1 Slab Dynamics in the Transition Zone 2 Magali I. Billen∗ 3 Department of Geology, University of California. Davis, Davis, CA 95616, USA 4 Abstract Seismic images of horizontal slab segments in, across or below the transition zone invoke scenarios in which slabs are laid down in the mantle through progressive trench retreat. However, observations of subduction characteristics do not exhibit a clear correlation between trench retreat and slab dip in the transition zone. Instead analysis of a range of subduction characteristics demonstrates that while transition-zone slabs include slabs of many ages and subduction velocities, with both retreating and advancing trench motion, they also have several enigmatic characteristics such as faster sinking rates and a larger range in slab dip than slabs that extend to either shallower or deeper depths. Comparison of subduction characteristics with several analytical and numerical models of subduction dynamics suggest that many of the possible mechanisms for trapping slabs in the transition zone (e.g., positive buoyancy sources, viscous resistance, slab weakening) are only viable if the slab is already shallow-dipping. Two scenarios for formation of stagnant slabs are proposed: 1) trench retreat prior to slabs entering the transition zone or caused by the negative buoyancy forces associated with the wadsleyite and ringwoodite phase transitions, and 2) slow, lateral migration of slabs in stable subduction zones. 5 Key words: slab dynamics, subduction, rheology, mantle composition, transition zone 6 1. Introduction 7 The Japanese subduction zone is characterized by long term subduction of old lithosphere (125–132 Ma) at rates 8 of 86–93 mm/yr (Lallemand et al., 2005), suggesting that the sinking slab has more than enough negative buoyancy 9 to pull the subducting plate and to sink deep into the mantle. Yet seismological observations show that the slab 10 is subducting at a shallow dip of 19–26◦ extending more than 800 km laterally before reaching the transition zone 11 and lies horizontally within the transition zone for another 600 km (Niu et al., 2005). While trench retreat is often 12 suggested as a cause of stagnant slabs in the transition zone, the present day trench retreat rate in Japan is only 20 13 mm/yr contributing less than 3◦ of slab shallowing per million years. 14 The Japan slab is also characterized by scattered seismicity to depths of 670 km with down-dip compression axis at 15 all depths (Isacks and Molnar, 1969) indicating that the slab remains stiff enough to transmit stresses up-dip. Seismic ∗ Corresponding Author. Email address: [email protected] (Magali I. Billen) Preprint submitted to Physics of Earth and Planetary Interiors May 4, 2010 16 data indicate that the 410-km phase change is elevated in the slab contributing to the negative buoyancy of the slab, 17 while the 660-km phase change is depressed over a broad region below the horizontal slab, which appears to rest on 18 this boundary (Niu et al., 2005). However, there is also new evidence for a metastable olivine wedge extending from 19 400 to 560 km at the core of the slab (Jiang et al., 2008). 20 So why has the Japan slab failed to sink deeper into the lower mantle? Is the positive buoyancy of a meta-stable 21 olivine wedge or delayed transformation to perovskite at 660-km to blame? Has intense deformation locally weakened 22 the slab and prevented it from pushing into the higher viscosity lower mantle? Did transient trench roll-back in the 23 past cause shallowing of the slab and therefore setting the stage later trapping of the slab in the transition zone? 24 While the Japan slab is a particularly well-studied stagnant slab (Fukao et al., 2010), these questions can be asked 25 of any of the present-day slabs that appear to be stagnant in the transition zone (e.g., Tonga, Java, Hebrides). Is the 26 stagnation due to a lack of sufficient negative buoyancy, changes in slab strength, the background mantle viscosity 27 structure, geometric effects, or all of these, possibly with each subduction zone exhibiting a unique combination? 28 Are stagnant slabs a transient feature of all subduction zones (Fukao et al., 2001) or does a particular combination of 29 conditions need to occur? 30 Isolating the first order cause of stagnant slabs is a difficult task given the limited number of observations, and 31 in particular the limited constraints on the evolution of many of these subduction zones. Instead, here I attempt to 32 eliminate possible causes by combining analysis of subduction characteristics with comparisons to predictions from 33 analytical models and the results of recent analog and numerical simulations of subduction. 34 2. Enigmatic Subduction Characteristics 35 The simplest models consider first order effects of the driving forces of subduction in combination with the effects 36 of coupling a sinking slab with mantle flow, and provide basic intuition on the expected behavior of slabs. For 37 example, we expect a slab with more negative buoyancy (e.g., older and/or longer) to sink more quickly, or a stiffer 38 slab (e.g., colder, dryer, and/or less deformed) to have a more shallow dip. However, as many studies have shown 39 before subduction zone characteristics do not appear to exhibit such straight-forward correlations (Jarrard, 1986; 40 Lallemand et al., 2005; Heuret and Lallemand, 2005). 41 In the following discussion slabs are divided into three groups: slabs with a maximum depth less than 410 km are 42 shallow-mantle slabs (squares), slabs with a maximum depth between 410 km and 670 km are transition-zone slabs 43 (triangles), and slabs with a maximum depth greater than 670 km are deep-mantle slabs (circles). The subduction 44 characteristics data are from Lallemand et al. (2005) and include 159 transects across subduction zones that are not 45 disturbed by nearby collision or ridge/plateau subduction. Transects near slab edges are more likely to be affected by 46 three-dimensional geometry (open symbols), while other transects (filled symbols) are expected to be more sensitive 47 to characteristics of the subducting plate such as the age of the plate (slab age). In this data set because individual 48 subduction zones are represented by multiple transects the behavior of adjacent segments of the subduction zone are 2 Figure 1: Dependence of slab sinking rate on subduction zone characteristics (Lallemand et al., 2005). Slab sinking rate versus (a) slab-pull force (F sp ), (b) slab age, and (c) slab depth. Symbols: slabs with a maximum depth of 0–410 km (squares), 410–660 km (triangles), 670–1300 km (circles); data from near a slab-edge (open) and non-slab-edge (filled). Black dashed lines in (a) show expected increase in slab sinking rate with increased buoyancy from Stokes’ flow for uniform and layered mantle viscosity. Thin-white lines in (b–c) indicate groups of data with an apparent sinking-velocity versus slab-age trends: trends d2 and d4 have no depth dependence, while trends s1, s2, d1 and d3 could be due to slab depth, slab age or both. 49 coupled. Therefore, these transects should not be treated as statistically independent observations. However, the 50 large number of transects allows for the identification of trends between characteristics, which do vary along strike in 51 many subduction zones. These trends can be compared to predictions from models to identify the physical processes 52 affecting subduction dynamics (e.g., Lallemand et al. (2005); Billen and Hirth (2007)). 