Mon. Not. R. Astron. Soc. 313, 99±111 (2000) Chemical composition of eclipsing binaries: a new approach to the helium-to-metal enrichment ratio  lvaro GimeÂnez3,4 Ignasi Ribas,1w Carme Jordi,1,2 Jordi Torra1,2 and A 1 Departament d'Astronomia i Meteorologia, Universitat de Barcelona, Av. Diagonal 647, E-08028 Barcelona, Spain Institut d'Estudis Espacials de Catalunya, Edif. Nexus-104, Gran CapitaÁ, 2-4, E-08034 Barcelona, Spain 3 Laboratorio de AstrofõÂsica Espacial y FõÂsica Fundamental, Apartado 50727, 28080 Madrid, Spain 4 Inst. AstrofõÂsica de AndalucõÂa, Apartado 3004, 18080 Granada, Spain 2 Accepted 1999 October 21. Received 1999 October 18; in original form 1999 August 12 A B S T R AC T The chemical enrichment law Y(Z) is studied by using detached double-lined eclipsing binaries with accurate absolute dimensions and effective temperatures. A sample of 50 suitable systems was collected from the literature, and their effective temperatures were carefully re-determined. The chemical composition of each of the systems was obtained by comparison with stellar evolutionary models, under the assumption that they should fit an isochrone to the observed properties of the components. Evolutionary models covering a wide grid in Z and Y were adopted for our study. An algorithm was developed for searching the best-fitting chemical composition (and the age) for the systems, based on the minimization of a x 2 function. The errors (and biases) of these parameters were estimated by means of Monte Carlo simulations, with special care put on the correlations existing between the errors of both components. In order to check the physical consistency of the results, we compared our metallicity values with empirical determinations, obtaining excellent coherence. The independently derived Z and Y values yielded a determination of the chemical enrichment law via weighted linear least-squares fit. Our value of the slope, DY=DZ 2:2 ^ 0:8; is in good agreement with recent results, but it has a smaller formal error and it is free of systematic effects. Linear extrapolation of the enrichment law to zero metals leads to an estimation of the primordial helium abundance of Y p 0:225 ^ 0:013; possibly affected by systematics in the effective temperature determination. Key words: stars: abundances ± binaries: eclipsing ± stars: evolution ± ISM: abundances ± galaxies: abundances. 1 INTRODUCTION The slope of the chemical enrichment law Y(Z), namely DY/DZ, is most frequently determined from observations of extragalactic H ii regions. Considerable disagreements are found in the results of various works. Indeed, Lequeux et al. (1979) found a value of about 3 whereas Pagel et al. (1992) obtained a raw value of 6, which was subsequently corrected to a final estimation of 4 ^ 1: On the other hand, Izotov, Thuan & Lipovetsky (1997) determined a lower value of the slope, close to 2. More recently, Izotov & Thuan (1998) published a very detailed discussion based on a sample of 45 low-metallicity H ii regions and derived a slope of DY=DZ 2:3 ^ 1: This result is also in agreement with the review of Peimbert (1995), which concluded that the observations are compatible with the theoretical value of about 2.5. Along with the works based on extragalactic H ii regions, other authors have w E-mail: [email protected] q 2000 RAS attempted a determination of DY/DZ through the analysis of the fine structure of the ZAMS as a function of Y and Z. The first results were very uncertain, as demonstrated by the value DY=DZ 5 ^ 3 obtained by Perrin et al. (1977)and the lower limit DY=DZ . 2 derived by Fernandes, Lebreton & Baglin (1996). The situation is slightly improved in the recent work of Pagel & Portinari (1998), who used the accurate Hipparcos parallaxes to infer a global estimate of DY=DZ 3 ^ 2: The same value was also found by Fernandes et al. (1998). A different approach was employed by Renzini (1994), who considered star counts in the Galactic Bulge to estimate the helium content of metal-rich stars. He obtained a value of DY/DZ from 2 to 3, with 3 being a strict upper limit. The accurate knowledge of DY/DZ is crucial for many astrophysical aspects, such as chemical evolution of the Milky Way and other galaxies, and for stellar evolution in general. We therefore attempted to undertake an estimation of the enrichment law from a new point of view, devoting special attention to evaluating the possible systematic effects. Our 100 I. Ribas et al. approach is based on the study of eclipsing-binary data. It is well known that double-lined eclipsing binaries are the source for the most accurate and simultaneous determinations of masses and radii (see e.g. Andersen 1991, hereafter A91). These determinations are possible through the analysis of radial velocity and light curves. Furthermore, if detached double-lined eclipsing binaries (hereafter DDLEBs) are considered, no significant mass transfer has occurred between the components, since they are smaller than their respective Roche lobes. In such cases, the mutual interaction can be safely neglected and the