Range of anionic emulsifiers
Application
Trade name
Product
group
Type
Pure
acrylic
Styreneacrylic
Dispersogen® LFA
Phosphate
Ester
Tristyrl phenol ether
phosphate
Emulsogen® APS 100
Sulfate ester
Allyl polyalkylene glycol
ether sulfate, ammonium salt
●
●
Emulsogen® EPA 073
Sulfate ester
Sodium alkyl ether sulfate
●
●
Vinyl
acetate
Properties
Styrenebutadiene
E-PVC
●
●
HLB
value
Appearance
Active
content
APEO
free
n.a.
Brownish,
viscous liquid
ca. 85%
3
n.a.
Clear to cloudy
yellowish liquid
ca. 100%
3
n.a.
Clear, colorless liquid
ca. 30%
3
n.a.
Clear, colorless to
yellowish liquid
ca. 30%
n.a.
Yellowish liquid
n.a.
Low VOC
(<1%)
3
Food contact regulation
Biodegradability
US FDA1
registration,
chapter 21 CFR
European
registration
Directive 10/2011
German
BfR2
-
NZIoC
PICCS
TSCA
(Taiwan)
(New
Zealand)
(Philippines)
(USA)
>80% (28d)
OECD 301A
§ 175.105, 176.170,
176.180, 177.1210
3
3
Readily
biodegradable
ca. 30%
3
3
Readily
biodegradable
Clear yellowish liquid
ca. 30%
3
-
n.a.
Yellowish brown liquid
ca. 50%
3
3
-
<10% OECD
302B
n.a.
Colorless, clear to
cloudy liquid
ca. 50%
3
3
Readily
biodegradable
78% (28d)
OECD 301B
§ 175.105, 175.300,
175.320, 176.170,
176.180, 176.210,
177.1200, 177.2800,
178.3400
3
BfR II, XIV,
XXXIV,
XXXVI
3
3
3
3
3
3
3
3
3
3
3
exempted
3 LVE
7
Label
Signal word
Hazard
statement6
Mixture
-
Warning
H320
Substance
label free
label free
label free
Irritant (Xi)
R36
Harmful (Xn),
Irritant (Xi)
R22, R38, R41
Irritant (Xi)
R36/38
Warning
R36/41
label free
label free
BfR XIV,
XXI, XXXIV
3
3
3
3
3
3
3
3
3 LVE
3
Mixture
>60% OECD
301B
3
BfR XXI,
XXXVI
3
3
3
3
3
3
3
3
3
3
Mixture
>93% (28d)
OECD 301B
3
BfR XIV,
XXI XXXIV
3
3
3
3
3
3
3
3
3
Mixture
3
3
3
3
3
Mixture
exempted
Mixture
Emulsogen® LCA 213
Sulfate ester
Allyl polyalkylene glycol
ether sulfate, ammonium salt
●
●
Emulsogen® PF 20 S
Sulfate ester
Polyalkylene glycol ether
sulfate, ammonium salt
Emulsogen® SF 8
Sulfosuccinate Dioctyl sulfosuccinate
Genapol® LRO liquid
Sulfonate
Sodium lauryl ether sulfate
●
●
●
●
n.a.
Clear liquid
ca. 27%
3
Readily
biodegradable
95% (28d)
OECD 301E
§ 176.210, 177.2800
3
BfR XIV, XXI,
XXXIV
Genapol® LRO paste
Sulfonate
Sodium lauryl ether sulfate
●
●
●
●
n.a.
Paste
ca. 68-70%
3
Readily
biodegradable
100% (28d)
OECD 301B
§ 176.210, 177.2800
3
Hostapal® BV conc.
Sulfate ester
Sodium alkyl aryl ether
sulfate
●
●
●
n.a.
Clear, colorless to
yellowish liquid
ca. 50%
-
<10% OECD
302B
Hostapal® BVQ 9
Sulfate ester
Sodium nonyl phenol
polyglycol ether sulphate
●
●
●
n.a.
