Chapter 17 Practice Quiz 2014 Moore/Tallman Name:___________________ Period_______ 1. A thermometer is in a beaker of water. Which statement best explains why the thermometer reading initially increases when LiBr(s) is dissolved in the water? A) The entropy of the LiBr(aq) is greater than the entropy of the water. B) The entropy of the LiBr(aq) is less than the entropy of the water. C) The dissolving of the LiBr(s) in water is an endothermic process. D) The dissolving of the LiBr(s) in water is an exothermic process. 2. In a chemical reaction, the difference between the potential energy of the products and the potential energy of the reactants is equal to the A) activation energy C) heat of reaction B) kinetic energy D) rate of reaction 3. Given: C 2H6(g) ® C2H2(g) + 2 H 2(g) –1 DH° = +1340 kJ•mol An alternate way to write this equation is: A) B) C) D) E) C2H6(g) + 1340 kJ ® C2H2(g) + 2 H 2(g) C2H2(g) + 2 H 2(g) + 1340 kJ ® C2H6(g) C2H6(g) ® C2H2(g) + 2 H 2(g) + 1340 kJ C2H2(g) + 2 H 2(g) ® C2H6(g) + 1340 kJ C2H6(g) – 1340 kJ ® C2H2(g) + 2 H 2(g) 4. Use the values of the standard heat of formation in the table to calculate the heat of reaction, DH°, for the reaction A) –7640 kJ C) +2,240 kJ E) +5,290 kJ B) –265 kJ D) –13,400 kJ 5. Given the equations: 12 O2(g)+ H 2(g) ® H2O(g)+ 243 kJ 12 O2(g) + 2H(g) ® H2O(g) + 661 kJ How much energy is needed to dissociate 1.00 mole of H2 according to the equation below? H2(g) ® 2H(g) A) 243 kJ C) 661. kJ E) 1320 kJ B) 418 kJ D) 904. kJ 6. Consider the equations: C(s) + O 2(g) ® CO 2(g) DH= –394kJ•mol –1 –1 CO(g) + O2(g) ® CO 2(g) DH= –283kJ•mol this information, calculate DH of the equation C(s) + O2(g) ® CO(g) A) –111 kJ•mol–1 C) –394 kJ•mol–1 E) +283 kJ•mol–1 7. I. A negative reaction. From B) –283 kJ•mol–1 D) –577 kJ•mol–1 H ( – H) indicates an exothermic BECAUSE II. with a negative than the reactants. A) B) C) D) H, the products have more energy I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 8. I. Heat is released with an endothermic reaction BECAUSE II. energy is released when bonds are formed. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 9. I. A positive DH tells you that the reaction is exothermic BECAUSE II. with a positive DH, the products have more energy than the reactants. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 10. Base your answer to the following question on the information below. Ammonium chloride is dissolved in water to form a 0.10 M NH4Cl(aq) solution. This dissolving process is represented by the equation below. State evidence that indicates the dissolving of ammonium chloride is an endothermic process. 11. To break a chemical bond, energy must be A) absorbed C) produced B) destroyed D) released 12. What occurs in order to break the bond in a Cl2 molecule? A) B) C) D) Energy is absorbed. Energy is released. The molecule creates energy. The molecule destroys energy. 13. Given the balanced equation representing a reaction: Cl 2 Cl + Cl What occurs during this reaction? A) B) C) D) A bond is broken as energy is absorbed. A bond is broken as energy is released. A bond is formed as energy is absorbed. A bond is formed as energy is released. 14. For a chemical reaction, the heat of reaction is equal to the A) potential energy of the reactants, only B) potential energy of the products, only C) potential energy of the products plus the potential energy of the reactants D) potential energy of the products minus the potential energy of the reactants 15. Given the balanced equation: 4Fe(s) + 3O 2(g) 2Fe2O3(s) + 1640 kJ Which phrase best describes this reaction? A) B) C) D) endothermic with H = +1640 kJ endothermic with H = –1640 kJ exothermic with H = +1640 kJ exothermic with H = –1640 kJ 16. Which statement correctly describes an endothermic chemical reaction? A) The products have higher potential energy than the reactants, and the H is negative. B) The products have higher potential energy than the reactants, and the H is positive. C) The products have lower potential energy than the reactants, and the H is negative. D) The products have lower potential energy than the reactants, and the H is positive. A + B ® C + heat, the potential energy of the products, compared to the potential energy of the reactants, is less and the reaction is exothermic less and the reaction is endothermic greater and the reaction is exothermic greater and the reaction is endothermic 18. Given the reaction: What is the heat of formation of nitrogen (II) oxide in kJ/mole? A) C) A) -16.69 kJ C) -445.1 kJ B) -667.7 kJ 20. When 25.7 grams of NaI dissolves in 80.0 grams of water in a calorimeter, the temperature rises from 20.5 °C to 24.4 °C. Calculate H for the process. A) -10.1kJ/mole C) 1724.8 kJ/mole B) -7.63 kJ/mole D) -2.45 kJ/mole 21. 1. Calculate the amount of heat given off when 12.5g of ethanol burns. C2H5OH +3O2 2CO 2 +3H2O H = -1368 kJ/mol 22. 1. What is the standard heat of formation ( H) for the following? 4NH 3 + 5O2 4NO + 6H2O Hf NH 3 = -46.19kJ/mol Hf NO = 90.37kJ/mol Hf H2O = -241.8kJ/mol 23. From the following enthalpy changes, C2H6O(l) + 3O 2(g) 2CO 2(g) + 3H 2O(l) H = -685.5 kJ C2H4O(l) + 5/2O2(g) 2CO 2(g) + 2H 2O(l) H = -583.5 kJ Calculate the value of H for the reaction: 2C 2H4O(l) + 2H2O(l) 2C2H6O(l) + O 2(g) 24. From the following enthalpy changes, S (s) + 3/ 2 O2 (g) SO 3 (g) H° = -395.2 kJ 2 SO 2 (g) + O 2 (g) 2 SO 3 (g) H° = -198.2 kJ 17. For the reaction A) B) C) D) 19. How much heat is released when 1.5 grams of NaOH is dissolved in water? Hsol=-445.1 kJ/mole B) D) Calculate the value of (g) SO 2 (g) H for the reaction: S (s) + O 2
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