components can be assumed to evolve like single, individual stars. Therefore, DDLEBs provide absolute dimensions for two single stars that can be assumed to have a common origin both in time and chemical composition. In this situation, evolutionary models should be able to predict the same age for both components of the system. The comparison between model predictions and observations determines the chemical composition that best reproduces the fundamental properties of the eclipsing-binary components. The initial helium abundance (Y) and metallicity (Z) computed in this way are related to the intrinsic composition, in contrast to spectroscopic determinations, which provide the atmospheric abundances and which might not be directly assimilated into the intrinsic composition when atmospheric peculiarities are present. Therefore, these Z and Y determinations can be confidently used for determining the helium-to-metal enrichment ratio, as we will show in the subsequent sections. This paper is organized as follows: the basic ingredients of our analysis, i.e. stellar evolutionary models and eclipsing-binary sample, are the subject of Sections 2 and 3; the fitting algorithm, including the numerical results and an evaluation of the errors and biases, are described in Section 4; the results of the metal content determination are compared with Figure 1. (a) Isochrones and evolutionary tracks computed with Genevagroup models (dotted line) and CG models (solid line) for a chemical composition of Z 0:02 and Y 0:30: The physical ingredients of these two models are very similar, as deduced from the resemblance between their tracks and isochrones. (b). Same as panel (a) but for Padova-group models (dotted line) and CG models (solid line) using a chemical composition of Z 0:02 and Y 0:28: In this case, most of the physical ingredients are also very similar, except for the adopted amount of convective overshooting, which shows up as a difference in the main sequence hook region increasing with mass. observational determinations in Section 5; Section 6 contains the interpretation of the fitting algorithm output (Z and Y) in terms of the chemical enrichment law (slope and primordial helium abundance); and, finally, a brief summary of the main results is provided in Section 7. 2 A D O P T E D E VO L U T I O N A RY M O D E L S We adopted the recent set of models of Claret (1995), Claret & GimeÂnez (1995), Claret (1997) and Claret & GimeÂnez (1998) (altogether referred to as CG models). These models are especially well-suited for our purposes because they cover a wide range, both in metallicity (Z) and initial helium abundance (Y), which allows us to consider Y as a free parameter. The prescriptions for dealing with some physical ingredients adopted by CG (such as mass loss, neutrino emissions, radiative opacities, equations of state or convective energy transport) are very similar to those considered by all current models. Our results will therefore not be influenced, from a general point of view, by the particular election of CG Figure 2. Left panel illustrates the way evolutionary tracks change as a function of the initial helium abundance (Y) in the log g 2 log T eff plane, for a given Z. In the right panel, the effect of a change in the initial metal abundance (Z), for a fixed Y, is shown. q 2000 RAS, MNRAS 313, 99±111 Eclipsing binaries: He/metal enrichment ratio models. This fact is illustrated in Fig. 1, where evolutionary tracks and isochrones computed with CG models, Geneva-group models (Schaller et al. 1992) and Padova-group models (Bressan et al. 1993) are compared. However, it is true that there are still, even for the main sequence region, open questions (convection parameters, mass-loss rate, etc.) that might have some influence on our results. An illustration of how chemical composition affects the evolution of a star is presented in Fig. 2, where evolutionary tracks for several initial masses with different chemical compositions are compared. As can be seen, a change in Y essentially influences the effective temperature of the model (Teff increases with Y). On the other hand, Z has a small effect on Teff (i.e. uncorrelated with Y) but a more noticeable effect on log g and on the predicted age. 3 SAMPLE OF ECLIPSING BINARIES A very careful selection of DDLEBs with accurate determinations (1±2 per cent errors) of masses and radii was compiled in A91. These systems were mainly observed and analysed by the Copenhagen group, although Andersen included some systems from Popper (1980) and other authors. The list comprises 45 systems, from which we discarded HS Aur, YY Gem and FL Lyr, since they have components with M , 1 M( and the CG models do not cover this range. A similar case is that of TZ For, whose primary component is in an evolved stage (core He burning), beyond the coverage of the CG models. EK Cep, whose secondary component is still in the pre-main sequence (PMS) phase, was not taken into account since only post-ZAMS models were considered with sufficient detail. Additionally, two systems (V624 Her and WW Aur) were