Record Depletion of Arctic Ozone – 2011 2011 has seen the largest ever depletion of Arctic stratospheric ozone. Studies carried out by the Alfred Wegener Institute for Polar and Marine Research in the Helmholtz Association (AWI) have just confirmed that anthropogenic destruction of Arctic ozone has never been so evident. See the press release from the Alfred Wegener Institute at: [http://www.awi.de/en/news/press_releases/detail/item/record_depletion_of_arctic_ozone_layer_caused_incre ased_uv_radiation_in_scandinavia/?cHash=d1e47412e17142c25c7a361a4229653b]. The World Meteorological Organization (WMO) also issued a press release in parallel to this work, it can be viewed at: [http://www.wmo.int/pages/mediacentre/press_releases/pr_912_en.html] Ozone is a gas that is found throughout the atmosphere but has its strongest concentrations in a region called the stratosphere. The majority of this ozone over Ireland is found in between the heights 15km – 30km and is frequently referred to as the ‘ozone layer’. This ozone layer acts as a shield that helps block most of the harmful ultraviolet radiation from the sun reaching the ground. Exposure to ultraviolet radiation can lead to a higher risk of skin cancer, eye cataracts and crop failure. For ozone destruction to occur, three conditions are required; very cold stratospheric temperatures, sunlight and the presence of ozone depleting substances such as industrial chlorofluorocarbons (CFCs) or related compounds. Ozone destruction was particular large this year due to unusually low temperatures in the atmosphere above the Arctic. The Montreal Protocol (and its amendments) has dramatically reduced the industrial release of further CFCs into the atmosphere. Despite the record low levels of Arctic ozone this year it is still expected that the depletion of ozone due to CFCs will not be a significant concern towards the end of the century. But as the existing CFC ‘burden’ already in the atmosphere will take many years before they it is naturally removed, seasonal ozone destruction will continue into the near future. Monitoring the ozone layer remains of critical importance. Monitoring Stratospheric Ozone in Ireland Met Éireann monitors stratospheric ozone above Ireland from its Meteorological and Geophysical Observatory at Valentia, Caherciveen, Co. Kerry. Two monitoring techniques are utilised to measure ozone high above Ireland. One is a ground based instrument called a Brewer Spectrophotometer, the other is a device called an Ozonesonde which is launched into the atmosphere attached to a weather balloon. Total Column Ozone (Brewer Spectrophotometer) The MK IV Brewer Ozone Spectrophotometer #088 was installed at Valentia Observatory in February 1993. It has been in constant operation ever since. The Brewer is an automated instrument which is continuously taking measurements during daylight hours. Much information is contained in the light coming from the sun. By analysing the light reaching the ground, information on the Earth’s atmosphere, which the light has just passed through, can be extracted. The Brewer instrument uses this technique to make very accurate total column ozone measurements when the sun is directly visible (a Direct Sun [DS] measurement) and can also make a good approximation of total column ozone in cloudy conditions (a Zenith Sky [ZS] measurement). Met Éireann Valentia Observatory - April 2011 Fig.1 MkIV Brewer #088 located at Met Éireann’s Valentia Observatory, Co. Kerry Fig.2 The ozone time series for Valentia in 2010. Direct sun data (DS; red), zenith sky data (ZS; blue) and smoothed DS data (green) are shown. The dashed blues lines show the typical climatological variation of ozone expected at Valentia. (Graphic generated by the WOUDC) Vertical Profile Ozone (Ozonesondes) Since January 1994 Valentia Observatory has run an Ozonesonde programme, monitoring vertical ozone profiles in air masses moving into Ireland / Europe from the Atlantic. Valentia uses ECC6A ozonesondes (ECC 5A 1994 1997) which are flown on meteorological weather balloons. An ozonesonde is based on a mechanical pump which sucks air in from its surroundings and passes it through a chemical sensing cell. From this the ozone concentration in the sampled air can be determined. Fig.3 A typical example of a vertical ozonesonde profile from Valentia Observatory showing the height and concentration of the ozone layer above Ireland. Fig.4 Looking at a year’s worth of weekly ozonesonde ascents side by side one can see the varying nature of stratospheric ozone above Ireland. (Graphic generated by the WOUDC) Met Éireann Valentia Observatory - April 2011 Combining total column ozone and vertical profiles Both the total column ozone measurements from the Brewer and the vertical profile measurements from the ozonesondes have their advantages. The Brewer can provide routine automated ozone measurements throughout the day. The ozonesondes provide important information on the vertical structure of the ozone layer. Combining the two programmes greatly complement each other as well as providing a useful quality control tool. Fig.5 This graph compares the total column ozone as measured by the Brewer at Valentia (blue), the value obtained by the NASA Ozone Monitoring Instrument onboard the AURA satellite (green) and the integrated ozone value as derived from ozonesondes at Valentia (red). Excellent agreement can be seen between the three ozone monitoring techniques. By combining ground, balloon and satellite ozone observations from all over the world, the annual cycle of ozone and it hopeful future recovery can be monitored and measured. For further information contact: Met Éireann, Valentia Observatory, Caherciveen, Co. Kerry, Ireland Tel: +353 (0)66 9473460 Email: [email protected] Other Links of interest: The European Space Agency - Record loss of ozone over Arctic http://www.esa.int/esaCP/SEMIF24SZLG_index_0.html World Ozone and Ultraviolet Data Centre (WOUDC) – Ozone maps http://woudc.ec.gc.ca/e/ozone/Curr_allmap_g.htm NASA – Ozone facts http://ozonewatch.gsfc.nasa.gov/facts/ozone.html Met Éireann Valentia Observatory - April 2011
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