SAFETY DATA SHEET
PRODUCT NAME: Foamplus® B5504
EFFECTIVE DATE: 12/9/2015
DISTRIBUTOR: Storopack, Inc., Cincinnati, Ohio
SECTION 1: IDENTIFICATION
PRODUCT NAME: Foamplus® B5504
OTHER MEANS OF IDENTIFICATION: Foamplus® B component, Foamplus® poly, Rimline® SA 97045
RECOMMENDED USE AND RESTRICTIONS: Reactant to produce foam-in-place packaging
DISTRIBUTOR INFORMATION:
STOROPACK, INC.
4758 Devitt Drive
Cincinnati, OH 45246
WEBSITE: www.storopack.us
TELEPHONE NUMBER:
Main Office: 513-874-0314
HMIS RATINGS
SECTION 2: HAZARD IDENTIFICATION
GHS Classification:
Serious eye damage:
Category 1
GHS Label element
Hazard Pictogram:
Signal Word:
Danger
NFPA RATINGS
Hazard Statements:
H303 May be harmful if swallowed.
H318 Causes serious eye damage.
Precautionary Statements:
Prevention:
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician
if you feel unwell. Rinse mouth.
P301 + P312 + P330 + P310 IN IN EYES. Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste disposal plant
Other hazards: The following percentage of the mixture consists of ingredient(s) with unknown acute
toxicity: 1.637 %
SECTION 3: COMPOSITION
Chemical Name
CAS Number
Polyether polyol
Poly(oxy-1,2-ethanediyl),.alpha.-tridecyl-.omega.-hydroxy
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine)
Not assigned
24938-91-8
3033-62-3
Composition %
1-3%
13-30%
0.1-1%
IMPURITIES AND ADDITIVES: Non-hazardous components present at less than 3% are not listed. The exact
percentage of composition has been withheld as a trade secret.
SECTION 4: FIRST AID MEASURES
General advice:
Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled:
In case of eye contact:
If swallowed:
If unconscious place in recovery position and seek medical advice.
If symptoms persist, call a physician.
Small amounts splashed into eyes can cause irreversible tissue damage
and blindness.
In the case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Most important symptoms and effects, both acute and delayed: None known.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training.
First Aid responders should pay attention to self-protection and use the
recommended protective clothing
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation.
Notes to physician:
Symptomatic and supportive therapy as needed. Following severe exposure
medical follow-up should be monitored for at least 48 hours.
The first aid procedure should be established in consultation with the doctor
responsible for industrial medicine.
SECTION 5: FIRE-FIGHTING MEASURES
Suitable extinguishing media:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Unsuitable extinguishing media:
None known.
Specific hazards during fire fighting:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion products:
Carbon dioxide (CO2)
Carbon monoxide
Specific extinguishing methods:
No data is available on the product itself.
Further information:
Standard procedure for chemical fires.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations.
Special protective equipment:
for fire-fighters
Wear an approved positive pressure self-contained breathing for
apparatus in addition to standard fire fighting gear.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment.
Environmental precautions:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for containment and cleaning up:
Soak up with inert absorbent material (e.g. sand, silica gel, acid
binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
SECTION 7: HANDLING AND STORAGE
Storage Temperature:
Storage Period:
10-30˚C (50-86˚F)
6 months
Advice on protection against fire and explosion:
Normal measures for preventive fire protection.
Advice on safe handling:
Do not breathe vapors/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Dispose of rinse water in accordance with local and
national regulations.
Conditions for safe storage:
Keep container tightly closed in a dry and well-ventilated
place.
Electrical installations / working materials must comply
with the technological safety standards.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ingredients with workplace control parameters
Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator.
Hand protection remarks: The suitability for a specific workplace should be discussed with the producers of
the protective gloves.
Please observe the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into consideration the
specific local conditions under which the product is used, such as the danger of
cuts, abrasion, and the contact time.
Eye protection:
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing problems.
Please follow all applicable local/national requirements when selecting protective
measures for a specific workplace.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Skin and body protection: impervious clothing
Choose body protection according to the amount and concentration of the
dangerous substance at the work place.
Hygiene measures:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday
It is good practice in industrial hygiene to avoid contact with solvents by using
appropriate protective measures whenever possible.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Color:
Odor:
Odor Threshold:
pH:
liquid
light yellow
amine-like
No data is available on the product itself.
