Newsletter of the Department of Mineral Sciences Volume 4, Number 1 In this Issue New GVP Website DMS Open House In Search of the Chelyabinsk Meteorite | Rocks ∙ Meteorites ∙ Gems ∙ Volcanoes ∙ Minerals | Summer 2013 The Global Volcanism Program Launches VOTW4.0 - Contributed by Liz Cottrell As far as volcanoes are concerned, May 20th is an important date. You might think I’m referring to the infamous magnitude 6 eruption of Krakatau volcano, Indonesia, in 1833 that killed tens of thousands – but you’d be wrong. On May 20th, 2013 Smithsonian’s Global Volcanism Program (GVP) launched a new website at www.volcano.si.edu, bringing an entirely new look and increased functionality to over 1 million unique visitors annually. At year three, the launch marks a major milestone in GVP’s six-year strategic plan as one of the Programs funded by the NMNH Director’s Office. The project was motivated by the desire to give scientists, civil authorities, and the public, access to GVP’s database of volcanoes and eruptive histories, now known as “Volcanoes of the World 4.0.” The name refers to the 3rd Edition of the “Volcanoes of the World” book published in 2010 by Siebert et al. – a compendium and gazetteer of the last 10,000 years of volcanic eruptions. The book stands as one of volcanology’s most trusted and valued resources and the new website empowers the user to access the book’s exhaustive tables through intelligent and customizable queries of a relational database and to download the information in spreadsheet format for further analysis. Screenshot of the GVP homepage at www.volcano.si.edu. Page 2 Volume 4, Number 1 Summer 2013 GVP Website Launch (cont.) Web-enabled access to the database will allow GVP to participate in numerous data-driven collaborative research and civil service opportunities in the coming decade with partners at universities in the US and overseas, domestic and international government agencies, and other international organizations. Partial screenshot of the Weekly Volcano Activity Report page. Chair of Mineral Sciences Tim McCoy Newsletter Editor Michael Wise Dept. of Mineral Sciences MRC 119 [email protected] In response to a survey of GVP’s online community, the new site also boasts a new look and navigation that brings our most up-to-date volcano information from the Smithsonian/USGS Weekly Volcano Activity Reports and volcano images to the fore. GVP data researcher and webmaster Ed Venzke led the project team from GVP, which also included GVP Director Liz Cottrell and GVP volcanologist Ben Andrews. In order to enable the database to be searched online, Venzke had to first migrate the content to a new platform and redesign the schema. This entailed the first true audit of GVP’s database in the program’s 45year history. As such, the launch was three years in the making. The project was funded through GVP’s programmatic funding (Director’s Office), a CIS IRM (Collections Information Systems and Information Resources Management) Pool Award, and a contract from the World Organization of Volcano Observatories (WOVO), housed within the Earth Observatory of Singapore. WOVO is one of the many international organizations that rely on GVP to provide “backbone” cyber infrastructure for volcano-related research, monitoring, and hazards-response. Page 3 Volume 4, Number 1 Summer 2013 Education & Outreach On June 5, 2013, volcanologist Ben Andrews and mineralogist Michael Wise were stationed in the Janet Annenberg Hooker Hall of Geology, Gems and Minerals (GGM) as part of the Museum of Natural History annual “Morning in the Museum” event where interns from throughout the Smithsonian had an opportunity to explore the exhibiBen Andrews talks to a group of Smithsonian interns in the Plate Tectonics tions before the Gallery of GGM during NMNH’s Morning in the Museum event. Photo by Museum’s doors open to the public. Michael Wise. Rick Wunderman, Christoph Popp and Brendan McCormick (not pictured) participated in the Smithsonian's "Become a Pilot Day" (June 15, 2013) held at the National Air and Space Museum’s Steven F. Udvar-Hazy Center at Chantilly, VA. The three