53 54 Slab Sinking Rate. Slab-pull depends primarily on the age of the slab (which determines the density anomaly) and √ the length of the slab (which determines the volume of the slab) and is defined as F sp = k∆ρL A where k = 4.8 × g, 55 g = 9.81 m/s2 , ∆ρ is the average density anomaly, L is the length of the slab, and A is the slab age (Carlson et al., 56 1983). Slab-pull is considered the main driving force for plate motions at the surface of the earth, therefore one would 57 expect that the sinking rate (Vr ) of slabs in the mantle would be correlated with the available slab-pull force. However, 58 the data show that instead there appears to be a maximum speed limit on the sinking rate of slabs equal to about 60 59 mm/yr, regardless of the available slab-pull force (Figure 1a). 60 When sinking rate is compared to the two main factors in the slab-pull force equation some correlations emerge 61 from the data (Figure 1b, c). First, slab sinking rate is not simply related to slab age, although separate trends with 62 similar slopes exist for different aged shallow-mantle slabs (s1–s2) and deep-mantle slabs (d1–d4). Second, the 63 maximum sinking rate increases from 10 mm/yr for slabs of only 100 km depth to 60 mm/yr for slabs with maximum 64 depths of 300 km (trend s1 and s2; Figure 1c) as would be expected for a model in which the slab-pull force increases 65 as the volume of the slab increases. However, deeper than 660 km the sinking rate is only moderately correlated with 66 either slab depth (trends d1 and d3) or slab age (trends d2 and d4). 3 67 The upper limit on the sinking rate and the weak dependence of sinking rate on slab pull force for lower-mantle 68 slabs suggests that beyond a certain depth, the increase in negative slab buoyancy is roughly balanced by an increase 69 in viscous stresses on the slab perhaps caused by an increase in viscosity with depth (Jarvis and Lowman, 2007). 70 Transition-zone slabs, however, do not fit any of these trends and clearly stand-out as being the only slabs with very 71 fast sinking rates of up to 150 mm/yr (Figure 1c). 72 Slab Dip. In the corner-flow model of subduction a rigid sinking slab drives flow in the mantle, which in turn induces 73 pressure gradients that partially support the weight of slab (Batchelor, 1967). The corner-flow model is commonly 74 used to predict slab thermal structure, but also makes the dynamical predictions that slab dip should: 1) decrease with 75 increasing convergence velocity (subducting plate velocity plus overriding plate velocity) and 2) increase with slab 76 age (i.e., density). This model correctly predicts the mean dip of slabs (Stevenson and Turner, 1977; Tovish et al., 77 1978) and is consistent with the weak trend of decreasing slab dip with convergence velocity in the data (Figure 2a). 78 However, the data show three separate trends of increasing slab dip with slab age for slabs younger than 80 my and 79 older than about 120 my, but a negative trend for slabs between 80 and 120 my old (Figure 2b). Previous analysis of 80 these slab dip versus slab age data concluded that there was no correlation between these two characteristics (Heuret 81 and Lallemand, 2005), whereas the complex pattern suggests that perhaps these apparent trends are instead an artifact 82 of other non-physical correlations in the data. In particular, many of the data points making up the two trends for slabs 83 less than 80 my also show a positive correlation between slab age and slab depth (s1, s2, d1; Figure 2c) and therefore 84 slab dip may instead be dependent on slab depth. 85 A plot of slab dip versus slab depth exhibits separate trends for upper-mantle slabs versus lower mantle slabs 86 (Figure 2d). The dip of upper-mantle slabs increases with slab-depth, while the dip of lower-mantle slabs decreases 87 with slab depth. Transition zone slabs shallower than 670 km fit the trend of upper-mantle slabs, while slabs that 88 have reached 670 km do not follow either trend. This pattern of slab dip dependence on slab depth is not predicted 89 by simple analytical models, but may be understood from viscous flow models simulating the interaction of relatively 90 stiff slabs with a layered mantle viscosity structure. 91 In models studying the behavior of slabs with varying age or convergence rate Billen and Hirth (2007) found that 92 all models with relatively stiff slabs and a moderate increase of lower mantle viscosity had a distinctive evolution of 93 slab dip with slab depth (Figure 3). In all these models the slabs start with a shallow dip of 30◦ , which then steepens 94 to 60–90◦ as the slab lengthens in the upper mantle. This behavior has been observed in many models of subduction 95 (Becker et al., 1999; Bellahsen et al., 2005; Funiciello et al., 2006). However, once the slab starts to sink into the more 96 viscous lower mantle the difference in sinking rates between the upper and lower mantle forces the upper-mantle 97 portion of the slab to migrate laterally away from the subduction zone (Figure 3). Because the slab is too stiff to 98 thicken or buckle, it accommodates the difference in sinking rate by partitioning some of the slab-pull force into 99 lateral motion of the slab. This lateral migration slowly leads to shallowing of the upper-mantle portion of the slab. 100 The rate of migration depends on the slab age, convergence rate, and the mantle and slab viscosity structure (Figure 4 Figure 2: Dependence of slab dip on subduction zone characteristics (Lallemand et al., 2005). Slab dip versus (a) convergence velocity (Vconv ), (b) slab age, and (d) slab depth. Slab-age and slab-depth are correlated with each other (c): the apparent slab dip dependence on slab age is in fact a dependence of slab dip on slab depth. Symbols: same as in Figure 1. Thin-white lines in (c) indicate groups of slab age and slab-depth correlations. Black dashed lines in (d) indicate evolution of slab dip with slab depth in 2D numerical models of slab evolution (Figure 3). 5 101 3). Partitioning of the gravitational (i.e., radially-directed) pull force of the slab into lateral motion is not possible for 102 simple Stokes’ sinking of isoviscous or low viscosity slabs, but instead requires the strength of the slab to redirect this 103 force. 104 The pattern of increasing slab dip with slab depth for shallow-mantle slabs (and some transition-zone slabs) and 105 decreasing slab dip with slab depth for deep mantle slabs in the observational data is in good agreement with the 106 evolution of slabs found in the numerical models (dashed lines in Figure 2d). These models did not include any of 107 the phase change anomalies associated with the transition zone or motion of the trench, so they indicate the behavior 108 of slabs independent of most of the complications of the transition zone. Therefore it is no surprise that the transition 109 zone slabs that have reached 660 km do not follow the trend predicted by these models and is another indication 110 that the apparent anomalous behavior of slabs interacting with the transition zone. Interestingly, another group of 111 anomalous slabs appears at a depth of 1200 km (Figure 2d) and may indicate yet another region of changing mantle 112 structure that interferes with the descent of slabs through the lower mantle. 113 Trench Motion. One commonly-proposed cause for the trapping of slabs in the transition zone is that trench roll- 114 back lays the slab down at a shallow angle, distributing the negative buoyancy of the slab over a larger area and 115 allowing viscous stresses to prevent further sinking of the slab into the lower mantle (e.g., Griffiths et al. (1995); 116 Christensen (1996); Goes et al. (2008)). This type of model predicts a strong correlation between decreasing slab dip 117 and increasing trench roll-back rate (positive Vt ) for transition zone slabs that is not observed in the data (Figure 4a). 118 The lack of correlation of slab dip with trench velocity may therefore indicate that trench roll-back is not a primary 119 cause of stagnation of slabs in the transition zone, or that the roll-back episodes are transient features that are difficult 120 to correlate with present-day slab shapes. 