Electronic Chemicals Honeywell Ammonium Hydroxide Honeywell Ammonium Hydroxide various grades and packaging available O- N+ H Appearance and Odor Colorless, transparent liquid with very pungent odor Odor Threshold 5–20 ppm may not have changed significantly, the Vapor Pressure 460mm Hg at 68˚F (30˚C) demand for purity has increased dramati- Formula Weight 35 cally. Specific Gravity 0.901 (25%), 0.895 (30%) (H2O=1) Water Solubility Completely soluble in water Density 7.5 lbs/gallon Boiling Point 39.7˚C (25%), 30.4˚C (30%) Melting Point -57.7˚C (25%), -91.5˚C (32%) Hazard Class 8 used in semiconductor manufacturing for over 30 years. While fabrication processes Device manufacturing of today and tomor- H H overview Ammonium Hydroxide (NH4OH) has been H H row has little tolerance for contaminants on the wafer surface. Honeywell has devoted a considerable amount of time and resources to help ensure that customers benefits receive high-purity chemicals to meet their • Reduced contamination and defect densities • Centrally located manufacturing facility enabling a wide etch process latitude • Guarantees for a range of specifications • Tunable to customers’ needs design and yield goals. features • Ultra High-purity (UHP) Ammonium Hydroxide • Efficient logistics and supply • In-line and finished-product quality monitoring • Various grades available • Multiple container sizes Product Characteristics: • 1-year shelf life • Available in 1-gallon bottles, drums, totes and bulk The typical specification guidelines and typical analytical results should be used as a reference only. Actual results may vary depending upon grade, package type and configuration. Furthermore, specifications and typical reporting limits are subject to change. Therefore, please contact your sales representative to discuss in further detail process capabilities and specification limits that can be mutually agreed upon. Honeywell Electronic Materials USA: 1-509-252-2102 China: 86-21-28942481 Germany: 49-5137-999-9199 Japan: 81-3-6730-7092 Korea: 82-2-3483-5076 Singapore: 65-6580-3593 Taiwan: 886-3-6580300 ext.312 www.honeywell.com/sm/em Specification Assay (wt %) Color Appearance Residue after Ignition Residue after Evaporation Substances Reducing KMnO4 as (O2) Chloride Nitrate Phosphate Sulfate Carbon Dioxide Aluminum Antimony Arsenic Barium Beryllium Bismuth Boron Cadmium Calcium Chromium Cobalt Copper Gallium Germanium Gold Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Niobium Potassium Silver Sodium Strontium Tantalum Thallium Tin Titanium Vanadium Zinc Zirconium UNITS — APHA — — — — Cl NO3 PO4 SO4 CO2 Al Sb As Ba Be Bi B Cd Ca Cr Co Cu Ga Ge Au Fe Pb Li Mg Mn Mo Ni Nb K Ag Na Sr Ta Tl Sn Ti V Zn Zr TYPICAL VLSI 28.0-30.0 7 — 2 ppm — To Pass Test 300 ppb 400 ppb 200 ppb 800 ppb 10 ppm 30 ppb 25 ppb 25 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 200 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb 30 ppb Packaging Group III SPEC GUIDELINES ULSI SLSI 28.0-30.0 28.0-30.0 7 7 To Pass Test To Pass Test 2 ppm — — — To Pass Test To Pass Test 200 ppb 100 ppb 400 ppb 100 ppb 100 ppb 50 ppb 200 ppb 100 ppb 10 ppm 3 ppm 3 ppb 1 ppb 3 ppb 1 ppb 3 ppb 1 ppb 1 ppb 1 ppb 10 ppb 1 ppb 10 ppb 1 ppb 2 ppb 1 ppb 1 ppb 1 ppb 8 ppb 1 ppb 3 ppb 1 ppb 1 ppb 1 ppb 1 ppb 1 ppb 1 ppb 1 ppb 4 ppb 1 ppb 1 ppb 1 ppb 10 ppb 1 ppb 3 ppb 1 ppb 1 ppb 1 ppb 2 ppb 1 ppb 1 ppb 1 ppb 10 ppb 1 ppb 5 ppb 1 ppb 10 ppb 1 ppb 5 ppb 1 ppb 1 ppb 1 ppb 5 ppb 1 ppb 1 ppb 1 ppb 10 ppb 1 ppb 10 ppb 1 ppb 1 ppb 1 ppb 1 ppb 1 ppb 10 ppb 1 ppb 3 ppb 1 ppb 10 ppb 1 ppb Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, express or implied. Information provided herein does not relieve the user from the responsibility of carrying out its own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained. Statements or suggestions concerning the use of materials and processes are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe any patent. The user should not assume that all toxicity data and safety measures are indicated herein or that other measures may not be required. PB1021011Rev9 ©2011 Honeywell International Inc. TYPICAL REPORTING LIMITS VLSI ULSI SLSI 29.0 29.0 29.0 <7 <7 <7 — — — <2 ppm <2 ppm — — — — — — — <300 ppb <200 ppb <100 ppb <400 ppb <400 ppb <100 ppb <200 ppb <100 ppb <50 ppb <800 ppb <200 ppb <100 ppb <10 ppm <10 ppm <3 ppm <0.30 ppb <0.03 ppb <0.01 ppb <0.25 ppb <0.03 ppb <0.01 ppb <0.25 ppb <0.03 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb <0.30 ppb <0.02 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.08 ppb <0.01 ppb <0.30 ppb <0.03 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.04 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb <0.30 ppb <0.03 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.02 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb <0.30 ppb <0.05 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.05 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <2 ppb <0.05 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.01 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb <0.30 ppb <0.03 ppb <0.01 ppb <0.30 ppb <0.10 ppb <0.01 ppb
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