rejected because the small errors quoted seem to be underestimated (the fractional radii come from single-band light curves and the systems are partially eclipsing). This makes a total of 38 systems adopted from Andersen's compilation. We have also considered the revisions and updatings for four systems (V539 Ara, b Aur, EE Peg and DM Vir) that have appeared since 1991. A complementary search of the literature was done in order to enlarge the list with recent publications. A careful evaluation of the accuracy of the parameters led to a final number of 12 additional systems: AD Boo, IT Cas, Y Cyg, V380 Cyg, V909 Cyg, HS Hya, TV Nor, V3903 Sgr, V906 Sco, CD Tau, BH Vir and HV 2274. The latter, which belongs to the LMC, was included because of its low metal content, which will be of great help in establishing the chemical enrichment law for a wide range of metallicities. The physical properties of the components of the 50 DDLEBs in the sample are listed in Table 1, and a log M 2 log g plot is shown in Fig. 3. Unfortunately, the effective temperatures of the systems listed in A91 were not so carefully evaluated as the absolute dimensions: they were adopted directly from several publications, with no further revision. These temperatures are thus highly non-uniform, since different calibrations were used by different authors. Most of the temperatures, coming from analysis dating down to 1975, were based on old photometric calibrations. Since then, atmosphere models (Kurucz 1979, 1991, 1994) have been very much improved yielding new and more accurate photometric calibrations. This fact drove us to undertake a revision of all effective temperatures with the aim of using state-of-the-art calibrations and a procedure as uniform as possible. We collected the available standard photometry for all systems from the source references. Preference was given to intermediate-band rather than wide-band measurements. Part of this work has already been done by ourselves and published in a previous paper (Jordi et al. 1997b), which includes individual StroÈmgren photometry for a large fraction (29) of the systems in our current sample. The photometric grids of Napiwotzki (1998, private communication), based on Kurucz ATLAS9 atmosphere models (Kurucz 1991, 1994), were adopted for temperature determination. These grids are an improved version of those presented in Napiwotzi et al. (1993) by considering revised atmosphere models and including the metallicity dependence on the photometry. For six of the remaining systems, individual StroÈmgren photometry was also available. For five systems we used joint StroÈmgren indices, whereas the temperatures of six binaries (the coolest ones) had to be based on Johnson±Cousins photometric calibrations (Popper 1980). The temperatures of the components of TV Nor were computed from their joint Geneva photometric indices (intermediate-band). The effective temperature of CD Tau is based on the `infrared flux method' (IRFM) (Blackwell et al. 1990) applied to IR photometry. Two systems (Y Cyg and EE Peg) have accurate spectroscopically-determined effective temperatures. They come from NLTE model fits to Balmer lines in the case of Y Cyg, and synthetic spectra fitting in a wide spectral range for EE Peg. Finally, the temperatures of V380 Cyg and HV 2274 are based on atmosphere model fits to UV spectrophotometry. The adopted Teff values for all systems and their errors are also listed in Table 1. 4 Figure 3. log M 2 log g plot of the DDLEBs included in our sample. 1s error bars are also shown, and are even smaller than the size of the symbol in some cases. The presence of systems below the ZAMS line for Z 0:02 and Y 0:28 is related to chemical composition differences. q 2000 RAS, MNRAS 313, 99±111 101 THE FITTING ALGORITHM Stellar evolutionary models describe the interior structure and the observable properties of a star (R, Teff, L, M) of a given initial mass and chemical composition (X,Y,Z), as a function of time. On the other hand, the analysis of DDLEBs yields high-accuracy determinations of the mass and the radius (or log g) of the components, and also their effective temperatures. Since only for a very few systems is the atmospheric metallicity [Fe/H] accurately known, we ignore this information at this point. Thus, the age of the system and both Z and Y are the unknown parameters of our DDLEBs. The knowledge of only the masses and radii of the 102 I. Ribas et al. Table 1. Masses, surface gravities and effective temperatures for the 50 DDLEBs included in our sample. Name BW Aqr V539 Ara b Aur AD Boo GZ CMa EM Car QX Car YZ Cas IT Cas PV Cas SZ Cen WX Cep CW Cep RS Cha RZ Cha Y Cyg MY Cyg V380 Cyg V442 Cyg V478 Cyg V909 Cyg V1143 Cyg DI Her AI Hya HS Hya KW Hya x 2 Hya GG Lup TZ Men UX Men TV Nor U Oph V451 Oph EW Ori V1031 Ori M/M( log g (cgs) log Teff (K) 1.488 ^ 0.022 1.386 0.021 6.24 0.07 5.31 0.06 2.381 0.020 2.306 0.020 1.438 0.016 1.237 0.013 2.206 0.019 2.005 0.018 22.89 0.32 21.43 0.33 9.267 0.122 8.480 0.122 2.314 0.021 1.350 0.010 1.330 0.009 1.328 0.008 2.815 0.050 2.756 0.054 2.317 0.026 2.277 0.021 2.539 0.050 2.329 0.045 13.52 0.39 12.08 0.29 1.858 0.016 1.821 0.018 1.518 0.021 1.509 0.027 17.57 0.27 17.04 0.26 1.811 0.025 1.786 0.030 11.1 0.5 7.02 0.25 1.564 0.024 1.410 0.023 16.67 0.45 16.31 0.35 1.98 0.03 1.75 0.03 1.391 0.016 1.347 0.013 5.185 0.108 4.534 0.066 2.145 0.038 1.978 0.036 1.255 0.008 1.219 0.007 1.978 0.036 1.488 0.017 3.613 0.079 2.638 0.050 4.116 0.040 2.509 0.024 2.487 0.025 1.504 0.010 1.238 0.006 1.198 0.007 2.053 0.022 1.665 0.018 5.198 0.113 4.683 0.090 2.776 0.063 2.356 0.052 1.194 0.014 1.158 0.014 2.473 0.018 2.286 0.016 3.981 ^ 0.020 4.075 0.022 3.926 0.017 4.096 0.022 3.930 0.010 3.962 0.010 4.180 0.011 4.364 0.019 3.989 0.012 4.083 0.016 3.857 0.017 3.928 0.016 4.140 0.020 4.151 0.021 3.995 0.011 4.309 0.010 4.158 0.009 4.175 0.020 4.165 0.025 4.171 0.024 3.486 0.008 3.677 0.007 3.640 0.011 3.939 0.011 4.059 0.024 4.092 0.024 4.047 0.023 3.961 0.021 3.909 0.009 3.907 0.010 4.136 0.012 4.145 0.012 4.007 0.023 4.014 0.023 3.166 0.027 4.132 0.038 3.999 0.016 4.146 0.019 3.919 0.015 3.909 0.013 4.403 0.012 4.288 0.017 4.323 0.016 4.324 0.016 4.297 0.018 4.307 0.017 3.584 0.011 3.850 0.010 4.326 0.006 4.354 0.006 4.079 0.013 4.270 0.010 3.712 0.015 4.188 0.019 4.301 0.012 4.364 0.010 4.225 0.010 4.303 0.009 4.272 0.009 4.306 0.009 4.221 0.010 4.278 0.012 4.081 0.015 4.153 0.018 4.038 0.014 4.196 0.015 4.401 0.010 4.426 0.010 3.560 0.008 3.850 0.019 3.800 ^ 0.007 3.807 0.007 4.268 0.012 4.248 0.012 3.971 0.009 3.964 0.009 3.805 0.006 3.775 0.007 3.927 0.017 3.914 0.017 4.531 0.026 4.531 0.026 4.395 0.009 4.376 0.010 3.959 0.014 3.821 0.016 3.811 0.007 3.811 0.007 4.032 0.012 4.027 0.012 3.878 0.015 3.893 0.015 3.912 0.012 3.944 0.012 4.449 0.011 4.439 0.011 3.883 0.010 3.859 0.010 3.816 0.010 3.816 0.010 4.538 0.008 4.534 0.008 3.850 0.010 3.846 0.010 4.309 0.007 4.299 0.013 3.839 0.006 3.833 0.006 4.484 0.015 4.485 0.015 3.987 0.021 3.944 0.021 3.820 0.008 3.816 0.008 4.241 0.020 4.185 0.020 3.851 0.009 3.869 0.009 3.813 0.003 3.806 0.003 3.900 0.006 3.836 0.007 4.068 0.008 4.043 0.008 4.170 0.014 4.041 0.024 4.022 0.010 3.857 0.012 3.785 0.007 3.781 0.007 3.960 0.007 3.892 0.005 4.211 0.015 4.188 0.015 4.037 0.016 4.006 0.017 3.776 0.007 3.762 0.007 3.889 0.028 3.923 0.026 Ref. 1,2 2,3 2,4 5 1,2 1 1,2 1,2 6 1,2,7 1,2 1,2 1,2 1,2 1,2 8 1,2 9 1 1 10 1,2 1,2 1,2 11 1,2 1,2 1,2 1,2 1,2 12 1,2 1,2 1 1,2 Table 1 ± continued Name EE Peg IQ Per AI Phe z Phe PV Pup VV Pyx V1647 Sgr V3903 Sgr V760 Sco V906 Sco CD Tau CV Vel BH Vir DM Vir HV 2274 (LMC) M/M( 2.156 1.335 3.521 1.737 1.236 1.195 3.930 2.551 1.565 1.554 2.101 2.099 2.189 1.972 27.27 19.01 4.980 4.620 3.378 3.253 1.442 1.368 6.100 5.996 1.165 1.052 1.454 1.448 12.2 11.4 0.024 0.011 0.067 0.031 0.005 0.004 0.045 0.026 0.011 0.013 0.022 0.019 0.037 0.033 0.55 0.44 0.090 0.073 0.071 0.069 0.016 0.016 0.044 0.035 0.008 0.006 0.008 0.008 0.7 0.7 log g (cgs) 4.129 4.327 4.208 4.323 3.596 3.997 4.122 4.309 4.256 4.278 4.089 4.088 4.253 4.289 4.058 4.143 4.177 4.259 3.656 3.858 4.087 4.174 4.000 4.023 4.307 4.351 4.108 4.106 3.536 3.585 0.013 0.009 0.019 0.013 0.014 0.012 0.009 0.012 0.010 0.011 0.009 0.009 0.012 0.012 0.016 0.013 0.021 0.019 0.012 0.013 0.010 0.012 0.008 0.008 0.014 0.017 0.009 0.009 0.027 0.029 log Teff (K) 3.940 3.802 4.111 3.906 3.705 3.793 4.149 4.072 3.840 3.841 3.979 3.979 3.975 3.949 4.580 4.533 4.217 4.202 4.017 4.029 3.792 3.792 4.254 4.251 3.789 3.750 3.806 3.806 4.362 4.364 0.005 0.005 0.008 0.008 0.012 0.010 0.010 0.007 0.010 0.010 0.009 0.009 0.014 0.014 0.020 0.022 0.013 0.013 0.020 0.020 0.004 0.004 0.012 0.012 0.005 0.006 0.010 0.010 0.003 0.003 Ref. 13 1,2 1 1,2 1 1,2 1,2 14 1,2 15 16 1,2 17,18 2,19 20 References±1: A91, 2: This work, 3: Clausen (1996), 4: NordstroÈm & Johansen (1994), 5: Lacy (1997a), 6: Lacy et al. (1997), 7: Popper (1987), 8: Simon, Sturm & Fiedler (1994), 9: Guinan et al. (in preparation), 10: Lacy (1997b), 11: Torres et al. (1997), 12: North, Studer & KuÈnzli (1997), 13: Linnell, Hubeny & Lacy (1996), 14: Vaz et al. (1997), 15: Alencar, Vaz & Helt (1997), 16: Ribas, Jordi & Torra (1999a), 17: Popper (1997), 18: Clement et al. (1997), 19: Latham et al. (1996), 20: Ribas et al. (1999b). components does not unequivocally determine these parameters. Therefore, the effective temperatures of the components, although we know them not to be so reliable as the absolute dimensions, need to be included in the algorithm. This is because a change in the value of Y is equivalent to changing the effective temperature (see Fig. 2), or, in other words, the value of the effective temperature mostly determines the initial helium abundance of the system, whereas it has less effect on the initial metal abundance. If a chemical enrichment law, i.e. Y(Z), is assumed, the knowledge of the masses and radii is sufficient to unequivocally determine the best fitting isochrone (see Ribas 1996; Jordi et al. 1997a; Pols et al. 1997). However, if the isochrone is forced to fit all data, including the observed effective temperature, any systematics present in its determination may introduce a bias on the derived ages and metallicities. When Y is left free, its determination may be affected by any systematics in the temperature, but these systematics would have little influence on the estimation of the age and the metallicity. Therefore, we preferred to make use of all the observational information, and not to impose any restriction on the initial helium abundance with the aim of avoiding possibly biased solutions. Another point that might introduce some bias is the age origin. The evolutionary models of CG place their time origin on the ZAMS. But there is a PMS phase whose duration depends on the mass of the star. Several simulations for the ages and mass differences of the stars in our sample showed that the effect of not considering the time spent in the PMS phase is negligible and that it does not introduce any bias. However, for the q 2000 RAS, MNRAS 313, 99±111 Eclipsing binaries: He/metal enrichment ratio 103 sake of completeness, the ages derived from our post-ZAMS models were corrected for a very small additive term, due to PMS evolution, which we computed from the models of Iben (1965). 4.1 Foundations of the algorithm When the mass and the surface gravity are known, each combination (Z,Y) in the evolutionary models predicts an age and an effective temperature for the star. We therefore constructed a function (x 2) that depends on the difference of the predicted ages for both components log tA 2 log tB ; and on the difference between the observed (superscript `obs') and model predicted (superscript `mod') effective temperatures log T obs eff A;B 2 log T mod eff A;B : Our algorithm is based on finding the initial chemical composition that provides the smallest possible value of this function, i.e. the best description of the observed properties of the system components. Therefore, two procedures are involved: interpolation in the evolutionary models and minimization of a bidimensional function. (i) The interpolation procedure uses as input data, on the one hand, the grid of evolutionary tracks of CG computed for different (Z, Y) values (Z 0:004±0:03; Y 0:18±0:42) and, on the other hand, the following stellar parameters: the initial chemical composition (Z*, Y*), the observed (instantaneous) mass (M*) and the observed surface gravity (log g*). Three basic steps are then followed. The first step consists in the calculation of a set of evolutionary models (SEM) for the assumed chemical composition (Z*, Y*) by interpolating within the discrete grid of (Z, Y) values. Taking into account the uniform distribution of the grid points, the interpolation can be easily performed, first as a function of Y and then as a function of Z. Some tests indicated that the best results are obtained when using a linear interpolator in Y and a logarithmic interpolator in Z. In the second step, complete evolutionary tracks for the observed mass M* of each component are interpolated between two contiguous tracks of the SEM at (Z*, Y*). Logarithmic interpolation yields the best results as indicated by several tests. Finally, in the last step, the evolutionary track for M* is linearly interpolated at the observed log g* yielding the age, effective temperature, luminosity, initial mass and internal structure constants. An iterative scheme was used to correct the interpolation mass (which was initially adopted as M*) by taking into account mass loss during the evolution (CG adopted the equation from Nieuwenhuijzen & de Jager 1990). Thus, the initial mass (MZAMS) of the star is obtained, after a few iterations, in such a way that a zero-age star with MZAMS evolves and yields a star of M* M* , M ZAMS and log g* after losing a fraction of the mass via stellar wind. We have to mention that this correction was very small (below 1 per cent) for most systems in our sample. The most critical system is probably EM Car, but even in that case the amount of mass loss is insignificant (2 per cent). A flux diagram that shows all the steps and the parameters involved in the interpolation procedure is presented in Fig. 4. An evaluation of the interpolation errors was done in two steps (see Asiain, Torra & Figueras 1997 for a complete description of this procedure). First, a whole SEM of a given (Z,Y) was suppressed and interpolated from the remaining ones. The resulting and the suppressed SEMs were then compared for several different masses, which yielded the values listed in the first three rows of Table 2. This is actually an overestimation of the actual mean interpolation errors by about a factor of four, since the density of the initial grid was degraded when suppressing a certain q 2000 RAS, MNRAS 313, 99±111 Figure 4. Flux diagram showing the individual steps of the interpolation procedure. Input data are Z*, Y*, M* and log g*. Notice the iterative process designed to correct for mass loss. Table 2. Standard deviations of the difference between actual and interpolated evolutionary tracks for several different masses. The figures listed here are, approximately, a factor of four larger than the estimated mean errors. The first three rows correspond to the interpolation for a given (Z, Y ), and the remaining rows correspond to the mass interpolation alone. s (D log Teff) s (D log g) s (Dt /t ) s (D log Teff) s (D log g) s (Dt /t ) 15 M( 5 M( 2.5 M( 1.5 M( 0.002 0.017 0.045 0.002 0.010 0.006 0.001 0.009 0.035 0.002 0.007 0.015 0.007 0.018 0.038 0.002 0.010 0.019 0.010 0.028 0.035 0.005 0.010 0.009 (Z, Y). The error due to mass interpolation was evaluated in the same way, i.e. by eliminating a whole track of a given mass from the SEM and interpolating it from its neighbours. The results of the comparison of the interpolated track with the real track are shown in the last three rows of Table 2. These values are also an overestimation of the mean interpolation errors by about a factor of four, for the same reason as previously exposed. In summary, the interpolation errors can be estimated to be below 1.5 per cent in all the parameters for the evolutionary stages of the systems in the sample. (ii) The interpolation procedure previously described provides the age and the effective temperatures, among other parameters, of each component of the system for a given (Z*, Y*). We therefore obtain two age determinations that can be mutually compared, and two effective temperatures that can be compared to the observational determination. Thus, the following function for each DDLEB system was evaluated: x2 Z; Y vlog t log tA 2 log tB 2 s2log tA s2log tB vlog T A mod 2 log T obs eff A 2 log T eff A 2 slog T A vlog T B mod 2 log T obs eff B 2 log T eff B ; 2 slog T B 1 104 I. Ribas et al. where t is the age, s p is the standard error associated to the parameter p and v p is the relative weight that is assigned to p. The criteria for the weight system were the following: twice the weight to the ages than to temperatures, since the former come from the more reliable determinations (masses and radii) and the temperature of the primary was given twice the weight than that of the secondary, since the latter is usually fainter and its photometric indices have larger uncertainties. With this prescription, the relative (non-normalized) weights were the following: vlog t 6; vlog T A 2; vlog T B 1: 2 Nevertheless, tests made with different weight systems showed a very weak influence on the final results. This can be explained by the essentially uncorrelated behaviour of Z and Y, i.e. Z depends mostly on the age and Y is determined by the value of the effective temperature. Owing to the small effect of the weight system used, we decided not to adopt any special criteria depending on the characteristics of a given system, e.g. totally eclipsing cases. Equation (1) makes use of all the information available for the eclipsing binaries. Considering either TeffB/TeffA or T effB 2 T effA instead of the actual values of the temperatures could be an alternative functional form. The advantage of such an approach is obvious, since the temperature ratio (or difference) can be obtained from the light curve analysis and it is a scale-independent quantity. Several tests were made in order to evaluate the possibility of using this prescription. The results were negative since the temperature ratio essentially does not depend on Z and it varies very slowly as a function of Y, thus the temperature ratio is not a discriminant parameter. Therefore, the actual value of the effective temperature is needed to obtain an estimation of the initial helium abundance of the system. There should exist a certain chemical composition that yields the same ages for both components and effective temperatures identical with the observed ones, i.e. x2 0: But, taking into account the observational errors and the inaccuracies of the models, our algorithm searches for the smallest value of x 2 that is assumed to represent the chemical composition that best reproduces the observed parameters of the components. x 2, as defined in Eq. (1), is a non-analytical bidimensional function, and the `downhill simplex method' (Nelder & Mead 1965) was used to find its minimum. The computational implementation of this method, which requires only function evaluations and no derivatives, is explained in Press et al. (1992). In the regions where the function is multivalued, i.e. main sequence hook (MS hook), the x 2 function was computed by taking into account all the different value combinations (three or nine, depending on the position of one or both components in the multivalued region). In such a case, we adopted the combination that yielded a smaller value for x 2. 4.2 Results From its definition, the x 2 function becomes more sensitive to Z and Y changes when both components of the DDLEB system have Figure 5. 