~"Bo "ito ~o-33004/99
REGD. NO. n L.-33004/99
~"Pt.I
Ofil
Q:ne <5a~ette of ~ndia amr~:mOI
EXTRAORDINARY 'mlT H-l.9U'$ 3-d'Q"-~ (i) PART n-Section 3-Sub-section (i) ~ it 9(f11i1tlfl PUBLISHED BY AUTIlORlTY ~,~
5781
NEW
No. 9,
NOVEMBER
q:qfi!lWI
18, 1934
20t2IKARTIKA
1934
am Cf1 ~
~
~~,9~,2012
m:CfiT:A. 820(3T).-~ mcfiR, ~ ('W8JUT) 31f~, 1986 (1986 q;r 29) Cfi1 '1:ffiJ 11 a:m: 25 31Qt::r >r0
~ q;r
~~, ~ Cffi:8JUT) f.T<ri:I, 1986 q;r
~~ enB ~ ~ f.p:'1f~f{ijJd f.T<ri:I or-mit
312lfu: : ­
1. (t) ~f.F:rq'fq;rm~-,rq~ (ma;rur) (.,.,fr~~~)~, 2012 i I
(2) it~-B~<ttmth:§j-A~~ I
2. ~ (ma;rur) f.r<rtr, 1986 -B :­
(Cfl) ~ I -B ~ ~ 38, ~tilqifI1Cfii.1 (311~ afu:~) afu: ~ ~~ ~~ ~ '11:,-­
CD 1=<'fP Q 2 ~ 31~ !'Ifq fte.<'fY -B, "~" wax\ ~ ~ 1:f{ f.n:;:j 31an:
wax\ "31. ~"
~ I
am:
m
(ii)
31'cr -B, f.rq
!>!fCl~4i
-nm ~,
t
am:
.­
'*
w
"(~,~,
~, clllsqlCfiI(Cfi)
~
50
~~(S02)
~~
~(NO)
~q:)U[ (PM)
1700
350
(f{(.Yf
450
i1B
10
100
150
200
(f{(.Yf
CfiTiif.:r ~
i1B
~ (CO)
(f{(.Yf
50
1150
250
350
05
50
100
150
~ift i.TRf"ifiT 3% ~ 1:f{ ~ fen4r \lITQ; I
(2) FSCfilfcf;'ll ~ ~ 1:f{ ~ ~ ~ l"1l-A ~ fcl:;<;rr \lITQ; I
(3) CfiTiif.:r~ ~~~~ ~ ~1~~I~:g (PA) ~ ~1~~I$g (MA)
-M~~ (PTA) am:~~~ (DMT) ~~1.JT!iB-Bthr.mmr~
fZU1'ilit.-( 1 )
~I~~~~~~ PAIMA~enBtTI~~30!000
r-r >rft; crr:f -A <i>l1 Cfi1 f.l4dY 11 ~ -B "i.1Tll ~ ~, <@{ ~ )lCfl]\ Cfi1 ~ ~ ~
'J:n;;c~ ~ ~ ~
<i>l1 ~ <li11 30 ~
<tt fqq;ft ~ I
m
4279 GI12012 (I)
/
IPART
THE GAZETTE OF INDIA: EXTRAORDINARY
(0
!l~SEC.
(3 )
(2)
(4)
_____________
. _____________
, ..-----1.---------------------­
_.____________________
~
~1$~lCf(>l1fhfl
3fcF{>f
(~)1l(
~i~ cillc
ct:m
~
30
cm~
31tHl fc:llli
~ ;:m;r ~, Q$) (>!lc·i)S;:I$(>!
~~
4iYli>1CfcCfl cillc
iiW:m Rl~cilc-c, ~ cillc
~~~_~=~l(M~) 3-fR (QCl1dT~) _C(>Iie
. E'1$$1;jf<i1 fll$"11$5
Q$)(>l);;:fJ?I$(>I
cillc,
75
_ _ _+_______________+
__-------1
cillc­
, (HeN)
cfl3lMr(HAPs )­
t)-gt3n"$, 111~'II$ i>f)<i1 BfCti..t III (>I ~­
t)-gt~
$fI'lfll$Ac (~~) ~
3-fR
~~
-------------­
---­
0.1
-~------'---­
,¥151$<i1
cillc
~:;;:' - ­
.
