10/29/2015 Reminder: › Democritus only stated an atom was the smallest indivisible particle of matter that retained its identity. 1 10/29/2015 Dalton, years later had increased our knowledge of the atom but still his model would have been the same as Democritus. 1897 -- J.J. Thomson (physicist) Thomson experimented by passing electricity through gases at low pressures. This gas was trapped in a vacuum sealed glass with two electrodes connected to an energy source. 2 10/29/2015 2 CRT Cathode Ray Tube electrodes › Anode (positively charged electrode) › Cathode (negative charged electrode) When Thomson passed the energy through the gas a “glowing beam” appeared and went from Cathode (-) Anode (+) 3 10/29/2015 Beam was actually a CATHODE RAY › Beam of charged particles that travel from the cathode to the anode. Thomson then approached the beam with a magnet. › This experiment led him to declare that there must be something smaller than just the atom. › Completely shattered Democritus atomic theory. 4 10/29/2015 Evidence from Thomson’s Experiment › 1. When bringing the – pole of the magnet near the ray, the ray deflected away from the magnetic field. › 2. When bringing the + pole of the magnet near the ray it was attracted towards the magnetic field. › 3. The cathode ray traveled from cathode to anode. Cathode Ray Tubes and TV/Computers 5 10/29/2015 Conclusions: › There must be something that makes up atoms that has a negative charge!!! › Thomson named this a “corpuscle of electric charge”. Later named the electron Thomson’s Model › Plum Pudding Model › “think chocolate chip cookie” 1911 – Ernest Rutherford Gold Foil Experiment › Bombarded a piece of gold foil with alpha particles (positively charged particles). 6 10/29/2015 7 10/29/2015 Gold Foil Experiment Observations: › 1. a large majority of alpha particles passed directly through the foil. › 2. few particles were deflected when shot at the foil. › 3. rarely, one particle would come back almost directly at the alpha source Conclusions: › 1. Most of an atom consists of empty space. › 2. There lies a condensed positive mass in an element. Rutherford discovered the positively charged atomic nucleus. 8 10/29/2015 Although Rutherford was credited with the positive nucleus, Eugene Goldstein was credited with the discovery of protons. “Anode beam” – similar to Thomson 9 10/29/2015 Mass ratio tests were experimented on these subatomic particles to tell us: Subatomic Particle Electric Charge Actual Mass Relative Mass (amu) Electron -1 9.11 x 10-31 kg 0 Proton +1 1.67 x 10-27 kg 1 1932 – James Chadwick There had to be something else!! › 1. This particle had to be electrically neutral. › 2. This particle had to contribute to the atoms mass. Chadwick would later name this mystery particle the neutron; which is located in the nucleus of an atom. 10 10/29/2015 Subatomic Particle Electric Charge Actual Mass Relative Mass (amu) Electron -1 9.11 x 10-31 kg 0 Proton +1 1.67 x 10-27 kg 1 Neutron 0 1.67 x 10-27 kg 1 11
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