121 Trench velocity is correlated with subduction velocity and slab age (Lallemand et al., 2008). The data show that 122 most subduction zones with old slabs (Figure 4b) and faster subducting plate velocities (Figure 4c) have advancing 123 trenches (i.e., motion towards the overriding plate) with rates up to 50 mm/yr, and young slabs with slower subducting 124 plate velocities have retreating trenches with rates up to 50 mm/yr for shallow-mantle and deep-mantle slabs. Only 125 transition zone slabs have retreat rates up to 90 mm/yr, but these are not associated with shallow slab dip. These 126 correlations of trench velocity with both subduction velocity and slab age may be understood from both laboratory and 127 numerical viscous flow models of free subduction, which show that slab stiffness controls trench motion (Lallemand 128 et al., 2008). 129 First, Schellart (2005) showed that advancing trench velocity is correlated with increasing subduction velocity in 130 models with forced convergence. Advancing trench motion also occurs in models with higher viscosity slabs and is 131 promoted by sinking of stiff slabs into a higher viscosity lower mantle (Enns et al., 2005). In addition, increasing 132 along-strike width of the slab decreases the rate of retreating trench motion (Stegman et al., 2006; Schellart et al., 133 2007). A comprehensive numerical modeling study of trench motion considering plate age, stiffness, mantle structure 134 and plate width found that plate stiffness is the primary control on trench motion (Di Giuseppe et al., 2008, 2009) 6 Figure 3: Slab evolution without transition zone structure or trench motion. (a) reference model slab has initially shallow dip that steepens in the upper mantle until the slab reaches the upper-lower mantle viscosity increase. Difference in sinking rates in upper and lower mantle cause slab to migrate laterally in the upper mantle leading to more shallow dipping slabs. Both younger (b) and older (c) slabs have steeper dips because they are less stiff or more dense, respectively. Decreasing the integrated strength of the slab by lowering the yield stress (d) or increasing the water content (e) leads to steeper slabs. A larger increase in the lower mantle viscosity causes the slab to migrate laterally more quickly (f). Without an increase in lower mantle viscosity (g) the slab sinks vertically. All models have a composite diffusion-dislocation viscosity in the upper mantle and a diffusion creep viscosity in the lower mantle with plastic yielding. Other model parameters are listed in the figure. 7 Figure 4: Dependence of trench velocity on subduction zone characteristics (Lallemand et al., 2005). Trench velocity versus (a) slab dip, (b) subducting plate velocity (V sub ), (c) slab age, and (d) slab depth. Symbols: same as in Figure 1). Note two groups of transition zone slabs in (a): shallowly-dipping with advancing trench motion and steeply-dipping with rapid retreating trench motion. The group of shallowly-dipping transition-zone slabs with advancing trench motion are also the longest slabs in the data set. Symbols: same as in Figure 1 8 135 For transition zone slabs, the enigma remains, in that slab shape (dip) does not appear to be simply correlated with 136 slab age or trench velocity. However, comparison of the plot of slab-dip versus trench velocity (Figure 4a) with the 137 plot of slab-dip versus slab length (Figure 4d) shows that the most shallow-dipping transition-zone slabs are advanc- 138 ing and have very long slab lengths (longer than deeper mantle slabs). I will return to this observation in the discussion. 139 140 From this comparison of observations with model predictions, it appears that the dynamics of shallow slabs is 141 controlled mainly by increasing negative slab buoyancy with slab length and low viscous resistance to sinking. In 142 contrast, the dynamics of deep-mantle slabs is controlled by increased viscous resistance to sinking of the slab and 143 the ability of stiff slabs to partition the slab pull force into lateral motion of the slab or trench. Transition zone slabs 144 clearly stand-out as having different subduction zone characteristics than other slabs, which are not easily explained 145 by simple dynamical models that do not include special processes occurring in the transition zone. It appears that 146 whatever process(es) leads to the stagnation of slabs, it affects all slabs similarly independent of slab age, convergence 147 rate, or trench motion, and leads to fast sinking velocities under some conditions. 148 3. Dynamics of Slab Descent 149 The evolution of a slab as it descends through the mantle can be thought of as occurring through perturbations of 150 the slab’s vertical descent by the evolution of the rheologic structure of the slab. In other words, without the strength 151 of the slab, dense things sink vertically down through the mantle: changes in buoyancy (phase changes) or changes to 152 the background viscosity can only slow down or speed up the descent. A stiff slab, however, can redirect the sinking 153 motion into lateral motion of the slab, and of the plate or plate boundary at the surface, and in this case local changes 154 in buoyancy can lead to changes not just in the sinking rate of a slab but also its direction. 155 For the discussion of slab buoyancy forces below, I use the thermal structure of a slab from dynamic models of 156 subduction in which the subducting plate has a fixed age of 80 Ma and subducts at a rate of 5 cm/yr (Figure 5) and 157 other similar models with different plates ages and subduction rates from Billen and Hirth (2007). The shape of these 158 slabs is the result of simulations without any phase changes, meta-stable olivine or grain-size dependent rheology. 159 Therefore, the thermal structure is used to provide appropriate estimates of the various slab buoyancy forces. The 160 analysis buoyancy forces in the transition zone presented here is similar in some respects to that of Bina et al. (2001) 161 but uses different values for many of the phase transition parameters and, in particular, a different model of metastable 162 olivine (Mosenfelder et al., 2001). 163 3.1. Slab Buoyancy 164 Thermal Buoyancy. The largest source of buoyancy in a subduction zone is the thermal buoyancy of the slab, because 165 the volume of the slab is large in comparison to the volumes affected by phase changes. The density anomaly of a 166 slab is ∆ρ = ρo α∆T , where ρo = 3300 kg/m3 is the background density of the mantle, α = 1–3 × 10−5 K−1 is the 9 Figure 5: Slab thermal and rheologic structure from Billen and Hirth (2007) with predicted phase changes for an 80 my-old slab subducting at 50 mm/yr after (a) 20 my and (b) 40 my. High strain-rates cause viscous weakening surrounding the slab (η < 1020 Pa-s) while plastic yielding limits the maximum viscosity of the cold slab interior. Profiles across the slab at 410, 540 and 660-km (c) show low strain-rate cold interior and high-strain-rate surrounding mantle. Symbols: temperature (white contours every 300◦ C); viscosity (gray-scale image; note log-scale); phase changes: thick dark-gray (olivine-wadsleyite; γ = 4.0%, ∆ρ = 5.0%), solid-gray (wadsleyite-ringwoodite; γ = 7.0%, ∆ρ = 3.0%), dashed gray (calcium-perovskite, γ = 4.0%), dashed light-gray (garnet-ilmenite, γ = 4.0%), dashed white (ilmenite-perovskite, γ = −3.1%), dashed blackwhite (ringwoodite-perovskite+magnesiowustite, γ = −1.0%, ∆ρ = 7.0%), gray-shaded slab-interior (meta-stable olivine; grain size = 500 µm, ∆ρ = 5.0%, model 2 values from Mosenfelder et al. (2001): ∆G = −14.0 kJ/mol is the free energy of reaction, k = exp(13.421) µm/s-K is the growth constant, ∆H = 369 kJ/mol is the activation enthalpy, V = 1.0 cm3 /mol is the activation volume, and S = 3.35/d is the grain size area). 