Electronic Supplementary Material (ESI) for Dalton Transactions.
This journal is © The Royal Society of Chemistry 2015
Electronic Supplementary Information
Intensity (a.u.)
1•MeOH•H2O
1•H2O
1
5
10
15
20
25
30
2theta / degree
Figure S1 Powder XRD patterns for the compounds 1·MeOH·H2O, 1·H2O and 1 at
room temperatures.
The EPR spectra of the polycrystalline powders were measured for the compound 1’ in
the temperature range of 3.6 - 292 K. The spectra show resonances arising from the
mixture between LS and HS of Co(II). There were no indications at any temperature down
to approximately 3.6 K of resonances attributable to HS Co(II).
289 K
248 K
204 K
Intensity
98 K
50 K
3.6 K
50 K
101 K
201 K
292 K
1000
2000
3000
4000
5000
Frequency / Hz
Figure S2
ESR signals for the compound 1’ in the temperature range of 3.6 - 292 K.
500
180 K up
230 K up
0
Intensity
320 K up
-500
400 K up
280 K down
-1000
180 K down
-1500
6
8
10
12
14
16
18
2
Figure S3
Powder XRD patterns for the compound 1’ at various temperatures.
20