DMS volcanologists used photographs and maps to explain to visitors about the hazards of volcanic ash to aviation. Photo by Brendan McCormick. Page 4 Volume 4, Number 1 Summer 2013 Education & Outreach (cont.) A special Mineral Sciences Seminar was held on the morning of June 19, 2013 and featured some recent findings made using the Department’s Time-of-Flight Secondary Ion Mass Spectrometer (ToF-SIMS). Researchers from within (Departments of Mineral Sciences and Paleobiology) and outside (Carnegie Institution of Washington) of the National Museum of Natural History presented the results of four unique projects which highlighted some of the capabilities of the ToF-SIMS instrument. To learn more about the DMS ToF-SIMS instrument please visit the Department of Mineral Sciences website at http:// mineralsciences.si.edu/facilities/tofsims.htm. Also read the article in the Department’s Newsletter Vol. 3, No.1 (Summer 2012) at http:// mineralsciences.si.edu/news/newsletters/ DMSSummer2012Newsletter.pdf. DMS Open House The Department of Mineral Sciences held a laboratories open house for the entire museum on the afternoon of Wednesday, June 26, 2013. The purpose of the event was to educate museum staff about our experimental and analytical capabilities and how important these labs are to the increase and diffusion of knowledge. The laboratories that were showcased included the scanning electron microscope (SEM), electron microprobe, high-pressure experimental petrology and geobiomineralogy laboratories and the Time-of-Flight Secondary Ion Mass Spectrometer (ToF-SIMS). Many of the DMS staff who are frequent users of our lab facilities were on hand to demonstrate and explain the capabilities of each analytical instrument to our visitors. About 60 visitors attended the event. Top photo: Cari Corrigan demonstrates the use of the scanning electron microscope (SEM). Bottom photo: Brent Grocholski and Liz Cottrell explain the workings of the high pressure experimental petrology laboratory. Photos by Linda Welzenbach. Page 5 Volume 4, Number 1 Summer 2013 Research—Hunting the Chelyabinsk Meteorite - Contributed by Marina Ivanova At 9:22 a.m. (local time) on February 15, 2013 a bright fireball was seen by numerous observers in parts of the Kurgan, Tyumen, Ekaterinburg and Chelyabinsk districts (Russia). The burning meteor illuminated the early morning sky and images of the fireball were captured by many video cameras especially in Chelyabinsk. Residents of the Chelyabinsk district heard the sound of a large explosion as the meteor passed overhead and the impact wave destroyed many window glasses in Chelyabinsk and surrounding cities. Numerous (thousands) stones fell as a shower around Pervomaiskoe, Deputatsky and Yemanzhelinka villages ~40 km S of Chelyabinsk. The largest stones probably reached Chebarkul Lake, located 70 km W of Chelyabinsk. It is suggested that a stone broke the ice of the lake, but only small meteorite fragments were found around a 8 meter-sized hole in the ice, and divers did not find any stones on the bottom of the lake. Left photo: Bolide (fireball) over Russia. Photo by Marat Ahmetvaleev. Right photo: A 8 meter diameter hole in the ice of the Chebarkul lake. Photo courtesy of the Vernadsky Institute. Smithsonian meteorite expert Marina Ivanova and a team of scientists from the Russian Academy of Sciences arrived three days after the event to search for meteorite fragments near Deputatskoe village. Despite the fact that snow cover was ~60 cm, meteorite fragments were easily detected by the holes in the snow surface. The meteorite pieces were recovered and collected out of snow by local people who also helped in our search for the meteorite and investigation of its strewn field and trajectory. Stuck in the snow, fallen meteorite fragments created channels in the snow that led to the surface and were surrounded by a dense shell of coarse-grained snow that continued into vertical columns 15-25 cm in height. These columns were nicknamed “snow carrots. Big fragments reached the frozen ground surface while small fragments got stuck in the snow. In rare cases the