10 167 thermal expansion coefficient, and ∆T is the temperature difference between the slab and the surrounding mantle. The 168 maximum possible density anomaly is on the order of 90 kg/m3 (about 2.7% for α = 2 × 10−5 K −1 ), but because 169 the slab heats up as it descends the average density anomaly is usually not more than 30–45 kg/m3 (0.09–1.3%), 170 corresponding to temperature differences of 500–700◦ C (Figure 5). 171 When slabs reach the transition zone they have a total negative buoyancy in the range of -20 to -50×1012 N/m 172 (only the slab volume deeper than 200 km is included). Differences in the initial age of the slab or convergence rate, 173 as well the duration of subduction, can lead to differences of up to a factor of two in the thermal buoyancy (Figure 174 6a). Similarly, for strong dipping slabs the slab-pull force is partitioned into vertical and horizontal components, with 175 only about half the slab-pull force contributing to sinking for shallow-dipping slabs (< 30◦ dip). 176 Phase Changes. The density anomaly associated with the phase change of ringwoodite to perovskite and magne- 177 siowüstite at 660 km depth is consider a primary candidate for slab stagnation because the negative clapeyron slope 178 for the phase change leads to a delay of this reaction within the cold slab, and therefore forms a positive density 179 anomaly that can counteract the negative thermal buoyancy of the slab. Early dynamic models using values of the 180 clapeyron slope in the range of γ = 5–7 MPa/K (Christensen and Yuen, 1984; Christensen, 1996) showed that this 181 density anomaly can effectively trap a slab in the transition by creating a localized buoyancy anomaly on the order 182 45×1012 N/m (for a density difference of 7%; Figure 6b). This buoyancy force is greater than or equal to that of the 183 negative thermal buoyancy, and in particular, if a slab is non-vertical, only part of the thermal buoyancy is directed 184 down-dip. Therefore, the buoyancy anomaly of the phase change can temporarily remove the net driving force of the 185 slab. 186 Advances in the methods used to measure the clapeyron slope of ringwoodite phase change at 660 km have 187 resulted in smaller values for the clapeyron slope ranging from γ = −0.4 to −2.0 MPa/K (Fei et al., 2004; Katsura 188 et al., 2004), and therefore a smaller buoyancy anomaly of only 7 to 20 ×1012 N/m (Figure 6b). In this case, for a slab 189 more than 50–150 km long above the region going through the phase change, the thermal bouyancy will continue to 190 drive sinking of the slab (I will consider the effect of non-buoyancy related forces below). However, if prior dynamics 191 have significantly shallowed the slab dip, the local negative buoyancy of the slab may not be sufficient to overcome 192 this density anomaly. There are also other phase changes occurring around 660-km (garnet to perovskite γ = +1.3 193 MPa/K (Hirose, 2002), ilmenite to perovskite γ = −3.1 MPa/K (Fei et al., 2004)) which can also contribute to the net 194 buoyancy of the slab. In doing the calculation above, I consider that the full volume underwent the olivine system 195 phase change, so this value in effect takes into account the density anomalies from the other minerals in the slab. Note, 196 that the current laboratory-derived values for the Clapeyron slopes are also consistent with seismological observations 197 of the discontinuity in subduction zones (Bina and Helffrich, 1994; Lebedev et al., 2002b,a; Thomas and Billen, 2009), 198 however, these observations are not yet capable of further narrowing the range of acceptable values. 199 The phase transitions at the top of the transition zone also contribute to the net buoyancy of the slab, although these 200 phase changes have received less attention in consideration of transition zone dynamics. The olivine to wadsleyite 11 201 transition at 410-km has a clapeyron slope of 3.4 to 4.0 MPa/K and a density difference of 5% (Katsura et al., 2004). 202 The wadsleyite to ringwoodite transition at 540-km has a clapeyron slope of 4.0 to 6.9 MPa/K and a density difference 203 of 3% (Suzuki et al., 2000; Inoue et al., 2006). Because of the larger magnitude clapeyron slope of these phase changes 204 compared to the phase change at 660 km, the volume of slab contributing to the density anomaly is also larger (Figure 205 5). Therefore, each of these phase changes, with buoyancy values of −8 to −25 × 1012 N/m and −10 to −28 × 1012 206 N/m, can locally double the negative buoyancy of the slab (Figure 6b, d). If the slab is free to respond to this extra 207 source of slab-pull force, then the slab sinking rate should increase proportionally as the slab passes through each of 208 these phase transitions. 209 The additional negative buoyancy from these two shallow transition zone phase changes provides a simple expla- 210 nation for the observed group of fast sinking transition-zone slabs (Figure 1a–c). These are slabs that have undergone 211 the olivine to wadsleyite to ringwoodite transitions, but are not yet subject to the increased buoyancy at the base of the 212 transition zone, or increased viscous resistance to sinking in the lower mantle. 213 Metastable Olivine. The affect of the olivine to wadsleyite transition on slab dynamics in the transition zone has re- 214 ceived much more attention in terms of the potential effect of metastable olivine (Schmeling et al., 1999; Mosenfelder 215 et al., 2001; Tetzlaff and Schmeling, 2009). If olivine at the cold core of the slab is kinetically hindered from trans- 216 forming to wadsleyite (and then ringwoodite) this provides a positive buoyancy that can resist subduction of the slab 217 at the top of the transition zone. Recent seismic studies may have detected metastable olivine within the Japan slab 218 (Jiang et al., 2008) but the volume of material involved is unclear. Schmeling et al. (1999) concluded that the volume 219 of metastable olivine expected in young (70 my) slabs was too small to cause considerable slowing of the slab, but the 220 effect on older slabs (> 100 my) may be significant Schmeling et al. (1999); Bina et al. (2001). Recent simulations 221 also suggest that a feedback occurs between the formation of metastable olivine and the rate of subduction (Tetzlaff 222 and Schmeling, 2009). In these models, for old (cold slabs) the formation of metastable olivine slows the sinking 223 rate of the slab. This in turn allows the slab to warm, which produces less metastable olivine and allows the slab to 224 speed-up again. 225 Applying the model for formation of metastability of olivine from Mosenfelder et al. (2001) to the thermal models 226 from Billen and Hirth (2007) (Figure 5) predicts that buoyancy of the metastable olivine wedge is more than an order 227 of magnitude smaller than each of the other slab buoyancy sources for grain sizes of 500–1000 µm (Figure 6b). We 228 note that the slab age is younger (80 my) and therefore the slabs are warmer (∼ 100◦ C) than the models used by 229 Tetzlaff and Schmeling (2009) (130 my) and Bina et al. (2001) (140 my) and the volume of metastable olivine is very 230 sensitive to the thermal structure. In the models presented here, the small metastable olivine buoyancy is primarily 231 due to the narrow width (< 25 km) of the cold core region of the slab. Therefore, metastable olivine may cause time- 232 dependent variations in the sinking rate of very old slabs (Bina et al., 2001; Tetzlaff and Schmeling, 2009), but is not 233 likely to have an effect on younger slabs. 