LOTZ Laboratory for sustainable technologies in buildings Faculty of Mechanical Enginering University of Ljubljana ENERESE Training course Lecture #3 Renewable and low-ex technologies f energy supply in high energy efficient buildings BAT (best available technologies) for decentralized electricity production in buildings Lecturers prof. dr. Sašo Medved, Note: Some of the pictures in the presentation are used from other sources which are citated. Some pictures are download from web and authors are unknown. We would like to thank all known and unknown authors. Some schemes are taken from marketing and technical material of different companies to improve the quality of presentation and we want to make acknowledgment to those companies. This presentation should be used for education purposes only. Advance technologies for decentralized electricity production - PV electricity generation EU directive on “Green electricity” established in 2003, provides legal basis and targets for electricity production from RES for all EU member states. It looks like that one technology, called photovoltaics, benefit mostly from this directive. Photovoltaic systems consist of large number of solar cells gathered in solar panels or modules, convert solar energy directly into electricity There are several types of solar cells, but they are mostly made from silicon, very common element on Earth and have similar, but low efficiency in the range between 10 and 18%. Despite low efficiency of photovoltaic systems, areas of facades and roofs in buildings are in most cases large enough for independent electricity supply. In addition to that, building owners could sell electricity to the public grid and benefit from so called “feed-in-tariff” subsidies or other state benefits. Solar energy Solar radiation a form of electromagnetic radiation. Electromagnetic radiation covers a wide range phenomena from radio waves to x-rays and gamma rays. The sources of those radiation are different. The source as in case of solar radiation, is body with temperature above absolute zero (0K). This is so called thermal radiation. All electromagnetic radiation travel in vacuum with speed of light, but differs by wavelength and amount of energy they transfer. Photovoltaic cell (PV cell) Most common PV cells are made from silicon. The cell has two thin layers – bottom one, where small amount of boron is added to silicon (so called p-type layer with free positive charged holes) and few mm thick upper layer, where phosphorus is added to silicon (so called n-type layer because with free negative charged electrons). Putting those layers together voltage barrier (~ 0,7 V) rising in PV cell. n-type sillicon layer p-type sillicon layer - + + junction region as voltige barrier ~ 0,7 V PV cell – how electricity is generated Photons with sufficient energy can produced new electrons and holes. This results in internal electric field If resistant load -appliance like bulb or motor - is connected with PV cell electrons lives the PV cell and travel thought appliance and return to PV cell where bond together with “waiting” hole. The life of new electron-hole pair is ended, but appliance produce work in meantime. current of electrones I n-type sillicon layer p-type sillicon layer - + + junction region as voltige barrier U = ~ 0,7 V internal electric field applience Electrical power of PV cell is equal to Pe = U . I where U is approximately constant and depends on base material (mostly silicon) and added atoms (beside P, B also Cd, As,..), meanwhile electricity current is proportional to the density of solar radiation. current of electrones I n-type sillicon layer p-type sillicon layer - + + junction region as voltige barrier U = ~ 0,7 V internal electric field applience PV cell – efficiency The reason why conversion of solar energy into electricity by PV cell is relatively low (between 15 to 20%) is that only limited amount of photons of solar radiation has adequate energy to produce new electron-hole pairs. For silicon PV cell these are photons with wavelength less that 1,11 mm or having energy greater then 1,18 eV. Unfortunately entire energy of most photons with adequate energy can’t be convert into electricity ! Energy of photons (eV) Density of solar energy Solar radiation