Economic Geology Vol. 62, 1967, pp. 540-550 TIN BELTS ON THE CONTINENTS ATLANTIC R. D. AROUND THE OCEAN SCHUILING ABSTRACT Tin is inhomogeneously distributedon the continents,in relatively narrow, continent-sized belts. On a reconstruction of the continents around the Atlantic Ocean before continental drift, the belts extend un- brokenfrom one continentto another. As the agesof the tin mineralizations vary within the belts, an argument can be derived that the source of the tin and its associated elements must be in the crust. It is further speculatedthat concentrations of workabletin depositsoccur in the intersectionof orogenicbeltswith zonesof primitive enrichmentof tin. The ultimate causeof such primary geochemicalculminationsmay well lie back in the early history of the earth. INTRODUCTION A M•.T.•LLO•ENETIC provincemay be definedas an area characterized by a conspicuous concentration of a certainelementor groupof elements, as comparedwith otherareas. In suchprovincesthe element,or elements,are commonlydeposited by more than one geological processand at differenttimes. The conceptof a metallogenetic provinceimpliesthe existenceof large-scale chemicalinhomogeneities in that part of the crustor the mantlefrom which the ore-deposits ultimatelywere derived. As tin seemsto be an elementthat showsa stronglyinhomogeneous distribution,it seemedworth while to plot all the known economic and uneconomic occurrences of this element in North and South America, Africa and Europe. The investigationwas restrictedto thesecontinents,becauseit was hopedthat the data might, at the sametime, have somebearingon the theory of continentaldrift. Furthermorea review of this kind might be of somehelp in planningof future prospecting for tin deposits. The map (Fig. 1) providesthe factual basisfor the subsequent discussion. Acknowledgments.--Valuableinformationwas obtainedfrom the Directors of the GeologicalSurveysof Algiers, Angola, Argentina, Cameroon,CongoBrazzaville,Congo-Leopoldville, Dahomey,Ecuador, Liberia, Libya, Malawi, Mauretania, Peru, Senegal,Sierra Leone, SpanishSahara,Tanzania and Zambia, for which the writer wishesto expresshis thanks. The writer is further indebtedfor informationand assistanceto Sir Edward Bullard, Cambridge; Dr. G. C. Brouwer, formerly of the Bureau de RecherchesC•ologiqueset MiniSres,French Guyana; ProfessorDj. Guimaraesand Dr. J. B. Kloosterman, Brazil; Dr. Lepersonneof the Musde Royal de l'Afrique Centrale at Tervuuren,-Belgium; and Dr. Tagini of the Organisation S.O.D.E.M.I., Ivory Coast. Professor W. C. Burnham of the Pennsylvania State University kindly read the manuscript,and suggesteda number of im540 TIN BELTS ON CONTINENTS AROUND THE ATLANTIC 541 provements;ProfessorJ. Kalliokoskiof PrincetonUniversity is thankedfor his stimulatinginterestin the subject. A grant of the Billiton Mining Company as well as the stimulatinginterest of its Chief Geologist,Dr. G. L. Krol, is gratefullyacknowledged.The NetherlandsOrganizationfor the Advancement of Pure Sciencegrantedthe authora NATO ResearchFellowship at PrincetonUniversity, where most of this work was carried out. CONSTRUCTION OF MAP The heading"Tin" in the ArmoredBibliographyof EcoNoMic GEOLOGY, 1928--1963,provideda first setof references to tin-occurrences, whichwas expandedby a searchfor further data, both in older and in very recentliterature. The final list of references from whichthe map (Fig. 1) wascompiledcontains well over 500 titles, to which new literature is still being added. From these I have selected a shorter list of references that contains most of the data used in the construction of the map. The mapcontainsalsomuchunpublished information,whichwasobtainedon requestfrom the Directorsof manyGeological Surveys, as well as a number of individuals,all mentionedin the "acknowledgments." Comparedto the amountof informationpresentedon somemetallogenetic maps(age,size,typeof deposit),on the mapspresented hereinho distinction is madeon the basisof sizeof deposits. The only distinctionmadeis between thosedeposits that havebeenor are in production, and uneconomic $ccurrences. By differentiatingbetweenproductiveand unproductive locationsI feel that somequalitativemeasureof tin concentration is introduced. Someobjectionmightbe raisedagainstincludingplacerdeposits in a map ß • ' [l'•• 0 Fro. 1, A-D. i• I.• •' TIN-BELTS AROUNDTHE ATLANTIC OCEAN R.D. SCHUILING, 1966 ßTin-deposit (limit economic or marginal ) -- Approximate oftinbelts + Uneconomicoccurrence of tin minerals A, Europe; B, Africa; C, South America; D, North America. 