234 12 235 From this analysis of the positive and negative sources of buoyancy related to the slab, I conclude that 1) the 236 positive buoyancy associated with the phase changes at 660-km is not a good candidate for slab stagnation, although 237 it may cause a minor slowing of the slab descent rate, 2) the positive buoyancy of metastable olivine is unlikely to 238 cause even a minor slowing of the slab descent except for very old slabs, and 3) the negative buoyancy of the olivine 239 to wadsleyite to ringwoodite transitions at 410-km and 540-km could temporarily double the descent rate of the slab. 240 Each of these conclusions assumes that the majority of the negative thermal buoyancy of the slab is transmitted down 241 dip: if the dip is already shallow or the slab weakens locally, then the positive buoyancy sources can inhibit further 242 sinking of the slab. In either case, it appears that slab stagnation in the transition zone is caused by changes in slab 243 and/or mantle rheology and/or transient changes in trench motion, rather than changes in buoyancy. 244 3.2. Mantle Rheology 245 The speed at which slabs descend into the mantle is, to first order, determined by the Stokes sinking velocity: 246 that is, by the balance of the net negative slab buoyancy against the shear stresses on the side and tip of the slab. 247 Therefore, changes in the viscosity (and rheology) in the transition zone and the lower mantle can change the viscous 248 shear stresses and can modify slab descent. However, there are far fewer constraints on the rheology of the transition 249 zone and lower mantle, compared to what is known about the rheology of olivine in the upper mantle. 250 Radial Viscosity. The average absolute viscosity of the upper 1400 km of the mantle is 1021 Pa-s as constrained by 251 models of post-glacial rebound (Mitrovica, 1996). Models of the observed long wavelength geoid require an increase 252 in viscosity between the upper and lower mantle by about a factor of 10–100 (Hager, 1984; Forte and Mitrovica, 2001), 253 but whether this is a sharp or gradual increase and the depth at which it occurs is not well-constrained (Panasyuk and 254 Hager, 2000). Other observations of post-seismic deformation rates and other non-tectonic unloading events (rebound 255 of drying lakes or rebound following recent retreat of glaciers) also constrain the shallow upper-mantle viscosity to 256 be in the range of 1018 –1019 Pa-s and are often better fit by models using non-linear viscosity (Bürgmann and Dresen, 257 2008). Therefore, the upper-most mantle viscosity is probably on the order of 1018 –1020 Pa-s, while the upper-most 258 lower-mantle viscosity is 1021 –1022 Pa-s. 259 Deformation Mechanisms. Laboratory constraints on the rheology of olivine are consistent with dynamical con- 260 straints on the upper-mantle viscosity structure (Hirth and Kohlstedt, 2003; Bürgmann and Dresen, 2008). Olivine 261 deforms by a combination of diffusion creep (linear stress-strain-rate flow law) and dislocation creep (power-law 262 stress-strain-rate flow law) (Hirth, 2003; Karato et al., 2008). For reasonable estimates of the average grain size (10 263 mm), water content (1000 H/106 Si), and strain-rate on the order of 1 × 10−15 s−1 , the predicted viscosity is 1020 264 Pa-s and the deformation is roughly equally accommodated by the diffusion and dislocation mechanisms (Hirth and 265 Kohlstedt, 2003). In regions of higher strain-rate (directly beneath plates or surrounding slabs), deformation is primar- 266 ily accommodated by dislocation creep and leads to a reduction in viscosity to values of 1018 –1019 Pa-s (see viscosity 267 image and strain-rate profiles in Figures 5a–c). Deformation of olivine dominated by dislocation creep, which leads 13 Figure 6: Comparison of slab buoyancy sources and viscous shear forces. (a) Slab (negative) thermal buoyancy is the largest magnitude force due to the large volume of the slab thermal anomaly. (b) Buoyancy due to phase changes depends on the slab temperature, clapeyron slope and the density difference between the phases. Symbols: large circles indicate preferred values; small circles indicate range of previously-used values in the literature. (c) Shear force resisting sinking of the slab. Symbols: upper mantle absolute viscosity (UM), transition zone viscosity factor (TZ), lower mantle viscosity factor (LM). (d) Total force available to drive sinking of the slab as a function of the maximum slab depth for three different sets of phase change parameters and mantle viscosity structures. Symbols: P.C.: 1– γol−wa = 4.0 MPa/K, γwa−ri = 6.9 MPa/K, γ sp−pv = −1.3 MPa/K; 2–γol−wa = 2.0 MPa/K, γwa−ri = 4.0 MPa/K, γ sp−pv = −2.9 MPa/K; 3–metastable olivine with a grain-size of 500 µm and sinking rate of 5.0 cm/yr, γ sp−pv = −1.3 MPa/K; N–no phase changes. F shear : viscous shear models shown in (c). 14 Figure 7: Mantle mineralogy and rheology structure. Average radial mantle viscosity structure is constrained by geophysical observations, while dominant deformation mechanism is constrained by observation (or lack of) seismic anisotropy. The rheology of olivine is well-constrained by laboratory measurements, whereas viscous behavior of other minerals is estimated based on diffusion rates of major elements and theoretical considerations. Pv – perovskite; mw – magnesiowüstite. 268 to lattice-preferred orientation of crystals, is consistent with the widespread observation of shear wave splitting in 269 the shallow upper mantle and in subduction zones (Karato et al., 2008; Jadamec and Billen, 2010). In addition, the 270 pressure-dependence of the flow law predicts a gradual increase in viscosity with depth. 271 Much less is known about the rheology of wadsleyite, ringwoodite or perovskite. Seismic observations of shear- 272 wave splitting within the transition zone (Trampert and van Heijst, 2002) suggests that wadsleyite and ringwoodite 273 also deform by a combination of dislocation creep (i.e., a composite Newtonian and non-Newtonian viscosity), while 274 the lack of widespread shear-wave splitting in the lower mantle (Karato et al., 1995) suggests that deformation of 275 perovskite is dominated by diffusion creep (i.e., a Newtonian viscosity). 276 There are currently no direct measurements of the stress-strain-rate flow-laws, which determine the magnitude of 277 the viscosity and the conditions under which each deformation mechanism is active for wadsleyite, ringwoodite, per- 278 ovskite or magnesiowustite. However, estimates of these flow-laws and the viscosity magnitude have been based on 279 a combination of experimental results on the diffusion coefficients of major elements (Karato et al., 2001; Yamazaki 280 and Karato, 2001; Shimojuku et al., 2009), the plastic strength of these minerals (Weidner et al., 2001; Yamazaki 281 et al., 2009), and deformation theory (Karato et al., 2001; Shimojuku et al., 2009). These estimates predict that wad- 282 sleyite and ringwoodite have similar flow law parameters (similar diffusion coefficients) to olivine, while perovskite 283 deforming by diffusion creep would have a viscosity of 1022 Pa-s for a grain size of 2–3 mm. For all these minerals, 284 variations in the water content also affect the average viscosity: therefore a dry transition zone (Bercovici and Karato, 15 285 2005; Yoshino et al., 2008) may be 10–100 times more viscous than the upper-mantle. 286 Given the current state of observational and laboratory constraints, the best estimate of the mantle rheologic 287 structure (Figure 7) is one in which the upper-mantle and transition zone deform by similar flow-laws (composite 288 diffusion and dislocation creep) to that given by laboratory constraints on olivine. The transition zone may be drier 289 than the upper mantle and therefore more viscous by a factor of 10–100. The lower-mantle is likely dominated 290 by deformation by diffusion creep with a viscosity on the order of 1022 Pa-s. Therefore, in the absence of better 291 constraints, it is reasonable for current dynamical models to use the olivine flow laws in the transition zone, and a 292 modification of the olivine diffusion creep flow-law in the lower mantle (e.g., Schmeling et al. (1999); Cı́žková et al. 293 (2002); Billen and Hirth (2007)). 