Acta Geologica Hungarica, Vol. 45/4, pp. 359371 (2002) Paleogene igneous activity along the easternmost segment of the Periadriatic-Balaton Lineament Kálmán Benedek Department of Petrology and Geochemistry, Eötvös University, Lithosphere Fluid Research Laboratory, Budapest In the Pannonian Basin three Paleogene igneous regions can be outlined, namely the Zala Basin Shear Zone, the Velence Mts and the Recsk Region. These igneous regions are aligned along the easternmost Periadriatic-Balaton Lineament System. The igneous bodies are built up mostly by effusive rocks (andesite, dacite and basaltic andesite); however, intrusive rocks (tonalite, diorite) have been identified as well. The radiometric age of the effusive and intrusive rocks is scattered around 30 Ma, which falls into the range of the igneous bodies aligned along the Periadriatic Line (Bergell, Adamello, Riesenferner, Karawanke, etc.). Nevertheless, an Eocene onset of the magmatic activity in the Pannonian Basin is accepted on the basis of biostratigraphic data. As major and trace element composition range of the Paleogene igneous suites in the Pannonian Basin are basically the same, they are thought to have undergone the same pre-crystallization history. Geochemical characteristics of these calc-alkaline igneous rocks suggest that the magmatic activity represents a post-syncollisional volcanic arc environment. Key words: Paleogene, igneous rocks, Pannonian Basin, geochemistry, age, Periadriatic-Balaton Magmatic Belt Introduction The Periadriatic Line (PL), one of the most spectacular geologic formations in the Alps, developed as a result of dextral transpression (Schmid et al. 1989). As a consequence of the Cretaceous closure of the Tethys, oceanic lithosphere was subducted southward beneath the African microplate (Schmid et al. 1996). The age of the magmatic activity along the PL is scattered around 30 Ma (von Blanckenburg and Davies 1995), which postdates collision between Europe and Africa (Schmid et al. 1996). Therefore, these igneous rocks are post-syncollisional and not related to active subduction (Kagami et al. 1991; Schmid et al. 1996; Pamic and Palinka 2000). The Periadriatic-Balaton Magmatic Belt (PBMB) is built up mostly by intrusive bodies (Bergell, Adamello, Riesenferner, Karawanke, etc.); however, either dykes (lamprophyre, shoshonite and andesite) in the Alps (Deutsch 1984; Venturelli et al. 1984) or eroded pebbles of effusive rocks (mostly andesite and dacite) in the Perialpine molasses (Frisch et al. 1998; Benedek et al. 2001) are present. Address: Received: K. Benedek: H-1117 Budapest, Pázmány Péter sétány 1/c., Hungary e-mail: [email protected] 2 April, 2002 02365278/2002/$ 5.00 © 2002 Akadémiai Kiadó, Budapest 360 K. Benedek The pre-Neogene basement of the Pannonian Basin is built up by two megatectonic units: the ALCAPA Terrane in the north and the Tisia Terrane in the south (Csontos 1995; Kovács et al. 2000). The ALCAPA Terrane includes the Bakonyia Terrane, whose southern boundary is outlined by the Balaton Lineament, which is accepted to be the eastern continuation of the PL (Kázmér and Kovács 1985; Fodor et al. 1998; Haas et al. 2000). The Bakonyia Terrane was displaced horizontally eastward in the early Miocene (Majoros 1980; Tari et al. 1993; Fodor et al. 1998; Frisch et al. 1998) as a consequence of continental convergence between the Adriatic microplate (Africa) and stable Europe. Thus, the position of the Bakonyia Terrane at 30 Ma was somewhere between the Eastern and Southern Alps (Kázmér and Kovács 1985; Frisch et al. 1998, Fig. 2b). Along the extensively deformed zone of the easternmost Periadriatic-Balaton Lineament System (PBLS) three Paleogene igneous regions can be outlined in the Pannonian Basin from SW to NE (Csillag et al. 1980; Zelenka et al. 1983): the Zala Basin Shear Zone (ZBSZ), the Velence Mts and the Recsk Region (Fig. 1). The aim of the present paper is to give an overview of the easternmost segment of the PBMB, focusing only on the