spectrum Unused photon energy Energy barrier for Si PV cell 1,11 mm or 1,18 eV Photons with unsufficient energy Wavelenght l (mm) PV cell – types and efficiency Mostly used today are silicon PV cell produced from only one crystal of Si (this type is called monocristalline “mc-Si” PV cell) of several crystals of Si (this type is called polycrystalline “p-Si” PV-cell). This PV cells have highest efficiency: mc-Si 15 -18% and p-Si 12-16% Production of Si crystals are expensive and could be decreased if amorphous Si is used; this is another form of Si in environment; efficiency of “a-Si” cells are much lower – up to 8% Polycrystalline cell can be made from other materials and could be very thin; this are so called thin-film PV cell made from cadmium telluride (CdTe), gallium arsenide (GaAn) or copper indium deselenide (CIS); they are less efficient (12 – 14 %) but production is cheaper mc-Si p-Si CIS PV cell – types and efficiency Market share of different PV cell technologies PV cell – types and efficiency PV cell efficiency (%) PV cell efficiency (%) Efficiency of PV cell is independent on solar radiation density (if >100 W/m2), but decrease with cell temperature; that's why researchers try to combine solar heating (cooling of PV) and electricity production ! Solar radiatin (W/m2) PV cell temperature (°C) Photovoltaic modules For practical reasons PV cell are encapsulated in PV modules. Modules are in different size from some hundreds of cm2 to several m2. Most often modules in size of 1 m . 1,6 m are used in buildings. 40 to 50 PV cell are normally grouped together to produce 20 to 25 V of direct current (DC). tesnilo Sealing zgornje Glass steklo enkapsulacijsko Encapsulate sredstvo gel sončne celice Back cover zadnja plošča nosilni okvir Frame Each producer declare “peak electrical power (Wp)” for their PV modules. This is the electrical power when solar radiation is 1000 W/m2 and cell temperature is 25°C. This are ideal conditions and in hour-tohour operation the power is lower (of course 0 W during the night) Each producer declare “durability factor” for their modules. This is the guaranteed efficiency after 20 to 30 years of operation. Typically this is only 5 to 15% -> module having 100 Wp will have power of 90 to 95 W after 30 years of operation! PV technology is very durable ! PV systems Two types of PV system are most common: off-grid systems or island operation stand alone systems grid connected system Off-grid system could be low-voltage direct current (DC) (mostly 24 V) storing electricity in batteries. Between the batteries and users inverter could be installed to produce high voltage (220 V) alternating current (AC). This allows common appliance to be supplied with electricity and reduce the size of wires and reduce system cost. PV systems EXAMPLE: Grid Stand alone PV system with PV modules area of, inverter and batteries (capacity of 600 Ah). As backup methanol fuel cell is used. PV systems Grid connected system are so called PV solar power plants. They produce and send electricity to the public grid. In many countries investors in PV power plant are encourage with state incentives. This could be in form of “CO2 coupons” or as “feed-intariff”. Feed-in-tariff is price of electricity offered to investor in long them contract. Feed-in-tariffs for PV systems are normally 2 to 4 time greater then regular price of electricity (between 0,02 to 0,06 €/kWh depending of country). Such supporting schemes origin from EU RES-e Directive published in 1998 bust PV market in last decade. Largest Slovenian 107 kWp and EU PV power plant in Spain (23 MWp) (2008) Increasing of PV system efficiency Despite huge volume production increase of PV systems, the technological break-through is not happen yet. Nevertheless there are ways how to increase annually produced amount of electricity. PV modules can be mount on Sun tracking device. This way annually production of electricity can increase up to 60%. Mirrors with low concentration ration can be added to PV modules for increasing the solar irradiation. PV system electricity production can be increased by 30% or more. Integration into the buildings Mounting the PV modules into the building skin in most cases reduce electricity production because modules are not