294 Viscous Shear Force on the Slab. The effect of viscous shear stress on slab descent can be estimated using a simple 295 model in which the shear stress is proportional to the viscosity immediately surrounding the slab and the effective 296 strain-rate at the slab surface (σ shear = 2ηe f ˙e f . The effective strain-rate can be estimated as the sinking-rate divided 297 by a length-scale (˙e f = 2v sink /w slab is the strain-rate, v sink is the sinking rate of the slab, w slab is the slab width), 298 here taken as the half-width of the slab (50 km). The net shear force on a slab is given as the shear stress times the 299 area (per unit length) of the top and bottom surfaces (F shear = σ shear L slab ). With this simple model the viscous shear 300 force increases with slab length and descent rate, but is most sensitive to changes in the surrounding mantle viscosity 301 (Figure 6c). 302 For an upper mantle viscosity of 1019 –1020 Pa-s the viscous shear force is less than 5 × 1012 N/m for a vertical slab 303 extending from 200 to 600 km and is therefore always less than half, or even less than 10% of the negative buoyancy 304 of the slab. Slabs with shallow dip in the upper mantle will experience slightly larger viscous shear force because the 305 length of the slab is longer, but this is likely to only make a difference for very young and slowly subducting slabs. 306 However, increasing the viscosity of the lower mantle by a factor of 100 causes the viscous shear force to become 307 comparable to the driving force by a depth of around 1000 km. With an increase in lower-mantle viscosity by a factor 308 of 300 to 3 × 1021 –3 × 1022 Pa-s, the viscous shear forces outpace the negative buoyancy forces as the slab reaches 309 1000–1200 km depth (Figure 6c,d). 310 A viscosity increase in the lower mantle has been shown to effect the dynamics of slab evolution in the transition 311 zone in combination with the phase change buoyancy sources, both with and without trench roll-back. With trench 312 roll-back an increase in the lower-mantle viscosity helps to trap the slab across or just below the 660-km boundary, 313 however roll-back rates of greater than 4 cm/yr are generally needed to cause flattening of relatively weak (Chris- 314 tensen, 1996; Torii and Yoshioka, 2007) or stiff slabs (Cı́žková et al., 2002). In the absence of trench roll-back, stiff 315 slabs subduct easily into the lower mantle (Billen and Hirth, 2007), with or without the transition zone buoyancy 316 sources. However, weak slabs (a yield stress of 100 MPa) buckle before sinking into the lower mantle, creating very 317 broad thermal anomalies below the transition zone in the lower mantle (Běhounková and Cı́žková, 2008). Also, slabs 318 that are completely weakened by grain-size reduction due to the phase transitions do become trapped in the transition 16 319 zone (Tagawa et al., 2007). 320 321 Constraints on the mantle rheology and its affect on slab descent suggest that: 1) viscous resistance to sinking is 322 minor in the upper mantle, consistent with the observed increase in maximum sinking rate with slab depth in the upper 323 mantle (Figure 1c), and 2) increases in viscosity and the change in rheology in the lower mantle creates significant 324 resistance to sinking of the slab and can even cause the slab to stop sinking and perhaps buckle and pile-up within 325 the upper-most lower mantle (660–1200 km). This suggest that the observed speed-limit on slab descent rates (Figure 326 1a–c) is the result of a net zero balance between the growing viscous resistance on, and negative buoyancy of, the 327 lower-mantle portion of the slab. Therefore, only the upper-mantle portion of the slab is available to drive plate 328 motion through slab-pull, consistent with previous models of plate motion rates and directions (Conrad and Lithgow- 329 Bertelloni, 2002). However, these results do not explain how slabs become trapped within the transition zone in the 330 absence of trench roll-back. 331 3.3. Slab Strength 332 Variations in the slab strength remain the most promising mechanism for explain the trapping of slabs in the 333 transition zone in cases without rapid trench rollback. Within the subduction zone the tectonic plate undergoes such 334 strong deformation that essentially all of the elastic strength of the slab is lost and the plate deforms visco-plastically 335 (Goetze and Evans, 1979; Billen and Gurnis, 2005). Because of the strong temperature dependence of the viscosity, 336 the viscous stresses in the cold slab interior predicted for deformation by diffusion or dislocation creep exceed the 337 yield stress. Therefore, the cold interior of the slab probably deforms by a stress-dependent mechanism (Peierls 338 mechanism; Goetze (1978)) or plastic yielding. 339 Experimental constraints on the yield strength as a function of temperature predict the minimum yield strength (for 340 temperatures ∼900◦ ) to increase from 0.5–1.0 GPa for olivine to 2.0 GPa for wadsleyite and ringwoodite and 3.5 GPa 341 for perovskite (Weidner et al., 2001). In the absence of other processes the slab should become stronger with depth 342 and therefore be more effective at transmitting the negative buoyancy of the upper-mantle slab to deeper portions of 343 the slab. 344 The integrated strength of a slab depends on both the effective viscosity for the cold plastically deforming interior 345 and the viscously deforming outer portions of the slab, the rate of deformation of the slab and stress applied to the slab. 346 The effective strength is always lower than the maximum yield stress (Figure 8): for example, the average effective 347 strength of slab with a maximum yield stress of 1000 MPa is about 450–650 MPa (model 1) depending on its age, 348 while a slab with a yield stress of 500 MPa has an average effective strength of 300 MPa (model 4). 349 Perhaps unexpectedly, younger slabs may have a higher effective strength than older slabs simply because a 350 younger slab is less negatively buoyant and therefore is subject to a smaller applied stress (models 1–3; Figure 8). 351 Similarly, the effective stress is affected by the amount of viscous support from the lower mantle: less viscous re- 352 sistance in the lower mantle decreases the net stress acting on the slab, which results in a higher effective strength 17 Figure 8: Comparison of average integrated slab strength for Models 1–7 shown in Figure 3. Slab strength increases moderately for younger (1) and older slabs (3) due to lower driving stress or broader thermal anomaly, respectively. Slab strength drops significantly for lower yield strength or wet slabs (4–5). Increasing viscous support from the lower mantle (6) decreases the stress in the slab (because it deforms less), while decreasing viscous support from the lower mantle (7) increases stress in the slab (as it deforms at a faster rate). 353 (models 6, 7; Figure 8). The lithosphere is expected to be dry due to melting processes at the ridge, however, faulting 354 and subsequent serpentinization of the lithosphere during bending at the trench (Ranero et al., 2003) could decrease 355 slab strength by increasing the water content. This effect causes only minor increases in the dip of wet slabs compared 356 to dry slabs (model 5; Figure 3e). 357 Grain-size Weakening. Large variations in slab strength (by more than a factor of 10–1000) are possible through 358 localized changes in grain-size (Rubie, 1984; Rubie and Ross II, 1994). When grain size is very small (100–1000 359 microns) deformation by diffusion creep will occur at cold temperatures at a stress lower than the yield stress or 360 Peierls stress (Karato et al., 2001). At phase transition boundaries, the new phase nucleates as sub-micron-size grains 361 that slowly grow into larger grains. However, at cold temperatures, grain growth rates can keep grain sizes very small 362 (less than 100 microns) (Karato, 1989; Yamazaki et al., 1996, 2005; Nishihara et al., 2006). Because the diffusion 363 creep flow law has a power-law dependence on grain-size (power-law exponent of 3) a reduction in the average grain 364 size by a factor of 10 leads to a viscosity decrease by a factor of 1000. 