smallest fragments were found lying on the thin ice crust over the snow. The snow could be punched through by slow melting if stones were “warm”, then the snow probably was recrystallized as a result of higher temperatures, or alternatively the Marina Ivanova (left) and colleague Svetlana crystals may have grown from vapor on the Demidova (right) beginning their search for mewalls of the original channel, i.e. condensa- teorites. Photo by Cyril Lorenz. tion or hoarfrost. Page 6 Volume 4, Number 1 Summer 2013 Research—Hunting the Chelyabinsk Meteorite (cont.) “Snow carrots” containing meteorite fragment. “Snow carrot” is inverted in the right image. Photos by Svetlana Demidova and Cyril Lorenz. About 400 meteorite stones weighing 3.5 kg in total were recovered and are currently at the Vernadsky Institute. The meteorite stones and fragments are from 1 g to 1.8 kg in weight and from a few mm to 10 cm (mainly 3-6 cm) in size. The total mass collected by local people is certainly > 100 kg and perhaps > 500 kg. It is only <0.02% from the estimated pre-atmospheric size, 99.9% of the main mass was not found and probably presents atmospheric loss. The explosive break-up of the fireball was probably facilitated by its pre-entry shock-induced structure. The pre-atmospheric size of the meteorite was ~ 15-20 m, the total mass was ~7,000-10,000 t with the total energy of (100-500) kton TNT. Trajectory of the Chelyabinsk meteorite calculated by the coordinates of 211 collected samples (red line) in comparison with the trajectory determined by Czech researchers (blue line). Page 7 Volume 4, Number 1 Summer 2013 Research—Hunting the Chelyabinsk Meteorite (cont.) Samples recovered immediately after the fall are generally fresh but in some pieces there is evidence of weak oxidation of metal grains. The majority (2/3) of the stones are composed of a light lithology with a typical chondritic texture. A significant portion (1/3) of the stones consist of a dark finegrained impact melt containing mineral and chondrule fragments. On the territory of Russian Federation no fall this large has ever been observed. It is proposed that the A slice (a cut) of one of samples of the Chelyabinsk meteor- Chelyabinsk fall is the most draite. In this section you can see round grains (chondrules) matic LL5 chondrite fall and was and cracks (veins) filled with shock melt. Photo courtesy of the biggest meteorite fall in Russia www.meteorites.ru. since the Tunguska event in 1908. Recent Acquisitions The Division of Meteorites recently completed a purchase of a 81.9g sample of the Choteau pallasite meteorite, which found its way from a Montana estate sale to a variety of museums and institutions. The Choteau meteorite is classified as an ungrouped pallasite with some similarities to a very small group of pyroxene pallasites. The full slice contains a very good representation of the various silicate and metal phases that makes this pallasite unusual. In addition, the oxygen isotopic composition is unlike those for any other pallasites, and falls on the broad trend for acapulcoites and lodranites. The sample also exhibits a preserved heat altered zone, indicating a high degree of post fall preservation. Choteau is the second of its type represented in our collection, and adds breadth to a historically strong assemblage of iron meteorites. Did you know? There are three major classes of meteorites; stony meteorites, iron meteorites, and stony-iron meteorites. Stony meteorites are by far the most common. More than 95% of meteorites observed to fall to Earth are stony. They can be divided into chondrites (which contain millimetersized spherical bodies called chondrules) and achondrites. Both types are composed mostly of silicate minerals, but the great majority also contain metallic iron in small-scattered grains. Stony-iron meteorites, contain about equal proportions of metal and silicate material, and are rare (less than 2% of all known meteorites). Pallasites are stony-irons composed of a network of iron-nickel metal surrounding a greenish, silicate mineral called olivine. Iron meteorites are really composed of