Cfil~fc:l~ fctfclmCfiUT _Q'rQ", lJJ'I1! 3-fR t)-gt~ cillc
5.0
.---- 20.0---­
-10.'0\
i
$3ft,CI~lfI~QJ'I, ~, ~, QT3IT ~
{jT3lMr (HAPs),
5.0
,----,--.--,-J
I
_
2~~
50
USfiiR' 3("f1dif1l (fll(fjIr;q~)________,_ _ _
______
mer
d
~ ~ flr.iIJT.i ~ m:J
-----------------t----------t---­
{jT3lMr (lJJ'I1!, Q'rQ" 3-fR
lJJ'I1!, Q'rQ", ~ cillc
~at
20
.~)
~, JlI';Ii>f)<i1,
~, JlI$i>f)<i1, (HMR:CftI, ~
Q'lMR:CftI, ~, tfh;fr cillc
3-fR tfh;fr)
cfi3lMr (~, ~
_ _
i
~
__
o _ o _ _ _ _ _••_ _ o _ _ _ _ _ _
•
______
1
o:ifc;-111~, ~
3-fR~)
I (~),~,~
_' __ ._ .. ___________________. ___ ~k _____ ~~ ..
~.HAP- Q~:HCfie:tRll ~ ~ C1ifl{31()'"l/ ~ ~ ~ 3-nRT ~ ~<:r
$Cfi)(>I)Q Cf)(>!
Q'mcn 3f~ Ql/hH0\'tl/ 3fR
Q'mcn tR g QCJ!&! 3RR ~ ~ I
/
['llflT
1I-~
(J) 3(i)]
3
4 ~ 75 ElG1i1:flC{
$" ~ cfi'r a:r.AC1T c;m;t ~ tq;- Jf'R ~ ~ ~ ~ fcnm ~ ~ ~ AA lR, ~u:cT~ ~ a2IT q~Rcm;q~~~~ I (2) cfi'r a:r.AC1T 'Cffiit ~ tq;- Jf'R ~ CJ.ll>q ~ 10 ~ 76 fcnm ~ $ ~ AA lR,
~ u:cT 311c-(1~tf) tffi:ft" .wrm 'Cll(J tffi:ft" ~ Jf'R Cl'T&l cfi'r Uq;2ITd1 3f~ CITIm fI"-(:~)('!C1 ~ ~
75 ~ 500 ElG1<1:i'lc{
~~~I
(3) 500 ttG1A'kA ~
Q1",
(4) 3fRtCfi a:r.AC1T c;m;t
~ u:cT 311..-(1 f{tf) ~ 3fm:rT
75 ElCitA",c{ ~ ~ a:r.AC1T
Jf'R ~ ~ ~ 10 ~ 76 fcnm ~ $" ~ AA ~ ~ Jf'R CITIm Uq;2ITd1 ~ ~ ~ ~ ~ I ~ tq;'Cll(J
c;m;t tq;- Jf'R ~ ~ ~ 76 fcnm QTftf)(if ~ ~ AA lR, ~ u:cT ~ Jf'RCITIm~~~~~ I (i) (Cfl)
ffi cfi'r
311c-(1~Ch q:(>Iij1d! u:cT
Jf'R ClTPT
q:(>Ilftal u:cT 96%
cfi'r
dl,C1(1<H
CITIm cfi'r ¥: mR?r ~~m~~qm4r~ I (l.9) ~ lfNlj1<11 ~
cfi'r
~ ~ ~ ~ ;R- 3f~ ~ cfi'r ~ ~ ~ Jf'R 311"-(1~Ch If(>llj1JI u:cT ~~ ,1fR;J ~ cfi'r ~ ~ 4 {t.m. ~ Jf'R ~ ~
mtq;- $" u:rm q;r 200 mt ~.m. nfiC{ tJm I (dT) "Jf'tur ~ f{1f lR ~ ~ I tfi<;r ~ cfi'r ~ ~
~ m 'tci1 $" u:rm q;r 20 mt {t.m. /;RTc-{ tJ<rrr I 1.3
{t.m.