No data is available on the product itself.
Flash point:
> 250 °F Seta closed cup
Evaporation rate:
No data is available on the product itself.
Flammability (solid, gas): No data is available on the product itself.
Upper explosion limit:
No data is available on the product itself.
Lower explosion limit:
No data is available on the product itself.
Vapor pressure:
No data is available on the product itself.
Relative vapor density: No data is available on the product itself.
Relative density:
1.03
Density:
No data is available on the product itself.
Solubility(ies):
No data is available on the product itself.
Partition coefficient: n-octanol/water: No data is available on the product itself.
Autoignition temperature:No data is available on the product itself.
Thermal decomposition: No data is available on the product itself.
Viscosity:
420 mPa.s (21 °C) dynamic
Self-Accelerating decomposition temperature (SADT): No data is available on the product itself.
SECTION 10: STABILITY AND REACTIVITY
Reactivity:
Chemical stability:
Possibility of hazardous reactions:
Conditions to avoid:
No
No
No
No
decomposition if stored and applied as directed.
decomposition if stored and applied as directed.
decomposition if stored and applied as directed.
data available
SECTION 11: TOXICOLOGICAL INFORMATION
Information on likely routes of exposure: No data is available on the product itself.
Acute toxicity
Acute oral toxicity - Product:
Acute toxicity estimate: 1,832 mg/kg
Method: Calculation method
Acute inhalation toxicity:
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-:
LC50 (Not Assigned): 1.5 - 20.7 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine):
LC50 (Rat, male and female): > 2.204 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Method: OECD Test Guideline 403
LC50 (Rat, male and female): 4 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Acute dermal toxicity – Product: Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute toxicity (other routes of administration): No data available
Skin corrosion/irritation
Product:
Extremely corrosive and destructive to tissue
Serious eye damage/eye irritation
Product:
May cause irreversible eye damage
Respiratory or skin sensitization
Ingredients:
Polyether polyol:
Routes of exposure: Skin
Species: Guinea pig
Assessment: Does not cause skin sensitization.
Method: OECD Test Guideline 406
Result: Does not cause skin sensitization.
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-:
Routes of exposure: Skin
Species: Guinea pig
Result: Does not cause skin sensitization.
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine):
Routes of exposure: Skin
Species: Guinea pig
Method: OECD Test Guideline 406
Result: Does not cause skin sensitization.
Assessment: No data available
Germ cell mutagenicity
Ingredients:
Polyether polyol: Genotoxicity in vitro:
Test Type: Ames test
Species: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: Chromosome aberration test in vitro
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Species: Chinese hamster cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-: Genotoxicity in vitro:
Result: negative
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine):Genotoxicity in vitro:
Concentration: .08 - .18 mg/ml
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 479
Result: Not classified due to inconclusive data.
Metabolic activation: negative
Method: OECD Test Guideline 482
Result: negative
Ingredients:
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Genotoxicity in vivo:
Application Route: Intraperitoneal injection
Dose: 45 - 145 mg/kg
Method: OECD Test Guideline 474
Result: negative
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-: Genotoxicity in vivo:
Result: negative
Carcinogenicity
Ingredients:
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-:
Species: Not assigned
Result: Negative
Carcinogenicity - Assessment:
No data available
IARC
No ingredient of this product present at levels greater than or equal to
0.1% is identified as probable, possible or confirmed human carcinogen by
IARC.
ACGIH
No ingredient of this product present at levels greater than or equal to
0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
OSHA
No ingredient of this product present at levels greater than or equal to
0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No ingredient of this product present at levels greater than or equal to
0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Ingredients:
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-:-: Effects on fertility:
Species: Rat, male and female
Application Route: Oral
Method: OECD Test Guideline 421
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Effects on fetal development:
Species: Rabbit
Application Route: Dermal
General Toxicity Maternal: NOAEL (No observed adverse effect level): >=
12 mg/kg body weight
Method: OECD Test Guideline 414
Result: Teratogenic effects.
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-: Effects on fetal development:
Species: Rat, male and female
Application Route: Oral
General Toxicity Maternal: NOAEL (No observed adverse effect level): 50
mg/kg body weight
Result: No teratogenic effects.