iron and nickel and are extremely dense. They are pieces of the cores of asteroids. Page 8 Volume 4, Number 1 Summer 2013 New faces in DMS Tsing Bohu, a new visiting graduate student in the Department of Mineral Sciences, is currently studying biogenic manganese oxide minerals at University of Jena, Germany. Supported by the Institute of Genetics and Developmental Biology, Chinese Academy of Sciences, Tsing graduated from the Department of Microbiology, Inner Mongolia University. Tsing will work with Cara Santelli on studies of ROS initiated Mn (II) oxidation for 3 months. Tyler Imfeld, a returning intern from the 2012 NHRE program, recently graduated from Xavier University in Cincinnati with a BS in Biology. He is presently taking a year off from study, but is planning to begin a PhD program in the fall of 2014. This summer, he will be collaborating with Cara Santelli to investigate the presence of reactive oxygen species in manganese-oxidizing fungi. The ultimate goal of his project is to reveal the enzymatic processes behind the production of reactive oxygen species and manganese oxides in fungal species through culturing experiments and transcriptomics. Kristyn Hill is a senior at the Lock Haven University of Pennsylvania, majoring in Geology. She is interested in mineralogy, structural geology, and meteorites, and has previously studied pallasites (a group of iron-silicate meteorites thought to represent the coremantle boundary of a large, differentiated asteroid). During her internship in the Department of Mineral Sciences, she has been working with Cari Corrigan and Emma Bullock on the mineralogy and petrology of primitive enstatite chondrites. Kristyn is using the scanning electron microscope (SEM) and optical microscopy in looking at the sulfide mineral assemblages found in these enstatite chondrites, in order to unravel their thermal history on their parent asteroid. Page 9 Volume 4, Number 1 Summer 2013 New faces in DMS (cont.) Kelsey Livingston is working with Michael Evan Becker is a geology major (senior) at Virginia Tech of Blacksburg, Virginia. Evan is interested in mineralogy and is currently working with Michael Wise on a project to characterize the textures of graftonite-triphylitesarcopside intergrowths from granitic pegmatites. Using the textural features and chemistry of these phosphate minerals, Evan will attempt to better understand the processes of exsolution and replacement that are responsible for the development of this mineral association. Wise on a project that will investigate the crystallization history of apatite in the Black Mountain pegmatite from western Maine. Kelsey will use the cathodoluminescence properties of apatite to identify and characterize the textural relationship of apatite with other minerals within all zones and units of the pegmatite. She will also investigate the chemical evolution of apatite throughout the pegmatite. Kelsey is a junior geology major at Kutztown University, Pennsylvania. Michael Kebede is a rising senior at Montgom- ery Blair High School in Montgomery County, Maryland and is an intern with the YES! (Youth Engagement through Science) program this summer. Michael will be working with Michael Wise on understanding the development of exsolution textures in beusite-triphylite intergrowths in a pegmatite from the Yellowknife pegmatite field, Northwest Territories, Canada. Gabrielle Ramirez, a 2013 NHRE sum- mer intern, is a junior geology major at the University of Texas at Austin. She is working with Ben Andrews and Rob Dennen running experiments in the newly built volcanology lab at the MSC. The experiments are designed to study the dynamics and deposition of dilute pyroclastic flows of volcanoes. They will simulate scaled pyroclastic density currents and will quantify the run out characteristics and sedimentology of the experimental currents. They will be addressing the following questions: (1) What factors affect how far and how long a pyroclastic density current will travel? (2) How do the particles interact with each other and the air? (3) How are transport processes recorded by deposits? Page 10 