~
Jf'R
~
(i i i) (Cfl) ~ M CfiT ~a:rur Jf'R ~-nmc:r ~ f;l~ :jUI c)l ~ ~Tf!
(l.9)
~8JUTc)lw API RP 575 cpT ~an:r I (dT)
~ c)l ~ ~ <tfq c)l ~;R-"f;lfr8JUT u;: ~;R- ~ iSIR ~ ~
Jf'R <H{<hfl(1 3fiq ~;q dt cfi'r ~ I (tT) ~
dt c:.t:IT mMT cfi'r
~I
<H{<f"<H(i
cfi'r
~~
em ~ ~ 3fQlC\C1
~ ~ c)l ~
cfi'r
THE GAZETTE OF INDIA: EXTRA.oRDINARY 4
(I) ~ri u:cT ~ tq,
at
II-SEC.
lllfJll4l{UI c); crp;;q c); ~ crp;;q!.!ft>r 4lIJfc:l4l ;q1fJlChl (YOC)
cfiI
'l~
~99.9%) ~, ~CfiI ~;31~
rn cfil3"lI"("I~q:; ~ B(1/~ ~
cfiI
u;('1'
m-;Jf
~~ si'h: ~
0;(1
(~31'11.tT/~:3iTdT) ~~, 3\'fl\5lCi "'I{,cftq:;,{UI
'fri ~ c); 'fIT2T ~ ~ ~
'Cfi'di ~ qgr 99% ~, ~
cfiI~;~
(3) ~
3i"h'
~ B(1 c); ~ 3i1c-("If{q:; ~ ~ si'h:CiI$;;.hICi 3flCRUT
4lT
~ anll
(i) V OC Gfli'!c:fi,%
.w:rc:rr
(ii) 5("8diCi, dJT1f /tlCiJOt"tc{
__
~
_ _ _._-L-__
~ ('f:1.ff (I,<!\cISI$Ci:
(i) YOcGfli'!c:fi,%
3f~
(ii) 5("8;;;lCi, f.!1aJr/QCiJfIC{
~ /;jfI$i4'1Ci:
(i)YOC ~,%
3f~
(i i) 5 f{I diCi,
fa':r.".IT.I QCi JOtI c,,{
~ vi, fllJlIc-;q 368;jf01 ~ - :m<lT - ~
~
at,
8 "fJ(>!'ffi 3'$rr" n!!IT 3'fRl ~ Q1Ue;q)
III. 3m'/~ 31Tmft:r ~
c); ~
filMffifu1("1
Q1U~;ql ;# - ~
<fii
~ fj{S;;qiCh
3i"h' Qfcl~:ui m
~,31~:­
-,.--·-----·-·----·-r---------­
w.~.
3llPT
f------f------..- - - - - ­
"9
c.tiliifo'lc.ti fcrfc:rffi C,fiUT
~ QCit"I$~I$s CtfLQ'.) ~
100
QCi~I$;i1$5 (llJI".Q') ~-~­
JlI$fi1'BI$~e (tr.gJ.~.)
CNic:
~
5\'8diCi
-_._-_._------+--- - - - - - . - - - VOC-HAPs
c:Tft~qC1'-~-::3iI${:n'BI$~e (tr.gJ.~.)
(OO~, J:.TJItr~)
fa':r~
(~~)
sl$fCnCif$(>f, gl$fi1C'1I$~c
CNic:
~ 5("'B;;aCi
VOC-HAPs (~
25.0
(I,<!\CJ51$Ci )
-------,.-.--+-------..------------ ..
. ~.3ft, c:j"'fi)QJI, VOC-HAPs (~.3ft)
4'lfi'tQ(}f, ~,
~,QT.3ft) 0.5
mn.R' 5\'8di01 --.~
..----
---~~-.--.---------,~
50.0
I
[~n-~
3(i)]
5
~ 31~f{: ~- ~~ J(>II$Chl(>l, QtJfr-q)fQJlCi d(>lI$Ch)(>I, ~3iT-~ 31ICf'HI$5, i:rlfi'IQJl-RlCilll(>l
Cf(>l~;O$5 ~C1IJl{, ~-~~ ~ Cf&n~Ci, ~-Q¢fiI$(>I1C'1I$?I$ii'l, QT3iT, Q)Q"M'lGi 31ICffll$5, Q:qffh!fii~
~~ tll$C1I$S " I
[CfiT. tf. ~-150l7/l21200R-m.cIT.s~J
~r<WiT,~~
~.-1Fl31f~"lRR<t~-q~.31T. 844(~),~ 19~, 1986
Cl'iT.3IT.433 (31) ~ 18:mt<>r 1987;
JfR
~~Cfft~~~~~tf.
