The winter time air pollution in Cache Valley, Utah, USA: Causes and Possible Solutions Esmaiel Malek Department of Plants, Soils, Climate Utah State University Logan, UT 84322-4820, U.S.A. Telephone: 435-797-3284, Fax: 435-797-2117, E-mail: [email protected] The Utah Department of Environmental Quality has called a ’Red Air Quality Alert’ day for Davis, Salt Lake, Utah, and Weber Counties for Wednesday February 20, 2008. The Bear River District Health Department has called a RED day for Cache County. Wood-burn conditions and health statements are as follows: Cache County: Air Quality condition as issued by the Bear River Health Dept.: RED Health Advisory: Sensitive people (those with respiratory or heart disease, the elderly, and children) should reduce prolonged or heavy exertion outdoors. http://www.airnow.gov/index.cfm?action=airnow.DisplayTopStory&StoryType=1 Examples of the wintertime air pollution in Cache Valley, UT Southwest view of the valley Wellsville Mountains Polluted air Polluted air February, 2002, 4:00 p.m. Snow covered hill January, 2004 Everybody heard the news in January 2004, about the worst national air pollution in Logan, Cache County, Utah, U.S.A., a metropolitan area with a population of 102,720 (Toth et al., 2006). Among the media’s comments were: “Logan’s (the county seat) air is the dirtiest in the U.S.” “Logan’s air found worst to breathe in the U.S.” Cache Valley on a “good” day (Feb. 25, 2002) Cache Valley on a “moderate” day (Feb. 23, 2002: PM2.5 ≈ 40 µg/m3) Cache Valley on a “very bad” day (Feb. 16, 2004; PM2.5 = 101.6 µg/m3) Pictures: Dr. Martin What caused the high concentration of polluted material in the air in Cache Valley during the period of 8 - 15 January, 2004? Factors responsible for this highly winter-time polluted air in Cache Valley can be related to: ♣- Geography, ♠ - Meteorology, ♥ - Environment -♣ The Cache Valley geographical structure: North NW NE E W Valley center SW SE The bottom of Cache Valley (about 61 km long by 50 km wide) is about 1372 m (4500 ft) above msl and it is almost entirely surrounded by steep mountains reaching over 2743 m (9000 ft) above msl, forming a bowl around the Valley. ♠- Meteorology A- High pressure: High atmospheric surface pressure during the period of 8 - 15 January, 2004, acted as a lid, holding down the cold polluted air in Cache Valley under a thick sheet of warm air. ♠- Meteorology (continued) B- Precipitation & Wind: January 2004 (hourly data) b Wind speed, m/s Water equivalent, mm/h 12 9 6 3 0 1 3 2 5 4 7 6 9 8 11 10 13 12 15 14 17 16 19 18 21 20 Day Precip. U3 23 22 25 24 27 26 29 28 31 30 January 2004 (hourly data) b Wind speed, m/s Water equivalent, mm/h 12 9 6 3 0 1 3 2 5 4 7 6 9 8 11 10 13 12 15 14 17 16 19 18 21 20 23 22 25 24 27 26 29 28 31 30 Day Precip. U3 Lack of precipitation and almost calm conditions during the period of 8 - 15 January, 2004, kept the level of pollutants high in Cache Valley (no washout and ventilation). ♠- Meteorology (continued) C- Snow-covered surface: (Example of snow in Logan, UT: Courtesy of Tim Wright) -January 2004 averaged about 359 mm (14 inches) of snow, which boosted the cold-surface air temperature which averaged to about -19.5 oC (-3.1 oF) during this period. - High reflection of solar radiation by the snow-cover surface during the day caused less solar radiation absorption and lower temperatures. ♠- Meteorology (continued) D- Radiation budget: Pyrgeometers Pyranometers Frost-covered net radiometer Snow-covered net radiometer ♠- Meteorology (continued) D- Radiation budget: Almost cloudless-sky period Logan, Utah, USA, January 2004 Cloudiness, % 100 75 50 25 31 28 25 22 19 16 13 10 7 4 1 0 DOY Almost cloudless-sky period Malek, E. 1997 (c). Evaluation of effective atmospheric emissivity and parameterization of cloud at