Name__________________________________________ Sample Exam Questions #2 (Chapters 5, 8, 16, 9) Chemistry 112 Multiple Choice 1. The hump of the camel contains stores of a) water b) carbohydrates c) proteins d) triglycerides Reaction Pathway A Reaction Pathway B Energy Energy Energy Energy 2. Which of the following represents the fastest, thermodynamically favorable reaction? Reaction Pathway Reaction Pathway C D 3. Which of the following would dissolve in your coffee the fastest? (Assume equivalent masses.) a) powdered sugar b) table sugar c) sugar cubes d) a lollipop 4. A biological molecule is found to contain carbon, hydrogen, oxygen, nitrogen, and phosphorus. It is most likely to be a a) carbohydrate b) nucleic acid c) protein d) lipid 5. The small organic molecule succinate is an intermediate in sugar metabolism. The enzyme that catalyzes conversion of succinate also binds malonate, which is structurally similar to succinate. If malonate does not undergo reaction, what is its role in this reaction? a) substrate b) inhibitor c) product d) catalyst 6. Medically speaking, why is consumption of human brains potentially hazardous? a) Nonpolar drugs accumulate in brains, potentially leading to overdoses. b) Brains can be infected with prions, leading to the human form of mad cow disease. c) Brains are high in saturated fat and cholesterol, leading to increased risk of heart attack. d) Radioactive iodine accumulates in the thymus of the brain. 7. The function of an enzyme depends on which of the following? a) the sequence of its amino acids b) its three-dimensional structure c) specific interactions with its substrate d) all of the above 8. Chromatography is: a) used to separate molecules in a mixture based on properties such as polarity b) used to separate biological molecules with an electric field c) used to identify molecules based on interactions with electromagnetic radiation d) a general name for several types of tests that use color change to detect cocaine 9. A bag seized during a drug bust is believed to contain cocaine. Which of the following would be most conclusive that the material is cocaine? a) The material is a white powder. b) The material gives a positive result in the Scott test. c) The bag is labeled “cocaine.” d) The mass spectrum of the material is identical to that of a cocaine standard. 10. Who founded the world’s first crime laboratory? a) Sherlock Holmes b) Edmond Locard c) Gil Grissom d) Henry Faulds 11. Which of the following is the major advantage of PCR-STR when compared to RFLP? a) PCR-STR uses nuclear DNA, which is more unique. b) PCR-STR can be used on any biological sample, whereas RFLP analysis can be done only on blood. c) PCR-STR detects differences in genes, whereas RFLP monitors non-coding DNA. d) PCR-STR can be done on much smaller amounts of material. 12. Which of the following is not a macronutrient? a) water b) carbohydrates c) lipids d) proteins 13. How does the body regulate blood sugar levels? a) The rate of digestion slows or speeds up depending on blood sugar levels. b) Insulin signals cells to take up glucose when blood sugar is high. c) Insulin signals the liver to release glucose when blood sugar is low. d) The brain uses less sugar when blood sugar is low. 14. Low-density lipoproteins are the blood carriers of a) lactose b) oxygen c) fatty acids d) cholesterol 15. Which of the following is the function of the B vitamins in the human body? a) To provide extra energy to the cells b) To assist enzymes during metabolism c) To be used as building blocks for the production of new proteins d) To eliminate unnecessary waste products from the body Short Answer 1. Circle all examples of potential energy below. (Flash is my dog.) Flash taking a nap Flash at the top of a hill on a sled Flash’s body fat Flash’s dinner Flash ready to jump off a dock Flash chasing a soccer ball 2 2. a) Draw the energy diagram for the energetically favorable reaction of diamonds converting to graphite, labeling the reactant and the product. b) On the same diagram, draw the same reaction in the presence of a catalyst. c) Why doesn’t all your diamond jewelry convert to graphite, given that this is the energetically downhill direction for this reaction? 3. Next to each statement below, write the corresponding law of thermodynamics. _____ You can put a pig into a machine and get sausage, but you can't put sausage into the machine and get the pig back. _____ You can’t get there from here. _____ My shoe is off; my foot is cold, I have a bird I like to hold. _____ You can’t make an omelette without breaking a few eggs. 4. Circle all the exothermic processes below. Put an “X” in the box next to any processes for which entropy increases. fireworks going off photosynthesis: 6 CO2 (g) + 6 H2O (g) 6 O2 (g) + C6H12O6 (s) cold pack reaction: NH4NO3 (s) NH4+(aq) + NO3- (aq) sublimation of H2O burning wood 5. You are going on a backpacking trip and have to carry all your own food. a) Which would provide the most energy: a pound of fat, a pound of sugar, or a pound of protein? (Circle one choice.) pound of fat pound of sugar pound of protein 3 all are equivalent b) In terms of good health, does it matter what source of energy you bring? (That is, would fats, sugars, and proteins all be equivalent?) Briefly explain. 6. For each type of evidence below, name the best technique for its analysis at the crime lab and give a one-sentence description of the data produced and its interpretation. a) tissue sample from Anna Anderson to determine whether she was Anastasia Romanov b) debris collected from a possible arson c) bag of white powder seized in a drug bust d) blonde hair recovered from the rape of a brunette 7. Fill in the letter(s) of the appropriate description(s) for each of these molecules. A molecule may have more than one description. Molecules: __________ Carbohydrate __________ Lipid __________Protein __________Nucleic Acid Descriptions (may be used more than once): A) building block of cell membranes B) composed of amino acid building blocks C) composed of monosaccharide building blocks D) generally contains only carbon, hydrogen, and oxygen E) most useful in forensic settings F) the molecule shown here belongs to this class of compound H2 C H3C CH3 H2 C H2 C H2C CH HO 4 H2C CH3 CH C C C H2 C CH CH C H2 C H2 CH3 CH CH3 CH2 CH2 C H CH H2 C 8. Sickle cell anemia is an example of a genetic disease. a) What protein is affected in sickle cell anemia and how does this cause disease? b) Mad cow disease is also caused by a problem with a protein. How does this disease differ from a genetic disease? Problems. You must clearly show your work for full credit. 1. This question is about the energy bar with the label shown here. a) How many Calories are in this energy bar? b) With the correct number of significant figures, how many joules is this? If you didn’t get an answer for part a, use 100 Calories and do this question anyway. (Hint: 1 cal = 4.184 J) 2. A closed vessel contains 104 g of C2H2 and 300 g of O2 that react to form carbon dioxide and water. 236 kJ of heat are released per mole of C2H2. a) Write the balanced equation for this reaction. b) How much heat is released in this reaction? 5
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