Species: Rat, male and female
Application Route: Dermal
General Toxicity Maternal: NOAEL (No observed adverse effect level): 50
mg/kg body weight
Result: No teratogenic effects.
Reproductive toxicity - Assessment:
No data available
STOT-single exposure:
No data available
STOT-repeated exposure:
No data available
Repeated dose toxicity
Ingredients:
Polyether polyol:
Species: Rat, male and female
NOAEL (No observed adverse effect level): >= 1000 mg/kg
Application Route: Oral
Exposure time: 31 Days
Number of exposures: 11 hours/day
Method: OECD Test Guideline 407
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-:
Species: Not Assigned
Application Route: Skin contact
Species: Rat, male and female
NOAEL (No observed adverse effect level): > 100 mg/kg
Application Route: Ingestion
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Species: Rat, male and female
NOEC: 8.2 mg/m3
Application Route: Ingestion
Test atmosphere: vapor
Exposure time: 336 h
Number of exposures: 6 h
Method: Subacute toxicity
Repeated dose toxicity - Assessment: No data available
Aspiration toxicity
No data available
Experience with human exposure
General Information:
No data available
Inhalation:
No data available
Skin contact:
No data available
Eye contact:
No data available
Ingestion:
No data available
Toxicology, Metabolism, Distribution
Neurological effects
No data available
Further information
No data available
No data available
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Polyether polyol: Toxicity to fish: LC50 (Leuciscus idus (Golden orfe)): > 1,000 mg/l
Exposure time: 96 h
Test Type: semi-static test
Test substance: Fresh water
Method: OECD Test Guideline 203
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Toxicity to fish:
LC50 (Brachydanio rerio (zebrafish)): ca. 131.2 mg/l
Exposure time: 96 h
Test Type: semi-static test
Test substance: Fresh water
Method: OECD Test Guideline 203
Ingredients:
Polyether polyol: Toxicity to daphnia and other aquatic invertebrates:
EC50 (Daphnia magna (Water flea)): > 100 mg/l
Exposure time: 48 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 202
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Toxicity to daphnia and other aquatic invertebrates:
EC50 (Daphnia magna (Water flea)): 102 mg/l
Exposure time: 48 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 202
Ingredients:
Polyether polyol: Toxicity to algae:
LC50 (Desmodesmus subspicatus (Scenedesmus subspicatus)): > 100 mg/l
Exposure time: 96 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 201
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Toxicity to algae:
ErC50 (Selenastrum capricornutum (green algae)): 24 mg/l
Exposure time: 72 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 201
M-Factor (Acute aquatic toxicity): No data available
Toxicity to fish (Chronic toxicity): No data available
Ingredients:
Polyether polyol: Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity):
NOEC (Daphnia magna (Water flea)): >= 10 mg/l
Exposure time: 21 d
Test Type: semi-static test
Test substance: Fresh water
Method: OECD Test Guideline 211
M-Factor (Chronic aquatic toxicity): No data available
Ingredients:
Polyether polyol: Toxicity to bacteria:
IC50 (activated sludge): > 10,000 mg/l
Exposure time: 3 h
Test Type: static test
Test substance: Fresh water
Method: OECD Test Guideline 209
Toxicity to soil dwelling organisms: No data available
Plant toxicity: No data available
Sediment toxicity: No data available
Toxicity to terrestrial organisms: No data available
Ecotoxicology Assessment
Acute aquatic toxicity: No data available
Chronic aquatic toxicity: No data available
Toxicity Data on Soil: No data available
Other organisms relevant to the environment: No data available
Further information:
The following percentage of the mixture consists of ingredient(s) with unknown hazards to the aquatic
environment: 1.637 %
Persistence and degradability
Ingredients:
Polyether polyol: Biodegradability:
Test Type: aerobic
Concentration: 100 mg/l
Result: Inherently biodegradable.
Biodegradation: 1.9 %
Exposure time: 28 d
Method: Inherent Biodegradability: Modified SCAS Test
Test Type: aerobic
Concentration: 20 mg/l
Result: Not readily biodegradable.
Biodegradation: 40 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
Test Type: aerobic
Inoculum: Mixture
Result: Inherently biodegradable.
Biodegradation: 22 %
Exposure time: 28 d
Method: ISO 5815
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Biodegradability:
Inoculum: activated sludge
Result: Inherently biodegradable.