365 Laboratory constraints on grain-growth kinetics are still limited and the volume of slab material under-going a 366 net grain-size reduction depends on the assumed growth-rate, presence of water, and temperature (Karato, 1989). 367 To test the effect of grain-size induced weakening of the slab following the olivine to wadsleyite transition Cı́žková 18 368 et al. (2002) systematically varied the grain-size and timing of grain-growth within a slab in 2D numerical subduction 369 models. They found that even with a grain-size reduction by a factor of 100 (viscosity decrease of 106 ) in the cold 370 slab interior the slab was still able to subduct into the lower mantle unless slab roll-back rates exceeded 4 cm/yr. The 371 grain-size weakened slabs continued to transmit the thermal buoyancy force of the slab to deeper portions of the slab 372 because the outer (warmer) regions of the slab remain viscously strong (Cı́žková et al., 2002). Only if the entire slab 373 permanently loses all of its strength in the transition zone, does this type of processes lead to trapping of the slab 374 (Tagawa et al., 2007). 375 However, grain-size reduction weakening of the slab may still be a viable mechanism for causing localized defor- 376 mation of the slab at 660-km, as this is the only depth at which all the minerals in the slab undergo a phase transition at 377 nearly the same depths. Grain-growth rates for combined perovskite and periclase samples suggest very slow growth 378 and small grain size (Yamazaki et al., 1996). Therefore, grain-size weakening of the slab at 660-km depth could affect 379 slab deformation at this boundary, but there are presently no models testing this possible mechanism. 380 4. Two Scenarios for Stagnant Slabs 381 The analysis of the slab buoyancy forces, viscous resistance to sinking and slab strength demonstrate that in the 382 absence of trench motion it is difficult for these processes to modify the behavior of an initially steeply-dipping slab. In 383 addition, the observations of slab-dip show that slabs tend to steepen as they lengthen in the upper mantle. Therefore, 384 in order to trap slabs in the transition zone, it is necessary to shallow the slab by other means either before or after it 385 reaches the transition zone. However, because the observations show no clear correlation between trench motion and 386 slab dip, it is necessary to propose two different mechanism for slab stagnation, depending on the stage of subduction 387 (new versus long-term) and stability of the overriding plate (Figure 9). The first mechanism, which applies to new 388 or unstable subduction zone, is trench roll-back (Funiciello et al., 2003; Bellahsen et al., 2005; Schellart, 2005) that 389 occurs before the slab reaches the base of the transition zone. The second mechanism, which applies to long-term, 390 stable subduction zones, is a decrease in slab dip by lateral migration of the deeper slab relative to the position of the 391 trench (Billen and Hirth, 2007). 392 Scenario 1: Transient Trench Retreat. Trench motion in 2D and 3D numerical models is primarily dependent on the 393 strength of the slab: strong slabs have advancing trench motion once they reach the bottom of the model domain, while 394 weaker slabs have retreating trench motion (Di Giuseppe et al., 2008). This behavior is interpreted as being controlled 395 by the increased resistance to bending (or unbending) with increased slab strength (or age), and is consistent with the 396 observation that trench motion is correlated with age (Figure 4b; Lallemand et al. (2008)). However, retreating motion 397 occurs for both strong and weak slabs before reaching the bottom of the model domain (i.e., base of the transition 398 zone), although the rate of retreat is faster for younger slabs (Figure 9a; t3 to t5 ). Models of subduction initiation also 399 exhibit a stage of rapid trench retreat as subduction becomes self-sustaining (Hall et al., 2003). 19 400 Kinematically, trench retreat as the slab sinks freely through the upper mantle occurs because the sinking rate of the 401 slab is higher than the rate at which the plate is being pulled into the mantle. Dynamically the partitioning of motion at 402 the trench occurs because energy dissipation caused by bending of the slab at the trench decreases the amount of slab- 403 pull force transferred from the sinking slab to the plate (e.g., Appendix A, Billen and Hirth (2007); Conrad and Hager 404 (2001)). To accommodate the difference in the rates of motion without stretching the slab, the trench motion must 405 balance the difference in the rate of motion of the slab and the rate of motion of the plate: Vt = V slab −V plate . Therefore, 406 unlike models with a fixed trench position (Billen and Hirth, 2007), if the trench is free to move, steepening of the 407 slab as it lengthens in the upper mantle will be partly balanced by trench retreat resulting in more shallow dipping 408 slabs entering the transition zone. 409 Shallowing of the slab as it enters the transition zone may also occur in response to acceleration of the slab caused 410 by the additional negative buoyancy from the olivine to wadsleyite to ringwoodite phase transitions (Figure 9a; t5 to 411 t8 ). This acceleration could increase the discrepancy between the slab velocity and plate velocity and lead to more 412 rapid trench roll-back or effective roll-back of the slab around 410-km: both causing further shallowing of the slab 413 above the transition zone. However, once the slab starts to interact with the increased viscous resistance of the lower 414 mantle and the phase transition at 660-km, the decrease in slab velocity could lead to a rapid decrease trench retreat 415 rate, and may even switch into trench advance for stronger, older slabs (Figure 9a; t8 to t9 ). 416 This time-dependent scenario is consistent with the observation that in general, young (weaker) slabs in the upper 417 mantle and transition zone exhibit trench retreat rates up to 50 mm/yr, while there is no clear correlation between the 418 retreat rate and the dip of each slab for the present-day (Figure 4a). In other words, the present-day slab shape in the 419 transition zone, is the result of transient trench motion while the slab was sinking into the transition zone, and not a 420 result of the trench motion once the slab has reached the base of the transition zone. Because this scenario depends 421 on changes in trench motion in response to the changing dynamics of the slab, it also requires that the overriding 422 plate can respond to this changing force by accommodating trench retreat via deformation or back-arc spreading in 423 the overriding plate. 424 This first scenario may be valid in places like the Marianas, where the trench is currently advancing, but was 425 recently rolling back and appears to have a flat slab portion just below the transition zone, Java where the trench is 426 currently stationary, but rapid retreat occurred at 30 Ma, or in Tonga, where rapid roll-back starting in 5–10 Ma, may 427 be responsible for the more shallow dip of the slab above 400 km (Fukao et al., 2001; Sdrolia and Müller, 2006). 