Yellow liquid
ca. 40%
-
9% (28d)
OECD301D
Hostapal® BVQ 25
Sulfate ester
Sodium nonyl phenol
polyglycol ether sulphate
●
●
●
n.a.
Clear yellowish liquid
ca. 30%
-
23% (21d)
OECD301D
Hostaphat® 1306
Phosphate
ester
Alkyl ether phosphate
●
●
●
n.a.
Clear, yellowih liquid
ca. 100%
3
-
44% (28d)
OECD 301B
Hostapur® OS liquid
Sulfonate
Sodium olefin sulfonate
●
Hostapur® SAS 30
Sulfonate
Sodium alkyl sulfonate
●
Hostapur® SAS 60
Sulfonate
Sodium alkyl sulfonate
Hostapur® SAS 93
Sulfonate
Sodium alkyl sulfonate
3
3
Composition5
3
●
●
NECI
(Korea)
Readily
biodegradable
●
●
KECI
(China)
3
Ammonium alkyl ether
sulfate
●
IECSC
(Japan)
-
Sulfate ester
●
ENCS
(Europe)
-
Emulsogen® LA 083
●
EINECS
(Canada)
46% (28d)
OECD301B
Sodium lauryl sulfate
●
DSL
(Australia)
-
Emulsogen® EPA 1954 Sulfate ester
●
AICS
3
-
Hazardous labeling according to GHS3
or Dangerous Susbstance Directive4
Inventory registration status
7
3
3 LVE
3
3
3
3
3
3
3
3
3
3
Mixture
✖
Irritant (Xi)
R36/38
3
3
3
3
3
3
3
3
3
3
Mixture
✖
Irritant (Xi)
R38, R41
BfR XIV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
3
Substance
Danger
H315, H318, H412
BfR XIV
3
3
3
3
3
3
3
3
3
3
Mixture
Irritant (Xi),
Dangerous for the
environment (N)
R41, R52/53
-
3
3
3
3
3
3
3
3
3
Mixture
label free
label free
3
3
3
3
3
3
3
3
3
Mixture
Warning
H315, H411
§ 178.3400
3
3
3
3
3
3
3
3
3
Substance
Danger
H315, H318, H411
3
3
3
3
3
3
3
3
3
3
Mixture
Irritant (Xi)
R38, R41
Irritant (Xi)
R38, R41
Irritant (Xi)
R38, R41
Danger
H302, H315,
H318, H412
-
-
●
●
n.a.
Yellowish clear liquid
ca. 40%
3
3
Readily
biodegradable
>80% (28d)
OECD 301B
§ 175.105, 178.3400
●
●
●
●
n.a.
Clear, slightly
yellowish liquid
ca. 30%
3
3
Readily
biodegradable
>89% (28d)
OECD 301E
§ 176.170, 176.180,
178.3400
3
BfR XIV,
XXXVI
3
3
3
3
3
3
3
3
3
3
Mixture
●
●
●
●
●
n.a.
Yellowish soft paste
ca. 60%
3
3
Readily
biodegradable
>89% (28d)
OECD 301E
§ 176.170, 176.180,
178.3130, 178.3400
3
BfR II, V,
VI, XIV, XV,
XXI, XXXIV,
XXXVI
3
3
3
3
3
3
3
3
3
3
Mixture
●
●
●
●
●
n.a.
Yellowish tablets
ca. 93%
3
3
Readily
biodegradable
>89% (28d)
OECD 301E
§ 176.170, 176.180,
178.3400
3
BfR XIV,
XXXVI
3
3
3
3
3
3
3
3
3
3
Substance
6
label free
3
7
●
1 Product listed in chapter 21 CFR of the US Food and Drug Administration
2 The product meets the requirements of the Bundesamt für Riskikobewertung (German authority of risk assessment) 3 Hazardous labeling according to the Globally Harmonized System
4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC)
5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals
as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the
“Regulation on classification, labeling and packaging of substances and mixtures “ on 16.12.08 (EU regulation 1272/2008).