lava rocks. Note that explosive rocks are also present in the Pannonian Basin (Fig. 1); however, they are beyond the scope of the paper. Geological background and petrography Zala Basin Shear Zone (ZBSZ) The Mesozoic basement, consisting mainly of Triassic and Cretaceous units, and Eocene sequences in the ZBSZ are covered by thick Miocene sediments (Kõrössy 1988). The Paleogene igneous series were divided into two subgroups by Benedek (2002). In the south (PusztamagyaródNagybakónak Zone), intrusive rocks (tonalite and minor diorite) have been identified in drilling cores (Fig. 1). The northern boundary of the intrusive body is outlined by a characteristic dextral strike-slip fault. The intrusive rocks show hypidiomorphic texture and consist of plagioclase, amphibole, biotite, quartz, rutile, apatite, zircon, opaque minerals, rare potassium feldspar and garnet. In the tonalite, rare mafic enclaves (max. size of 20 cm in diameters) occur with texture identical to that of their host rock. In contrast, the northern segment of the ZBSZ (BakNova half-graben) is mostly characterized by andesite, dacite and explosive igneous rocks (Fig. 1). These rocks, showing porphyritic texture, contain plagioclase, amphibole, biotite, quartz, clino- and orthopyroxene, opaque minerals, rutile, apatite, zircon and garnet. Andesite and dacite contain abundant mafic inclusions of rounded or irregular shape and chilled texture. Benedek (2002) suggested that a portion of the andesite and dacite is dyke-like in appearance. It was concluded by the author (Benedek 2002) that the ZBSZ did not function uniformly in tectonic aspects during the Paleogene; thus, effusive and intrusive Acta Geologica Hungarica 45, 2002 50km N Lak A N la E a eB I ton MID Mór 32.3 ± 1.0 32.0 ± 1.4 Ad-2, -3 Ság-2 44.2 ± 3.4 39.9 ± 4.1 35.4 ± 4.3-(50.5 ± 4.4) V E L E N C E M T S . O N Bfv-1 A T 30.7 ± 1 B A L Á Z A L A - B A S I N S H E A R Z O N E Sümeg R B L s de ar i Alps in D Eastern Carpa E L I N Pannonian Basin Si-1, and -2 Bu-2, and -3 Úh-1 Bakony Mts. 29.1 ± 1.2-(37.8 ± 1.4) 31.2 ± 1.4-32.9 ± 1.3 36.8 ± 2.6; 42.5 ± 2.6 33.2 ± 1.8-38.7 ± 3.0 Csv-18 32.7 ± 4.7 34.8 ± 3.7 Tó-1 20°E R E C S K R E G I O N 37 ± 10 th P E S T P L A I N B U D A M T S . 32.2 ± 0.9 Kl-1 Budapest 34.3 ± 1.3 32.5 ± 0.5 Bö-1 Kálvária hill 36 ± 17 Ci-2 19°E ia n s Fig. 1 Locations of Paleogene magmatic rocks in the Pannonian Basin with a compilation of available geochronological data (Baksa, 1975; Balogh, 1985; Nagymarosy et al. 1986; Darida-Tichy 1987; Horváth and Tari 1987; Dunkl and Nagymarosy 1992; Benedek 2002) 33.9±1.4 33.0±1.5 30.4±1.5 28.6±1.8 27.9±1.3 34.9±1.4 31.6±1.3 31.1±2.8 29.3±1.2 31.6±1.3 34.9±1.4 33.9±1.3 27.3±1.1 32.5±1.4 27.1±1.4 26.0±1.2 27.9±1.1 47°N 18°E boreholes penetrating Paleogene effusive rocks data from stratigraphic evidence K/Ar, U/Pb data from massive boreholes penetrating Paleogene intrusive rocks magmatic rocks transcurrent fault zone FT data from massive magmatic rocks FT, K/Ar, Ar/Ar data from tuff layers cities of Tertiary sediments R E C S K main exposure areas of the Paleogene Surface/subsurface outcrops of igneous regions volcanic rocks 17°E H A G N U N A I R A D Ó N R E N I L 48° N Paleogene igneous activity along the easternmost segment of the Periadriatic-Balaton Lineament 361 Acta Geologica Hungarica 45, 2002 362 K. Benedek suites were juxtaposed during the escape period of the Bakonyia Terrane. The andesitic and dacitic series was placed by Frisch et al. (1998) to the southeast of the hidden Tauern Window. The intrusive series was eastward relative to the effusive zone at 30 Ma, very close to the location of the recent Karawanke tonalite. The intrusive zone most likely represents a strike-slip duplex due to the Miocene dextral displacement along the PBLS. Velence Mts The effusive material of the Velence Mts (Fig. 1) is partly buried by Neogene clastic sediments. In rising to the surface, the magma intersected Lower Paleozoic slates, Carboniferous granites and Permo-Triassic