installed in optimal position. That’s why financial support for such PV systems is higher ! Building integrated PV modules offer many advantages such as: Modules can replace facade and roof construction and decrease the cost of building Modules are weather durable therefore maintenance of buildings can be cheaper Modules can improve building envelopment properties – reduce heat transfer coefficient (U) and provide shading of large glass areas Guarantee long term income for the owner Emphases the “green view” of the building And reduce the use of land for installing PV system Integration into the buildings PV modules producers developed solutions to atract architects and investors. Some examples: PV modules can be opaque or semi transparent Density of the solar cell in PV modules can be custom made adjusted to desired visual effect, natural lighting, shading. Source: http://www.dansksolenergi.dk; http://www.concerto-sesac.eu; http://www.solarpv.co.uk; http://photovoltaic-shingles.com; http://drexelcorp.wordpress.com Integration into the buildings Solar cells can be in different colours to emphases appearance of the building PV modules can be integrated in standardized solutions of building constructions Source: http://www.dansksolenergi.dk; http://www.concerto-sesac.eu; http://www.solarpv.co.uk; http://photovoltaic-shingles.com; http://drexelcorp.wordpress.com Electricity production – rule of thumb Rule of thumb Yearly production of PV system having size of 1 m2 installed in the area with annual global solar irradiation 1100 kWh/m2 and optimal orientated position is: 120 – 140 kWh/m2 (for pc-Si modules) Very often PV modules integrated into the buildings are not orientated optimal, therefore reduction factor, shown on the figure, must be taken into account. From figure optimal slope and orientation of PV modules can be seen as well – representing with red area on the chart ! (Attention: chart is valid for latitudes between 30°and 50°) Electricity production – role of thumb EXAMPLE: PV system will be installed in city having annual global solar irradiation 1800 kWh/m2. PV modules will be installed on southeast vertical facade. What will be yearly electivity production with 100 m2 of mc-Si modules? What will be pre-tax income if “feed-in” tariff is 0,4 €/kWh and what will be simple return rate if installed kW of PV system cost 3500 € ? Orientation factor (presented by red dot on previous figure) is 0,65 Annually produced electricity will be: E ~ 120 kWh/m2 . 1800 kWh/m2a / 1100 kWh/m2a . 0,65 . 100 m2 = E ~ 12,8 103 kWh/a Annual income will be: 12,8 103 kWh/a . 0,4 €/kWh = 5120 E 1m2 of PV modules have power of 120 W. Therefore total power of PV system is 12 kW. Simple rate of return is 12 kW . 3500 € / 5120 E/a = 8,2 years Electricity production – calculation methods Public available computer tool Site and PV modules orientation Load definition Electricity production – calculation methods Operation principle PV module selection Follow recommendations Iterative optimization Environmental issues of PV Several principles can be used for justify PV systems regarding to their environmental impact. Here are some examples ! Embodied energy – ratio between produced electricity to energy needed for production of PV modules versus ; Si cells produce in life time (in general 30 years) 10 to 20 times more energy that it is needed for production Reduce emissions of greenhouse gases and other air pollutants – emissions can be reduced between 60 to 90% regarding to energy grid mix Recycling – not commercial, it is proposed that recycling of Si will reduce energy consumption to 1/3 More complex method are available – for example PI – pollution index method (http://envimpact.org) suggested following relations for electricity production (less is better): from coal PI = 885; PV PI = 52 , from wind PI = 9 ; from hydro PI = 0,5 The future of PV The price of electricity produced by PV system will decrease in next 20 years to the level equal to fossil and nuclear electricity. This will be achieved even with today known technologies. New development in PV cell producing will further decrease price of PV systems Source: SunWorld The future of PV PV will be leading technology in the cities of tomorrow Source: SunWorld Intro to other