According the EU regulation, the classification and labteling has to be done until:
- 01.12.2010 for substances
- 01.06.2015 for mixtures (i.e. chemical preparations)“
✖
✖
✖
Risk phrases:
R22: Harmful if swallowed
R36: Irritating to eyes
R38: Irritating to skin:
R36/38: Irritating to eyes and skin
R41: Risk of serious damage to eyes
R52: Harmful to aquatic organisms
R53: May cause long-term adverse effects in the aquatic environment
R52/53: Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
n.a. Not applicable
6
Hazard Statements:
H302: Harmful if swallowed
H315: Causes skin irritation
H318: Causes serious eye damage
H411: Toxic to aquatic life with long lasting effects
H412: Harmful to aquatic life with long lasting effects
7 LVE = Low volume exempt
✖
label free
✖
✖
✖
Emulsion Polymerization
Range of anionic and
nonionic surfactants
Range of nonionic emulsifiers
Application
Trade name
Product
group
Type
Emulsogen® 4084
EO/PO block
copolymers
60% EO, 40% PO
Emulsogen® EPN 118
Pure
acrylic
Styreneacrylic
Vinyl
acetate
Properties
Styrenebutadiene
E-PVC
Active
content
APEO
free
Low VOC
(<1%)
Food contact regulation
Biodegradability
US FDA1
registration,
chapter 21 CFR
European
registration
Directive 10/2011
Hazardous labeling according to GHS3
or Dangerous Susbstance Directive4
Inventory registration status
German
BfR2
HLB
value
Appearance
AICS
DSL
EINECS
ENCS
IECSC
KECI
NECI
NZIoC
PICCS
TSCA
(Australia)
(Canada)
(Europe)
(Japan)
(China)
(Korea)
(Taiwan)
(New
Zealand)
(Philippines)
(USA)
18
Pale yellow wax
ca. 100%
3
3
-
<10% (28d)
OECD302B
§ 175.105, 176.180,
176.200, 176.210,
177.1200, 177.1680
3
BfR XIV,
XLVIII, LIII
3
3
3
3
3
3
3
3
3
Composition5
Label
Signal word
Hazard
statement6
3
Substance
label free
label free
label free
Harmful (Xn),
Irritant (Xi)
R22, R41
●
●
●
Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 11 moles EO
●
●
●
●
15
Clear colorless liquid
ca. 80%
3
3
Inherently
biodegradable
> 80 % OECD
302 B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV,
XXXVI
3
3
3
3
3
3
3
3
3
3
Mixture
Emulsogen® EPN 217
Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 21 moles EO
●
●
●
●
17
Clear colorless liquid
ca. 70%
3
3
Inherently
biodegradable
> 80 % OECD
302 B
§ 176.170, 176.180,
181.30
3
BfR XIV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
3
Mixture
label free
label free
label free
Emulsogen® EPN 287
Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 28 moles EO
●
●
●
●
17,5
Clear colorless liquid
ca. 70%
3
3
Inherently
biodegradable
> 80 % OECD
302 B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV,
XXXVI
3
3
3
3
3
3
3
3
3
3
Mixture
label free
label free
label free
Emulsogen® EPN 407
Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 40 moles EO
●
●
●
●
18
Clear colorless liquid
ca. 70%
3
3
Inherently
biodegradable
> 80 % OECD
302 B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
3
Mixture
label free
label free
label free
●
●
●
13
Clear to cloudy liquid
ca. 100%
3
3
Readily
biodegradable
>80% (28d)
OECD301E