542 R. D. SCHUILING I •.l e• ß IS Fro. 1 B. whichpurportsto give informationon the primarydistributionof tin. However, as it is commonexperiencethat placer depositsof tin are never, or rarely,locatedfar from their primary source,it is felt that on the scaleof the map this introducesno ambiguities. TIN BELTS From an inspectionof Figure 1 it is obviousthat tin occurrences showan unevenlydistributionoverthe continents.They are concentrated in elongated TIN BELTS ON CONTINENTS AROUND THE ATLANTIC 543 / +/ / + / + / I I / / / / / / / / e+ //, q+/ t,/ / / F•G. 1C. zonesthat can be refered to as "tin belts." Although in detail one may havea differentopinionon whereto draw the boundariesof thesebelts (and on this scaledetailsmay be mattersof severalhundredkilometers!), it seems certain that the overall distribution can be characterized as "belt-like." It may well be that someclustersof tin occurrences that have not been dis- 544 R. D. SCHUILING ++ 44-+ 4- D FIG. 1D. tinguished asbelts,suchasthosein CanadaandCentralAfrica,will eventually form parts of beltswhen more occurrences are found. The followingtin beltsare distinguished: 1. The Andeanbelt, richestin Bolivia,can be tracedfrom Argentinainto Bolivia,Peru and probablyColombia. The age of the depositsrangesfrom Mesozoicto Middle Tertiary, althoughin Argentina the belt containssome small Precambrianoccurrences.The depositsare related geneticallyto Mesozoicintrusivesor Tertiary extrusives. 2. The East Brazilian belt extends from Rio Grande do Sul in a north- easterlydirectionthrough the coastalstatesof Brazil up to Cear/t and Rio Grandedel Norte, where it terminatesat the Atlantic Ocean. Many of the depositsare in pegmatites, associated with beryl and lithium silicates. As far as is known, mostor all of the depositsare Precambrianand a numberof them in thisbelthavebeendatedat 750 m.y. 3. The Rond6nia-Guyanabelt. This area is still largely unknown,with the tin fields of Rond6niahaving been discoveredonly in recentyears, and someof the occurrences to the northeastof Rond6niadiscovered as recentlyas 1965. A large part of the connection betweenRond6niaand Guyanais obscuredby the Tertiary of the Amazonbasin. An ageof 940 m.y. is reported from Rond6nia (29), whereasthe agesof the granitesand pegrnatitesassociated with tin mineralizationin French Guyanaare around2,100 m.y. TIN BELTS ON CONTINENTS AROUND THE ATLANTIC 545 4. The Rocky Mountain belt extendsfrom Mexico through California, New Mexico,Nevada,Washingtonand British Columbiato Alaska. It seems to be the counterpartof the Andean belt in South America, as it contains depositsbothrelatedto Tertiary volcanicsand to Mesozoicintrusives. 5..4 smallbeltmaybranchoff the RockyMountainbeltin the U.S., going into Coloradoand South Dakota (Black Hills). Althoughthis belt is based on rather few occurrences, it is interestingto note that it would correspond to Burnham's(3) Eastern belt, definedon the basisof high trace-element content(especiallytin) in chalcopyrite and to a lesserextent sphalerite. In New Mexico and SouthDakota somepegmatiticdepositsof Precambrianage are included in this belt. 6. The .4ppalachianbelt extends from Alabama to New Brunswick and Nova Scotia. Its southernend disappearsunder the Mississippidelta and the Gulf of Mexico, and it may be buriedin and aroundNew Jerseyunder a Mesozoiccover. It containsboth Precambrian,mainly pegrnatiticdeposits, and Paleozoicoccurrenceswhich are in somecasescharacterizedby greisen. 7. The Central .4frican belt extendingfrom Natal through Swaziland, Transvaal,SouthernRhodesiainto EasternCongoand Uganda,containspeg- matites,lodesandpipes,whichare definitelyPrecambrian(around2,100m.y.; in Rwanda-BurundiandKatangabetween870 and 1,000m.y.). It is tempting to speculate that the recentlydiscovered Precambriantin depositsof the Eastern Desert of Egypt and thoseto the north of I(haroum are part of this same belt. 8. The South I/Vest.4frica-Nit7eriabelt starts at the very tip of South Africa, wheretin was minedfrom the Kuils river, near Capetown. Most of the numeroustin depositsin South West Africa, are related to "Younger Granites" of late or post-Karrooage (Jurassic?), but others are related to Precambrian granitesandpegmatites.The beltformsa relativelynarrowstrip alongthe Atlantic Oceanin Angola,the Congos,Gabonand Cameroon,striking almostdue north into Nigeria. Extensivetin mineralization,both Precambrianand Jurassicoccurin Nigeria, and analogousmineralizationhasbeen discovered recentlyin formerFrenchNigeria (Air and Zindermassives). In southernAlgeria extensivetin mineralizationoccursin the Hoggar Massif. The belt is probablycontinuouswith sometin occurrences in easternAlgeria, throughthe still poorlyprospected Sahara,wherethe lack of water prevents prospecting by panning. The ageof the youngergranitesis datedas Jurassic in Nigeria and as Eocenein Cameroon. 