UKanTeach Lesson Plan Format Balancing Oxidation Reduction Reactions Author(s): Trinda Wheeler Team Members: Trinda Wheeler Date lesson will be taught: November 16-17 Grade level: 10-11 Lesson Source: Holt Chemistry Concepts: Oxidation/Reduction, Oxidation Numbers, Balancing Redox Reactions Reducing and Oxidizing Agents Objectives: Identify atoms that are oxidized or reduced through electron transfer, Assign oxidation numbers to atoms in compounds and ions, Identify redox reactions by analyzing changes in oxidation numbers for different atoms in the reaction, Balance equations for oxidation-reduction reactions through the half-reaction method. Kansas Science Standards, Benchmarks, and Indicators: STANDARD 2A: CHEMISTRY Benchmark 3: The student will gain a basic concept of chemical reactions. 1. ▲ understands a chemical reaction occurs when one or more substances (reactants) react to form a different chemical substance(s) (products). There are different types of chemical reactions all of which demonstrate the Law of Conservation of Matter and Energy. a. Chemical reactions are written as balanced chemical equations. In ordinary chemical reactions, the number and kind of atoms must be conserved. b. Examples of chemical reactions are synthesis, decomposition, combustion, single and double replacement, acid/base, and oxidation/reduction. Materials list:Apple slices Rusted iron Candle Matches ELMO Projector Notecards Advance preparation: Day1: Cut apple slices at least 20 minutes prior to class Prepare and copy handouts Prepare PowerPoint with definitions and oxidation rules Day 2: Prepare and copy handouts Prepare PowerPoint with video and balancing rules Handouts: Day1: Assigning Oxidation Numbers Toolkit Students will take notes during the lesson. Day 2: General Plan for Balancing Redox Equations Students will take notes during the lesson. Accommodations: There are no students with IEP’s in this class. Students will work in pairs and groups, where peer support can accommodate learning styles. The teacher will circulate among the groups to check for understanding and provide assistance when needed. Safety: No chemicals will be used in this lesson. Instead, videos will be shown for “virtual” demonstrations. Five-E Plan Day 1 – 50 minutes Teacher Does Engage: Learning Experience(s) Time: ___5___minutes Display browned apple slices, a rusted piece of iron, and a burning candle. Explain that these reaction are oxidation reactions. Many, though not all oxidation reactions involve oxygen. Probing Questions Critical questions that will connect to prior knowledge and create a need to know. Student responses Expected Student Responses/Misconceptions What evidence do you see that chemical reactions have and/or are taking place here? The apple turned brown. The iron rusted. The candle emits light, heat, and smoke. What could have been done to stop these reactions? Don’t cut up the apple, or seal it up after cutting. Paint the iron. Blow out the candle. What is a common reactant in the three reactions? Oxygen Teacher Does Explore: Learning Experience(s) Time: __25____minutes Review polar and ionic bonds. Define oxidation, reduction, and redox reactions. Show definitions and simple example reaction equations on PPT. Probing Questions Critical questions that will guide students to a common set of experiences. Student responses Expected Student Responses/Misconceptions What happens to the electrons involved in ionic bonds? Polar covalent? Ionic-electrons are transferred resulting in ions. Polar-electron is unequally shared, more likely to be near one atom. Since Na loses an electron when forming NaCl, is it reduced or oxidized? What happens to Cl? Na - Oxidized. Cl - Reduced Teach mnemonic devices to What do you think OIL RIG keep oxidation and might stand for? reduction straight (on PPT). How about LEO the lion says GER? Oxidation Is Losing electrons, Reduction Is Gaining electrons. Losing Electrons is Oxidation, Gaining Electrons is Reduction. Explain oxidation numbers and their necessity in balancing redox equations. If an atom’s oxidation number decreases in the reaction, is it reduced or oxidized? Reduced. (This will likely require some explanation relating to the definition of oxidation numbers) Misconception: Oxidation number are the same as charge – they are not! Handout oxidation numbers toolkit and go through each rule. As a class, assign ox. #’s for S2O72-. Which rule applies/help us? g. Ox# of O is -2 How do find the ox# of S? Solve for x: 2x+(-14)=-2 In pairs, have students assign ox# to each atom in an assigned molecule. Molecules/ions: NH4+, Al, H2O, Pb2+, H2, PbSO4, KClO3, BF3, Ca(OH)2, Fe2(CO3)3, H2PO4-, NH4NO3, KOH, NO3-, NaClO4 Which rule(s) apply? What should be on the right side of equation to solve for the unknown ox #? Various answers. Teacher Does Explain: Learning Experience(s) Time: __10____minutes Have each group label their assigned molecule with oxidation numbers (all will be written on the board). Probing Questions Critical questions that will help students clarify their understanding and introduce information related to the lesson concepts/skills. Student responses Expected Student Responses/Misconceptions Which rule(s) did you use? Various answers. What equation did you use to solve for unknowns? Does anyone disagree with their answer? Why? Teacher Does Extend / Elaborate: Learning Experience(s) Time: __5____minutes Show video demonstrating three oxidation states of Mn. Note that glazes on pottery contain transition metals which changes color after firing in the kiln in the presence of oxygen. Probing Questions Critical questions that will help students extend or apply their newly acquired concepts/skills in new situations. Student responses Expected Student Responses/Misconceptions I’m using KMnO4. What is the oxidation number of Mn? +7 Mn is reduced