31~ ~ dfm.Cl'iT.fc1 512 (31), ~ 9 ~ 2009; m.CIiT.fc1 543 (31),
~ 22 ~ 2009; m.CIiT.fc1 595 (31) ~ 21
3i'<IT@
2009; m.CIiT.fc:t 794 (31) ~ 4 ~ 2009;
m.CIiT.f.i 826 (31) ~ 16~ 2009; m.CIiT.fc1 01 (31) ~ 1 ~ 2010; m.CIiT.fc1 61 (31) c:rrfug 5 ~
2010; m.CIiT.f.i 485 (31) ~ 9 ¥
2010; m.CIiT.fc1 608 (31)
nrfn.sr 21 ~
2010; m.CIiT.fc1 739 (31) ~ 9
RldkH 2010; m.CfiT.fc1 809 (31) ~ 4 ~ 2010; m.CIiT.fc1 215 (31) c:rrfug 15 ~ 2011; m.CIiT.fc1 221
(31) c:rrfug 18 ~ 2011; m.CIiT.fc:t 354 (31) ~ 2 ~ 2011; m.CIiT.fc:t 424 (31) c:rrfug 1 ¥
446 (31) ~ 13
3iR'
WI" 2011;
2011; m.CIiT.fc:t
m.CIiT.fc1. 152 (31) ~ 16 ~ 2012; m.CIiT.fc1. 266 (31) ~ 30 ~ 2012
m.CIiT. fc:t. 2 77 (31) ~ 3 1 Jl'T'& 2012 c)l 00 ~ ti'~ii'tf;;:r f$tj -.rnr I
MINISTRY OF ENVIRONMENT AND FORESTS
NOTIFICATION
New Delhi, the 9th November, 2012
GS.R. 820(E).- In exercise of the powers conferred by sections 6 and 25 of the Environment
(Protection) Act, 1986 (29 of 1986), the Central Government hereby makes the following rules further to
amend the Environment (Protection) Rules, 1986, namely:­
1. (1) These rules may be called the Environment (Protection) Fourth Amendment Rules, 2012.
(2) They shall come into force on the date of their publication in the Official Gazette.
2. In the Environment (Protection) Rules, 1986,­
(a) in Schedule I, in the entries against serial number 38 relating to 'Petrochemical (Basic and
Intermediates),­
(i) in the entries under column 2, for the word "EFFLUENT", the letter and word "A.
Effluent" shall be substituted;
(ii) at the end, the following entries shall be inserted, namely:­
!
S.No.
!
(1)
Industry
(2)
i
...
Parameter
(3)
-~-.
Standards
(4)
B. Emission from Chimney I Stack
j
Limiting concentration in mglNm , unless stated
Fuel Type Existing
New plants I Expansion of
. Existing Plant
Plants
50
50
Gas
I
I
"(Furnace,
Boiler,
Heater,
Vaporiser)
Sulphur Dioxide
(S02)
1700
350
450
Liquid
Oxides of Nitrogen . Gas
(NOx)
Liquid
Particulate Matter
(PM)
I Gas
10
Liquid
100
-
850
250
350
I
05
50
--
THE GAZETTE OF INDIA: EXTRAORDINARY
6
~. (2)
(1)
-
I
(4)
I
(3)
Carbon Monoxide
, (CO)
Note,­
(i)
~
Liquid
150
I
200
I
100
I
-------,
~
150
I
I
I
All values shall be corrected to 3% Oxygen.
Wet scrubber shall necessarily be operated at the time of decoking.
.