carbonate sediments (DaridaTichy 1987). In the central part of the volcanic area hydrothermally altered rocks occur at the surface. In this area the original rocks, which could have been pyroclastics and lavas, were affected by multiphase alteration (Molnár 1996). Close to this volcanic center, a small dioritic subvolcanic body has been penetrated (Pázmánd-2). Józsa (1983) described abundant andesitic dyke swarms crosscutting the adjacent Carboniferous granite. The lava rocks include andesites and basaltic andesites, but basalts, dacites and trachyandesites were also described (Darida-Tichy 1987). The porphyiritic constituents are represented by plagioclase, amphibole, biotite, clino- and orthopyroxene, quartz and, in some samples, garnet. Mafic inclusions of chilled texture are hosted by a variety of different effusive rocks (Józsa 1983). Recsk region During the Paleogene a calc-alkaline subvolcanic body and its dykes (Fig. 1) were emplaced into Triassic carbonates (Baksa 1975) in the Recsk region. In the central part of the area subvolcanic andesite (and diorite) has been identified. In the porphyritic andesite plagioclase, amphibole, biotite, apatite, rutile, quartz and opaque minerals are the main rock-forming minerals. The primary rocks (andesite, diorite) were affected by different secondary alterations (for details see Baksa 1975). The carbonate host rock was thermally altered by the subvolcanic body. Contemporaneously, an andesitic stratovolcano was built up on the surface. The basement of the volcanic succession is Triassic limestone (Földessy 1975). The volcano consists of lava and pyroclastic rocks. The lava is mainly porphyritic andesite containing plagioclase, amphibole, biotite, quartz, opaque minerals, garnet, zircon and apatite. The entire volcanic succession is crosscut by subsequent andesitic dykes. Acta Geologica Hungarica 45, 2002 Paleogene igneous activity along the easternmost segment of the Periadriatic-Balaton Lineament 363 The age of the Paleogene igneous rocks Zala Basin Shear Zone Eocene marl was deposited over the Mesozoic basement in the ZBSZ, the upper part of which (Bartonian) was interfingered with volcanogenic sediments (Kõrössy, 1988). The marl deposited between the NP (nannoplancton) 15/16 zone boundary and NP18 (about 4243 and 38Ma) and the oldest volcanoclastic layers are known from the NP16 zone (about 4243 Ma; Nagymarosy, pers. com.). Based on this observation, the entire volcanic succession was accepted as Eocene (Kõrössy 1988). However, new K/Ar data measured on mineral separates (amphibole, biotite, plagioclase) from the intrusive and effusive rocks, are scattered from 28.6±1.8 Ma to 33.9±1.4 Ma and from 26.0±1.2 Ma to 34.9±1.4 Ma, respectively (Fig. 1, Benedek 2002). As Eocene sediments have not been identified over the intrusive rocks in the southern part of the ZBSZ (Kõrössy 1988), the radiometric ages are considered to be the formation ages. On the other hand, a detailed petrographic study of effusive rocks in the northern part of the ZBSZ, an XRD study and paleontological data of the interfingering Eocene marl deposits suggest that simultaneous emplacement of the effusive and the sedimentary rocks is doubtful. It is suggested that the andesite and dacite were emplaced as dykes in the Eocene marl; thus, the effusive rocks can be considered to be of Oligocene age as indicated by radiometric data. It is noteworthy that also Balogh et al. (1983) reported an Oligocene K/Ar age 30.7±1 Ma) of a small tonalite body on the NE of the Zala Basin shear zone along the Balaton Line (Balatonfenyves). Velence Mts The onset of the volcanic activity in the Velence Mts is emplaced in the Middle Eocene by observing the interfingering oldest tuffaceous layers and the shallow marine Middle Eocene sediments (Darida-Tichy 1987). However, the radiometric age determination of the massive andesite and subvolcanic diorite yielded 29.1±1.2 Ma and 31.2±1.4 Ma, respectively (Balogh 1985), which suggests the presence of