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV,
XXXVI
3
3
3
3
3
3
3
3
Substance
Danger
H302, H318
13,5
Clear liquid
ca. 80%
3
3
Readily
biodegradable
>61% (28d)
OECD301B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV,
XXXVI
3
3
3
3
3
3
3
3
Mixture
✖
Harmful (Xn),
Irritant (Xi)
R22, R41
✖
Emulsogen® LCN 070 Fatty alcohol
ethoxylate
C11 oxo alcohol, ethoxylated
with 7 moles EO
Emulsogen® LCN 088 Fatty alcohol
ethoxylate
C11 oxo alcohol, ethoxylated
with 8 moles EO
Emulsogen® LCN 118
Fatty alcohol
ethoxylate
C11 oxo alcohol, ethoxylated
with 11 moles EO
●
●
●
●
14
Clear liquid
ca. 80%
3
3
Readily
biodegradable
>61% (28d)
OECD301B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV,
XXXVI
3
3
3
3
3
3
3
3
Mixture
✖
Harmful (Xn),
Irritant (Xi)
R22, R41
Emulsogen® LCN 158
Fatty alcohol
ethoxylate
C11 oxo alcohol, ethoxylated
with 15 moles EO
●
●
●
●
16
Clear liquid
ca. 80%
3
3
Readily
biodegradable
>75% (28d)
OECD301B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV
3
3
3
3
3
3
3
3
Mixture
✖
Harmful (Xn),
Irritant (Xi)
R22, R41
Emulsogen® LCN 217
Fatty alcohol
ethoxylate
C11 oxo alcohol, ethoxylated
with 21 moles EO
●
●
●
●
17
Clear liquid
ca. 70%
3
3
Readily
biodegradable
>75% (28d)
OECD301B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV,
XXXVI
3
3
3
3
3
3
3
3
Mixture
label free
label free
label free
Emulsogen® LCN 287
Fatty alcohol
ethoxylate
C11 oxo alcohol, ethoxylated
with 28 moles EO
●
●
●
●
17,5
Clear liquid
ca. 70%
3
3
Readily
biodegradable
>75% (28d)
OECD301B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV
3
3
3
3
3
3
3
3
Mixture
label free
label free
label free
Emulsogen® LCN 407 Fatty alcohol
ethoxylate
C11 oxo alcohol, ethoxylated
with 40 moles EO
●
●
●
18
Clear liquid
ca. 70%
3
3
Inherently
biodegradable
> 80 % OECD
302B
§ 175.105, 176.170,
176.180, 181.30
3
BfR XIV, XXI,
XXXIV
3
3
3
3
3
3
3
3
Mixture
label free
label free
label free
Emulsogen® TS 200
Tristyryl
ethoxylate
Tristyryl ethoxylated with
20 moles EO
●
●
●
14
Yellowish brown liquid
ca. 100%
3
3
-
10-35% OECD
302B
BfR XIV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
Substance
label free
label free
label free
Genapol® PF 10
EO/PO block
copolymers
10% EO, 90% PO
●
●
●
13
Clear colorless liquid
ca. 100%
3
3
Readily
biodegradable
100% (28d)
OECD 301B
§ 175.105, 176.180,
176.200, 176.210,
3
BfR V, VI,
XIV, XXXVI
3
3
3
3
3
3
3
3
3
3
Substance
label free
label free
label free
Genapol® PF 20
EO/PO block
copolymers
20% EO, 80% PO
●
●
●
14
Slightly cloudy,
colorless liquid
ca. 100%
3
3
Readily
biodegradable
99% (28d)
OECD 301F
§ 175.105, 176.180,
176.200, 176.210,
3
BfR V, VI,
XIV, XXXVI
3
3
3
3
3
3
3
3
3
3
Substance
label free
label free
label free
Genapol® PF 40
EO/PO block
copolymers
40% EO, 60% PO
●
●
●
16
Slightly cloudy,
colorless liquid
ca. 100%
3
3
Readily
biodegradable
61% (28d)
OECD 301F
§ 175.105, 176.180,
176.200, 176.210,
3
BfR V, VI,
XIV, XXXVI
3
3
3
3
3
3
3
3
3
3
Substance
label free
label free
label free
Genapol® PF 80
EO/PO block
copolymers
80% EO, 20% PO
●
●
●
●
19
Wax