technologies for decentralized electricity production In this century we will probably face fundamental changes in energy supply systems. Not only because limited reserves of fossil fuels, but because wide implementation of decentralized electricity production in so called smart grid systems. Example of such systems are so called “micro combined heat and power generation” (mCHP) systems. High efficiency of electricity production is established by utilization of waste heat as by product. Such systems use natural gas or biomass fuels to generate heat. In most cases combustion engine or Stirling engine is used to convert heat into mechanical work for electricity generation. Intro to other technologies for decentralized electricity production In addition to the large, hundred and more meters high turbines, small scale building integrated wind turbines could supply electricity to consumers in the building. There are several technologies, mostly adapted to low wind velocity in urban areas. Fuel cells are another technology for combined heat and electricity generation. Fuel cell combines molecule of hydrogen and oxygen into molecule of water and generate free electrons or electricity current. Fuel cell system could consists reformer which produces hydrogen from natural gas or liquid biofuel, avoiding problems of storing and transportation of the hydrogen. High efficiency of electricity production (up to 45%) and high overall efficiency (up to 90%) without environment impacts is the most important advantage of this technology. Intro to CHP (cogeneration) In principle cogeneration is process of production of electricity in more efficient way comparing to ordinary thermal power stations. In thermal power stations vapour (most often water steam) or hot gases (most often compressed flue gases from combustion chamber) processes are used to convert heat produced by burning of feed-in fuel into mechanical work needed to drive electricity generator. Thermodynamic system that convert heat into mechanical work is called heat engine. Theoretical efficiency of heat engine or amount of internal energy of the fuel that can be converted into the mechanical work is defined with Carnot efficiency. In engineering practice, efficiency of electricity production is lower due to the heat losses. Part of these losses, related to the heat that must be transferred from the process into environment can be use for heating. In the thermal power stations excess heat must be transferred to environment using cooling towers. This wasted heat can be used for heating of teh buildings. In this case power plant operates as cogeneration system. Intro to CHP (cogeneration) Because in the large power plants amount of the heat that must be realised to the environment is much more then the heat demand or the settlements are to far from power plant, only small part of excess heat can be used. More efficient combined heat and power production is possible in district heating systems, where power generation is adopted to heat demand during the year. Unfortunately heat supply during the summer cause high (50% or more) heat losses in distribution system. This problems can be avoid in case of block-type cogeneration units (or micro combined heat and power units mCHP) which can be installed in residential buildings. In most cases they have power up to 50 kW. Cogeneration Separate power and heat generation Efficiency of CHP (cogeneration) 100 kWh fuel Power plant h = 30% waste heat waste heat 70,5 kWh 100 kWh 30 kWh heat 60 kWh electricity 30 kWh heat 60 kWh 70 kWh 10,5 kWh fuel Boiler h = 85% fuel CHP unit htot = 90% waste heat electricity 10 kWh Efficiency of CHP (cogeneration) All year relative heat demand (1) Efficiency of cogeneration depends on hour-by-hour consumption of heat. CHP unit should be in operation at least ~ 4000 hours per year to be economical. Several modules can be combined to avoid operation of cogeneration units at lower efficiency at partial load. 1 0,8 0,6 Tolerance regarding outdoor temperature 0,4 CHP module 2 0,2 CHP module 1 0 0 DHW heating 1000 2000 3000 4000 5000 6000 7000 8000 8760 h/a CHP technologies CHP technologies defer mainly regarding to the process of production of mechanical work as follows: internal combustion engine (ICE; Otto