9..4 rather poorly definedbelt extendsfrom Liberia to Morocco. In its southernpart tin mineralization occursmainlyin Precambrianpegmatites, but in Moroccosomeoccurrences seemto be related to Hercynian intrusives. 10. The Iberian belt strikesthrough Spain and northernPortugal. The tin-tungstenmineralization is relatedto late-Hercyniangranites. 11. The .4rmorican belt, in the western part of the Massif Central, extendsthroughBrittany into Cornwall. All depositsare relatedto Hercynian granitesand consistof veins,and disseminated cassiterite in greisen. If, as suggested in Figure1 thisbeltincludes alsotheTuscanyandElbaoccurrences, then part of the belt is of Tertiary age. 546 R. D. SCHUILING 12. TheErzgebirge province.Herethepredominant deposits aregreisentype,with associated lithium-micas, relatedto Hercyniangranites. It cannot be ascertained whetherthisprovince is part of a largertin belt. RoughIy90% of the occurrences, includingall but one of the pastor presentproducersfall into the abovebeltsthat occupylessthan half the land surfaceunderconsideration. A calculation showsthat the averagedensityof tin-occurrences withinbeltsis morethan20 timesthe averageoutsidethebelts. The actualnumberof occurrences anddeposits withinthe beltsis evenhigher than indicated,becauseit is necessary to representcloselyspaceddeposits in tin-fieldsby only one point, whereasoccurrences outsidethe belt are commonlysingle,isolatedlocalitiesrepresenting mineralogical curiositiesin some well-studieddepositof otherminerals. The lithologicalmap of the Republic of Ruandafor exampleshowsover100tin localities whichare represented by only 5 pointson Figure 1. This is one of the reasonswhy a methodof contouring to establish the outlinesof the belt wouldbe ratherunsatisfactory. A countof the numberof occurrences and depositsshowsthe following: 452 points 54 points One could argue that the belts representmountainousareas where discoveryof depositsis madeeasierby the work of erosion. This is only part of the explanationof the belt-likepatterns,as tin depositsare absentfrom areas that are rich in other mineral deposits,and as the belts themselvesinclude large segments coveredby youngersediments or extrusives. Someexamples of this have beennoted above,and severalexamplescould be given to show that the beltsare not simplythe morefavorablyexposedpartsof the continents under consideration. It must be recognized,however,that the belts cannotbe tracedon an absolutely objectivebasis,because our samplingof the continents is still very uneven. The discoveryof two tin occurrencesin Antarctica is more significant,with possibleties to Tasmaniaand Eastern Australia, than the discoveryof two tin occurrences in Western Europe. It is interestingto note that the accompanying maps would have shownmore blank spaceonly a few yearsago; someof the major discoveries in the last decadesincludethe Rondtnia tin fields,the Eastern Egypt occurrences, the stanniferousgranites in northern Nigeria, the cassiteritefind north of Khartoum and the tin depositat Mount Pleasant,New Brunswick. TIN BELTS AND CONTINENTAL DRIFT The foregoingsectiondealsmainly with the directly observabledistribution of tin occurrencesand points to a possiblepracticaI applicationof the observeddistributionpattern in prospecting. In this sectionthe observed distributionof thesecontinent-sized phenomenais consideredin their relationshipas evidencefor continentaldrift. The tin beltsof Figure 1 are replotted on Bullard'sreconstruction of the continentsbeforedrifting (2). As can be seenfrom this Figure 2, there are someremarkablecoincidences. TIN BELTS ON CONTINENTS AROUND THE ATLANTIC 547 a. The East Brazilianbelt seemsto be the directcounterpartof the SouthwestAfrican-Nigeriabelt. b. The Rond6nia-Guyana belt seemsto have its extensionin the LiberiaMorocco belt on the African side. c. The Appalachianbelt seemsto join the Armoricanbelt. d. The Late-HercynianIberianbelt joinsmorecloselythe late-Hercynian Armoricanbelt, if the Gulf of Biscayis closed. e. The Iberian belt seems to be the continuation of the Southwest Africa- Nigeriabelt. f. The Andeanand Rocky Mountainbeltsare continuous and tin-free; CentralAmericais missing. g. The groupof occurrences in southwestGreenlandformsthe continuation of the Armorican and the Iberian belt. The remarkablepattern of beltsin Figure 2 alonecannotconstituteconvincing evidencefor continentaldrift, but it is