pb(C2H3O2)2 (aq) + 2 HCl (aq) PbCl2 (s) + 2 HC2H3O2 (aq) (b) (c) Find the molar masses of the substances in the reaction. Pb(C2H3O2)2: HCl: PbCl2 1(207.2) + 4(12.01) + 6(1.008) + 1(1.008) + 1(35.45) 1(207.2) + 2(35.45) 4(16.00) = 325.29 g/mol = 36.46 g/mol = 278.10 g/mol Find the mass of lead acetate required to react to form 94.5 g of lead chloride. 2(12.01) + 4(1.008) + 2(16.00) = 60.05 g/mol GIVEN: WORK: ANSWER: 94.5 g PbCl2 1 mol PbCl2 1 mol Pb(C2H3O2)2 94.5 g PbCl2 278.10 g PbCl2 1 mol PbCl2 325.29 g Pb(C2H3O2)2= 111 g Pb(C2H3O2)2 1 mol Pb(C2H3O2)2 111 g Pb(C2H3O2)2 DESIRED: ?g Pb(C2H3O2)2 (d) HC2H3O2: Calculate the molecules of acetic acid produced when 94.5 g of lead chloride is formed. GIVEN: WORK: 94.5 g PbCl2 1 mol PbCl2 2 mol HC2H3O2 4.09 × 1023 94.5 g PbCl2 molecules 278.10 g PbCl2 1 mol PbCl2 23 6.022 × 10 molecules HC2H3O2= 4.09 × 1023 molecules HC2H3O2 HC2H3O2 1 mol HC2H3O2 DESIRED: ? molecules HC2H3O2 ANSWER:
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