Oligocene igneous rocks, too (Fig. 1). Recsk region Unfortunately, few detailed radiometric age data of the subvolcanic body and the stratovolcano of the Recsk region have been published. The subvolcanic body of Recsk is considered to be Priabonian, because its basement and cover fall into the Nummulites fabianii zone. Up to the present only one radiometric age (37±10 Ma) of the subvolcanic andesite has been published (Baksa 1975, Fig. 1). Similarly to the subvolcanic body, the age of the andesitic stratovolcano of Recsk has been accepted to be Priabonian on the basis that the volcanic material of the stratovolcano intercalates with marine sediments which contain Acta Geologica Hungarica 45, 2002 364 K. Benedek Nummulites fabianii (Földessy 1975). Also the basement and the cover of the stratovolcano contain of Nummulites fabianii. However, it is important to note that some pyroclastic layers are thought to be Oligocene in age (Földessy 1975). Geochemistry Whole rock geochemistry The compilation of available major and trace element data (Downes et al. 1995; Benedek, 2002) suggests that there is no significant difference in the geochemical range of the igneous suites from the ZBSZ, Velence Mts. and the Recsk region (Figs 2, 3). This implies that these samples underwent a similar pre-crystallization evolution. The K2OSiO2 and the AFM (not shown) diagram of the igneous rocks show that the analyzed samples fall in the field of high-K to medium-K calcalkaline series. The studied samples range from basaltic andesite through andesite to dacite; thus, truly primitive, basaltic and highly evolved rhyolitic magmas have not been found. Values of TiO2, Al2O3, Fe2O3 and MgO decrease with increasing SiO2, whereas Na2O increases (not shown). These general trends of calc-alkaline magmas are thought to be consistent with fractionation of main rock-forming minerals (plagioclase, olivine, clinopyroxene, amphibole, Downes 16 K2O+Na2O wt% 14 Phonolite 12 Tephriphonolite 10 8 Ttrachydacite Phonotephrite Foidite Tephrite Basanite 6 Rhyolite Trachyandesite Basaltic trachyandesite Trachybasalt 4 Dacite Basalt Andesite Picrobasalt 2 40 45 Basaltic andesite 50 55 SiO2 wt% 60 65 70 75 Fig. 2 Na2O+K2O (wt%)-SiO2 (wt%) diagram of the Paleogene magmatic rocks in the Pannonian Basin. Analytical data were taken from Downes et al. (1995) and Benedek (2002). Legend: X intrusive rocks from the Zala Basin shear zone, O effusive rocks from the Zala Basin shear zone, n Recsk region (andesite), p Velence Mts (andesite) et al. 1995). Alternatively, magma mixing process can also be responsible for similar trends (Gill 1981). Trace element values of Ni, Cr in the samples studied are low (Ni=4128 ppm, Cr=10155 ppm) and do not correlate with SiO2. The highest concentrations of Acta Geologica Hungarica 45, 2002 Paleogene igneous activity along the easternmost segment of the Periadriatic-Balaton Lineament 100 Sample/MORB Fig. 3 MORB-normalized (Sun and McDonough 1989) trace element pattern of the Paleogene magmatic rocks in the Pannonian Basin. Analytical data were taken from Downes et al. (1995) and Benedek (2002). Legend: dashed lineintrusive rocks from the Zala Basin shear zone, solid lineeffusive rocks from the Zala Basin shear zone, n Recsk region, p Velence Mts 365 10.0 1.00 0.10 0.01 Sr K Rb Ba Th NbCe P Zr Sm Ti Y Yb Sc Cr Ni Ni and Cr were found in a pyroxene-amphibole andesite from the Velence Mts, and diorites from the ZBSZ. Th, Rb and Sr (LILE) behave incompatibly throughout the entire magmatic suite in the MORB-normalized trace element diagram (Fig. 3). All samples are depleted in Nb relative to Ce and Th which is a characteristic feature of subduction-related magmatic rocks (Downes et al. 1995). The Lan/Ybn ratio is 423 in intrusive and 525 in effusive rocks; the Ce/Yb ratio is 1355 in intrusive and 1365 in effusive rocks. These ratios are within the characteristic range of melting in a garnet-bearing source region (Patino et al. 2000). Benedek (2002) compared the composition