or Diesel engine); can use natural gas of LG, biogas of liquid biofuels; most common used in buildings; high efficiency (33-40% for electricity production, overall 80 to 100% if condensing technology is used); in Japan more than 300.000 gas driven units are in operation; microturbines; are gas engines with electrical power output 30 to 500 kW; microturbines have lower efficiency comparing to ICE (25 - 30% for electricity production, overall up to 70%) ; but have better partial-load efficiency, lower maintenance cost and lower emissions of NOx, CO and hydrocarbons, Stirling engine; convert heat into mechanical work without any emissions, still in development Fuel cells are another CHP technology. Electrochemical process is used for electricity generation in this devices. Fuel cells will be presented in separate chapter. CHP technologies – internal combustion engine single-cylinder 4stroke 580 cc engine; electrical efficiency 26% to 27%, heat efficiency 61% to 74% with flue gas condensing unit; up to 10 modules may be networked and operated via an integrated master controller; Source: http://www.senertec.de/en/derdachs/technology.html CHP technologies – internal combustion engine Vitobloc 200 18 kWel/36kWth 4 cilinder gas engine natural gas driven, biogas, sewer and landfill gas as option electrical efficiency 29%, heat efficiency 57% units up to 401 kWel, 549 kWth Source: http://www.viessmann.co.uk/etc/medialib/ CHP technologies – internal combustion engine Source: http://www.viessmann.co.uk/etc/medialib/ CHP technologies – microturbine Microturbine driven CHP consicts of highspeed generator, comppresor and turbine wheels that are on the same rotating shaft, the only moving part in teh enginee. This enable compact size and long time reliability. Turbec T100 100 kWel , 155 kWht natural gas driven overall efficiency 77% Source: http://www.turbec.com CHP technologies – Stirling engine Stirling engine is so called hot air engine or external combustion engine. Mechanical work is produced by periodic expansion and contraction of gas (helium) sealed inside the engine. Different heat sources can be used, biomass, solar energy and geothermal energy are one of them. Stirling engine driven CHP are still under development, pilot applications with smaller size (1 to 40 kW) with efficiency of electricity production 10 % to 30% and overall efficiency up to 80 % are in operation. Solar dish with Stirling motor driven generator Pilot Stirling engine driven CHP; 3 kW Pe, 10,5 kW Pth; heat is produced burning gases produced by gasification of pellets. Source: http://sunmachine.si/sunmachine_pellet Economy and environmental impacts Small scale CHP systems are more expensive per unit of size comparing to large community scale systems. The cost of combustion driven CHP systems is between ~ 1200 € to 700 € per kWe (Pe 100 – 5000 kW) and for microturbine driven CHP systems between ~ 2000 € to 1400 € per kWe (Pe 100 – 5000 kW). However, the difference in price become lower in recent years. It is common that small scale CHP systems are included in subsidy scheme for energy efficient electricity production. In Slovenia, for example, feed-in tariff for electricity produces by small CHP 23,71c€ per kWhel for the systems that operates not more than 4000 h per year. Due to the high overall efficiency, small scale CHP produce much lower emissions comparing to ordinary fossil fuel power plants – at least 4 times lower emissions of CO2 comparing to coal fired power plants and more then twice lower emissions comparing to natural gas fired power plants. Intro – wind generators Kinetic energy of wind is result of solar energy absorbed on the Earth surface and rotation of the Earth. As any other fluid, air in lowest part of the atmosphere, called troposphere, is driven by pressure differences between high pressure Anticyclone and low pressure Cyclone regions. Utilization of wind energy becomes most economic technology for electricity production from renewable energy sources in recent years. More then GW of wind turbines operates in EU and y% of electricity is produces in EU in this way today. Beside large wind turbines, many producers offer the small turbines, adapted to the integration in buildings. Potential of wind energy Most often, wind is specified in “windrose” charts. Such chart presents average yearly wind velocity in certain directions for selected location at height 10 m above the ground. S SSZ Wind velocity at height h(m) above the ground can be calculated by eq.: SSV 4 SZ SV 3 2 ZSZ VSV 1 0 Z Due to the friction between moving air layers, wind velocity increase from ground level (where w = 0 m/s) to maximal value at ~ 1000 m above clear space ground. 