local scale. Atmos. Res. 41-54. Malek, E. (2008). Cloud contribution to the daily and annual radiation budget in a mountainous valley. Doi.10.1016/j. atmosres.2008.11.029. ♠- Meteorology (continued) E- Inversion: Inversion is the increase of temperature with height, which prevents vertical air motion and traps pollutants in the air. Vertical air temperature can be measured by radiosonde, tethersonde, acoustic, etc., approaches (some require complex and expensive equipment). The Cache Valley vertical air temperatures have been measured by the HOBO temperature sensor/data logger (Martin, 2006). Thermister inside the radiation shield Data logger Whiteman et al. 2000 ♠- Meteorology (continued) E- Inversion: Inversion during the period of 8 - 15 January, 2004. http://www.arl.noaa.gov.ready-bin/mainarc.pl The bottom line is that during the winter, Cache Valley typically has a very small air shed available, where pollutants will accumulate and become concentrated. http://www.airquality.utah.gov/Public-Interest/Current-Issues/cache-valley-PM/ Science/CacheValleyScience.htm - Environment ♣ Air pollution is referred to as the degradation of air quality resulting from unwanted gases and particulates occurring in the air. ♣ These substances in the atmosphere may result in adverse effects to humans, animals, vegetation, and materials. ♣ The air quality index (AQI) is used for reporting the severity of air pollution levels to the public. ♣ The AQI incorporates one or a combination of five criteria pollutants: 1-Ground level ozone, 2- Particulate matter (PM2.5 or PM10, e.g., PM2.5 is the gravitational mass of all particles with 2.5 µm in diameters), 3- Carbon monoxide, 4- Sulfur dioxide, 5- Nitrogen dioxide. - An AQI value is calculated daily for each of these pollutants. Ground level ozone, and PM2.5 are the major concerns in Cache Valley. - The highest AQI for an individual pollutant is the AQI value for that day. (http://www.airnow.gov) Air Quality Index (AQI) Values When the AQI is in this range: 0 to 50 51 to 100 PM2.5 (µg m-3) 0 – 15.4 15.5 – 40.4 101 to 150 40.5 – 65.4 151 to 200 201 to 300 301 to 500 65.5 – 150.4 150.5 – 250.4 > 250.5 Levels of Health Concern Colors ...air quality conditions are: ...as symbolized by this color: Good Green Moderate Yellow Unhealthy for Sensitive Groups Orange Unhealthy 132 µg Very Unhealthy Hazardous m-3 Red Purple Sources of PM2.5 in Cache Valley The single major contributor of PM2.5 in Cache Valley is motorized vehicles. Other minor sources are: home heating and industry. The atmosphere is ammonia-rich, due in part to agricultural activities, but ammonia does not produce particulate matter (PM2.5) until it reacts with nitrogen oxides (NOx , 8.3x103 kg/d) and sulfur oxides (SOx, 8.5x103 kg/d), from automobile and diesel exhausts to produce ammonium nitrate and ammonium sulfate. Martin (2006): http://www.airquality.utah.gov/Public-Interest/Current-Issues/cache-valleyPM/Outreach/Cache%20Valley%20Air%20Quality%20Studies%202006.pdf Sources of Ammonia in Cache Valley: - Cache Valley is the State of Utah leader in dairy products. Ammonia is produced form (2002 Agriculture Census) : 106,000 cattle, 7,300 sheep and lambs, 7,500 pigs, 1,200+ poultry , and 50,000 minks. These animals generate a great deal of ammonia (average 24-h wintertime = 9.2 µg/m3 (13.9 ppb)), which is a major contributor to the high level of PM2.5 in the Valley. On-road automobile emissions Martin (2006) - Road-side emissions monitoring of over 12,000 moving vehicles in Cache Valley showed that approximately 4.5% and 10.3% of the Valley’s vehicles would fail inspections tests for NOx and VOCs, respectively, and that these vehicles were responsible for 25.4% and 47.8% of the valley-wide emissions. - The study also found that majority of the vehicles that would fail