of intrusive rocks (tonalite, diorite) from the ZBSZ to that of some Periadriatic plutons. Close geochemical similarity of the Karawanke (~30 Ma; Scharbert 1975) and the intrusive rocks from the ZBSZ has been successfully demonstrated. It is noteworthy that Karawanke tonalite is similar in composition to other Paleogene tonalite bodies along the PL, such as Bergell, Adamello, and Riesenferner. However, the Pohorje tonalite (Pamic and Palinka 2000) is enriched in LILE, La, and Ce relative to those of other Periadriatic intrusives, suggesting a slightly different evolution. Furthermore, the age of this intrusive body is early Miocene (Deleon 1969; Márton et al. 2002). The close analogy of the age data and geochemistry of the Periadriatic intrusives including Karawanke (Scharbert 1975; Blanckenburg and Davies 1995), and the intrusive rocks from the ZBSZ supports a genetic relationship between these bodies. Acta Geologica Hungarica 45, 2002 366 K. Benedek Clinopyroxene as an indicator of tectonic environment Clinopyroxene is one of the first crystallizing phases in igneous environments and its composition can reflect initial composition of coexisting melt. The low (0.03010.0512) Al2O3/SiO2 ratio of clinopyroxenes studied in andesite from the ZBSZ and the Velence Mts. (Downes et al. 1995; Benedek 2002) reflects tholeiitic or calc-alkaline primary magma (LeBas 1962). Leterrier et al. (1982) constructed a series of discriminant diagrams in order to distinguish magmatic host rocks based on the composition of clinopyroxenes. These diagrams confirm that the samples have been originated from an orogenic calc-alkaline suite (Fig. 4). Using discriminant functions of Nisbet and Pearce (1977), clinopyroxene composition data fall within the field of volcanic arc basalts and oceanic floor basalts (Fig. 4), though the oceanic floor basalt origin can be excluded based on the geological background (Frisch et al. 1998). The relationship of intrusive and effusive igneous rocks In the ZBSZ the intrusive and effusive rocks have a similar radiometric age. As their whole rock composition range is basically the same, a series of hydrous mineral analyses (amphybole, biotite) has been carried out in order to compare their crystallization history. Amphiboles and biotites in the intrusive rocks are fresh, whereas in the effusive rocks they vary from unaltered to corroded, remelted or opaquemineral-rimmed even in the same thin section. Amphibole phenocrysts are magnesium-hornblende in the intrusive samples, whereas in effusive rocks they are tschermakite based on the classification of Leake et al. (1997). The log (XF/XCl) vs. XMg diagram (Fig. 5; Munoz and Swenson 1981; Munoz 1984; Morrison 1991) for hydrous minerals is a very informative tool to compare halogen composition of a variety of different igneous rocks. The diagram shows that amphiboles and biotites have a higher XF/XCl ratio in effusive rocks than in intrusive rocks. Some of the effusive amphiboles and biotites developed a thin, Fe-Ti-oxide-rich, corroded or remelted rim (Benedek and Szabó 2000), which indicates that they were outside of their stability field and re-equilibrated when the magma was ascending to the surface. Rutherford and Hill (1993) described a similar reaction rim around amphibole from the Mount St. Helens (USA) in dacite and explained the texture as a consequence of decreasing H2O in the coexisting melt (degassing) while rising to the surface. Therefore, it is most likely that the amphibole and biotite in effusive rocks from the ZBSZ were incapable of being in equilibrium with coexisting melts. As fluorine is generally partitioned into the melt phase and chlorine into the separated fluid phase during degassing of magma (Dingwell et al. 1985; Webster and Holloway 1990; Caroll and Webster 1994), it is expected to see increasing fluorine and decreasing chlorine content in the melt phase. This process provides a reasonable explanation for higher Acta Geologica Hungarica 45, 2002 Paleogene igneous