Back Lesson Print Name Class Date Skills Worksheet Concept Review Section: Oxidation-Reduction Reactions Choose the statement from Column B that best matches the term in Column A, and write the corresponding letter in the space provided. Column A Column B ______ 1. reduction a. a chemical reaction in which a substance gains electrons ______ 2. oxidation b. any chemical process in which electrons are transferred from one substance to another ______ 3. redox reaction c. a chemical reaction in which a substance loses electrons ______ 4. oxidation number d. substance that causes reduction to happen and is itself oxidized ______ 5. reducing agent e. number assigned to an atom in a polyatomic ion or molecular compound based on the assumption of complete transfer of electrons ______ 6. half-reaction f. substance that causes the oxidation of other substances and is itself reduced ______ 7. oxidizing agent g. the part of a reaction that involves only oxidation or reduction Determine the oxidation number for each atom in the following chemical formulas. 8. ZnCl2 9. SO3 10. HNO3 11. Al2(SO4)3 12. PbO Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 1 Oxidation, Reduction, and Electrochemistry Back Lesson Print Name Class Date Concept Review continued 13. CO2 14. H2SO4 15. Write the half-reaction for the conversion of hydrogen peroxide to water. 16. Identify which of the following reactions is a reduction reaction and which is an oxidation reaction. Write the balanced overall ionic equation for the redox reaction between these two. Mg £ Mg 2 2e O2 4e £ 2O2 Balance the following equations using the half-reaction method. 2 2 17. MnO (in acidic solution) 2 SO2 £ SO4 Mn 2 18. NO (in acidic solution) 3 Cu £ NO Cu 19. H2S NO 3 £ NO2 S8 (in acidic solution) 20. In this equation identify which atoms where reduced and which were oxidized. 2K(s) Cl2(g) £ 2KCl(s) Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 2 Oxidation, Reduction, and Electrochemistry Back Lesson Print PAGE TEACHER RESOURCE Answer Key Concept Review: OxidationReduction Reactions 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. a c b e d g f Zn: 2, Cl: 1 S: 6, O: 2 H: 1, N: 5, O: 2 Al: 3, S: 6, O: 2 Pb: 2, O: 2 C: 4, O: 2 H: 1, S: 6, O: 2 H2O2(aq) 2H(aq) 2e £ 2H2O(l) oxidation, reduction, 2Mg O2 £ 2Mg2 2O2 ; Mg O2 2MgO 2 2MnO 4 5SO2 2H2O £ 2Mn 2 5SO4 4H 2 2NO 3 3Cu 8H £ 2NO 3Cu 4H2O 8H2S 16NO 3 16H £ 16NO2 S8 16H20 K is oxidized and Cl is reduced. Concept Review: Introduction to Electrochemistry 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. salt bridge or porous barrier 18. Electrons flow from the higher voltage electric current, ampere electrode electrochemical c b e d f a h g cathode electrolyte oxidation reduction “pressure” in the negative terminal through a metal circuit, which includes the light blub, towards the positive terminal. 19. Zn(s) £ Zn2(aq) 2e, anode 20. Cu2(aq) 2e £ Cu(s), reduction Concept Review: Galvanic Cells 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. simple two, outside, two, thin indirectly, inefficient directly, simple, efficient possible galvanic chemical, electrical portable acidic alkaline carbon alkaline steel lead lead(II) sulfate galvanic, electrolytic rechargeable galvanic Daniell Ag, cathode; Zn, anode; 1.5614 V Cu, cathode; Pb, anode; 0.4681 V 2e 2 Zn(s) Cu (aq) –£ Zn2(aq) Cu(s), spontaneously to the right E (0.34) (0.76) 1.10 V 2e £ Cl2(g) 2I(aq) I2(s) 2Cl(aq) – spontaneously to the left E (0.54) (1.36) 0.82 V 2e £ Cu2(aq) 2Ag(aq) Cu(s) – 2Ag(s) spontaneously to the right E (0.80) (0.34) 0.46 V the deterioration of metals due to oxidation reactions with their environment oxygen, water, and ions Copyright © by Holt, Rinehart and Winston. All rights reserved. Holt Chemistry 101 Oxidation, Reduction, and Electrochemistry
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