Volume 4, Number 1 Summer 2013 In The Media Tim Rose was interviewed for a piece entitled “Mining For A 'Mother Lode' Of Gold In Montgomery County “ by American University Radio (WAMU 88.5). The interview can be heard on the American University Radio website at http://wamu.org/programs/ metro_connection/13/05/10/mining_for_a_mother_lode_of_gold_in_montgomery_county. Selected Publications The cover of the June 14, 2013 issue of Science (lower right) features a polished thin section (70 micrometers thick) of volcanic glass viewed in transmitted light. The sample (catalog number NMNH115296-3) was selected from the Smithsonian’s Petrology Collection. The image credit goes to Glenn Macpherson, Tim Gooding, and Liz Cottrell. The issue also contains an article on MidOcean ridge basalts authored by Liz Cottrell. Beck A. W., McSween H. & Bodnar R. (2013) In situ laser ablation ICP-MS determination of trace element concentrations in dimict diogenites: Further evidence for harzburgitic and orthopyroxenitic lithologies. Meteoritics and Planetary Science. 48, 1050–1059. Carmichael, M. J., Carmichael, S. K., Santelli, C. M., Strom, A. & Bräuer, S. L. (2013) Mn(II)-oxidizing bacteria are abundant and environmentally relevant members of ferromanganese deposits in caves of the upper Tennessee River Basin. Geomicrobiology Journal, doi:10.1080/01490451.2013.769651 Cottrell, E. & Kelley, K. A. (2013) Redox Heterogeneity in Mid-Ocean Ridge Basalts as a Function of Mantle Source. Science, 340, 1314-1317. birnessite. American Mineralogist, 98, 671679. Kita, N. T., Welten, K. C., Valley, J. W., Spicuzza, M. J., Nakashima, D., Tenner, T. J., Ushikubo, T., MacPherson, G. J., Welzenbach, L., Heck, P. R., Davis, A. M., Meier, M. M. M., Wieler, R., Caffee, M. W., Laubenstein, M. & Nishiizumi, K.. (2013) Fall, classification, and exposure history of the Mifflin L5 chondrite. Meteoritics & Planetary Science, 48, 641-655. Pohwat, P. W. (2013) Connoisseur's Choice: Diopside Merelani, Arusha Region, Tanzania. Rocks & Minerals, 88, 166-173. Pohwat, P.W. (2013) Connoisseur's Choice: Fluorite, Part 2, Huanggang Mine, Inner Mongolia, China. Rocks and Minerals, 88, 250-261. Reddy, V., Le Corre, L., O'Brien, D. P., Nathues, A., Cloutis, E. A., Durda, D. D., Bottke, W. F., Bhatt, M. U., Nesvorny, D., Buczkowski, D., Scully, J. E. C., Palmer, E. M., Sierks, H., Mann, P. J., Becker, K. J., Beck, A. W., Mittlefehldt, D., Li, J-Y., Gaskell, R., Russell, C. T., Gaffey, M. J., McSween, H. Y., McCord, T.B., Combe, J-P. & Blewett, D. T. (2013) Corrigendum to "Delivery of dark material to Vesta via carbonaceous chondritic impacts" [Icarus 221 (2012) 544–559]. Icarus, 223(1): 632. Singerling, S. A., McSween, H. Y. & Taylor, L. A. (2013), Glasses in howardites: Impact melts or pyroclasts?. Meteoritics & Planetary Science, 48, 715–729. Fleeger, C. R., Heaney, P. J. & Post, J. E. (2013) A time-resolved X-ray diffraction study of Cs exchange into hexagonal H- Tang, Y., Zeiner, C. A., Santelli, C. M. & Hansel, C M. (2013) Fungal oxidative dissolution of the Mn(II)-bearing mineral rhodochrosite and the role of metabolites in manganese oxide formation. Environmental Microbiology, 15, 1063-1077. Page 11 Volume 4, Number 1 Summer 2013 Meetings & Abstracts Wise, M.A. (2013) Crystallization conditions of epidote in granitic pegmatites. Moretz, L., Heimann, A., Bitner, J., Wise, M., Rodrigues Soares, D. & Mousinho Ferreira, A.C. (2013) The composition of garnet as an indicator of rare metal (Li) mineralization in granitic pegmatites. New Hampshire and Maine May 26 - June 2, 2013 Wise, M.A. (2013) The discrimination of LCT and NYF granitic pegmatites using mineral chemistry: A pilot study. Yonts, J., Heimann, A., Bitner, J., Wise, M., Soares, D. & Ferreira, A. (2013) The composition of gahnite as an indicator of rare metal (Li) mineralization in granitic pegmatites. Cottrell, E. (2013) Mantle Redox Heterogeneity. – Keynote Address Awards & Grants Five projects from Mineral Sciences were recently funded by the 2013 Small Grants Awards. Congratulations go out to the following individuals: Ben Andrews - Magma decompression rates