activity along the easternmost segment of the Periadriatic-Balaton Lineament 0.18 Ti A 0.09 Alkaline basalt Tholeiitic or calc-alkaline basalt 0 0.5 0.05 0.8 Ca+Na 1.1 B Non-orogenic basalt 0.25 0 Orogenic basalt 0 0.75 Ca -1.2 -1.1 -1 1 -0.9 C -0.8 VAB WPA F2 Ti+Cr Fig. 4 Discrimination diagrams of clinopyroxenes studied in andesite from the Zala Basin shear zone and the Velence Mts. (Downes et al. 1995; Benedek 2002). (A-B) The host magma of the clinopyroxenes studied is tholeiitic or calc-alkaline in character and the magmatism took place in an orogenic environment (Leterrier et al. 1982). The elements are calculated as cationic values. (C) The composition of the clinopyroxenes studied fall within the field of volcanic arc basalt and oceanic floor basalt. Discriminant functions (F1, F2) were calculated after Nisbet and Pearce (1977). Abbreviations: volcanic arc basalt (VAB), oceanfloor basalt (OFB), withinplate tholeiitic basalt (WPT), within plate alkalic basalt (WPA). Legend: O effusive rocks from the Zala Basin shear zone, p Velence Mts 367 OFB -0.7 -2.4 VAB OFB -2.5 -2.6 WPT F1 fluorine and lower chlorine content in amphiboles and biotites from the effusive rocks compared to those in intrusive rocks. As the intrusive bodies were crystallized completely a deep magma chamber (about 715 km using Al-in hornblende geobarometers; Benedek and Szabó 2000, using methods of Hammarstrom and Zen 1986; Hollister 1987; Johnson and Rutherford 1988; Schmidt 1992); therefore, significant volatile loss could not occur during their evolution. On the other hand, the fluid composition in the melts of the effusives could undergo partitioning on the way to the surface, slowly becoming fluorine rich. These phenomena can be explained in that effusive volcanism took place on an extensively faulted and fractured lithosphere relative to the intrusive magmatism. Acta Geologica Hungarica 45, 2002 368 K. Benedek 1.8 Amphibole Conclusions log (XF/XCl) log (XF/XCl) Paleogene igneous occurrences in the Pannonian Basin are aligned along the SWNE trending Peri0.6 adriatic-Balaton Lineament System. Based on the published data, the 0 following conclusions can be 0.5 0.6 drawn: X Mg 1. Paleogene igneous rocks in the 2 Pannonian Basin are represented Biotite by effusive (basaltic andesite, 1.5 andesite, dacite, trachyandesites) 1 and intrusive (tonalite, diorite) rocks. 0.5 2. The radiometric age of the 0 igneous rocks dated is mostly Oligocene (around 30 Ma), though -0.5 0.3 0.4 0.5 0.6 stratigraphic data suggest Eocene X Mg onset of the Paleogene magmatic activity, too. Fig. 5 3. The chemical composition Log (XF/XCl) vs. XMg plot of amphibole and biotite range of the igneous rocks from the compositions from the intrusive and effusive rocks studied volcanic regions is similar in the Zala Basin shear zone (Benedek 2002). Cl, F and it is analogous to other igneous and Mg are given in mole fraction. Legend: Xintrusive rocks from the Zala Basin shear zone, Orocks aligned along the Periadriatic effusive rocks from the Zala Basin shear zone Lineament in the Alps. 4. The presence of intrusive and effusive rocks indicates that magmatic activity was taking place under differing tectonic environments. 5. Based on radiometric age and geochemical data, Hungarian Paleogene igneous rocks are suggested to be the easternmost prolongation of the Periadriatic-Balaton Magmatic Belt. 1.2 Acknowledgements Csaba Szabó (ELTE) is thanked for comments and the helpful review of the manuscript. József Jósvai and Csaba Bokor (Hungarian Oil Company, MOL Rt.) are gratefully acknowledged for useful comments and for permission to publish this work. The author is also grateful to L. Fodor (MÁFI), A. Nagymarosy (ELTE), I. Dunkl (University of Tübingen) and Zs. Nagy (University of Missouri-Rolla) for helpful comments. The author also thanks T. Zelenka (Hungarian Geological Survey) and J. Pamic (Croatian Academy of Sciences) for their helpful reviews. 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