ca. 100%
3
3
-
<10% (28d)
OECD302B
§ 175.105, 176.180,
176.200, 176.210,
3
BfR XIV,
XLVIII, LIII
3
3
3
3
3
3
3
3
3
3
Substance
label free
label free
label free
Genapol® X 080
Fatty alcohol
ethoxylate
C13 oxo alcohol, ethoxylated
with 8 moles EO
●
●
●
●
Genapol® X 307
Fatty alcohol
ethoxylate
C13 oxo alcohol, ethoxylated
with 30 moles EO
●
●
●
●
Genapol® X 407
Fatty alcohol
ethoxylate
C13 oxo alcohol, ethoxylated
with 40 moles EO
●
●
Genapol® X 1003
Fatty alcohol
ethoxylate
C13 oxo alcohol, ethoxylated
with 100 moles EO
●
Genapol® X 1005
Fatty alcohol
ethoxylate
C13 oxo alcohol, ethoxylated
with 100 moles EO
●
●
12
Slightly cloudy,
colorless liquid
ca. 100%
3
3
Readily
biodegradable
60% (28d)
OECD 301F
§ 175.105, 176.170,
176.180, 176.200,
176.210, 181.30
3
BfR V, VI,
XIV, XV, XXI,
XXXIV,
XXXVI, LI, LII
3
3
3
3
3
3
3
3
3
3
Substance
18
Clear colorless liquid
ca. 70%
3
3
Readily
biodegradable
100% (25d)
OECD 301B
§ 176.170, 176.180,
176.200, 181.30
3
BfR V, VI,
XIV, XV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
3
Mixture
●
18
Clear colorless liquid
ca. 70%
3
3
Readily
biodegradable
100% (25d)
OECD 301B
§ 176.170, 176.180,
176.200, 181.30
3
BfR V, VI,
XIV, XV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
3
●
●
19
Clear colorless liquid
ca. 35%
3
3
-
50-60% OECD
301B
§ 176.170, 176.180,
176.200, 181.30
3
BfR V, VI,
XIV, XV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
●
●
19
Clear colorless liquid
ca. 50%
3
3
Readily
biodegradable
>95% (25d)
OECD 301B
§ 176.170, 176.180,
176.200, 181.30
3
BfR V, VI,
XIV, XV, XXI,
XXXIV
3
3
3
3
3
3
3
3
3
●
Danger
H302, H318
label free
label free
label free
Mixture
label free
label free
label free
3
Mixture
label free
label free
label free
3
Mixture
label free
label free
label free
1 Product listed in chapter 21 CFR of the US Food and Drug Administration
2 The product meets the requirements of the Bundesamt für Riskikobewertung (German authority of risk assessment) 3 Hazardous labeling according to the Globally Harmonized System
4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC)
5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals
as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the
“Regulation on classification, labeling and packaging of substances and mixtures “ on 16.12.08 (EU regulation 1272/2008).
According the EU regulation, the classification and labteling has to be done until:
- 01.12.2010 for substances
- 01.06.2015 for mixtures (i.e. chemical preparations)“
6 Risk phrases:
6 Hazard Statements:
R22: Harmful if swallowed
H302: Harmful if swallowed
R36: Irritating to eyes
H315: Causes skin irritation
R38: Irritating to skin:
H318: Causes serious eye damage
R36/38: Irritating to eyes and skin
H411: Toxic to aquatic life with long lasting effects
R41: Risk of serious damage to eyes
H412: Harmful to aquatic life with long lasting effects
R52: Harmful to aquatic organisms
R53: May cause long-term adverse effects in the aquatic environment
R52/53: Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment