Impacts and threats to groundwater Deliverable D1.1 Partner: Joanneum Research Forschungsgesellschaft mbH H. Kupfersberger 2 Deliverable summary Project title Acronym Date due Final version submitted to EC Complete references Contact person Contact information Authors and their affiliation Project homepage Confidentiality Key words Summary (publishable) for policy uptake Groundwater and Dependent Ecosystems: New Scientific and Technological Basis for Assessing Climate Change and Land-use Impacts on Groundwater GENESIS Contract number 226536 Month 10 in GENESIS Month 10 in GENESIS Hans Kupfersberger Joanneum Research, Institute for Water, Energy and Sustainability, Elisabethstr. 18, A-8010 Graz, Austria, [email protected] Hans Kupfersberger (JR) www.thegenesisproject.eu Public groundwater systems, land use impacts, Groundwater Directive, GENESIS test sites Groundwater systems in Europe significantly differ with respect to their geological settings, climate conditions, size, land-uses and water utilization. In order to review the present situation on European scale, 17 test sites from 15 different countries have been evaluated. Conflicts of interest may arise between various groundwater uses and users that result in a wide range of impacts on aquifer systems. Within this report, impacts and threats are described in detail on (i) groundwater dynamics, recharge and water balance of groundwater systems, (ii) substances leaching to groundwater aquifers due to different land-uses and (iii) groundwater dependent ecosystems interacting with surface water. These results will be input for the working packages where research on processes in groundwater systems and their mathematical implementation in models is conducted. Additionally, likely future scenarios of groundwater systems use can be deduced from the test sites which will lead to the development of economical and social viable measures for groundwater protection. In this context, the national River Basin Management Plans have also been analyzed. Finally, possible gaps with respect to the WFD and the GWD encountered at the test sites are discussed and a general overview of modeling approaches used is compiled. 3 List of GENESIS partners Norwegian Institute for Agricultural and Environmental Research (CO) Bioforsk Norway University of Oulu UOULU Finland Joanneum Research Forschungsgesellschaft mbH JR Austria Swiss Federal Institute of Technology Zurich ETH Switzerland Luleå University of Technology LUT Sweden University of Bucharest UB Romania GIS-Geoindustry, s.r.o. GIS Chezk Repulic French National institute for Agricultural research INRA France Alterra - Wageningen University and Research Centre Alterra The Netherlands Helmholtz München Gesundheit Umwelt HMGU Germany Swiss Federal Institute of Aquatic Science and Technology EAWAG Switzerland University of Science and Technology AGH Poland Università Cattolica del Sacro Cuore UCSC Italy Integrated Global Ecosystem Management Research and Consulting Co. IGEM Turkey Technical University of Valencia UPVLC Spain Democritus University of Thrace DUTh Greece Cracow University of Technology CUT Poland University of Neuchâtel UNINE Switzerland University of Ferrara UNIFE Italy Athens University of Economics and Business- Research Centre AUEB-RC Greece University of Dundee UNIVDUN United Kingdom University of Zagreb - Faculty of Mining, Geology and Petroleum Engineering UNIZG-RGNF Croatia Helmholtz Centre for Environmental Research UFZ Germany Swedish Meteorological and Hydrological Institute SMHI Sweden University of Manchester UNIMAN United Kingdom 4 Table of contents 1. Overview of impacts and threats to typical GWs and GDEs within the Genesis test sites ....................................................................................................... 9 1.1. Impacts and threats on groundwater dynamics, recharge and water balance of groundwater systems .............................................................................. 20 1.1.1. Grue site, Norway ....................................................................... 21 1.1.2. Rokua site, Finland ...................................................................... 21 1.1.3. Murtal aquifer, Austria.................................................................. 21 1.1.4. Zagreb site, Croatia ..................................................................... 22 1.1.5. Vosvozis site, Greece ................................................................... 22 1.1.6. Mancha Oriental site, Spain ............................................................ 22 1.1.7. Areuse site, Switzerland ................................................................ 23 1.1.8. De Kromme Rijn site, The Netherlands............................................... 23 1.2. Impacts and threats on substances leaching to groundwater aquifers due to different land-uses ............................................................................................. 24 1.2.1. Grue site, Norway ....................................................................... 25 1.2.2. Koycegiz-Dalyan (KD) site, Turkey .................................................... 26 1.2.3. Caretti site, Italy ........................................................................ 26 1.2.4. Feucherolles site, France............................................................... 26 1.2.5. Murtal site, Austria ...................................................................... 27 1.2.6. Zagreb site, Croatia ..................................................................... 27 1.2.7. Vosvozis site, Greece ................................................................... 27 1.2.8. Mancha Oriental site, Spain ............................................................ 28 1.2.9. Areuse site, Switzerland ................................................................ 28 1.2.10. Czestochowa site, Poland ............................................................. 28 1.2.11. Bitterfeld site, Germany .............................................................. 29 1.2.12. Po valley site, Italy .................................................................... 30 1.2.13. De Kromme Rijn site, The Netherlands ............................................. 30 5 1.3. Impacts and threats on groundwater dependent ecosystems interacting with surface water …… ............................. ………………………………………………………………………………...31 1.3.1. Grue site, Norway ....................................................................... 32 1.3.2. Rokua site, Finland ...................................................................... 32 1.3.3. Koycegiz-Dalyan (KD) site, Turkey .................................................... 32 1.3.4. Vosvozis site, Greece ................................................................... 33 1.3.5. Sumava site, Czech Republic .......................................................... 33 1.3.6. Czestochowa site, Poland .............................................................. 34 1.3.7. Bogucice site, Poland ................................................................... 34 1.3.8. Lule site, Sweden ........................................................................ 34 1.3.9. Po valley site, Italy ...................................................................... 35 1.3.10. De Kromme Rijn site, The Netherlands ............................................. 35 1.4. Possible gaps with the WFD and/or GWD .............................................. 36 1.4.1. Grue site, Norway ....................................................................... 37 1.4.2. Rokua site, Finland ...................................................................... 37 1.4.3. Koycegiz-Dalyan (KD) site, Turkey .................................................... 37 1.4.4. Caretti site, Italy ........................................................................ 37 1.4.5. Zagreb site, Croatia ..................................................................... 38 1.4.6. Vosvozis site, Greece ................................................................... 38 1.4.7. Areuse site, Switzerland ................................................................ 38 1.4.8. De Kromme Rijn site, The Netherlands............................................... 38 1.5. 2. Impacts and threats on groundwater systems and River Basin Management Plans39 A general overview of modeling approaches used and their purposes ................... 41 2.1. Grue site, Norway ......................................................................... 43 2.2. Caretti site, Italy .......................................................................... 43 2.3. Murtal aquifer, Austria .................................................................... 44 2.4. Feucherolles site, France ................................................................. 44 2.5. Zagreb site, Croatia ....................................................................... 45 6 2.6. Vosvozis site, Greece ..................................................................... 45 2.7. Mancha Oriental site, Spain .............................................................. 46 2.8. Bogucice site, Poland ..................................................................... 47 2.9. Lule site, Sweden .......................................................................... 48 2.10. Po valley site, Italy ........................................................................ 48 2.11. De Kromme Rijn site, The Netherlands ................................................. 48 7 Groundwater systems in Europe significantly differ with respect to their geological settings, climate conditions, size, land-uses and water utilization. In order to review the present situation and measures on European scale, 17 test cases from 15 different countries have been evaluated. The areas include the Mediterranean zone, Central and Western Europe as well as Scandinavia; hydrogeological regimes range from lagoon systems, fractured rock, sand and gravel aquifers and karst systems to peatlands and eskers. Typically, conflicts of interest may arise between various groundwater uses and users, e.g. drinking water supply, agriculture, hydropower generation or groundwater dependent ecosystems. Additionally, groundwater use results in a wide range of impacts on the aquifer systems like altering groundwater dynamics and balance or worsening groundwater quality due to leaching of substances. Based on the analysis of case studies of groundwater systems and groundwater dependent ecosystems the most relevant and actual impacts and threats shall be revealed. These results will be input for further working packages where research on processes in groundwater systems and their mathematical implementation in models is conducted. Furthermore, likely future scenarios of groundwater systems use can be deduced from the test sites considering all relevant stakeholders which will lead to the development of economical and social viable measures for groundwater protection (WP6). The basis will be provided for model development testing and scenario simulations to generate new tools and improved insight for updates of the WFD and GWD. Within this report, first, an overview about geological settings, climate, hydrology and land-use of the different test sites is given. Then, impacts and threats are described in detail on groundwater dynamics, recharge and water balance of groundwater systems, on substances leaching to groundwater aquifers due to different land-uses and on groundwater dependent ecosystems interacting with surface water. Moreover, possible gaps with respect to the WFD and the GWD are discussed. Finally, a general overview of modeling approaches used and their purposes with a specific focus on model requirements and data availability and needs is put together. The site characteristics presented here are based on information provided by the corresponding project partners. The work package leader is responsible for making selection thereof, interpretation and summary (at the beginning of each chapter) of the facts. 8 1. Overview of impacts and threats to typical GWs and GDEs within the Genesis test sites Because of interdependencies and to better understand the impacts and threats to groundwater systems a short introduction to the geological setting, the climate conditions, the hydrology and the current land-use that prevail at each test site is given as a basis. In order to restrict the report to a reasonable extent and to avoid replication of unspecific information only excerpts of the information provided from the partners responsible of the test sites is presented. The locations of the sites are shown in figure 3 of the DoW on a European scale. Overview of geological settings, climate, hydrology and land-use at the Grue site, Norway The area is situated above a deep basin filled with marine deposits beneath a top layer of fluvial sediments. Clay has been found at a depth of 13-15 m in several drill holes. Above this level the deposits consists mainly of sand with a top layer of flood plain sediments of coarse silt and sand. The thickness of the unsaturated zone normally ranges between 1.8 and 6 m. Average annual temperature and precipitation in this area is 3.3 ˚C and 635 mm, respectively. The mean groundwater recharge is estimated to be at a size of 300 mm/year. Precipitation normally falls as snow in December–March with snowmelt in April. During winter the soil is frozen. The pattern of groundwater recharge has a seasonal cycle with minima in summer and winter and maxima in spring due to infiltration of water from snowmelt. The flow pattern of the aquifer is characterised by groundwater flow towards the river most of the year. Only during flood peaks in spring and autumn water will flow into the aquifer from the river Glomma. Overview of geological settings, climate, hydrology and land-use at the Rokua site, Finland The Rokua esker (area 70 km2) is located in Northern Finland, in the region of Northern Ostrobothnia. It is a part of a chain of esker ridges stretching from the island of Hailuoto in Gulf of Bothnia to Ilomantsi in eastern Finland. Rokua is a large glaciflucial deposit with the highest point rising 80 meters above the surrounding wetland areas (200 meters above sea level). The esker consists mainly of sandy soils. During its formation in the last glaciation, the glaciers and meltwaters loosened homogenous material from easily crumbling and weathered surface bedrock, which were deposited in Rokua. Small “kettle” lakes are situated within the esker area. Most of these lakes have no outlet or inlet: the water level is dependent of the ground water level of the esker. 9 The climate is cold with snow cover lasting throughout the winter until late April. The average precipitation in the area is 500-600 mm and 30-50 % of precipitation is estimated to recharge the groundwater. The annual average temperature is 2.0 degrees Celsius. The Rokua esker sandy recharge areas remain in quite natural state. In the lowland discharge areas intensive peatland drainage mainly for forestry, but to some extent also for agriculture and peat harvesting has been carried out since 1940’s. Small amounts of the Rokua groundwater (100 – 200 m3/d) is used as drinking water by the residents and in the Rokua Spa and health center. The regulated lake Oulu is located at one end of the esker. Overview of geological settings, climate, hydrology and land-use at the Caretti site, Italy The site is located in the Po plain (Pianura Padana), immediately to the east of the historical centre of the city of Ferrara. The size of the contaminated area at the moment is estimated 0.026 km2, the areal size of the entire multi-layered aquifer system (of regional extension) is about 11,164 km2. The general conceptual model of the Po plain is that one of a multi-aquifer system, made of porous sandy aquifers and clayey-silty aquitards. The main aquifer in this area is the deeper 1st confined regional aquifer (A1-I), composed by medium-fine grained sand of 20 m average thickness. The aquifer A1-I is locally separated at the top by a 6 m thick clayey aquitard from the above A01 aquifer. Even if at the site scale A1-I is separated by A01, it is still to be defined if there are connections between the two aquifers on a broader area at the regional scale. The hydraulic conductivity is in the range of 1-8×10-4 m/s and the hydraulic gradient corresponds to 0.4-1 ‰. Recharge of the aquifer A1-I occurs by leakage through the confining layer and by lateral recharge from the Po river, which is in contact with the sandy aquifer 8 km to the north. Using the data of a meteorological station from 1990 to 1998, the average rainfall in Ferrara results in about 700 mm/year, with a mean temperature of 13°C. One of the main Italian petrochemical plants is located very close to the city of Ferrara. The plant has produced, among various compounds, Poli Vinyl Chloride (PVC), starting from VC monomer (from 1953 to 1998) and halomethanes (since 1951 to 1984). Groundwater contaminations by chlorinated hydrocarbons were detected not only in subsurface of the plant area, but also in at least 3 urbanized sites in the city surroundings. Considering that some of the contaminated sites are located up groundwater gradient of the plant, the chlorinated hydrocarbons could have originated from the plant itself via illegal waste disposal at locations surrounding the site. During the 1950’s excavation of clay pits started to derive raw materials for brick production. Since the 1960’s the pits were used as waste disposals. Urbanization of the surrounding area started and grew progressively until the beginning of the 1990’s. Surface dumps remnants vanished below a vegetated cover. Between 2000 and 2003, the discovery of the contamination halted the development of new 10 residential areas. As a consequence, since 2004 the municipality of Ferrara took over the responsibility of the site characterization of the whole area defined as the Caretti site. Contamination at Caretti site probably affects also the confined aquifer used as the main groundwater source of Ferrara province. By the way, the nearest well field plant is not affected by contamination, because located quite far away (8 km) and up gradient to contamination source and because the aquifer is always recharged by the Po River. Nearby the site, groundwater of the first confined aquifer is not used for drinking purposes; irrigation wells are present but they do not show evidence of contamination. Overview of geological settings, climate, hydrology and land-use at the Murtal aquifer, Austria The quarternary valley floor of the river Mur downstream the alpine area to the Slovenian border covers an area of more than 300 km². The groundwater system is built up by an unconfined shallow stream aquifer with a thin soil cover. The quaternary fluvial-glacial sediments typically show high hydraulic conductivities. In the floodplain area Eutric to dystric Fluvisol including sandy alluvial sediments dominate, whereas at the terraces Dystric Cambisol (siliceous; loamy-sandy) can be found. The riverine zone mostly is covered by riparian forests. Due to the topographic situation the intensive use of the sub-alpine basins results into conflicts of interests between the ever-increasing use of the resource land and water. Agricultural production of high yield crops as well as agricultural biomass production is increasing resulting into high nitrate concentrations in groundwater for the last and future decades. The average precipitation, groundwater recharge and temperature in the study area is 750 mm, 350 mm and about 11°, respectively, which can be summarized in general as a moderate alpine foothills climate. Overview of geological settings, climate, hydrology and land-use at the Feucherolles site, France Located 50 km west of Paris a field experiment started in 1998 to study the long-term effects of repeated applications of urban waste composts. The site is located on the plateau of Alluets Le Roi (48°53’ N; 1°58’ E). Developed on quaternary loess deposits, the soil is a silt loam Glossic Luvisol and is representative of loamy soils of Paris Basin regional area. The size of the field site is 6 ha whereas the total area of the plateau is about 180 km2. On the field experiment, the soil is conventionally cropped with a biannual rotation winter wheat-maize, two major crops of the region. The geological stratification of the plateau of Alluets-le-Roi is typical of the Parisian Basin. A 2-m layer of loess covers a buhrstone clay bed called “Argiles à Meulières” that crowns the sands and sandstones of the Oligocene “Sables de Fontainebleau” formation (50 to 60 m depth) which constitutes the main aquifer of the region. The main use is for drinking water supply. The aquifer recharge has a mean value estimated to 80 mm/year y. Climatic data are currently measured on site since 2002 and climatic series are available in the vicinity at a daily frequency (since 1971). 11 The clay bed constitutes a discontinuous aquitard on which a temporary perched water table may be formed. A recent piezometric study on the experimental site has shown that the temporary perched water table flows out laterally to draining windows or channels located within the clay bed. These zones of preferential infiltration are mainly located in small topographical depressions and have an important contribution to the recharge of the underlying sand aquifer. Overview of geological settings, climate, hydrology and land-use at the Köyceğiz Dalyan (KD) site, Turkey KD case study region is in semi humid class under the influence of Mediterranean climate characteristics, with a hot, dry summer season and a warm, rainy winter season. January is the coldest month with an average temperature of 9.2°C, July is the warmest month with an average temperature of 28.8°C and the annual average temperature is 18.3°C in the site. Long term average annual precipitation was found to be around 1083 mm. Long term average annual evaporation was found to be around 1200 mm. A decreasing trend for precipitation and evaporation between 1985 and 2000 is observed. The KD case study area has a relatively heterogeneous geological structure and geomorphology at the two sites of Dalyan channel. The watershed itself is considered as a tectonic depression zone. There are alluvial and karstic regions. There are several geologically interesting features such as hot and cold water springs, springs that contain high amount of salinity and hydrogen sulphide. Lime-free brown soil, which is characterized by high clay content and sometimes stony clay texture with pebbles, is the dominant soil type in the area. The second major type of soil, the Mediterranean red-brown soil composed of hard limestone, granite, and rocks, is typically in dry climate conditions. Alluvial soil types have thicker soil cover whereas red-brown and brown soils are too shallow. Lime is mostly observed on alluvial and hydromorphologic soils. Main source of potable water in the site is groundwater. There are 3 deep wells to supply water to Dalyan town with 200 m3/h production capacity. Both surface water and groundwater are used for irrigation in the area. An irrigation channel from Akköprü reservoir on Dalaman river reaches to the site and serves to farmers. Annualy safety pumping amount of water for Okçular-Dalyan Village Plain was estimated as 14x106 m3/year. 70% of total area is covered with natural vegetation that contains forest, scrub and frigana vegetations. Agricultural activitiy is 25% of the total land use and common in Dalyan Town side of case study area. Nitrogen loads that reach the aquatic ecosystem were calculated as 9.2 tons N/year from point sources and 61.5 tonsN /year from non-point sources. Similarly, phosphorus loads were calculated as 1.37 tons P/year from point sources and 5.14 tons P/year from non-point sources. 12 Overview of geological settings, climate, hydrology and land-use at the Zagreb site, Croatia The Zagreb aquifer system is located in the NW part of the Republic of Croatia, along the Sava River. It covers an area of approximately 350 km2 and is the only and therefore exceptionally important source of potable water for the Croatian capital. The aquifer system is built of two Quaternary aquifers which can be divided into three basic units: aquifer system overburden built of clay and silt; shallow Holocene aquifer built of medium-grain gravel mixed with sands; and deeper aquifers from Middle and Upper Pleistocene, with frequent lateral and vertical alterations of gravel, sand and clay. The average seasonal resources are estimated to be at the size of the 105 × 106 m3/year. Average annual temperature and precipitation are 11.7°C and 920 mm, respectively. Thus, this area represents aquifers in temperate climate. The Sava river, which is the main source of groundwater recharge within aquifer system, is in direct hydraulic connection with the shallow aquifer, which has extremely high values of hydraulic conductivity (up to 3000 m/day). The right bank of the Sava River is dominated by the intensive agriculture, even near the largest well field in this area. Numerous well fields are accommodated within this aquifer system. Overview of geological settings, climate, hydrology and land-use at the Vosvozis site, Greece Vosvozis catchment area covers an area of 340 km². The river’s length is 40 km. Vosvozis river discharges into Ismarida lake. In the coastal part of the study area a system of coastal lagoons is formed, where surface, groundwater and seawater interact. All the area of Ismarida lake and the coastal lagoons forms an extremely important ecosystem. From the geological-hydrogeological point of view, the upper part of study area, i.e. the part from the Bulgrarian borders down to the mountain feet, is formed by Palaeozoic crystalline rocks of the Rhodope massif, mainly consisting of gneisses, marbles and amphibolites. The plain area is formed by tertiary sediments (molasic and alluvial deposits), mainly consisting of intercalations of permeable and less permeable layers. The permeable formations consist of fine to medium grained sands and gravels, whereas the less permeable formations consist of silts and clays. The total thickness of those sediments is estimated to range from 50 to 500 meters, based on borehole data. The climate is characterized as Mediterranean with dry hot summers and mild winters. The average annual precipitation is approximately 650mm, whereas the average annual temperature is 15ºC. The average groundwater recharge is estimated approximately 120mm/yr. In those sedimentary formations two important aquifer systems are found. The first one is located close to Komotini city. The total daily discharge pumped from the Komotini wellfield reaches 23,000 m3/d providing domestic water to almost 70,000 inhabitants of the Komotini city and the surrounding 13 settlements. Groundwater pumping is taking place mainly during summertime, whereas during the rest of the year Vosvozis river is used directly for domestic consumption, and when its water is of appropriate quality (suspended load). The origin of the water extracted from the aquifer in the Komotini wellfield is the nearby Vosvozis river, rain infiltrated directly into the aquifer, and lateral inflows from the northern mountains. The second major aquifer system is known as the Sidirohori aquifer, located on the southern part of the study area, where water for irrigation use is abstracted from. This aquifer is important as it interacts both with Vosvozis river as well as with Ismarida lake and the wetland area Overview of geological settings, climate, hydrology and land-use at the Mancha Oriental site, Spain La Mancha Oriental aquifer system (Hydrogeologic System 08.29) is located at the South-East of Spain, on the eastern side of La Mancha plains (Castilla-La-Mancha region), extends over 7,260 km2 within the Jucar river basin district, and contains one of the largest carbonate aquifers in Spain. The aquifer has as its natural drainage the Jucar River in the stretch between two reservoirs (Alarcon and Molinar), of about 80 km. The region has a mild Mediterranean climate, with dry summers and precipitations in spring and autumn. Semi-arid and with extreme cold winters (under 6°C) and hot summers (above 24°C), the average annual temperatures vary between 13°C and 14.5°C. Precipitation varies between 350 mm in the south and 550 in the north. The average groundwater recharge is estimated to 165 mm/year. The hydrogeological system can be considered as a multilayer aquifer, composed by 9 hydrogeological units from which only 3 can be considered as aquifers. The first one is from the Jurassic period, and it is mostly a confined aquifer constituted by dolomites and highly karstified limestone with a thickness of 250-500 meters and transmissivites between 2400 and 12000 m²/day. The Cretaceous aquifer behaves as unconfined in the north and confined in the rest; its thickness is between 50-150 meters and its transmissivites are lower than in the Jurassic aquifer. The Miocene aquifer is the most exploited one, and it behaves as an unconfined aquifer with transmissivites of about 480-8400 m2/day. There is a hydraulic connection between them, which can be vertical or lateral, depending on the sector. The Miocene aquifer is hydraulically connected to the Jucar river; the river is gaining in some reaches and losing in others. A 3D groundwater flow model is available. The aquifer supplies water for the irrigation of about 70,000 ha., provided with modern irrigation techniques (mainly sprinklers and centre pivot systems), and for urban consumption to a population of over 275,000 inhabitants. The annual water draft is about 400 Mm3 for irrigation and 25 Mm3 for urban supply. 14 Overview of geological settings, climate, hydrology and land-use at the Areuse site, Switzerland The study area is localised in the Northwest part of the Canton de Neuchâtel (Switzerland) near the French borderline. The total Areuse catchment area covers an area of 407 km2. The Areuse river’s length is 46 km. The upper Jurassic limestone (320 to 350 m of thickness) makes up the aquifer. These fissured limestones overlay an Argovian marls-limestone complex, considered as relatively impervious and hence acting as a regional aquiclude. In the central part of synclines, a porous aquifer is located, partially disconnected from the karstic aquifer, consisting of Cretaceous deposits (marls and sandstone). The Taillères Lake is based in these deposits. The Areuse spring, also called “La Doux” spring (750 m) is the major outflow from the basin. Average annual temperature and precipitation in this area are 5°C and 1500 mm, respectively. Precipitation normally falls as snow in December - March with snowmelt in April. A large part of groundwater recharges originates from snow, which can strongly influence seasonality and duration of flood events. The spring presents high variations of its discharge along the year: the maximum, the minimum and the annual mean are respectively 53.5 m3/s, 270 l/s and 4.86 m3/s for the 1959-2009 period. Areuse catchment area is representative of rural conditions. It is covered by forest (about 36%) composed by oaks, firs and spruces and by meadows (about 64%) used for pasture and rearing. Urbanization is limited (~2500 inhabitants corresponding to 20 people/km2) to villages in this mountainous area because of harsh climatic conditions. The karst groundwater resource is used as drinking water. Some pumping wells are located within the karst aquifer. In the dry summer of 2003, water shortage occurred for some communities and as a reaction the communities switched to an alternative water source. A number of pumping wells are located in the alluvial aquifer downgradient of the spring, which indirectly depend on the discharge from the spring. The river Areuse that is fed by the Areuse spring is used for hydroelectrical production. Overview of geological settings, climate, hydrology and land-use at the Czestochowa site, Poland The Czestochowa case site (area 2365 km2) lies in the southern part of Poland. The borders of the case site correspond to the borders of the Main Groundwater Basin MGWB 326. The MGWB 326 aquifer is naturally divided by the Warta river into two subbasins: (i) MGWB 326 (S) with documented disposable water resources of 4,220 m3/h on the area of 170 km2, (ii) MGWB 326 (N) with documented disposable water resources of 8,900 m3/h on the area of 570 km2. The area of the case site is shared by two main Polish river basins: part of it lies within the basin of the Warta River – the main right-hand tribuatry of the Odra River while the other part belongs to the Pilica river basin – the left tributary of the Vistula catchment. Rivers often change their character from gaining (70% of the total flow from groundwater) 15 to draining even within short sections which together with a fracture – karstic geological structure (high seepage) make groundwater flow conditions complex and vulnerable to hydrological conditions. Average yearly precipitation varies between 600 and 800 mm/year. The climate is continental with low humidity and relatively high seasonal amplitudes of temperature; the average yearly temperature is 70C. The industrial activities of the Czestochowa town include textile, metallurgical, iron, steel, paper and food processing. Urban areas and villages cover ca. 20% of the surface. The remaining part is mainly agriculture and forestry. Groundwater is the only resource of water for the Czestochowa region. At present 99% of inhabitants is connected to the local water supply system based on 4 main groundwater intakes . The total water consumption is 163 Mm³/year (2006). For the late 90s of the XX century considerable decrease of water consumption in the domestic sector has been observed – water consumption dropped by 20%. The average water use in the region of Czestochowa now is 169 l/day/capita. Overview of geological settings, climate, hydrology and land-use at the Boguice site, Poland The aquifer is located in the south of Poland. It covers the area of ca. 200 km2 and belongs to the category of medium groundwater basins in Poland. The hydrogeology of the aquifer can be considered in three areas: the recharge area related the outcrops of the Bogucice Sands in the south, the central confined area generally with artesian water, and the northern discharge area in the Vistula river valley. The effective base of the aquifer is the top of the clay and claystone of the Chodenice Beds. The groundwater movement takes place from the outcrops in the south, in the direction of the Vistula river valley where the aquifer is drained by upward seepage through semipermeable clayey formations of the Tertiary Grabowiec Beds. Intensive exploitation decreased the water table in some localities causing downward seepage. The upper, shallow aquifer located in Pleistocene-holocene sediments is related to drainage system of Vistula river and its tributaries. Unsaturated zone consists mainly of sands and loess of variable depth, from 0 in wetland areas to approximately 30 meters in the recharge area of deeper aquifer layers. Soils are Cambisols developed on loess and clays in hilly areas, Podzols and Luvisols developed on sands and Fluvisols developed in river valleys. The climate has intermediate character between oceanic and continental. The yearly average precipitation in the area is 725 mm, evapotranspiration 480mm and runoff 245mm. The recharge of the groundwater is on the level of 8 to 28 percent of the precipitation. The annual average temperature is 8.2 degrees Celsius. Globally, urban areas and villages cover ca. 20% of the surface. The remaining part is mainly agriculture (60%) and forestry (20%). In the eastern part of the area, forests and wetlands dominate. The principal economic role of the deeper aquifer is to provide potable water for public and private users. Estimated disposable resources of the MGWB 451 are 40,000 m3/d with typical well capacities of 4 to 200 m3/h. Hospitals and food processing plants also exploit some wells. The yield of 16 the aquifer is insufficient to meet all the needs and, as a consequence, licensing conflicts arise between water supply companies and industry on the amount of water available for safe exploitation. Overview of geological settings, climate, hydrology and land-use at the Lule site, Sweden Luleå river is historically a highly regulated water body with 15 river dams on it. Regulation is closely related to hydropower production which is the major application of it. The biggest reservoirs are located in the upstream part of the river. Case study site is situated in the middle stream of Luleå river. Kalix river has its basin to the NE from Luleå river and remains the last large pristine river in Europe. Both sites are located about 100-120 km from the river mouth. Quaternary sediments in both areas built very complex picture. There are sediments of different type and genesis. This makes identification of similar conditions in both pristine and regulated rivers more complicated. Major area of the two presented case studies is covered with glacial and postglacial depositions. Moraine is the dominating type of sediments. Areas surrounding the rivers are covered by coarse grained sand, gravel and clay in Luleå case study, and fluvioglacial sediments with interlaying of sand and clays in Kalix case study. The climate in this area is subarctic, with monthly average temperature ranging from -15oC in January to +14oC in July. Luleå river freezes in December, and remains frozen until April. About 45% of the precipitation comes in the form of snow, and accumulates during winter until snowmelt in May. Rainfall decreases gradually from the mountains towards the Gulf of Bothnia, averaging from 1000-1500 mm/year down to 400-700 mm/year, respectively. Evapotranspiration rate is very low. Effective precipitation is around 300-350 mm/year in the coastal area. This portion of water mainly recharges groundwater in the vicinity. Overview of geological settings, climate, hydrology and land-use at the Bitterfeld site, Germany The Bitterfeld region is located in the southeast of Saxony-Anhalt, Germany, and has a history of about one hundred years of extensive mining and chemical industry. An area of about 235 km2 is affected in the Bitterfeld region, of which an area of 25 km2 shows a significant groundwater contamination, containing a volume of about 200 million m3. The contaminated area of Bitterfeld is located in the floodplain of the Mulde River. The upper aquifer consists of Quaternary sands and gravels. The Quaternary unit can be divided into a lower part, represented by lower terrace sediments of the Weichselian Mulde and overlying sediments, composed of braided river deposits of a smaller tributary stream. Both are separated by a hydraulically effective clay layer. This aquifer is in parts underlain by the upper oligocene lignite seam acting as a local aquitard. The lignite seam has been intensively mined in the southern part of Bitterfeld. The base of this 17 hydrogeological section is represented by middle Oligocene clays (Rupelian clay). The latter unit is considered to be the regional scale aquitard, hence corresponding to the base of the groundwater pollution. Among the different tasks of land reclamation and restoration of pre-mining groundwater conditions, the management of hazardous-waste deposits and groundwater remediation are the most urgent. Underground and open-cast mining activities since 1830 led to an extensive lowering of the groundwater table and a change of the groundwater dynamics. The consequences of the currently rising groundwater level are not only damages to buildings, but also the mobilizing effect on contaminants and their transport into basements of inhabited structures (buildings, houses). In the northwest of Bitterfeld, several former opencast lignite mines have been used as landfills for chemical wastes. Since the industrial dumps were incompletely sealed and are in contact with the groundwater, the contaminants affected the groundwater directly. The landfills currently show a stagnating emission pattern. The concentrations reach several hundreds of mg/l, exceeding effluent standards by several orders of magnitude. Conventional ‘‘pump and treat’’ technologies are economically unfeasible in the long term, due to the fact of the continuous output from the landfills and the necessary volumes of about 4 million m³ per year. Overview of geological settings, climate, hydrology and land-use at the Po valley, Italy The size of the study is about 12500 km2. The extension is about 3 degrees of longitude (8°30’E 11°30’E), and 1 degree of latitude (44°50’N - 45°50’N). The regional authorities assessed 834 “fontanili” springs which are semi-natural lowland springs. The infiltrated water coming down from Alps tends to rise up from soil in a strip located in the flat area between Alps and river Po. Monks in the middle age drilled wells is this strip and they put pipes 5-10 m deep for increasing the soil depth above ground water table. Water rising up from soil by the pipes creates small ponds and canals. In the study 3 fontanili are monitored. The general conceptual model of the Po plain is that of a multi-aquifer system, made of porous sandy aquifers and clayey-silty aquitards. The alluvial nature of the deposits explains the stratigraphic complexity of the site. For modelling proposes, the agricultural development regional survey (ERSAF) divided the regional flat area into 14 homogeneous zones. The temperature in the region increase from North to South and from West to East, the annual average is between 12 and 13 °C. Rainfall increases from South to North and from East to West. The range of annual rainfall in the study area is between 600 and 1200 mm. The main uses in the study area are not irrigated arable land (63% of the study area), rice fields (9%) and urbanised (16%). At the present the trend show a reduction of agricultural uses with and a rise of urban uses (6.2% within 1990-2000). Rice crop is present in the Eastern and Western part of the region. Near 18 Milano monks realised “Marcite” system: springs were canalised allowing grass growth also during winter by thermal irrigation. Groundwater in this region is used as drinking and as irrigation water. Overview of geological settings, climate, hydrology and land-use at the Kromme Rijn site, The Netherlands The catchment of the Langbroekerwetering area, located in the province of Utrecht, comprises a network of artificial channels, of which the main channel of the network, the Langbroekerwetering, is about 135 km long. The water levels in the entire channel system are controlled by a series of hydraulic structures. The channel width is about 6—10 m. The depth is about 8 – 10 m and the mean discharge increases from about 20 m3/s to about 32 m3/s over a stretch of 2.8 km. The Doorn waste water treatment plant has a mean discharge of 4 m3 s-1 (1992—1993), flowing into the Langbroekerwetering via a 24 km long ditch system, which is in addition to diffuse sources from agriculture a major source of nutrients in the study area. The annual precipitation between 1971 and 2000 amounts to ca. 800 mm/a and the precipitation surplus is estimated at 270 mm/a. The mean annual temperature is about 10 oC. The hydrogeological scheme of the subsoil can be subdivided into low conductive layers (clayey and loamy material) and relatively high conductive aquifers (sandy and gravel-like material) due to fluvial sedimentation by the river Rhine before the building of dams. Human induced drift sands became common on the Utrechtse Heuvelrug. Only after artificial fertiliser became widely available in the second part of the 19th century, the Utrechtse Heuvelrug was reforested. Nowadays, most of the push moraines are covered with forest, both coniferous and deciduous. The groundwater flow South of the Utrecht Ridge is directed westward to the Kromme Rijn. At the Utrecht Ridge precipitation water infiltrates through the well-drained sand layers. Part of the infiltrated water exfiltrates at the foot of the Utrecht Ridge, at the transition between the high and lower sandy soils. Another section follows a longer path through the deep subsurface, in the first or second aquifer, and may locally seep upward in more westerly areas. The seepage influence is truncated by the presence of the Amsterdam-Rhine canal that makes a deep incision into the sandy aquifers. Also in terms of the landscape the canal is a formidable barrier. 19 1.1. Impacts and threats on groundwater dynamics, recharge and water balance of groundwater systems Three major reasons can be identified that significantly influence groundwater recharge and the water balance of groundwater systems. The most obvious cause of all is overexploitation, typically for the use as agricultural irrigation. At the Greek site the observed drawdown between the starting of the pumping period in May and the end in September reaches 20m. In Spain a maximum depletion of 100 m of groundwater levels has been reached in 30 years of exploitation. As a consequence, flow patterns of hydraulically connected surface water reservoirs become affected. At the Greek site the groundwater level decline induces recharge from Vosvozis River and Ismarida lake (which was not the case before), diminishing thus an important source for the wetland system. Another threat is the intrusion of seawater in the wetland area (which is also relevant at the Turkish lagoon site). In Spain the streamflow of the Jucar River becomes depleted. Thus, direct effects for groundwater dependent ecosystems are related to groundwater overpumping. The next reason deals with more general kinds of land use like gravel mining activities, increased sealing of ground surfaces due to urbanisation and industrialization and artificial groundwater recharge (washing sites, drinking water purpose) which all disturb natural conditions. An important component within this group is the regulation of rivers that interact with groundwater which may lead to riverbed erosion (potentially changing a feeding into a gaining river), the reduction of areal recharge from flooding due to embankments and the prevention of any water exchange due to the colmation of water reservoirs that were built for hydro power generation. A special case is the drainage of peatlands in Finland which results into an easier decline of groundwater levels in eskers. Increased drainage (e.g. installation of subsurface drains) has also contributed to the hydrological degradation in the Netherlands. Finally, climate change and with it the modification (or reduction) of seasonal water availability will influence groundwater dynamics and the water balance of groundwater systems. Especially in mountain regions small temperature variations will define the rainfall, snowfall and snowmelt. In the Swiss karst aquifer with no buffer capacity some pumping wells were abandoned after the dry summer of 2003, because their yield became insufficient. In addition, during the dry autumn 2009, the spring discharge (and hence the river discharge) was too low for hydroelectrical production and likely had also some affect on the river ecosystem. Furthermore, climate change may lead to increased agricultural irrigation. In detail the following characteristics on groundwater dynamics, recharge and water balance of groundwater systems are encountered at the respective case study sites. 20 1.1.1. Grue site, Norway Within the Grue study area, about half of the local households get their drinking water from local groundwater wells. In very dry years, some groundwater are also be used for irrigation of potatoes in parts of the area. At present, the current local use of groundwater does not cause severe impacts or threats on dynamics, recharge and water balance of the groundwater system in the case study area. However, locally altered flow patters around wells and areas with artificially increased recharge, e.g. washing sites, might be important for the local patterns of spreading of contaminants. Climatic changes may lead to increased agricultural irrigation and altered land use. Both river water and groundwater might be used for irrigation, and the effects of increased irrigation on the aquifer hydrology will differ dependent on the choice of sources water. Although several hydropower plants exists within the catchment of river Glomma, the degree of runoff regulation is low in Glomma, and hydropower regulation is thus have minor importance for the hydrology of the case study aquifer. 1.1.2. Rokua site, Finland A key hypothesis is that peatland drainage has resulted in changes ingroundwater dynamics. As the water is more easily drained from the esker, less groundwater gradient is required to maintain the natural outflow and hence the groundwater levels can have been reduced. To some extent the recharge can have been changed with climate or varied naturally. Also more intense construction of roads and housing might have changed runoff patterns to some extent. However, the site remains quite in natural state. 1.1.3. Murtal aquifer, Austria Gravel mining activities change the land surface and influence groundwater quantity and quality. Increasing urbanisation and industrialization leads to different groundwater recharge and higher water demand. Resulting groundwater level changes, as well as surface water flooding influence the ecosystem. Due to the restoration of natural dynamics of particular river sections flooding of the riverine area will change in areal extent and time. Additionally, artificial groundwater recharge using different sources of water is implemented. In general this type of groundwater shows an extreme vulnerability to climate change. 21 1.1.4. Zagreb site, Croatia The Sava river represents the main source of water for the Zagreb aquifer system. Although recharge also occurs through precipitation, the changes in the Sava river elevations dominantly influence the changes in the groundwater levels across the whole aquifer. Quantity of ground water is diminishing continuously due to negative trends of ground water levels. The main reasons for lowering of groundwater levels are (1) embankment of the Sava river which stopped occasional flooding of the area and potential infiltration to groundwater; (2) extensive riverbed erosion due to upstream Sava river regulation; (3) excessive pumping at the municipal and industrial well fields; and (4) prolonged drought periods. Ground water levels have already reached the minimum levels (top elevation of the well screens) on some well fields, causing water scarcity during droughts. 1.1.5. Vosvozis site, Greece The already conducted research revealed that Sidirohori aquifer shows serious groundwater level decline. Groundwater drawdown from May (beginning of pumping period) to September (end of pumping period) in certain location reaches 20m, leading to the obvious conclusion that the aquifer system is overexploited. Moreover, groundwater level decline induces recharge from Vosvozis river and Ismarida lake, diminishing thus an important source for the life of the wetland ecosystem. Another threat due to groundwater level decline is the intrusion of seawater in the wetland area, causing thus a serious alteration in the initial character of this protected ecosystem. 1.1.6. Mancha Oriental site, Spain The considerable development of the irrigation systems during the period 1975-2000 has caused significant decrease in the piezometric levels of the aquifer, which have been decreasing continuously since 1975. A maximum depletion of 100 m of groundwater levels has been reached in 30 years of exploitation. This water level decrease has also depleted the streamflow from the Jucar River. The estimated available groundwater resource is 325 hm3/year, while exploitation is close to 400 hm3/year (exploitations have been increased to 400 hm3/year in 2005, with a distribution of 96 % agriculture, 3.5 % urban water supply, 0.5 % industry). Despite a pumping wells substitution by using surface water has been carried out in recent years (with a 20 % of reduction), we are dealing with an overdrafted aquifer, which does not meet the good groundwater quantitative status as stated in the WFD. Furthermore, the Water Agency has made public offers to buy water rights from farmers (to stop pumping) in order to protect the river downstream users. Several measures are under study to control the overexploitation: pumping quotas, prices, improving global irrigation efficiency, pumping substitution by surface water, etc. It is worthwhile mentioning that the aquifer is planned to be declared as overexploited, which means that well extractions will be limited, irrigated surface will not be increased and users communities (irrigation districts) will be set up as a control mechanism. 22 1.1.7. Areuse site, Switzerland Mountain basins are the most vulnerable environments from point of view of climate change. Their fundamental sensitivity to temperature changes affects rainfall, snowfall and snowmelt. Climate change in mountain basins could therefore result in substantial changes in the runoff regime. Snowmelt runoff is an important source of groundwater recharge for the Areuse Spring. Temperature changes are particularly significant for region around or below 1000 meters because the winter mean temperature at this altitude is around 0°C and even small variations in temperature may determine if precipitation falls are rain or snow. A preliminary evaluation suggested that climate change could indeed modify the seasonal availability of water at the spring. During the last 40 years, the snow melting period has advanced by about 1 month and the associated discharge tends to decrease while no trends in the mean discharge rate can be identified. Possible effects of climate change on the water use became already noticeable in the past years. After the dry summer of 2003, some pumping wells within the karst aquifer were abandoned because their yield became insufficient. In addition, during the dry autumn 2009, the spring discharge (and hence the river discharge) was too low for hydroelectrical production and likely had also some affect on the river ecosystem. 1.1.8. De Kromme Rijn site, The Netherlands Most lowland stream drainage-basins have a high population density and the land use is very intensive. The permeable subsoil acts as an integrating medium, thus providing a widespread dispersal of leached nutrients and transmission of water-table lowering. Most of the adaptation options to climate change will have severe impacts on economic sectors and on individuals. Over the last 50 years much attention has been given to improving agricultural production, resulting in higher water demands. The increased population needs more drinking water, which is mainly abstracted from groundwater. This and other factors have caused changes in groundwater recharge and water tables to fall. Lower water tables have adversely affected conditions in nature conservation areas. Furthermore, changes in land use and increased drainage (installation of subsurface drains) have contributed to this hydrological degradation. 23 1.2. Impacts and threats on substances leaching to groundwater aquifers due to different land-uses A common threat to groundwater quality is linked to the non-point source pollution of nitrate leaching from the soil through the unsaturated zone into the groundwater body. Typically, the nitrate mass derives from disproportionate use (i.e. amount and timing of application) of fertilizer in agriculture. This situation is present in many of the test sites, as for example in Spain, where nitrate contents of 125 mg/l have been observed, in Greece, where nitrates in some boreholes were detected in much higher concentrations compared to the EU limits, or also in Austria. In the Dutch lowlands, at periodically high groundwater events, an important part of the incoming nitrate will be denitrified and the soil has a relatively low binding capacity for phosphate. The Mean Highest Groundwater level is a good indicator for such events. If and when the soil is saturated with phosphate depends on the presence of metal oxides (and lime), the historical phosphate surpluses and the current agricultural practice. Cold climates represent a special condition in this respect since findings of several pesticides from grain and potato production demonstrate that slowly degradation of pesticides can form an important threat to deterioration of groundwater resources. Additionally, when the frozen soil subsequently thaws, the temporary water storages rapidly infiltrate into the subsurface. It is hypothesized, that the use of mobile pesticides on such areas might represent a particular threat to the groundwater quality. Pesticides have also appeared in the aquatic system of the Turkish test site with dichlorvos showing very high concentrations in all sets of experiments. However, fertilizer and pesticide applications are not the only pollution sources. In the Zagreb aquifer an entire mixture of emission sources exists comprising leaky sewerage, the city landfill, agriculture, illegal waste depositories, illegal gravel pits and also industrial facilities. High concentrations of pollutants like nitrates, atrazine, heavy metals and chlorinated hydrocarbons in groundwater confirm the impacts. At the Greek site point sources of pollution are given by industrial activities which discharge their wastewaters in Vosvozis river or in its tributaries in an uncontrollable manner which feed the aquifer body during the vegetation period. A comparable mixture of pollution sources is produced by the different kinds of wastes (urban wastes, inerts, sludge, ashes, and metallic objects) that were dumped at the Italian landfill site leading to the contamination of groundwater by halogenated (mainly chlorinated) aliphatic hydrocarbons. An additional threat to residents exists through potential vapours migration through the unsaturated zone. Due to hydrogeological characteristics and a complex history of pollution the contaminants at the German “megasite” Bitterfeld show a distinct vertical stratification and strong local variability. The main components of organic contamination were found to be benzenes and ethenes. Evidence was found for the in situ transformation (reductive dechlorination) of these substances which shall be confirmed by the use of constructed wetlands at the laboratory and the field pilot scale. 24 Leaching of substances into groundwater is not only related to excessive pollution but can also be favoured by hydrogeologic conditions. MGWB 326 in Poland has a very low resistance against pollutions coming from the terrain mainly because of lack of an insulation Quaternary layer. It is vulnerable to any, even small pollution resulting in a quick degradation of water resources. The main factors that influence groundwater quality are high concentration of various economy sectors and infiltration of pollutants from the Warta river. Karst aquifers have also specific hydraulic and hydrogeologic characteristics that render them highly vulnerable to pollution from human activities. The principle sources and causes of the groundwater pollution at the Swiss test site can be summarized as disposal of wastewater and agriculture. Indicators of contamination with faecal matter are regularly detected at the spring during flood events. At two test sites experimental facilities have been set up to study the water movement and the pollutant fate in the soil and the unsaturated zone. In France five different types of wastes and farmyard manure are applied to 5 plots and the water quality is monitored within the first meter soil profile by various devices. The impacts and threats concern the modification of leaching (concentration and fluxes) due to the effects of organic amendments on soil properties. At the Austrian site 32 lots with 1000 m² each are operated to evaluate the impacts of growing corn compared to crop rotation on nitrogen leaching into the groundwater using different fertilizing schemes. In the middle of the lots two high precision lysimeters were built, one of each located beneath a corn monoculture and a crop rotation lot, respectively. Data concerning amount and nitrate concentration of the leachate are collected at several depths. 1.2.1. Grue site, Norway The major threat to groundwater at the Grue case site is assessed to be leaching of pesticides used in crop production. The case site represents an area with intensive agricultural production in an area with cold climate. Several investigations of pesticides and nitrate in groundwater have been carried out during the period 1995-2007 at the Grue study area (Eklo 1997, Eklo et al. 2002, Eklo et al. 2004, Ludvigsen et al. 2008). Findings of several pesticides from grain and potato production in several drinking water wells demonstrate that in cold climate with slowly degradation of pesticides, pesticide leaching can represent an important threat to deterioration of groundwater resources and groundwater dependent ecosystems. In climate with frozen soils in winter, melt water are gathered and temporary stored in local depressions in the terrain early in spring. When the frozen soil subsequently thaws, the temporary water storages rapidly infiltrate the subsurface. It is hypothesized that use of mobile pesticides on such areas might represents a particular important threat to deterioration of groundwater in cultivated areas. 25 1.2.2. Koycegiz-Dalyan (KD) site, Turkey The agricultural activities based on polyculture, basically cotton, citrus fruits, pomegranate, wheat, corn, and horticulture. Annual fertilizer consumptions for the year 1998 in the site was calculated as 146.8 kg/ha/year N, and 54.2 kg/ha/year P, which are almost twice the country’s averages. Pesticides use in the area is approximately 12 kg-l/ha which is quite high compared to overall annual consumption value for all Turkey (1.25 kg-l/ha). In the vicinity of the study area, nitrate analyses were made at 6 different GW stations. Average nitrate concentration was 15.8 mg nitrate/L and a maximum nitrate concentration was 21.7 mg nitrate/L. Surface and bottom water samples were taken from 16 stations along the lagoon channel network and Alagol and Sulungur Lakes. Four pesticides had appeared (endosulfan, deltamethrin, dichlorvos and diazinon) in the aquatic system. Analysis results were around and/or slightly higher than the limits except dichlorvos. Dichlorvos appeared in all four sets of experiments with very high concentrations. 1.2.3. Caretti site, Italy The contamination of groundwater is represented by halogenated (mainly chlorinated) aliphatic hydrocarbons, mainly Perchloroethylene (PCE), Trichloroethylene (TCE) and Vinyl Chloride (VC). The original source material (solid-liquid mixture of chlorinated pitches with unknown composition), once disposed in the two dumps, induced gravity-driven percolation of DNAPL down to the bottom of the original clay pits. The wastes in the pits consist of a highly heterogeneous mixture of urban wastes, inerts, sludge, ashes, and metallic objects, more or less dispersed in a silty-clayey matrix originating from the ground works connected to the clay quarrying and dumping operations in the past. Analyses of the silty-clayey matrix mixed with the wastes, performed in some samples collected over the 2001-2003 period, show concentrations exceeding regulatory limits of metals (As, total Cr, Ni), chlorinated ethenes and PAH. At Caretti site impacts on groundwater quality are really serious. The main threat interests residential people and it is represented by potential vapours migration through the unsaturated zone. 1.2.4. Feucherolles site, France Three composts have been applied once every two years since September 1998: a co-compost of sewage sludge and green wastes (SGW), a municipal solid waste compost (MSW), a biowaste compost (BioW). A farmyard manure (FYM) is used as reference organic amendment and a control treatment is realized without organic amendment (CONT). Five plots corresponding to each treatment have been instrumented to follow water fluxes (tensiometers and TDR probes) in the first meter soil profile and to monitor water quality (wick lysimeters, porous cups). This instrumentation has been done in 2004. Since then, we collect data on a weekly basis for water content and weekly/monthly basis for soil solution collection. Lately (October 26 2009) piezometers have been installed in the middle of each plot. They will allow to monitor water quality at 2 m depth in the perched water table formed in winter. The impacts and threats concern the modification of leaching (concentration and fluxes) due to the effects of organic amendments on soil properties. Several elements or potential contaminants are concerned: dissolved organic carbon (DOC), nitrate and other major anions, trace metals and pesticides. Monitoring the presence of other trace organic contaminants such as PAH, LAS and phthalates is also planned since some of these compounds are present in significant amounts in urban waste composts. 1.2.5. Murtal site, Austria In the centre of the Murtal aquifer (near Wagna) a large scale agricultural experiment is run since 1987 consisting of 32 lots with 1000 m² each. It is the aim of this setup to evaluate the impacts of growing corn compared to crop rotation on nitrogen leaching into the groundwater using different fertilizing schemes. In the middle of the lots two lysimeters were built 1992, one of each located beneath a corn monoculture and a crop rotation lot, respectively. Data concerning amount and nitrate concentration of the leachate are collected at several depths. With the help of geophysical site investigations 8 different soil types could be identified, the thickness of the top soil varies between 25 and 215 cm. Based on the lysimeter data the two models SIMWASER and STOTRASIM that describe the soil water balance and the transformation of nitrogen respectively have been calibrated. It is the purpose of the models to compute the leachate of nitrogen at the bottom of every individual “hydrotop” (unique combination of cultivation, soil thickness and soil type). 1.2.6. Zagreb site, Croatia Developments of industry and fast growth of the City of Zagreb have considerably affected quality of groundwater in this aquifer system. Increasingly progressive groundwater pollution in the heterogeneous aquifer system underlying the City of Zagreb has been observed for the last twenty-five years. The most significant pollution sources are leaky sewerage, the city landfill, agriculture, illegal waste depositories, illegal gravel pits, and also industrial facilities. High concentrations of pollutants like nitrates, atrazine, heavy metals and chlorinated hydrocarbons in groundwater confirm the impacts of pollution sources on groundwater quality. 1.2.7. Vosvozis site, Greece Land uses in the Vosvozis river basin are mainly agricultural, cattle breeding, industrial and urban/residential. Point sources of pollution are formed from industrial activities which discharge their 27 wastewaters in Vosvozis river or in its tributaries in an uncontrollable manner and by private septic tanks (half of the population is served by such systems). Agriculture is the diffusive source of pollution for the study aquifer system, merely through the application of fertilizers and pesticides. The already conducted research showed that the main pollutant present in the groundwaters in nitrates, which in some boreholes was detected much higher than the EC standards. DUTH has started monitoring pesticides in groundwaters of Vosvozis river. Initial results showed that they currently do not seem to pose a threat for the groundwater system of the study area. 1.2.8. Mancha Oriental site, Spain The representative crops grown in the area are corn, barley, wheat, sunflowers, and alfalfa. The crops require high quantities of fertilizer and water to maintain elevated agricultural yield. These agricultural activities have been admitted to be potential sources of nitrate pollution due to extensive application of inorganic fertilizers. The continuous fertilizer application during the last decades has led to observe nitrate concentrations higher than 50 mg/l, which is the maximum allowable concentration (Drinking Water Directive, 80/778/EEC and its 49 revision 98/83/EC). It should be pointed out that nitrate contents of 125 mg/l have been observed. However, significant differences have been found within the different domains considered. All these facts ended up with the declaration of the aquifer as a nitrate vulnerable area by the Castilla-La Mancha regional government (2003). 1.2.9. Areuse site, Switzerland Karst aquifers have specific hydraulic and hydrogeologic characteristics that render them highly vulnerable to pollution from human activities. Karst groundwater becomes polluted more easily and in shorter time periods than water in non-karstic aquifers. The principle sources and causes of the groundwater pollution in Areuse catchment area can be summarized as disposal of wastewater and agriculture. Indicators of contamination with faecal matter are regularly detected at the spring during flood events. Due to more intense precipitation events in the future, such contamination events may become more frequent. 1.2.10. Czestochowa site, Poland MGWB 326 has a very low resistance against pollutions coming from the terrain mainly because of lack of an insulation Quaternary layer. The reservoir (generally unconfined aquifer) is exposed on a considerable area and thus it is vulnerable to any, even small pollution resulting in quick degradation of water resources. Surface water – groundwater interaction cause infiltration of pollutants from the Warta river as well. 28 The following changes are foreseen in the land use: (i) spatial expansion of the city of Czestochowa, (ii) development of regional systems of road transport, (iii) development of tourism based on objects of cultural heritage, environmental attractions and mining heritage parks. The main factors that have significant influence on groundwater quality are: (i) High concentration of various economy sectors and very intensive exploitation of groundwater resources, (ii) Hydro - geological conditions which make water layers sensible to infiltrating pollutions. The research done by the Polish Geological Institute enabled to identify the pollution sources in the area and estimate their contribution to groundwater quality: Geogenic – 15%, Anthropogenic – 45% and for 40% of pollutions their origins were not defined. 1.2.11. Bitterfeld site, Germany The contaminants at the Bitterfeld site show a distinct vertical stratification and high concentration levels alternate with low or zero levels. The experience during the last years of groundwater sampling gives a clear evidence of a strong local variability of the detected contaminants. These two facts make it very difficult to state distinct concentration levels as well as certain organic substances or compounds. The ‘main components’ of organic contamination were found to be chlorobenzene, 1,2dichlorobenzene, 1,4-dichlorobenzene, benzene, trichloroethene, cis -1,2-dichloroethene and trans- 1,2dichloroethene. High organic pollution with halogenated hydrocarbons was confirmed in both aquifers. Contamination of the groundwater with inorganic pollutants (e.g. heavy metals, arsenic, etc.) has proven to be of minor importance. The only noteworthy feature is the high levels of sulfate (up to 1000 mg/l) and chloride (about 1300 mg/l). The regional distribution of contaminants reflects in general their different sources and pathways and gives first results from a regional point of view, depending on the land-use classification of specific areas, e.g. industry, mining, settlements, agricultural and alluvial plains/meadows. Based on parts of this data set (290 wells, 1200 samples, each up to 180 contamination parameters), a specific contamination profile for this region was derived on the base of available monitoring data within the SAFIRA project. The influence of important parameters like detection limits and the statistical measures to estimate the average detected concentration on the results of the ranking procedure were investigated. Furthermore, a cluster analysis with the two criteria, detection frequency and average-detected concentration, reveals substances with similar behaviour in the environment in terms of persistence and mobility, and improves the contamination profile at the regional level. It was found that the median is the most suitable measure. High median values of more than 10 mg/l were calculated for cis /trans-1,2dichloroethene, 1,2-dichloroethane, chloroethene and monochlorobenzene. Using concentration and compound specific analysis (CSIA), several studies were performed in Bitterfeld to investigate the in situ transformation of chlorinated ethenes and benzenes. Findings indicated the reductive dechlorination of chlorinated ethenes and benzenes. It was suggested that 29 monochlorobenzene (MCB) was degraded under the anoxic conditions present in the aquifer. A further investigation using stable isotope tracers combined with in situ and well laboratory microcosms confirmed the mineralization and assimilation into microbial biomass of carbon derived from MCB. The research within GENESIS will focus on model systems, in this case constructed wetland systems with different sizes is planned, for the transfer of contaminated groundwater through a subsurface wetland system to an open water body: 1) laboratory scale and 2) a field pilot scale wetland, both running with contaminated groundwater from Bitterfeld. Previous research found reductive dechlorination of the dichloroethene via vinyl chloride to ethene and corresponding compound specific isotope fractionation and presence of groups of microorganisms capable of reductive dechlorination in a small laboratory scale wetland system. 1.2.12. Po valley site, Italy Because the dominant land use in the study area is “annual crops”, the most important class of pesticide in the study area is represented by herbicide. In Pavia province a high use of fungicides is recorded, but most of the hill part of this province is under vine crop. Regional administration reports that nitrates are the most important pollutant. The Administrator already identified vulnerable areas. In agriculture, the main distribute specie is amide. Urea is the most important fertiliser on maize crop. Animals and population are further important sources of nitrogen in the environment. A gap in knowledge exists in the description fate of pesticides and nutrients from groundwater to fontanili and from adjacent fields to fontanili. 1.2.13. De Kromme Rijn site, The Netherlands Sources of contamination to the deep and shallow groundwater in the study area include contamination with nitrate, phosphate and pesticides due to agriculture and various contaminations caused by roads, industrial sites, landfills, weed control, urban constructions and effluent discharges of wwtp’s. At periodically high groundwater events, an important part of the incoming nitrate will be denitrified and the soil has a relatively low binding capacity for phosphate. The Mean Highest Groundwater level is a good indicator for such events. If and when the soil is saturated with phosphate depends on the presence of metal oxides (and lime), the historical phosphate surpluses and the current agricultural practice. Combating diffuse pollution by nutrients is complicated by various factors: the cause-effect relationships are less clear and there is a large time lag between taking measures and actually seeing positive effects. 30 1.3. Impacts and threats on groundwater dependent ecosystems interacting with surface water In principle threats to groundwater dependant ecosystems may have a quantitative background (e.g. lowered water table), consist of a water quality issue (any kind of pollution) or are a combination of both (see previous chapters). In the case of interaction between groundwater and surface water bodies the ecosystem within the riparian zone (i.e. discharge area) will always be involved. In the following overview these test sites are shortly introduced that predominantly deal with impacts on groundwater dependant ecosystems. Due to surface streams or shallow groundwater that may contain significant concentrations of nutrients the risk of eutrophication of ecosystems exists in such different environments as the Greek coastal lagoon (nutrients coming form waste water discharge) and the shallow weathered bedrock aquifer in the Czech Republic (nutrients coming as leachate from agricultural fertilizer). At the latter site the situation is even worsened because of acid athmospheric depositions influencing the natural pH and the seepage of mine waters containing a variety of heavy metals. These elements have a direct toxic or inhibit effect on the fluvial biota as the riverbed sediments are incrusted by iron and manganese oxides to the dept about 10 – 15 cm. In the Po valley, Italy, a special GDE exists by so called fontanili, which basically are artesian wells dug by monks in the middle age. The role of the riparian strip is of particular interest in studying the movement and fate of pesticides and nutrients from groundwater to fontanili and from adjacent fields to fontanili. Equilibrium shifts in freshwater bodies, as a result of nutrient loading, have been reported at the Dutch test site. Water bodies characterised by clear water, macrophytes and predator fish (pike and pike perch) have been replaced by turbid water systems dominated by algae and freshwater bream, which is not a popular recreational fish. Another ecosystem test site is given by the Niepolomice Forest in Poland. It is a relatively large (ca. 80 km2), groundwater-dependent forest complex with wetlands and marsh areas occurring in several parts of the forest. Impact of long-term changes of water balance (including the impact of climate change) and anthropogenic pollution on the ecosystem functioning have been studied. The aquifer became a testing ground for different tracer methods to explore the dynamics and time scales of groundwater renewal and to build a good conceptual model, which is the basis for 3d numerical flow and transport modeling. The discharge pattern of Luleå river has changed after regulation, with high discharge values during the autumn and the ice-covered winter period and a decreased spring peak. Instead of overflooded areas during snowmelt, the water balance shows a net outflow of water in May, which lowers the water level in the reservoir one metre. During the summer, the water balance is positive and water is stored in the reservoir. The riparian zone processes are therefore altered compared to an unregulated river. Fe, Si, and P are retained in the reservoirs. This retention can be an effect of increased diatom production in stored water. Other chemical elements which are locked in reservoirs are S, DOC and Mn. 31 In detail the following site characteristics of groundwater dependant ecosystems are encountered at the respective case study sites. 