safe to say that the concept of tin concentration in belts and the theory of continentaldrift derive some strengthfrom each other. If we assumefor the moment that continental drift is supportedsufficientlyby independentevidenceof paleomagnetism, paleoclimatology, and otherlinesof geologicalreasoningto be usedas a working hypothesis, let us seewhere this leadsin connection with the tin belts. Continentaldrift is usually consideredto have taken place either from the Permian to the Tertiary, or, alternatively,is still taking place. If the agesof the tin depositsin the SouthwestAfrica-Nigeria belt are considered, a numberare Precambrian(pre-drift), an importantpart are Jurassic(during drift) and someare Eocene(after drift or at a later stageduringdrift). This is interpretedto mean that throughoutthis time the sourceof the tin must havebeencarriedalongby the movingcontinents. Hence this sourcemustbe locatedin the crust,or in that part of the uppermantlewhich adheredto the crust during drifting. Otherwiseif the sourceof tin is somelinear zonein the mantle, mineralizationwould have taken place in successivelydisplaced belts as the crust slid over this sourceof tin. It seemsreasonableto suppose that the idea of a crustal sourceholds also for the commonlyassociatedelements W, Ta, Nb, Be, Li, F. CAUSES OF TIN-CONCENTRATIONS There is anotherpoint that meritssomespeculation.It is rather obvious that in a generalway severalof the tin beltsfolloworogenictrends(Andes, RockyMountains,Appalachians, Armoricanbelt). It is onlyin muchsmaller segments of thosebelts,however,that largeconcentrations of occurrences and workabletin depositsare found. There may be someindicationon Figure 2 that for economicconcentrationsto occur, a combinationof a geochemical culminationand an "event" is necessary. A geochemical culminationis consideredto be a continent-sized, lower-crustalbelt along which a particular elementhasbeenenrichedrelativeto its normalabundance.An "event"is any geological process, by meansof whichthisenriched materialis broughtup, or further concentrated as for exampleby the development of graniteintrusions 548 R. D. $CHUILING ::::::::::::::::::::::::::::::::::::::: ............... . ..::i:i::. ............... ....•.•.:,:.:.;.:.. .......,.-,................ ., .......... ..:.:.•.:...•.:.•q.:.. ............ ........i:i:i:i:i:iiiii2!i ......... DARKER AREAS IN TIN-BELTS INDICATE CONCENTRATIONS WORKABLE OF DEPOSITS POSITION OF TIN-BELTS RECONSTRUCTION ON A OF THE CONTINENTS R, D. SCHUILING, 1966 Conhnentolfit after Bullordet ol. (1965) Fz•. 2. TIN BELTS ON CONTINENTS AROUND THE ATLANTIC 549 accompanyingan orogeny. Each of these factors alone is not sufficientto produceworkable deposits. A geochemicalculmination is passive,whereas certain eventslike pegmatiteformation, granite intrusion, or volcanicextrusions,may under favorableconditionsproducesometin minerals,even when starting with materialsoriginally poor in tin. Such occurrenceswill rarely exceedthe statusof mineralogicalcuriosities. Only if the appropriateprocess actson alreadyenrichedstartingmaterialwill economicconcentrations of tin minerals result. These conceptsfind somesupportin the data in Figure 2. The rich Boliviantin deposits are foundwherethe Rond6nia-Guyana belt strikesinto the Andes, whereaselsewherein the Andes the same apparentgeological processes produced onlyinsignificant concentrations of tin minerals. The same relationshipmay hold true for Mexico, where the Appalachianculmination joins the RockyMountainbelt. Anotherexamplemight be Cornwall,where the Iberian and the Armoricanbelt cometogether. Clearly,with only 12 beltsand provinces,and with evenfewer intersections,argumentslike thesecan neverbe completelyconvincing. The idea of an interactionbetweengeologicalevent and geochemicalculminationdoes seemlogical,and it is consistent with the smallamountof availabledata. The significant pointis that the ultimatecauseof the geochemical inhomogeneities may be due to someprocessaccompanying the earliestformationof the sialiccrust. -•, • VENING•V•EINESZ LABORATORY OFGEOPHYSICS ANDGEOCHEMISTRY, UTRECHT, •lpri124, 1967 REFERENCES 1. Brouwer, G. C., 1962, Sur la m•tallog•nie du Bassin du Maroni: 3me Congr•s G•ologique des Caraibes, Jamaica. 2. Bullard, E., Everett, J. E., and Smith, A. G., 1965, The fit of the Continentsaround the Atlantic Ocean: Trans. Roy. Phil. Sot., v. 258, p. 41-51. 3. Burnham, C. W., 1959, Metallogenlc provinces of the Southwestern United States and Northern Mexico: New Mexico Inst. Mines and Techn., Bull. 59, p. 1-76. 4. 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