428 Scenario 2: Stable Long-Term Subduction. Lateral migration of the slab away from the trench occurs in dynamical 429 models of subduction with a fixed trench, composite viscosity structure, stiff slabs and a more viscous lower mantle 430 (Figure 3; Billen and Hirth (2007)). The migration occurs because the difference in sinking rate of the slab in the 431 upper mantle (fast) compared to the lower mantle (slow) can not be accommodated by shortening or buckling of the 432 strong slab (Běhounková and Cı́žková, 2008). Shallowing of the slab via lateral migration requires stable, long-term 433 subduction because the rates of lateral migration are on the order of 10 to 20 mm/yr (Billen and Hirth, 2007). A slab 20 Figure 9: Two scenarios for the formation of stagnant slabs. a) Trench retreat before, and as, the slab reaches the transition zone, followed by fixed or advancing trench motion leads to shallow-dipping slabs with no correlation to present-day retreating trench motion. This scenario requires that the overriding plate can deform or move to accommodate trench retreat. b) For stable overriding plates, long-term subduction can lead to slow lateral migration and shallowing of the slab. For very shallow slab dips, the inability to transmit sufficient slab forces down-dip may allow the transition-zone portion of the slab to become stagnant and detach from the deeper slab. 21 434 that reaches the base of the transition zone with a vertical dip (Figure 9b; t1 to t3 ) and then continues to subduct into 435 the lower mantle, will take on the order of 50 to 100 million years to reach a dip of 20–30◦ (Figure 9b; t4 to t7 ). 436 As the slab approaches more shallow dipping geometry, it relies on the strength of the slab to transmit the overall 437 negative buoyancy of the slab to the slab-tip to overcome the local buoyancy anomaly associated with the 660-km 438 phase change (Figure 9b; t4 to t7 ). Local variation in the slab strength could prevent the negative slab-buoyancy 439 force from being fully transmitted to the transition-zone portion of the slab causing this portion of the slab to become 440 stagnant (Figure 9b; t8 to t9 ). This process can be viewed as a kind of instability, where above a certain dip, the slab- 441 transmitted stresses are sufficient to overcome resistance to sinking, but once a threshold dip is crossed, insufficient 442 stresses are transmitted to the slab-tip. The random orientation of moment tensor solution in very shallow-dipping 443 (< 20◦ ) portions of slabs compared to the down-dip alignment of moment tensor solution in all other slabs (Brudzinski 444 and Chen, 2005) supports this conclusion that stagnation of the slab is the result of a loss of down-dip transmitted 445 stresses. 446 For this scenario, stagnant slabs evolving from long-term shallow subduction are characterized by a very long slab 447 with shallow dip throughout the upper mantle, flattening of the slab tip within the transition zone, and evidence of 448 earlier (long-term) subduction in the form of a deeper slab segment in the lower mantle. This predicted evolution is 449 consistent with the observation that slab dip is directly correlated with slab length, in particular for shallow-dipping 450 transition-zone slabs (Figure 4d). This suggest that these stagnant slabs, started out as deep-mantle slabs that progres- 451 sively shallowed during long-term stable subduction, but have crossed the stability threshold leading to slab stagnation, 452 and in some cases, to detachment of the deeper portion of the slab. 453 This second scenario may be valid in places like Japan, where there has been little or no trench retreat and long term 454 subduction, the former Farallon slab, where there had been long-term stable subduction and a stagnant slab remains in 455 the transition zone (van der Lee and Nolet, 1997), or the central Aleutians, which has had stable subduction for more 456 than 60 my, little or no trench retreat, but also has a stagnant slab in the transition zone (Fukao et al., 2001; Sdrolia 457 and Müller, 2006). 458 5. Conclusions 459 Observations of subduction zone characteristics provide many important insights on slab dynamics both outside 460 and inside the transition zone, by illustrating the ways in which slab behavior deviates from simple model predictions, 461 and by making it possible to isolate combinations of parameters contributing to observed behavior. By comparing 462 these observations to a range of model predictions, two scenarios for the formation of stagnant slabs are proposed: 463 episodic trench retreat of young slabs with unstable overriding plates, and slow lateral migration of older slabs with 464 stable overriding plates. These two scenarios are consistent with the inferred behavior of shallow-mantle and deep- 465 mantle slabs, and with the behavior of slabs in numerical and laboratory models of subduction. 466 First, the observations show that slabs which have not yet reached the transition zone or have subducted beyond 22 467 it, appear to behave as existing physical models predict: 1) upper-mantle slabs steepen and sink more quickly with 468 increasing slab depth consistent with models with stiff slabs and a composite rheology, 2) lower-mantle slabs shallow 469 with increased slab depth and advancing trench roll-back rate, and show no dependence of sinking rate on slab-pull, 470 indicating that a high viscosity lower mantle supports and anchors the slab; and 3) both upper and lower mantle slabs 471 exhibit a moderate dependence of slab dip on slab age and a maximum sinking rate of 60 mm/yr, consistent with 472 models with stiff slabs, a composite upper mantle rheology and a higher viscosity lower mantle. 473 Second, observations of transition zone slabs show that: 1) the transition zone is currently occupied by slabs 474 with the full range of observed subducting plate ages, convergence velocities and trench roll-back rates, and therefore 475 the modification of the descent of slabs through the transition zone may be independent of these characteristics; 2) 476 these are the only slabs with a sinking rates of greater than 60 mm/yr and up to 150 mm/yr indicating that there is a 477 significant local increase in the negative buoyancy of the slab, consistent with current phase change data for the 410- 478 km and 540-km phase transitions, and no increase in viscous shear stresses; and 3) these slabs exhibit no correlation 479 of slab dip with trench retreat rate, as is predicted by models with a freely-sinking slab and no overriding plate. 480 Consideration of the buoyancy forces in the slab using current constraints on phase changes shows that 1) the 481 thermal bouyancy of the slab is many times larger than all other sources of buoyancy due to its larger volume; 2) the 482 increase in negative buoyancy of the slab as it converts from olivine to wadsleyite and ringwoodite can more than 483 double the local slab-pull force; 3) due to the very small volume of slab that may be affected by metastable olivine the 484 associated positive buoyancy is not likely to impede sinking of the slab, but would instead be associated with a non- 485 accelerated sinking rate; and 4) due to the small clapeyron slope of the major phase change at 660-km, the associated 486 small positive buoyancy is not expected to impede subduction of a stiff steeply-dipping slab. Therefore, while the 487 buoyancy sources due to phase changes above 660-km may aid in subduction, the buoyancy sources at 660-km are 488 insufficient to impede subduction into the lower mantle unless the slab already has a shallow dip. 489 Formation of a shallow-dipping slab, either due to transient trench retreat or slow lateral migration of the slab at 490 depth, is necessary for any of the other physical processes (buoyancy, increased viscous resistance, reduction in slab 491 strength) to trap a slab in the transition zone. Transient trench retreat is driven by the difference between the slab 492 velocity and the plate velocity, and should increase as the slab crosses the phase transitions at 410-km and 540-km. 493 Lateral migration of slabs accommodates the difference in sinking rate between the slab that has entered the more 494 viscous lower mantle and the faster sinking slab in the upper mantle. 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