3-D and contour plots of the x 2 function (equation 1) for eight eclipsing-binary systems in the sample. Cases with well-defined minimum, shallow and elongated minimum, and minimum outside the (Z,Y) range are shown for illustrative purposes. The discontinuity in the bottom panels is caused by the location of the system in a multivalued region (MS hook). q 2000 RAS, MNRAS 313, 99±111 Eclipsing binaries: He/metal enrichment ratio different locations in the H±R diagram. This can be easily understood in terms of an isochrone that has to fit two points in the H±R diagram with given error bars: the closer the two points, the larger the range of Z and Y that can fit both at the same time. Thus, our analysis yields only reliable results for those eclipsing-binary systems whose components are separate enough in the log M 2 log g diagram. For the remaining ones, no information about the model predictions can be extracted from isochrone fitting. The separation was defined as s M A 2 M B 2 log gA 2 log gB 2 S 3 s2MA s2MB s2log gA s2log gB of the sample are shown in Fig. 5. Examples of systems with a well-defined minimum or a shallow minimium were selected for illustrative purposes. Also, some systems with components close to the multivalued region or with a minimum outside the explored (Z, Y) range are shown. In general, the depth of the minimum, which is related to the reliability of the solution, increases when both components are far from the ZAMS and when S is large. The latter has already been justified, and the former can be easily understood in terms of the age-degeneracy close to the ZAMS. In that position, small variations in the input parameters lead to very large variations in age, and so sensitivity of the function is greatly decreased. The results for those systems with a solution, i.e. those with a minimum in the covered (Z, Y) range, are shown in Table 3. GZ CMa, for which a small extrapolation was needed, is also included. The output best-fitting parameters include the age and the chemical composition (Z, Y) that best reproduces the system properties, and the corresponding value of x2min : The latter is and the minimum separation parameter was set to S 2; which means that both components have to be separated by at least twice the standard errors. With these restrictions, the number of DDLEBs selected for further analysis was reduced from 50 to 41. A 3-D plot and a contour plot of x 2(Z, Y) for several systems Table 3. Results of the fitting algorithm. Those systems with a minimum in the covered (Z, Y) range are listed in the left part, except for GZ CMa for which a solution involving a small extrapolation was accepted. The errors were computed through a Monte Carlo simulation (see text). Notice that V380 Cyg and HV 2274 are also listed, although their analysis was not done through the fitting algorithm. The right part contains further information for those systems that do not have a minimum in the covered (Z, Y) range. Name V539 Ara AD Boo GZ CMa EM Car YZ Cas WX Cep CW Cep V380 Cyg V442 Cyg V1143 Cyg AI Hya HS Hya KW Hya x 2 Hya TZ Men TV Nor U Oph V451 Oph V1031 Ori EE Peg AI Phe z Phe V1647 Sgr V3903 Sgr V906 Sco CD Tau CV Vel HV 2274 Name BW Aqr b Aur QX Car SZ Cen RS Cha DI Her GG Lup UX Men EW Ori IQ Per PV Pup V760 Sco BH Vir q 2000 RAS, MNRAS 313, 99±111 105 log age (yr) Z Y x2min 7.614 ^ 0.015 9.303 0.041 8.694 0.020 6.791 0.011 8.654 0.014 8.789 0.024 6.666 0.063 7.209 0.031 9.158 0.032 8.650 0.980 9.143 0.024 9.139 0.050 8.953 0.027 8.281 0.024 8.288 0.030 8.562 0.029 7.675 0.032 8.403 0.031 8.846 0.010 8.563 0.032 9.721 0.007 7.842 0.019 8.489 0.042 6.377 0.033 8.420 0.025 9.433 0.035 7.758 0.009 7.243 0.012 0.012 ^ 0.003 0.022 0.006 0.032 0.006 0.005 0.002 0.016 0.004 0.014 0.003 0.023 0.007 0.020 0.020 0.007 0.016 0.008 0.020 0.004 0.011 0.009 0.013 0.003 0.014 0.003 0.014 0.002 0.015 0.002 0.017 0.005 0.015 0.002 0.016 0.004 0.026 0.007 0.010 0.006 0.013 0.001 0.013 0.002 0.010 0.003 0.016 0.003 0.026 0.007 0.007 0.005 0.007 0.282 ^ 0.027 0.243 0.030 0.312 0.035 0.238 0.083 0.270 0.026 0.240 0.025 0.298 0.101 0.28 0.303 0.058 0.242 0.028 0.271 0.048 0.240 0.054 0.201 0.026 0.276 0.025 0.254 0.027 0.255 0.034 0.253 0.046 0.279 0.037 0.248 0.038 0.283 0.034 0.241 0.049 0.290 0.022 0.224 0.038 0.276 0.047 0.253 0.040 0.263 0.036 0.199 0.048 0.260 .03 0.039 0.205 0.079 0.001 0.156 0.081 0.252 0.086 0.385 0.044 0.060 0.121 0.180 0.113 0.217 0.209 0.054 0.045 0.134 0.106 0.725 0.043 0.017 0.500 0.133 0.032 Comments Unreliable extrapolated solution at Z @ 0:03 and Y @ 0:4: However, x2 , 1 in some regions. Unreliable extrapolated solution at Z @ 0:03 and Y @ 0:4: However, x2 , 1 in some regions. Extrapolated solution at Z 0:035 and Y 0:368; with x2min 0:047: Metal-poor solution, but very strongly dependent on the value of the overshooting parameter. Solution at Z 0:018 and Y 0:264; with x2min 2:32: x2 . 1 in all the (Z,Y) range. ZAMS system. No solution in the (Z, Y) range, but x2 , 1 in some regions. ZAMS system. No solution in the (Z, Y) range, but x2 , 1 in some regions. Extrapolated solution at Z 0:039 and Y 0:329; with x2min 0:018: Extrapolated solution at Z 0:042 and Y 0:336; with x2min 0:017: The solution places the B component between the first two points of the evolutionary track. ZAMS system. No solution in the (Z, Y) range, but x2 , 1 in some regions. ZAMS system. No solution in the (Z, Y) range, but x2 , 1 in some regions. No solution in the (Z, Y) range, but x2 , 1 in some regions. 