Norms for CO shall be monitored only in case of Phthalic Anhydride I
(iii)
(PA), Maleic Anhydride (MA), Terephthalic Acid (PTA) and Dimethyl
Terephalate (DMT) Plants. Norms for CO emissions shall not be applicable to
PA/ MA manufacturing standalone existing piants with an installed capacity
of less than 30,000 metric tonnes per annum, provided that such units have a
i chimney/stack of minimum 30 metres height for emitting Carbon Monoxide. I
Process Emission (Specific Pollutant)
Source
Limiting concentration in
(ii)
I
f--­
m~m3
Chlorine
Hydrochlor:c Acid Mist
Ammonia
Hydrogen Sulphide
Phosgene
Hydrogen Cyanide(HCNl
VOC (HAPs)- TDI and
MDI
VOC (HAPs), Benzene
and Butadiene
/
EDCNCM Plant and
Incinerator
EDC / VCM P4mt and
Incinerator
Wastewater stripper,
acrylonitrile plant,
caprolactum plant
Naphtha pre-treatment
plant, olefinplant
(TDI) and (MDI) plant
Acrylonitrile plant
TDI, Methylenediphenyl
Di-isocY.!illte (MDI) Plants
Benzene, Butadiene Plants
Exiting
Plants
10
New Plants
30
30
75
75
05
05
01
10
0.1
01
10
0.1
5.0
5.0
10
]0.0
20.0
VOC (HAPs), EO, VCM, EO, VCM, EDC, ACN, PO
EDC, ACN and PO
Plants
50
25
Organic Particulate
PA, MA and TDI Plants
Process Emission (General Pollutant)
Limitin¥ concentration in
Source
meINm
20
MA, PA, Phenol Plants
VOC (MA, PA and
Phenol)
100
Ethyl benzene (EB),
VOC (EB, Styrene,
Toluene, Xylene,
Styrene, Toluene, Xylene,
Aromatics, EG, PG Plants
Aromatics, EG and PG)
150
VOC (paraffin, Acetone
Non-methane, HC
(paraffin), Acetone, Olefms
and Olefins)
Plants
~"7,_~~
NOfE.- HAP - Hazardous Air Pollutants are those pollutants that cause cancer or other serious health
effects, or adverse environmental and ecological effects.
C. Standards for Fugitive Emission
Storage of Volatile Liquids: General Petrochemical/Petroleum Products.
Storae tanks with ca aci
between 4 to 75m3 and totJ'l1
vJ'\nrmr nr...,"".... {T\lD\ ~., -~--
3(i))
('ilPT II-~ 3(i)]
~
-j
I
7
(2)
Storage tanks with capacity between 75 to 500 m3 and total vapour pressure (TVP) of 10 to
76 kpa should have internal floating roof or external floating roof or fixed roof with vapour
control or vapour balancing system.
(3) Storage tanks with the capacity of more than 500 m3 and total vapour pressure (TVP) of 10
to 76 kpa should have internal floating roof or external floating roof or fixed roof with
vapour control system.
(4) The tanks with the capacity of more than 75 m3 and total vapour pressure (TVP) of more
than 76 kpa should have fixed roof with vapour control system.
(5) Requirement for seals in Floating Roof Tanks­
(i) (a) Internal Floating Roof Tank (IFRT) and External Floating Roof Tank (EFRT) shall
be provided double seals with minimum vapour recovery of 96%.
(b) Primary seal shall be liquid or shoe mounted for EFRT and vapour mounted for
IFRT. Maximum seal gap width will be 4 cm and maximum gap area will be 200
cm2/m oftank diameter.
(c) Secondary seal shall be rim mounted. Maximum seal gap width will be 1.3 cm and
maximum gap area will be 20 cm2 /m oftank diameter.
(d) Material of seal and construction shall ensure high performance and durability.
(ii) Fixed roof tanks shall have vapour control efficiency of 95% and vapour balancing
efficiency of 90%.
(iii) (a) inspection and maintenance of storage tanks shall be carried out under strict
control;
(b) for the inspection, API RP 575 may be adopted;
(c) In-service inspection with regard seal gap should be carried out once in every six
months and repair to be implemented in short time; and
(d) the possibility of on-stream repair of both shall be examined.
(iv) Storage tanks shall be painted with white colour shade, except for derogation of
visually sensitive area.