would be older than 1996. as of 2004, vehicle registrations from the Utah Department of Motor Vehicles showed the percentage of vehicles that are 1996 or newer be 49.4%, and, therefore, eligible for vehicle inspection and maintenance (I&M) program. - Agriculture emissions: Ammonia (NH3) - Automobile emissions, for instance: NOx and VOCs (as catalysts) After being combined: HNO3 + NH3 → NH4NO3 gas gas particle NH4NO3 = Ammonium Nitrate which considered as a particulate matter (PM) Microscopic view of PM (Courtesy of Dr. Silva, USU). Chemical Composition of Cache Valley PM2.5 -Ammonium Nitrate = ammonia + nitrogen oxides (NOx) (mostly from vehicles). -Ammonium Sulfate = ammonia + sulfur oxides (SOx) (diesel engines and coal.) -Organic Carbon = fuel vapors, solvent vapors and unburned fuel in exhaust from poorly maintained vehicles. -Elemental Carbon = incompletely combusted hydrocarbons (diesel soot, black and blue exhaust, wood-burning stoves, black smoke from incomplete coal burning). -Crustal Elements = dust from dirt roads and wind storms off the west desert. Monitoring sites throughout the Cache Valley Newly established site Loading BGI Air Sampler Comparison of Exposed and Unexposed Filters Changing PM 2.5 Filter Transport of Air Samplers Downloading RUN Data BGI PQ200A Air Sampler Control Panel and Sampling Apparatus http://atlas.utah.gov/website/amccurrent/ EPA recently strengthened the 24-h PM2.5 standard from the 1997 level of 65 µg m-3, and retained the current annual fine particle standard at 15 µg m-3 (12-18-2006).. Take it easy! Life goes on!! Concluding Remarks - The wintertime-high levels of particulate matters (PM2.5) in Cache Valley were associated with significant health problems within 1-5 days of exposure, ranging from: asthma attacks, increased ER visits, heart attacks, strokes, and may be to death. - Infants, young children, and the elderly were particularly vulnerable to the effects of PM2.5. What can be done to alleviate the wintertime high concentration of air pollutants in the Valley? - Cache Valley is the State of Utah leader in dairy products. Research is necessary to reduce ammonia from waste products and reduce the nitrogen oxides (NOx) and sulfur oxides (SOx) from automobile and diesel exhausts . Reduction of ammonia from animal waste products Animal feeding: - Reduced nitrogen diets (less crude proteins) - Dietary electrolyte balance to affect pH Waste treatment (confinement and storage): - Frequent removal - Biological nitrification of liquid wastes before discharge to lagoon - Acidify manure - Cover manure pits Reduction of nitrogen oxides (NOx) and sulfur oxides (SOx) from automobile and diesel exhausts. - Identification and repair or removal of old vehicles could result in a 15 percent reduction of NOx during wintertime inversions. - Community education (driving as little as possible, car pooling, or using public transportation) followed by behavioral changes with decreased vehicle miles traveled (VMT) could result in additional reductions of NOx emissions. Cache Valley Teens Taking Steps to Help Environment http://www.ksl.com/?nid=148&sid=818102 Warning tools: Main Street, Logan Main Street, Logan Main Street, Logan Main Street, Logan Meteorological and Environmental Aspects of One of the Worst National Air Pollution Episode (January, 2004) in Logan, Cache Valley, Utah, U.S.A. Esmaiel Malek* and Tess Davis* Randal S. Martin+ Philip Silva++ * Utah Climate Center, Department of Plants, Soils, and Climate, Utah State University, Logan, Utah, U.S.A. + Department of Civil and Environmental Engineering, Utah State University, Logan, Utah, U.S.A. ++ Department of Chemistry and Biochemistry, Utah State University, Logan, Utah, U.S.A. (J. Atmos. Res., 2006) Questions?
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