during volcanic eruptions, $4,860. Cari Corrigan - Impact cratering on the Earth and Moon, $4,700. Yulia Goreva - Optimizing sample selection and instrument capabilities for surface analyses, $4,230. Tim Rose - The Masks of Teotihuacan: Sourcing their raw materials, $4,550. Cara Santelli - Identifying the genetic pathways of Mn oxidation and biomineralization in fungi that promote remediation in Mn polluted environments, $5,000. Kudos Liz Cottrell was elected to office on the Infrastructure Development Committee for COMPRES (Consortium for Materials Properties Research in Earth Sciences). Page 12 Volume 4, Number 1 Summer 2013 “Blue Room” Makeover The Gem Vault area, best known as the “Blue Room”, in the Department of Mineral Sciences is currently being renovated. The “Blue Room” is the principal storage area for the Gem Collection and display-quality mineral specimens of the Mineral Collection. As part of the renovation project, the old glass display cases (which were about 50 years old) are being replaced by sturdier, more secure cabinets that will better accommodate many of the collection’s oversize specimens. Through the support of Carol Butler (Chief of Collections), the renovation project was made possible by funds from the NMNH Collections Program. View of the Blue Room before (left) and during (right) renovations. Photos by Michael Wise. Update to X-ray Diffraction Laboratory The Department of Mineral Sciences recently added a second Rigaku D/Max Rapid micro-Xray diffractometer unit to the X-ray laboratory. The X-ray diffractometer is the critical tool used for the identification of minerals and other crystalline materials. Data collection is extremely fast (it typically takes 5 minutes to acquire X-ray data) and diffraction data can be collected from powdered samples, aggregates, or single crystals. Diffraction patterns can also be collected from gems, archeological artifacts, and art pieces. Page 13 Volume 4, Number 1 Summer 2013 New Experimental Volcanology Laboratory In early June, the Experimental Volcanology Laboratory became operational – since that time, Ben Andrews, Gabby Ramirez (NHRE intern) and Rob Dennen (contractor) have been busy running pyroclastic flow experiments. The laboratory is located at the Museum Support Center (MSC) in Suitland, MD. The facility permits the study of unconfined, particle-laden density currents that model dilute pyroclastic flows from volcanoes. Several aspects of this facility make it unique and one-of-a-kind. The “tank” is big: the interior space measures 28 Experimental volcanology “tank” showing illufeet long, 20 feet across and 8.5 feet minated lasers. Photo by Rob Dennen. tall. The facility uses a custom set of laser sheets (built by Rob Dennen and Tim Gooding) to illuminate different planes within the experiments and provide 3D insights. Warm experiments can be run and thus processes dependent on thermal effects can be examined – for example, coignimbrite plumes can be generated. Sediment traps sample the deposits and allow for reconstruction of the deposit architecture. Splits from those sediment traps can also be brought back to Mineral Sciences from grain size analysis using a particle laser size analyzer. The experiments run within this lab are scaled such that they are dynamically similar to natural currents on Earth (or even Mars). These scaling parameters allow laboratory currents (20 cm thick, 5 degrees warmer than the room, and traveling at 10 cm/s) to improve our understanding of natural pyroclastic flows (200 m thick, 500 degrees, and traveling at 50 m/s). Currently, the research team is investigating the effects of eruption duration, eruption rate, and temperature on current Schematic diagram of the “tank”. runout and deposit morphology. Oblique image looking down on a flowing current. A) Illumination of the current with orthogonal laser sheets. B) Cross-stream slice using 650nm laser sheet. C) Horizonal slice of current with 532nm sheet. D) Streamwise, vertical slice with 450 nm laser sheet. Field of view is 8’ (streamwise) by 20’ (cross-stream).
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