Universität Bonn Physikalisches Institut Prof. Dr. Johann Kroha, Johannes Rentrop and Ammar Nejati 10.12.2014 http://www.kroha.uni-bonn.de/teaching/lectures-and-seminars/wt2014/tcmp Condensed Matter Theory I — WS14/15 Exercise 9 (Please return your solutions before 12:00 h Tue. 16.12.2014 [room PI 1.055].) 9.1 Green’s functions for phonons (10 points) Consider a one-dimensional chain of N atoms, each of mass M and coupled to one another via a nearest-neighbour linear coupling of strength K. The Hamiltonian describing such a system is " # N X p2j 1 2 H= + K(uj − uj−1 ) , 2M 2 j=1 where pj is momentum of the atom at site j and uj is the displacement of the atom at site j away from the equilibrium position. As discussed in the lecture, the Hamiltonian can be diagonalized in the form X 1 1 2 (1) pk p−k + M ωk uk u−k , H= 2M 2 k where uk and pk are conjugate variables, and ωk is the dispersion for phonons. a) Using the linear combination s ~ † b−k + bk 2M ωk r M ~ωk † pk = i b−k − bk , 2 uk = where b†k and bk are the phonon creation and annihilation operators respectively, write (1) in the final, second quantized form X 1 † H= ~ωk bk bk + . 2 k Note that [bk1 , b†k2 ] = δk1 ,k2 . b) We now consider the linear combinations Ak := bk + b†−k A†k := b†k + b−k . Calculate the non-interacting phonon propagator Dk0 (ω) by obtaining D n oE Dk0 (t − t0 ) ≡ − T Ak (t)A†k (t0 ) , via the equations of motion and performing a Fourier transform with respect to t. You can set t0 = 0 before the Fourier transform without loss of generality. Differentiate between the cases t > 0 and t < 0. 8.2: Phonons in a metal: Kohn anomaly (10 points) In metals, it is expected that the harmonic interactions between the ions of a lattice are not only between nearest neighbours, but long-ranged. The physical origin is that a displacement of an ionic charge induces an electric charge polarization in the electron sea, that is long-ranged and oscillatory in space. This oscillatory polarization then acts in its turn, on the other ions in the lattice. Here, we consider a 1d linear chain of ions (with lattice constant a) immersed in an electron sea. The force constant between an ion on the lattice site i and an ion on lattice site j is κi−j = κ0 sin[2kF (i − j)a] . kF (i − j)a a) Write down the classical Lagrangian for the system of ions and derive the equations of motion. b) Make an ansatz of plane-wave solutions for the ion displacements, qj (t) = q0 exp[i(kxj − ωt)], 2 2 xj = ja, and derive an expression for ω(k)2 and ∂ω ∂k . Show that ω(k) has a cusp (divergent slope) at k = 2kF . This effect is called the ‘Kohn anomaly’. b) Draw the curve for ω(k).
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