1.3.1. Grue site, Norway The main ecosystems influenced by groundwater hydrology and quality are the riparian zone in the discharge zone along the river Glomma. These ecosystems can be affected by groundwater contaminations and changes in groundwater hydrology. The river Glomma is the main receptor of the groundwater discharge from the case study area and will therefore be affected if the aquifer became polluted,. However, compared to the riparian zone, the proportion of water in the river originating from the agriculturally influenced aquifers along the rivers will be fairly small. A small groundwater influenced lake, the Lake Gruetjern, previously occurred within the case study area. However, recently the lake has been filled in by the Norwegian Water Resources and Energy Directorate as a part of an improvement of the flood protection constructions along the river. This may illustrate that groundwater dependent ecosystems are at risk of several reasons and may stress the importance of taking into consideration the requirements of the remaining groundwater dependent ecosystems in future groundwater management. 1.3.2. Rokua site, Finland The main threats at Rokua are related to forest drainage of peatlands surrounding the esker, climate change, some urbanization and to some extent water regulation. The main concern is that water levels in small lakes situated in the groundwater aquifer have been declining for the past decades. Different reasons for this decline have been discussed such as climate change or the land use and drainage, but this is yet uncertain as research is lacking on this complex ecosystem. It is essential for local residents, tourism and property owners of the Rokua communities to solve the reasons for the decline. The aquifer has a large value for recreation and nature conservation. Part of the aquifer is already protected by Natura 2000. 1.3.3. Koycegiz-Dalyan (KD) site, Turkey Variations and changes in climate might be significant factors for the overall changes in the flow regime. During extreme precipitation events, such as heavy rain fall and storms, since most of the precipitation is lost as run-off, less recharge to groundwater is expected. There are many springs and hot springs in the watershed. Particularly, the hot springs are significant, as they are among the facilities which attract tourists to visit the area. Coastal aquifers are sensitive to changes in water budget due to the interaction 32 between fresh and salt water in the subsurface along the coast. As recharge is decreased, the position of the freshwater and saltwater interface will move inland at a rate that is proportional to the decrease in recharge, and water quality can be compromised to the extent that freshwater availability is limited. 1.3.4. Vosvozis site, Greece Komotini’s wastewater treatment plant discharges treated wastewaters in Vosvozis river. Special attention should be focused on the Komotini’s industrial area which is not located within Vosvozis river basin but adjacent to it. This industrial area comprises plastic, paper, wood, food processing plants, as well as a thermo-electric power producing plant. Industrial waste waters are disposed in Filiouris river which discharges in the coastal lagoon ecosystem, thus forming a serious threat to it. The already conducted research showed that the main threat to the wetland ecosystem is eutrophication, diminishing its aerial and seawater intrusion which seriously affects the fragile wetland ecosystem. 1.3.5. Sumava site, Czech Republic Most of the former farmlands and meadows in the Lenora area were changed for pastries with an increased number of cattle breeding in the area. The cattle is held both on open pastries and inside stables with significant liquid and solid waste production that has been used for crop fertilization back at the pastries and meadows. The impacts on groundwater are significant, because of a quick response in water infiltration. There’re increased concentrations of nutrients present in the ground water (nitrates, nitrites, ammonia, phosphates...etc.) having negative impacts on groundwater quality. The results are decreased values of present ground water resources, because major ground water flow occurs in a shallow weathered bedrock aquifer only. Even more important impacts there’re negative influences on peat bogs and marshlands because of its oligotrophic ecosystems, which are very sensitive to nutrient leachate from agriculture. The negative impact combines with acid atmospheric deposition that influences natural basic pH of valley peat bogs. There exists a risk of eutrophisation especially from surface streams or shallow groundwater that may contain significant concentrations of nutrients. The leaching mine waters are a significant source of a variety of heavy metals, in the stream of Golden Creek there have been also high contents of iron and manganese observed. These elements have a direct toxic or inhibit effect on the fluvial biota as the riverbed is incrusted by iron and manganese oxides to the dept about 10 – 15 cm. This situation is well describing importance of bottom layers permeability and connectivity to hyporheic zone. To assess the direct impact of mine waters, there’s necessary to perform detailed flow experiments with use of appropriate tracers. Besides, there can be 33 indicia of mining technologies detected – namely limited solvents applied during the construction of Nadeje adit and possible relicts of mine installation (esp. floating and sedimentation cycle). 1.3.6. Czestochowa site, Poland Attention is focused on the NATURA 2000 area covering the southern part of the Wiercica river basin, where headwaters of the river are located (springs controlled by groundwater discharge). Good water quality as well as specific climatic conditions are favourable for existence of mosaic of biotops: in dry and warm conditions some southern species are met while in wet and cold - mountain and boreal ones. In the area significant groundwater resources are documented (30 000 cum/day), planned for exploitation after 2025. 1.3.7. Bogucice site, Poland Eastern part of the upper aquifer is occupied by Niepolomice Forest. This is a relatively large (ca. 80 km2), compact, groundwater-dependent forest complex. The depth of water table is generally shallow, with wetlands and marsh areas occurring in several parts of the forest. The Niepolomice Forest is part of NATURA 2000 network (code: 12 0002). Impact of long-term changes of water balance (including the impact of climate change) and anthropogenic pollution on the ecosystem functioning within the Niepolomice Forest has been studied. The GDE protection needs good conceptual model with dynamics and time scales of groundwater renewal. The aquifer became a testing ground for different tracer methods, used in combination with 3d flow and transport modeling. There is also some evidence of contamination from a linear source of pollution, a contaminated river draining large municipal landfill located close to the southern border of the aquifer. 1.3.8. Lule site, Sweden In order to study hydropower regulation impact on river-groundwater interaction, two study locations were chosen: Luleå river case study was taken as a primary location and Kalix river case study (pristine conditions) as reference one. The sites were chosen to be similar in climate, topography, river width, geological and geohydrological settings. Difficulties with site identification are dense forest areas, steep embankments of both rivers in some places, and private land use. Discharge maximum in Kalix river occurs in May-June and has its winter base flow much lower, than that in Luleå river. Kalix river is mainly fed by dominating groundwater inflow during winter, while high water level in Luleå river reservoirs most probably effects this pattern and we might observe water loss from the river. The discharge pattern of Luleå river has changed after regulation, with high discharge values 34 during the autumn and the ice-covered winter period and a decreased spring peak. Instead of overflooded areas during snowmelt, the water balance shows a net outflow of water in May, which lowers the water level in the reservoir one metre. During the summer, the water balance is positive and water is stored in the reservoir. The riparian zone processes are therefore altered compared to an unregulated river. A thermocline is observed in the reservoir at a depth of 10-15m. Below this depth temperature, pH and dissolved oxygen decrease. However, the bottom water is still well oxygenated. As a result different from prior to regulation period amount of nutrients and other elements reach the Gulf of Bothnia. This applies also for the year season when it happens. Reservoirs construction and flow fragmentation as a result cause river to act as a sink. In such way Fe, Si, and P are retained in the reservoirs. Si is also trapped in water storages. This retention can be an effect of increased diatom production in stored water. Among other chemical elements and compounds which are locked in reservoirs are S, DOC, Mn. Kalix river receives most of its dissolved and particulate fractions from schist and spatially distributed outcrops of dolomite and limestone, located in Caledonian mountains. Midsummer flow dominates by high Ca concentrations, indicating large influence of water from the mountain area. During May when snowmelt appears in plane part of the river, water from woodland areas has major influence. This is indicated by elevated content of Si in river water. Si is related to TOC (peatland is a source), which is also high during the spring snowmelt. 1.3.9. Po valley site, Italy Fontanili are the dependent GW ecosystem studied into the project. They are mainly located in an agricultural landscape. Tough they are artificial systems they are heritage landscape elements. The main thread of these ecosystems comes from agriculture: pesticides and nutrient pollution and from land use change, in particular from urbanisation. 1.3.10. De Kromme Rijn site, The Netherlands Eutrophication (nitrogen and phosphorus) is the big issue for regional waters, where drainage of agricultural land leads to nutrient levels far exceeding standards. Eutrophication is probably aggravated locally by effluents from WWTPs that do not use technologies to extract nutrients, by urban storm waters, and by proximity to traffic routes via atmospheric deposition of nitrogen. Equilibrium shifts in freshwater bodies, as a result of nutrient loading, have been reported. Water bodies characterised by clear water, macrophytes and predator fish (pike and pike perch, popular with recreational fishermen) have been replaced by turbid water systems dominated by algae and freshwater bream (Brasem brasem), which is not a popular recreational fish. Standards in regional waters are 35 exceeded for many hazardous substances (heavy metals, pesticides, PAHs and PCBs), but usually to a lesser degree than for N and P. 1.4. Possible gaps with the WFD and/or GWD Based on the experience within the relevant test sites possible gaps of the WFD and the GWD are related to unconsidered processes, non-existing tools, missing thresholds neglecting uncertainty bounds and implementation glitches. Climate change is not directly covered in the WFD or the GWD. However, the changed water availability could lead to an imbalance between water availability and water use, violating Art. 4 of WFD, which imposes to ensure equilibrium between withdrawal and renewal of water. Furthermore, important gaps exist in knowledge about spreading patterns and advisory tools to prevent pesticide pollution of groundwater and groundwater dependent ecosystems in areas with winter climate and intensive crop production. Such tools will be important to be able to fulfil the implementation of the programmes of measures required by the directives. In the case of unmanaged landfills groundwater vulnerability maps concerning potential sources of point contamination should take both active risk centres and old/inactive risk spots into account. Definition of threshold values and environmental indices should not only reflect on the preservation of human health but also consider the needs of wetland ecosystems. In general, uncertainty in threshold values might reveal difficulties in assessing environmental and resource costs in this area. Though the peatlands lay in the groundwater discharge zone, these areas have not been considered as part of the aquifer or as part of the Natura 2000 protection area. An improved conceptual model for the groundwater dependent lake systems could solve the situation. For other test sites an integrated water management plan has not been developed yet. In the Netherlands a special situation exists since over many centuries natural water systems have been strongly adjusted and artificial structures built. Due to the high population density and to cope with an expected increase in flood risks multi-functional land use is seen as a key element of the solution to many of the current problems. In detail the following possible gaps within the WFD and the GWD are encountered at the respective case study sites. 36 1.4.1. Grue site, Norway Despite the importance of pesticides and nitrate in the GWD, as illustrated by the common European groundwater standard for these substances, there are still important gaps in knowledge about spreading patterns and advisory tools for pesticides in areas with cold climatic conditions. A main objective in the study at Grue is to improve the knowledge base for these issues and develop and test of advisory tools for measures to prevent pesticide pollution of groundwater and groundwater dependent ecosystems in areas with winter climate and intensive crop production. Such new knowledge and tools will be important to be able to fulfil the implementation of the programmes of measures required by the directives in a satisfactory manner. Another important contribution to the knowledge base for future implementing of the WFD and GWD is the new scenarios of impacts of land use on groundwater under altered climatic conditions. 1.4.2. Rokua site, Finland At present, the main treats seem to come from areas outside the actual area classified as the aquifer. The peatlands lay in the groundwater discharge zone and these areas have not been considered as part of the aquifer or as part of the Natura 2000 protection area. For protection of groundwater dependent ecosystems we need to better define the impacts of drainage and also the natural variability or impact of climate change. Also we need a better conceptual model for the groundwater dependent lake systems within the esker. 1.4.3. Koycegiz-Dalyan (KD) site, Turkey There are water unions in the watershed; however, an integrated water management plan is not developed yet. Thus, there are lots of wells in the watershed, with a depth of less than 10 m used by the households. Almost half of the wells are illegal, so the amount of water abstracted from the groundwater cannot be controlled, which causes the excess use of groundwater and seems to be threat on the system. Preventive actions towards decreasing the impacts of fertilizers and pesticides have been initiated by means of a protocol related to good agricultural practices in the special protection areas. 1.4.4. Caretti site, Italy Caretti site represents a story that can be replayed in other countries with environmental laws less restrictive with respect to Italy ones. In other words, what took place in Italy on the ‘60s-‘70s could take place again in other countries less developed concerning environmental protection laws. 37 A peculiar topic arising from this case study is the need of groundwater vulnerability maps that, concerning potential sources of point contamination, take into account both active risk centres (farms, chemical plants, nuclear plants,…) and old/inactive risk spots (like dumps, quarries, landfills, …). Regulatory laws could oblige to define sensitive areas around these potential sources of contamination and to make hydrogeological surveys before urbanization processes. 1.4.5. Zagreb site, Croatia Possible gaps might be expected regarding the assessment of the chemical status for the groundwater bodies in Zagreb area being at risk of failing the environmental quality objectives for groundwater. This assessment should be based on groundwater (environmental) quality standards and threshold values of pollutants and indicators of pollution. Unfortunately, the extent of interactions between groundwater and associated aquatic/terrestrial ecosystems, as well as the geochemical background values are still under investigations, so the threshold values might be underestimated or overestimated. According to the Guidance Document No 1of European Commission (Economics and the Environment – The Implementation Challenge of the Water Framework Directive), uncertainty in threshold values might reveal difficulties in assessing environmental and resource costs in this area. Furthermore, currently there is not enough evidence on the complete list of all pollutants characterising GW bodies in Zagreb area as being at risk. 1.4.6. Vosvozis site, Greece The main issue that should be addressed through Vosvozis case study concerning the WFD – GWD is the definition of threshold values and environmental indices not only for the preservation of human health but also for the wetland ecosystem. 1.4.7. Areuse site, Switzerland The main threats to the system are related to climate change that is not directly covered in the WFDGWD but is also an important process investigated within the GENESIS project. However, the changed water availability due to climate change could lead to an imbalance between water availability and water use, violating Art. 4 of WFD, which imposes to ensure equilibrium between withdrawal and renewal of water. 1.4.8. De Kromme Rijn site, The Netherlands Management and organisation of the watersystem is a major cause of the poor ecological score. The factors to be considered of importance comprise water table management; presence of dykes, barriers 38 and pumps; hardening of river banks and maintenance (mowing, duckweed, too much or too little dredging). The Catchment Vision of the Waterboard provides a blueprint for policy development during the period up till 2050. With regard to reducing flood risk, the following preferential sequence of measures is upheld: (1) holding on to the water as much as possible, i.e. micro-scale buffering in the headwaters of a catchment; (2) if that is not possible, storing it within the catchment, i.e. meso-scale buffering along the transporting subsystem; (3) if all fails, only then discharging it to the downstream area. So-called search areas have been identified for creating storage of water, intended as peak flow storage for combating downstream flooding and seasonal storage for combating problems caused by prolonged droughts. With respect to flood prevention, the target is to become ‘climate proof’, i.e. to solve problems induced by climate change in a region itself, and thus to not ‘export’ the problems to the downstream areas. In general, multi-functional land use is seen as a key element of the solution to many of the current problems. 1.5. Impacts and threats on groundwater systems and River Basin Management Plans Within the WFD the river basin was introduced as a single system of water management, i.e. administrative or political boundaries were replaced by geographical and hydrological units. The WFD substitutes several older and diverse directives and requires that at the river basin all existing technology-driven source-based controls must be implemented to limit water pollution. For surface waters good ecological status (quality of the biology community in combination with hydrological characteristics) and good chemical status are postulated by the WFD. Furthermore, other uses or objectives are foreseen that either imply higher protection measures or that, in special cases, allow for derogations from the overall requirements. Such cases include flood protection, drinking water supply, navigation or power generation. For groundwater, likewise, good chemical (no direct discharge into aquifers, monitoring requirements for groundwater bodies) and quantitative (abstraction limited to sustainable resource) status are called for. To coordinate the efforts towards the goal of good status for all waters river basin management plans (RBMPs) had to be elaborated. The key objectives comprise general protection of the aquatic ecology, specific protection of unique and valuable habitats, protection of drinking water resources, and protection of bathing water. Each RBMP is a comprehensive document of how the objectives set for the river basin are to be reached within the defined timescale including an assessment of the existing 39 legislation and if additional measures will be necessary. Additional components consist of an economic analysis of water use and the need for public participation. At the moment RBMPs exist only for some of the countries where the GENESIS test sites are located. Turkey, Switzerland and Croatia are currently not implementing the WFD. In Spain and Greece consultations have not yet started and in Poland consultations await adopting. Thus, active RBMPs exist for Norway, Sweden, Finland, Germany, The Netherlands, France, Italy, Austria and the Czech Republic. However, in some cases (e.g. France and Finland) the test sites are not really attached to a surface water network. On the basis of the Austrian RBMP the potential use of the discussed threats to groundwater systems and the suggested counteractions shall be evaluated. Austria is drained by the three major European rivers Danube, Elbe and Rhine, of which the Danube catchment in Austria is by far the largest of the three. The Lower Murtal aquifer is attached to the river Mur that discharges into the Drava river which flows into the Danube in Croatia. On a national scale, groundwater pollution by point and diffuse sources as well as quantitative pressure through withdrawals is estimated within the Austrian RBMP. Waste water treatment plants and abandoned hazardous sites are mentioned as potential point sources; however, due to only local impacts there is no risk for the good status of an entire groundwater body. Diffuse sources of pollution are existing through input of nutrients and pesticides from agricultural land management. The average nitrogen surplus in 2007 is 35 kg/ha. Based on surveys between 2006 and 2008 3 out of 136 groundwater bodies do not have good chemical status due to nitrate concentrations but all groundwater bodies comply with pesticide thresholds. Only 3% of the total groundwater resources are extracted for consumption purposes. The test site Lower Murtal aquifer is classified as an observation area indicating that the good chemical status is still met but that first measures to identify the sources of pollution have to be started. More than 30% of the observation wells (25/56) exceed the Austrian nitrate concentration threshold of 45 mg/l in groundwater. An increasing trend of nitrate concentrations in the aquifer around the agricultural research station in Wagna between 2002 and 2007 could be successfully reversed. It is explicitly stated in the Austrian RBMP that the prediction of the impacts of initiated actions to reduce pollutant input is extremely difficult since the heterogeneous soil and subsurface conditions combined with varying meteorological conditions strongly influence transfer and reaction processes. With respect to diffuse pollution sources originating from the agricultural sector (i.e. nitrate) legislative and monetary measures have already been implemented. Legislative measures comprise: periods where nitrogen fertilizers may not be applied, regulations for storage of animal manure and quantitative limitations of nitrogen fertilizers that may be applied. Financial incentives include among others: application of crop rotation, taking land out of agricultural production, 40 lot specific documentation of agricultural practices, application of Nmin method, sowing of catch crops with corn and continuing education. Future measures that are planned to be implemented consist of crop specific fertilizer application and fertilizer application based on measured volumes of remaining nitrate in soil abdication of fertilization in autumn after harvest of main crop and increase of storage capacity to enable regional animal manure management. Finally it is emphasized that it might be difficult to timely evaluate the above measures due to long groundwater renewal times (up to 30 years in some areas). Summarizing, the major impacts and threats to groundwater systems as well as general, and in some cases also specific, measures to counteract are included within the national RBMPs. However, due to the scale of the basin perspective little attention was attributed to the significance of local hydrogeological and meteorological conditions, though the importance of these factors is acknowledged. For most of the GENESIS test sites the national RBMP do not provide new information since the sites were actually selected because of existing problems with groundwater quality and/or quantity. Thus, the national RBMPs can be seen to give valuable input as starting points with respect to suggested measures for the process oriented research work in GENESIS. Moreover, the modelling and scenario WPs will enlarge the available toolbox to quantify and assess the impact of land use scenarios onto groundwater systems and GDEs. 2. A general overview of modeling approaches used and their purposes By this chapter we wanted to document for which purposes what kind of models have already been applied at the test sites. In particular, the focus is on data needs and availability as well as on identification of modeling requirements. At some sites a lot of modeling experience already exists in diverse aspects, thus the aim is at extension or further refinement. Higher spatial resolution of existing 3D flow and transport regional model (Visual Modflow Pro) will be introduced at the Bogucice site. Also, improvement of model structure, better characterization of surface water – groundwater interaction and inclusion of GDE (more stable isotopes measurements needed) problems is envisaged to better define GWD requirements with respect to DWPA and GEPA. 41 At the French experimental site the plot scale is the spatial scale of interest. For water transport a combination of HYDRUS_1D and the crop model STICS is applied. The model CANTIS has been used to fit the decomposition of organic matter and N dynamics in the top soil. The CANTIS model is integrated as a module in the transport model PASTIS (Prediction of Agricultural Solute Transformations in Soil). PASTIS will simulate nitrate losses and balances in each treatment. A similar model approach was developed at the agricultural test site in the Murtal aquifer. Numerical models describing the soil water balance (SIMWASER) and the transformation of nitrogen (STOTRASIM) are being combined to compute the leachate of nitrogen at the bottom of every individual “hydrotop” (unique combination of cultivation, soil thickness and soil type). Furthermore, data sets from monolithic high precision lysimeters (sine 1987) may be used to validate unsaturated flow and transport models and their coupling with a groundwater model in order to predict the impact of land use changes on the water cycle. To illustrate how washing sites for pesticide spraying equipment might contaminate neighbouring drinking wells, the pattern of groundwater flow in a small area was simulated with Modflow and ModPath at the Grue site. To illustrate the importance of diffuse pollution from different soils and the leaching of different pesticides, MACRO_DB and PRZM have been used. However, the models have not been coupled, and the leaching models have not been calibrated and validated against results from field experiments. For the Spanish site a socio-hydro-economic modelling framework is developed which allows selecting sustainable cost-efficient measures and management strategies to achieve a good quantitative and chemical groundwater status in an uncertain environment. An optimization model is a central element that enables to define efficient fertilizer allocation in agriculture so that the environmental constraints can be met. Since emissions are what can be controlled, but the concentration at the receptor sites are the policy targets, it is necessary to relate both through the proper numerical simulation of the pollutants leaching, transport and fate within the aquifer. The response matrix describes the influence of pollutant sources upon concentrations at the control sites over time. Crop production and nitrogen leaching functions can be derived from agronomic simulation models like EPIC. For a couple of other test sites clear visions exist about future numerical model applications. At the Italian landfill site the general idea is modeling organic compounds migration from the source to the human receptors. The needs related to modeling are taking into account biochemical attenuation processes and assess the risk for human receptors related to vapours migration through the unsaturated zone. Missing data include hydraulic connection between aquifers and assessment of biodegradation rates by means of contaminant isotopes. For the Zagreb aquifer the universal transport modeling approach consists of achieving a better understanding of the transport regime of heavy metals and quantifying the dominant controlling process. The Greek partner plans to use the SWAT model to predict the impact of various land management practices on water, in large complex watersheds with varying soils, land use and management conditions 42 over long periods of time. Furthermore, DUTH has recently installed 3 lysimeters on selected sites. Results will be used as boundary conditions for groundwater modelling. At the Dutch site an integrated hydrological model comprising modules for saturated groundwater, unsaturated soil water and surface waters is already in operation. To avoid long computation times simulation runs just for extreme events, so-called method of stochasts, have been made operational in combination with the SIMGRO-model. For each of the stochasts a discrete number of realizations are defined, which are then combined to events. For each of the model cells the results are evaluated in terms of inundation depth, yielding cumulative frequency functions. In detail the following modelling approaches have been implemented at the respective case study sites. 