Biodegradation: < 10 %
Exposure time: 28 d
Method: OECD Test Guideline 302B
Inoculum: activated sludge
Result: Not readily biodegradable.
Biodegradation: 2 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
Ingredients:
Polyether polyol: Biochemical Oxygen Demand (BOD):
355 mg/g
Ingredients:
Polyether polyol: Chemical Oxygen Demand (COD):
1,600 mg/g
BOD/COD: No data available
ThOD: No data available
BOD/ThOD: No data available
Dissolved organic carbon (DOC): No data available
Physico-chemical removability: No data available
Stability in water: No data available
Photodegradation: No data available
Impact on Sewage Treatment : No data available
Bioaccumulative potential
Ingredients:
Polyether polyol:Bioaccumulation: Does not bioaccumulate.
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Bioaccumulation: Bioaccumulation unlikely
See user defined free text
Ingredients:
Polyether polyol: Partition coefficient: n-octanol/water:
Pow: 0.73 - 1.82 (25 °C)
pH: > 12
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): -: Partition coefficient: n-octanol/water:
log Pow: -0.34 (20 °C)
Method: Partition Coefficient
Mobility in soil
Mobility: No data available
Ingredients:
N,N,N’,N’-tetramethyl-2,2’-oxybis(ethylamine): Distribution among environmental compartments:
See user defined free text
Stability in soil: No data available
Other adverse effects
Environmental fate and pathways: No data available
Results of PBT and vPvB assessment: No data available
Endocrine disrupting potential: No data available
Adsorbed organic bound halogens (AOX): No data available
Hazardous to the ozone layer
Ozone-Depletion Potential:
Regulation: 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I Substances
This product neither contains, nor was manufactured with a Class I or
Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82,
Subpt. A, App.A + B).
Additional ecological information - Product: No data available
Global warming potential (GWP): No data available
SECTION 13: DISPOSAL CONSIDERATIONS
Waste from residues:
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Send to a licensed waste management company.
Contaminated packaging: Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
SECTION 14: TRANSPORT INFORMATION
International Regulation
IATA
Not regulated as a dangerous good
IMDG
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
DOT Classification
Not regulated as a dangerous good
SECTION 15: REGULATORY INFORMATION
TSCA - 5(a) Significant New Use Rule List of Chemicals:
Not relevant
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
ETHYLENE OXIDE (EO) CAS-No. 75-21-8 Component RQ 10 (lbs) Calculated product RQ (lbs) *
* Calculated RQ exceeds reasonably attainable upper limit.
SARA 311/312 Hazards: No SARA Hazards
SARA 313:
This material does not contain any chemical components with known CAS numbers that
exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section
313.
Clean Air Act
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act
Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC's (40 CFR 60.489).
Pennsylvania Right To Know
Water
7732-18-5
Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy24938-91-8
Oxirane, 2-methyl-, polymer with oxirane, ether with oxybis[propanol] (2:1) 63466-93-3
30-50%
20-30%
10-20%
Oxirane, 2-methyl-, polymer with oxirane, ether with 1,2,3-propanetriol (3:1) 9082-00-2
5-10%
California Prop 65
WARNING! This product contains a chemical known in the State of California to
cause cancer.
Oxirane
75-21-8
Oxirane, 2-methyl75-56-9
Benzene, (1-methylethenyl)98-83-9
WARNING: This product contains a chemical known in the State of California to
cause birth defects or other reproductive harm.
Oxirane
75-21-8
Methanol
67-56-1
The ingredients of this product are reported in the following inventories:
TSCA: On TSCA Inventory
DSL: All components of this product are on the Canadian DSL.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan),
KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16: OTHER INFORMATION
The information contained herein is believed to be accurate. It is provided for the purpose of hazard
communication in accordance with OSHA guidelines as a part of Storopack’s product safety program. It is
not intended to constitute performance information concerning the product and accuracy or completeness of
the information contained herein, or product results in any specific instance, and Storopack hereby expressly
disclaims any implied warranties or merchantability or fitness for a particular purpose or any warranties or
representations whatsoever, expressed or implied.
Purchasers and users of this product and encouraged and requested to advise those who may come in
contact with this product of the information contained herein.
To determine the applicability or effects of any law or regulation with respect to this product, users should
consult their legal advisor or the appropriate government agency. Storopack does not undertake to furnish
advice on such matters.