D. Storage of Benzene, VCM and ACN
(i) FRT with vapour for incineration with 99.9% of removal efficiency for volatile organic
compounds (VOC) shall be provided; or
(ii) IFRT/EFRT with double seals, emission-reducing roof fitting and fitted with fixed roof
with vapour removal efficiency of at least 99% shall be provided; or
(iii) Internal floating roof and nitrogen blanketing in between fixed and floating roofs shall be
provided.
THE GAZETTE OF INDV\ : EXTRAORDfNARY
8
(Emission control for Road tank, truck I Rail tank, wagon loading)
Naphtha:
Loading
(i) VOC reduction, %
(i) 2::99.5
or
of
or
(ii) Emission, gm/m]
I (ii) <5
Volatile
Products
Benzene and Butadiene:
(i) VOC reduction, %
(i) ~99.99
or
or
3
(ii) Emission, mg/m
, (ii) ~ 20
T oluene/Xylene:
(i) VOC reduction, %
(i) ~99.98
or
or
(ii) Emission, mg/m3
(ii) < 150.".
(b) in Schedule VI, in Part D relating to General Standards, in the entries under item III relating to
LoadlMass based Standards, after serial number 8 relating to 'Glass Industry' and entries relating
thereto, the following serial number and entries shall be inserted, namely :­
S.
Industry
Parameter
Standard
No.
"9
~
Petrochemicals
(Basic and
Intermediates)
,
Source
Organic
Particulate
VOC-HAPs
(TDI +MDI)
VOC-HAPs
(Benzene +
Butadiene)
VOC-HAPs
(EO, VCM,
EDC, ACN +
PO)
Phthalic anhydride (PA),
Maleic anhydride (MA),
Toluene Di-isocyanate (TDI)
plants .process emission
(Toluene Di-isocyate) TDI,
Di­
Methylenediphenyl
(MDI)
Plantsisocyante
Process emission
Benzene, Butadiene Plants Process emission
EO, VCM, EDC, ACN, PO
Plants - Process emission
Quantum limit in
gmlhour for Newl
Expansion Plants
(gmlhr)
100
0.5
25.0
50.0
Abbreviations: EG Ethylene Glycol, PG Propylene Glycol, EO - Ethylene Oxide, VCM - Vinyl
Chloride Monomer, EDC Ethylene Di Chloride, ACN - Acrylonitrile, PO - Propylene Oxide, HCN
Hydrogen Cyanide.".
[F. No. Q-15017/1212008-CPWJ
AJAY TYAGl, Jt. Secy.
9
th
th
November, 1986 and subsequently amended vide notifications numbers S.O. 433 (E), dated 18 April
1987; G.S.R. 97 (E), dated the 18th February, 2009; G.S.R. 149 (E), dated the 4th March, 2009; G.S.R.
512 (E), dated the 9th July, 2009;G.S.R. 543 (E), dated the 22nd July, 2009; G.S.R. 595 (E), dated the
21 st August, 2009; G.S.R. 794 (E), dated the 4th November, 2009; G.S.R. 826 (E), dated the 16 th
November, 2009; G.S.R. 01 (E), dated the 1st January, 2010; G.S.R, 61 (E), dated the 5th February,
2010; G.S.R. 485 (E), dated the 9th June, 2010; G.S.R. 608 (E) ,dated the 2pt July, 2010; G.S.R. 739
(E), dated the 9th September, 2010; G.S.R. 809(E), dated, the 4th October, 2010, G.S.R. .215 (E), dated
the 15 th March, 2011; G.S.R. 221(E), dated the 18th March, 2011; G.S.R. 354 (E), dated the 2nd May,
2011; G.S.R. 424 (E), dated the 1st June, 2011; G.S.R. 446 (E), dated the 13 th. June, 2011; G.S.R. 152
(E), dated the 16th March, 2012; G.s.R. 266(E), dated the 30th March, 2012; and G.S.R. 277 (E), dated
the 31 sl March, 2012.
Note.- The principal rules were published in the Gazette of India vide number S.O. 844 (E), 19
l
.---­
Printed by the Manager, Government of India Press, Ring Road. Mayapuri, New Delhi·llOOM
---------.-~-
and Published by the Controller of Publications, Delhi·11 0054