5 V ZJZ VJV JZ JV JJZ JJV J Windrose for City of Ljubljana h m v h v(10m) 10 s where v(h) (m/s) is wind velocity at height h (m) above the ground, v(10m) wind velocity 10 m above the ground and coefficients dependent on surface roughness (0,1 for sand surface; 0,13 for pastures; 0,30 for large settlements) Wind speed distribution above the ground level for different surface roughness Potential of wind energy Production of electricity by wind turbines can be established only if hour-byhour wind velocities is known. In absence of meteorological data, Weibull probability distribution be used to calculate probability of wind velocity p(v): k k 1 k v p v l l e v l 1 If value of shape parameter of distribution k is equal to 2, Weibull probability distribution converts into Rayleigh probability distribution. If scale parameter l is equal to: l 2 v av m s Probability of wind velocity can be calculated base on the average wind yearly velocity: 2 p v v e 2 2 v av v 4 vav 1 Potential of wind energy p(v) 0,45 p(v) p(v) 0,3 measured 0,4 0,25 vav=2m/s 0,35 Rayleigh destribution vav=2.8m/s v= 0,3 0,2 0,25 vav=4m/s 0,2 0,15 v= vav=6m/s 0,15 vav=8m/s v= 0,1 0,1 v= 0,05 0,05 0 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 v (m /s) 0 1 2 3 4 5 6 7 8 9 10 11 12 v (m /s) Example: How many hours per year will wind velocity will be 4 m/2 if average yearly wind velocity vav is 6 m/s ? Using diagram on the left, p(v) is equal to 0,12. Number of hours per year when wind velocity will be 4 m/s is therefore: h N 0,12 8760 1051 year Power of wind turbine Theoretical approach 1 E m v2 2 Air volume with mass m (kg) and velocity v (m/s) has kinetic energy equal to: m2 kg 2 J s If equation id divided by time differential (dt) mass of the air is replaced by mass flow rate. Considering the continuity equation , relation for wind turbine power can be developed: 1 1 E 1 m 1 1 E m v2 P v2 A v v2 A v 3 2 dt dt 2 dt 2 2 m .V m where r is air density (kg/m3), A area of wind capturing (diameter of the rotor (m2) and v wind velocity (m/s). It can be seen that wind turbine will produce more energy at the sea level (since density of the air is 1,225 kg/m3 (25°C, 1 bar) at the sea level and 1.184 kg/m3 at same conditions at altitude 600 m. In bought cases wind turbine power depends on cube of velocity. kg m2 J W 2 s s s Power of wind turbine Theoretical approach Even in theory, all kinetic energy could not be transformed because this results to the zero velocity behind turbine and mass flow rate through the turbine is then zero. Optimal reduction of air velocity at the outlet of the turbine define maximal efficiency which is called “Betz coefficient” and have value of 0,597 (59,7%). In reality efficiency is lower, but contemporary wind turbine have efficiency or power coefficient cp between 38% and 42%. 1 P cp A v 3 2 kg m2 J W 2 s s s Power coefficient cp for different wind turbines as function of speed number l; speed number is ration between tip rotation speed of the rotor and wind velocity Power of wind turbine Engineering approach Producers of wind turbines present power diagram for each of their product. Such diagram shows not only maximum power of the wind turbine, but how power is related to the wind velocity. rated power Wind turbine power (kW) 500 Typical power curve for wind turbines with cut-in and cutout wind velocities and region (above 10 m/s) where power of wind turbine is constant at maximum value. 