in the presence of NaOH and sugar. What do you think the changing colors were showing us? Different oxidation states for Mn. (They are +7, +6, and +4) What type of element has different oxidation states? Transition metals. Teacher Does Evaluate: Include summative evaluation below. Time: __5____minutes Probing Questions Critical questions that ask students to demonstrate their understanding of the concepts and process skills. These questions must directly relate to the lesson’s performance objectives. Student responses Expected Student Outcomes Quiz (This is not for a grade, it is to let me know if we are ready to move tomorrow. You may use your notes and your toolkit.): What happens to the electrons of an atom when it is oxidized? Electrons are lost. What happens to the oxidation number of an atom when it is reduced? The oxidation number decreases. During a reaction, KMnO4 is changed to K2MnO4. Find the oxidation number of Mn in each compound and determine if manganese was oxidized or reduced. Mn in KMnO4 = +7, Mn in K2MnO4 = +6. Mn was reduced. Day 2 – 50 minutes Teacher Does Probing Questions Critical questions that will connect to prior knowledge and create a need to know. Student responses Expected Student Responses/Misconceptions What were our mnemonic devices? OIL RIG LEO the lion says GER Is oxidation number the same as charge? Sometimes, but not always. Show video of airbag deploying when granny hits the bumper with her purse. How does an airbag work? A reaction causes a release of gas. Show 2-step reaction. How can we tell if this is a redox reaction? Assign oxidation numbers to the reactants and products. Engage: Learning Experience(s) Time: ___5___minutes Give students teacher’s general impression of the quizzes papers from day 1 and review oxidation vs. reduction. Assign oxidation numbers (with help of class) to show it is redox. Teacher Does Explore: Learning Experience(s) Time: __25____minutes Handout General Plan for Balancing Redox Reactions and explain each step by demonstrating the full process (I do) As a class, complete the steps for balancing a redox reaction equation together (We do) Probing Questions Critical questions that will guide students to a common set of experiences. This handout spells out the steps for balancing redox reactions. What is the initial unbalanced equation? How do I assign ox #’s? Why do we use halfreactions? How do I balance charge? Assign pairs of students What is the initial overall one of five redox reactions equation? to balance. Each pair will How do you find unknown then join with the other oxidation #’s? pairs assigned the same What are the halfreaction to compare reactions? solutions (You do) I do: HCl(aq) + HNO3(aq) HClO(aq) + NO(g) We do: Cr2O72-(aq) + Br-(aq) You do: Cu(s) + SO42-(aq) Cu2+(aq) + SO2(g) Fe(s) + O2(aq) Fe3+(aq) + H2O MnO4-(aq) + Fe2+(aq) Mn2+ + Fe3+ Br-(aq) + H2O2(aq) Br2(aq) + H2O MnO2(s) + Cu+(aq) Mn2+(aq) + Cu2+(aq) Teacher Does Explain: Learning Experience(s) Time: __10____minutes One representative from each group will write the solution on the board. Student responses Expected Student Responses/Misconceptions Determine from question posed. Use the toolkit rules. They isolate the key ions or atoms whose ox #’s change. Add electrons to the more positive side. Varies. Solve for unknowns using the charge of atom/ion. Varies. Cr3+(aq) + Br2(l) Probing Questions Critical questions that will help students clarify their understanding and introduce information related to the lesson concepts/skills. How did you know which atoms/ions to use in the half reactions? Student responses Expected Student Responses/Misconceptions Change in oxidation number from reactant to product. Why can you add H+ and H2O into the reaction? Reaction takes place in acidic, aqueous solution. How did you balance the charge when you needed to add different numbers of electrons to the half reactions? Multiply the entire half reaction(s) by an appropriate number to make them equal. Probing Questions Critical questions that will help students extend or apply their newly acquired concepts/skills in new situations. Student responses Expected Student Responses/Misconceptions Review definitions of oxidation and reduction. What is the difference between oxidation and reduction? Oxidation: Losing Electrons, increase in oxidation number. Reduction: Gaining Electrons, decrease in oxidation number. Introduce terms: oxidizing agent and reducing agent What do you think an oxidizing agent does? A reducing agent? Causes oxidation. So if an oxidizing agent causes oxidation, what do you think happens to the oxidizing agent? What happens to the reducing agent? It is reduced. Teacher Does Extend / Elaborate: Learning Experience(s) Time: __5___minutes Causes reduction. It is oxidized. Teacher Does Evaluate: Include summative evaluation below. Time: __5____minutes Probing Questions Critical questions that ask students to demonstrate their understanding of the concepts and process skills. These questions must directly relate to the lesson’s performance objectives. Student responses Expected Student Outcomes Quiz (Mentor teacher will determine if this will be for a grade, so students should assume that it is): Use the half-reaction method to balance the following redox reaction in acidic, aqueous solution. Show your steps clearly. Ag ( s) NO3 (aq) 3 Ag ( s) 3 Ag (aq) 3e Ag (aq) NO( g ) NO3 (aq) 4H 3 O (aq) 3e 3 Ag (s) NO3 (aq) 4H 3 O (aq) NO( g ) 6H 2 O(l ) 3 Ag (aq) NO( g ) 6H 2 O(l ) If time remains, pairs of students will be instructed to write a three-question quiz with separate answer sheet on material from the two days. Pairs will then switch with another pair and each will answer the other’s questions. Quizzes would then be handed in to check for misconceptions or misunderstandings.
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