2.1. Grue site, Norway Some groundwater and leaching simulations have been performed at the Grue site as minor parts of a previous project surveying pesticide contents in groundwater. To illustrate how washing sites for pesticide spraying equipment might contaminate neighbouring drinking wells, the pattern of groundwater flow in a small area around a selected washing site was simulated with Modflow and ModPath. To illustrate the importance of diffuse pollution from different soils and the different leaching of different pesticides, MACRO_DB and PRZM have been used for to simulate pesticide leaching from different soils. Contrasting the holistic perspectives in Genesis, the previous model simulations were performed to illustrate separate questions and the models have not been coupled, and the leaching models have not been calibrated and validated against field results from field experiments. The simulation models and the underlying conceptual models are based on results from soil investigations and analyses, but have not taken into consideration the impacts of winter climate and local topography. The approaches, the coupling of models and the field experiments providing data for model calibration and verifications thus makes the modelling in Genesis clearly different from the previous preliminary modelling at Grue. 2.2. Caretti site, Italy At Caretti site the general idea is modeling organic compounds migration from the source to the human receptors, through GW flow system. The conceptual model is a multi-aquifer system, where a first shallower aquifer and the 1st confined regional aquifer are affected by contamination. Source of contamination is located below water table. Contamination is represented by chlorinated organic compounds, mainly VC, TCE and PCE. The most dangerous for human health is represented by VC. 43 No numerical model of Caretti site (local scale) has been done until now, because UNIFE is performing a new detailed characterization of the site (WP2 and WP3). The needs related to modeling are: Study the contaminant migration, taking into account biochemical attenuation processes; Predict migration of contaminants; Assess the risk for human receptors related to vapours migration through the unsaturated zone. Missing data include: Hydraulic connection between aquifers and with direct and lateral recharge (cooperation started with UFZ in order to analyze environmental isotopes) transport parameters of the aquifers (WP3); solutes parameters with respect to transport processes (WP3); assessment of natural attenuation processes (cooperation started with UFZ in order to assess the biodegradation rates by means of contaminant isotopes, microbiological essays). 2.3. Murtal aquifer, Austria The model SIMWASER describes the relation between soil water balance and plant growth depending on weather, plant and soil characteristics on a daily basis. On top of that the nitrogen and carbon dynamics within the soil are simulated by the STOTRASIM model. The combination of the two models allows for the computation of nitrogen leaching beneath so-called hydrotopes which represent a unique combination of lot cultivation, soil type and soil thickness. The resulting groundwater recharge and nitrate concentration time series are further used as input conditions to a transient model of saturated groundwater flow. This output-input coupled model is well calibrated for a 15 years time period and can be used for scenario calculations of the spatial and temporal impacts of different land use options on groundwater quantity and quality. The scenarios also comprise the prediction of extreme events or the impact of climate change effects on the water cycle. The collected data sets from monolithic high precision lysimeters in combination with groundwater monitoring results may also be used to validate different sets of unsaturated flow and transport models, even a model comparison for simulating nitrate leaching can be carried out. 2.4. Feucherolles site, France Spatial scale of interest is the plot scale. INRA EGC is currently using several approaches to model the transport of water and solutes through the soil profile. 44 For water transport, HYDRUS_1D and the crop model STICS are combined. HYDRUS_1D is used to get hydrodynamic parameters by inversion of the field data on water content and water potentials in the different instrumented plots (i.e. corresponding to the five different treatments 4 organic amendments and control). STICS is used to get the crop/plant parameters taking into account the dry mass production and crop yields in each treatment plot. These parameters are used to describe water uptake by the crop in HYDRUS_1D. Concerning nitrate, the set of parameters has to be enriched with parameters concerning the dynamics of organic matter and nitrogen. These data originate from laboratory scale incubation experiments. The model CANTIS has been used to fit the decomposition of organic matter and N dynamics in the top soil for the several plots of the field trials. The CANTIS model is integrated as a module in the transport model PASTIS (PASTIS Model, Prediction of Agricultural Solute Transformations in Soil Monodimensional Transport). PASTIS simulations will be done using the set hydrodynamic and crop parameters validated with the Br experiment. PASTIS will simulate nitrate losses and balances in each treatment. Losses of N by leaching concern the amount of N leaving the first 1,2 m of the soil profile. The simulations will be compared to nitrate balances estimated from measurements in the soil profile and from crop exportations. 2.5. Zagreb site, Croatia The general transport modeling approach consists of achieving a better understanding of the transport regime of heavy metals and quantifying the dominant controlling process. For that purpose the two sites within the Zagreb aquifer system are chosen, the Stara Loza wellfield and the new Kosnica wellfield which is still in the planning phase. Since the background values for heavy metals are missing, the approach where initial conditions are set to zero everywhere in the model domain will be applied. Data needs exist in the following areas: Hydraulic conductivity and effective porosity parameters. Geochemical (heavy metals) maps of topsoil (different scales); horizontal distribution of total metal contents in the soil surface layer. Geochemical, mineralogical, sedimentological and pedological data of soil profiles at different locations 2.6. Vosvozis site, Greece For the case study of Vosvozis, DUTH uses the following models : In order to predict surface runoff and nutrient loadings on surface waters, DUTH uses SWAT model. Thus, it is possible to predict the impact of various land management practices on water, 45 in large complex watersheds with varying soils, land use and management conditions over long periods of time and to make scenarios related to climate changes. In order to study flow and contaminant transport in the unsaturated zone, DUTH has installed on August 2009 three lysimeters on selected sites of the study area. The main purpose of the lysimeters is to study the flow and contaminant transport in the unsaturated zone and to determine the actual evapotranspiration in our study site. Results will be used as boundary condition for the groundwater modelling. Existing data comprise: Meteorological data from 5 meteorological stations operating in the broader study area for the last twenty years; Data of three gauging stations at Vosvozis river consisting of biweekly measurements from August 2005 on; Land uses, soil types and the digital elevation model; Hydrochemical data from 25 irrigation boreholes for the time period 2003 to 2006 (only during irrigation time); Piezometric data from 25 irrigation boreholes from 1995 on (quaterly measurements). 2.7. Mancha Oriental site, Spain The developed socio-hydro-economic modelling framework allows selecting sustainable cost-efficient measures and management strategies to achieve the good quantitative and chemical groundwater status in an uncertain environment. Management Model An optimization model is developed to define efficient fertilizer allocation in agriculture: when, where and by how much fertilizer reductions have to be applied to meet the ambient standards (groundwater quality) in specific control sites in the aquifer. The efficient allocation maximizes the present value of the net social benefit. The net social benefit equals the benefit received from the use of the resource minus external costs imposed on the society, including costs of damage from pollutants in the environment. Unless the level of pollution is very high indeed, the marginal damage caused by a unit of pollution increases with the amount emitted, and the marginal control cost increases with the amount controlled. Efficiency is achieved when the marginal cost of control is equal to the marginal damage caused by the pollution for each emitter. Since emissions are what can be controlled, but the concentration at the receptor cites are the policy targets, it is necessary to relate both through the proper numerical simulation of the pollutants leaching, transport and fate within the aquifer. In the proposed hydro-economic modelling framework, the non-point pollution abatement problem was stated as the maximization of welfare from crop production subject to constraints that control the environmental impacts of the decisions in the study region. Welfare was measured as the private net revenue, calculated through crop production functions and data on crops, nitrogen and water prices. The hydro-economic model integrates the environmental impact of fertilization by simulation of soil 46 nitrogen dynamics and fate and transport of nitrate in groundwater with the economic impact (agricultural income losses) of water and fertilization restrictions, assessed through agronomic functions representing crop yields and crop prices. The decision variables of the problem are the sustainable quantities of nitrogen per hectare applied in the different crop areas (pollution sources) to meet the environmental constraints. Pollutant Concentration Response Matrix The response matrix describes the influence of pollutant sources upon concentrations at the control sites over time. The number of columns, n, equals the number of crop areas (pollution sources) times the number of years within the planning horizon. The number of rows, m, equals the number of control sites times the number of simulated time steps in the frame of the problem. The simulated time horizon corresponds to the time for the solute to pass all the control sites, and it is independent of the length of the planning period. Agronomic simulation Crop production and nitrogen leaching functions can be derived from agronomic simulation models like EPIC. GLEAMS and NLEAP are also popular models for simulating nitrate leaching. In EPIC, a crop growth /chemical transport simulation model help defines functions relating crop yield, and groundwater nitrate leaching to water applied, on-ground nitrogen fertilization and nitrogen stock in the soil. These functions will depend on local conditions on soils, climate, irrigation water, tillage, and other operations. Data needs and availability The aforementioned modelling approach requires a large quantity of data related to groundwater information and also on demands. The groundwater information includes data coming from climatology, geology, piezometric heads (154 locations with data from 1975 until 2005), recharge/pumping estimates (remote sensing images + ET model), pumping tests, time series of nitrate concentration and streamflow measurements. On the other hand, information on demands covers temporal and spatial crop distribution, crop water requirements (ET), urban water supply demand, fertilizer use, pumping well spatial distribution, crop prices and farmers cost data. 2.8. Bogucice site, Poland 3D flow and transport model (Visual Modflow Pro, version 4.3) is available for the study area. In the framework of Genesis project, higher spatial resolution of existing model will be introduced. Also, improvement of model structure, better characterization of surface water – groundwater interaction and inclusion of GDE problems is envisaged. After recalibration, the 3D flow and transport regional model will be useful for groundwater management purposes, better understanding of the system, better definition of GWD requirements with respect to DWPA and GEPA. Coupling of the climate model 47 (developed by SMHI under WP5) to existing flow and transport model (through fluctuations of the infiltration rate) will enable prediction water table fluctuations in the study area. Data availability related to modeling (which is also mostly true for Czestochowa test site): (i) 3D flow and transport regional model, (ii) environmental tracers, wells discharge, hydraulic heads, (iii) basic climatic data necessary for climate submodels. Data needed: (i) stream flow measurements (better characterization of surface water – groundwater interaction), (ii) GW level fluctuations, (iii) stable isotopes measurements (better characterization of GW –GDE interaction). 2.9. Lule site, Sweden With the help of groundwater data, obtained from observation wells installed orthogonal to the river flow, we plan to create a conceptual model. This model is aimed to reconstruct the exchange between river water and groundwater aquifer through the hyporheic zone. We will be able to identify direction of water flow through the river bed wall, thus say whether groundwater feed the river or river drains into the surrounding. 2.10. Po valley site, Italy Studies are required to understand the role of riparian strip in fontanili status mitigation. The modeling approach will include (i) development of vertical unsaturated nitrate and pesticide fate model to groundwater and (ii) development of a lateral groundwater solute flow model to fontanili. Additionally, the selected models have to allow performing the effect of land use change and of riparian vegetation. 2.11. De Kromme Rijn site, The Netherlands From previous studies an integrated hydrological model comprising modules for saturated groundwater, unsaturated soil water and surface waters is available. First attempts of modelling groundwater pollution by nitrate have been made, but should be elaborated by coupling the ANIMO model to the MODFLOW based groundwater model. This model linkage should be the basis of pesticide and heavy metal leaching to groundwater and loading of surface waters. In order to avoid long computation times short simulation model runs just for the extreme events can be performed as an alternative. This so-called method of stochasts has been made operational in combination with the SIMGRO-model. For each of the stochasts a discrete number of realizations are defined, for instance, 15 possible realizations for the total precipitation, ranging between 50 and 190 mm related to a 9-day period. The associated probabilities are derived from the probability curves representing 3 climate scenarios. The various realizations of the separate stochasts are then combined 48 to so-called events, which are run through with the SIMGRO model. For each of the model cells the results are put in ascending order in terms of inundation depth, yielding cumulative frequency functions. 49
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