400 300 200 100 cut-out velocity cut-in velocity 0 0 5 10 15 20 wind velocity (m/s) 25 30 Technology of small scale wind turbines Most common division of wind turbines is regarding to the position of rotation axe regarding to the wind velocity vector and horizontal axe wind turbines (HAWT wind velocity vectors are parallel to the rotation axe) and vertical axe wind turbines (VAWT wind velocity vectors are perpetual to the rotation axe). Small scale wind turbines could be: building mounted; smaller wind turbines installed on the roof; often in size of 1 to 2 kW pole mounted; free standing and erected in a wind exposed position; often in size of 5 to 10 kW Producer: TURBY BV VAWT mounted on flat roofs diameter 2m hight 3m tall cut-in velocity 4m/s Power curve Technology of small scale wind turbines Producer: RENEWABLE DEVICES LTD. HAWT cut-in velocity 4m/s Producer: SOUTHWEST WINDPOWER INC. HAWT diameter 3m hight 6m tall cut-in velocity 3 m/s Producer: NGup ROTORBLADES VAWT Technology of small scale wind turbines Most small scale wind turbines generate direct current electricity (DC) and require an inverter to convert it to alternating current electricity (AC). In off-grid systems battery are needed to store the energy. Production of electicity Most simple way to calculate the annual electricity production is using the capacity factor (CF). This is the ratio of actually produced electricity to theoretical maximal production per year. Typical capacity factors are between 20 to 40%. CF can be defined as whole year average power of wind turbine: h MWh E P CF 8760 MW 1 year year Example: Wind turbine has diameter of 90 m and power of 3 MW. What will be annual production of electricity if capacity factor at certain location is 36%. What will be specific energy production per m2 of device? kWh kWh 9,460,800 E 3000 0,36 8760 9,460,800 ;Espec 1487 2 2 year r m year This is much higher comparing to PV for example ! Production of electicity Število ur v letu, ko poha veter s hitrostjo v (ur/ leto) More deatiled calculation of electicity production with wind turbine is based on three steps: 1200 1000 1. Probability of wind velocity p(v) should be use for determination of number of operation hours at different wind velocities for selected location 800 600 400 200 0 2. Power curve of the wind turbine must be selected. Moè vetrnice v odvisnosti od hitrosti vetra v (kW) 0 2 4 10 6 8 Hitrost vetra (m/ s) 12 14 16 300 imenska moè vetrnice 250 200 150 100 vklopna hitrost vetra 50 izklopna hitrost vetra 0 0 Pridobljena energija pri razliènih hitrostih vetra v (kWh/ leto) 3. The sum of the products between number of operation hours and power of the wind turbine at same velocity must be calculated; this sum represents a total yealy amount of produced electicity. 4 8 20 12 16 Hitrost vetra (m/ s) 24 2 4 10 6 8 Hitrost vetra (m/ s) 12 28 32 120 100 80 60 40 20 0 0 14 16 Small scale wind turbine cost and environment impacts Average cost of small wind turbines is 3000 € per kW of rated power for roof mounted turbines to 4000 € per kW of rated power for polemounted applications. Off-grid systems needs batteries which need replacing six to ten years. Cost of Pb accumulators is ~ 150 € per kWh of stored electricity. On-grid systems need inverter at a cost 1000 € ot 2000€. Environmental impacts which are characteristic for large wind turbines, such as possible impact on birds, habitats, visual impacts on landscape, vibration and noise emissions are much less significant in case of small scale buildings integrated wind turbines, but they all need to be considered before a turbine is installed. On the other hand heritage conservation legislation and assessment of whether the building structure is strong enough to support the weight of turbine and force of the wind. Intro to fuel cell (FC) Electrochemical energy conversion is direct conversion of chemical energy into electricity. A device that converts chemical energy into electicity is called fuel cell. electolite positive electrode (cathode) All fuel cells use hydrogen (as fuel) and oxygen (as oxidant) for operation but they defer regarding to type of electrodes (solid/fluid) and electrolyte (fluid/solid). O2 negative electrode (anode) Fuel cell is made from two electrodes (- anode and + cathode) and an intermediate electrolyte layer, H2 capable to transferring positive ions from negative to the positive electrode (or negative ions in opposite direction) but not allowed electrons to pass thought. Flow of electrons thought external circuit from negative to positive electrode provides electrical power of the appliance. Hydro-oxygen fuel cell In hydro-oxygen FC hydrogen gas is led to the porous negative electrode, allowing H+ions to diffuse thought electrolyte, meanwhile the electrons anted electrode material and may flow thought external circuit. If catalyst (platinum film eon the electrode surface) is present, the H2 dissociate at negative electrode in reaction: H2 This reaction is accompany with generation of the water and heat (at temperatures 50 to 800°C depending on FC type) that can be use for heating. heat H+ ions positive electrode (cathode) O2 4H 4e 2H2O O2 electolite Gaseous oxygen (or air) is led to positive electrode, where captured bought hydrogen ions and electrons: e- negative electrode (anode) 2H2 4H 4e R H2O Cogeneration system based on PEMFC with natural gas reformer Hot water tank PEFC stack H2 gas Air Air Backup water heater Recovered heat Hot water Fuel processor Natural gas Hot water DC electricity AC electricity DC/AC Converter Source: Tokyo gas Fuel cells technologies Examples of large scale pilot PEMFC of different Japan producers ENEOS celltech (former SANYO) TOSHIBA FCP Natural gas/ LPG 750W Natural gas/LPG 700W EBARA MATSUSHITA (Panasonic) TOYOTA Natural gas / Kerosene 1,000W Natural gas Natural gas 1,000W 1,000W Source : NEF Home Page Fuel cells technologies Examples of PEMFC cogeneration unit produced by Viewsmann and scheme of the cogeneration system; natural gas is used as “supplier” of hydrogen. Electrical rating power 2 kW; thermal power 3.5 kW Source : www.viewsmann.de Fuel cells technologies Solid oxide fuel cell (SOFC) use solid ceramic (zircon) as the electrolyte to conduct oxygen ions at positive electrode. This are high temperature fuel cells (operating temperature 800°- 1000°C) and have high efficiency of electricity production ~ 50%, but can ne up to 80% in the future. High operating temperatures enable autoreform of several fuels that content hydrogen. Some other FC are under development as well. For example phosphor acid fuel cell (PAFC) which use phosphoric acid H3PO4 acid as electrolyte or molten carbon fuel cell (MCFC) which use molten alkaline carbonate as electrolyte. SOFC MCFC PAFC Self evaluation Briefly explain how PV cell produce electricity from solar radiation ! Describe types of solar cells and their efficiency ! Draw U-I curve of photo cell and explain how is dependent on temperature and density of solar radiation ! What are PV modules ? What you know about sizing of the PV systems ? Describe procedure of sizing of the PV systems ! Explain how environment can benefit from PV systems ! Self evaluation Describe process of cogeneration and explain advantages of cogeneration Define efficiency of cogeneration regarding to electricity production in thermal power plant ! Describe technologies of cogeneration ! How wind potential is determined ? Describe technologies of small wind turbines ! Draw power curve of wind turbines versus wind velocity ! Explain how to calculate yearly produces electricity with small wind turbine ! What are fuel cells and how they work ? Describe types of fuel cells and their efficiency ! Describe how FC can be used as cogeneration system in buildings ! Literature/References M. J. Moran, H. N. Shapiro: Fundamentals of Engineering Thermodinamics; John Wiley & Sons, USA, 1998 Hsieh J.; Solar Energy Engineering, Prentice Press, 1986 Johanson et. All.; Renewable Energy; Sources for Fuels and Electicity, Island Press; 1993 B. Lenz, J. Schreiber, T. Stark; Sustainable building services, Detail Green Books; Germany, 2011 Daniels K., Hammann R.; Energy Design for Tomorrow, Axel Menges, 2008 RETSCreen simulation tool SunWorld Magazine SunandWind Magazine Source: http://www.dansksolenergi.dk; http://www.concerto-sesac.eu; http://www.solarpv.co.uk; http://photovoltaic-shingles.com; http://drexelcorp.wordpress.com References L.D.D. Harvey; “A handbook on Low-Energy Buildings and District-Energy Systems, Earthscan, UK 2006 B. Sorensen; Renewable energy conservation, transmission and storage; Elsevier, USA, 2007 B. Lenz, J. Schreiber, T. Stark; Sustainable building services, Detail Green Books; Germany, 2011 K. Nishizaki; The Japanese experience in micro CHP for residential use, 2008 K. Daniels, R. E. Hammann; Energy Design for Tomorrow; Edition Axel Menges; Germany, 2008 www.viesmann.de
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