106 I. Ribas et al. related to the quality of the best-fitting solution that the models are able to provide. Notice the large error in the age of V1143 Cyg, which is caused by the proximity of its components to the ZAMS. Information about the remaining systems (systems with ZAMS components, without a solution in the covered (Z, Y) range or with extrapolated solutions) is also presented in Table 3. Some comments on a handful of systems should be given at this time. The age and chemical composition of HV 2274 and V380 Cyg, both included in Table 3, were not computed using the fitting algorithm. Careful, individual analysis of these systems have been published separately (HV 2274: Ribas et al. 1999b; V380 Cyg: Guinan et al. in preparation). In the case of HV 2274, both components are too close in the log g 2 T eff diagram to be suitable for applying the fitting algorithm. Therefore, a spectrophotometric metallicity determination (checked against the known LMC metal content) was adopted. Only the age and Y were considered as free parameters, which were confidently determined in spite of the similarity of the components. V380 Cyg contains the most evolved massive star in the sample. At its evolutionary stage, the models are critically influenced by the value of the overshooting parameter. In Guinan et al. (in preparation), the analysis is done with a set of specially-built evolutionary tracks with various overshooting parameters, and by comparing with the spectrophotometric metallicity determination. The value derived from this detailed study is listed in Table 3. Finally, SZ Cen is also a moderately-evolved system but with intermediate-mass components. Similarly to V380 Cyg, the chemical composition obtained from the fitting algorithm is strongly influenced by the value of the overshooting parameter, owing to the critical location of the components in the log g 2 log T eff diagram. A thorough discussion on this point is provided in Ribas et al. (in preparation). Therefore, SZ Cen, with anomalously low metal and helium abundances obtained from the algorithm, was not considered for further work. Also in Ribas et al. (in preparation), other moderately-evolved intermediate-mass systems in the current sample (WX Cep, AI Hya and V1031 Ori) are shown not to experience the same kind of behaviour, owing to the less-critical location of their components in the log g 2 log T eff diagram. Therefore, the chemical composition determinations for these systems are reliable. 4.3 Errors The errors of the output best-fitting parameters were computed through a Monte Carlo simulation in order to achieve the best possible estimation and to be able to analyse the possibility of biases. We must point out that in both cases only the uncertainties of the input parameters were considered, since the interpolation errors were shown to be negligible. A very important remark must be made concerning the correlation of the errors associated with the parameters of both components. Actually, the relative values RB =RA ; M B =M A and T effB =T effA are known with a significantly better accuracy than the actual absolute values. The determination of these ratios comes from certain specific characteristics of the light and radial velocity curves that are accurately modelled. However, when the standard errors of M, log g and Teff for both components are provided, this correlation is not explicitly shown. We should remark here that k RB =RA is quite often a poorlydefined parameter for systems with very similar components and eclipses of equal depth. However, as we mentioned previously, we did not consider for further study those systems with similar components, therefore minimizing the possibility of such degeneracy. The correlation between the errors of the components has crucial importance when evaluating the uncertainties of our algorithm, since the relative position of the components in the H±R diagram, which fixes the slope of the isochrone, is better defined than their absolute location. Unfortunately, the errors of RB =RA ; M B =M A and T effB =T effA are not explicitly shown in most of the publications. In order to evaluate them, we compared the standard errors of the absolute parameters with the errors of the parameter ratios for several systems for which both of them are known. We found that, in all cases, the relative errors are a factor of 2.5 smaller than the error estimations of the parameters themselves. This error ratio was also adopted for all our systems. A simulation considering 500 points was run for each of the systems with a solution in the (Z, Y) range. This number ensures an statistical error below 5 per cent, which is suitable for our purposes. We generated a random set of parameters M, log g and Teff for the primary component following a normal distribution around the observed values with a standard deviation equal to the observed error. Once a new set of parameters is generated for the primary component, they are re-scaled to the secondary component by means of the ratios RB =RA ; M B =M A and T effB =T effA : Then, a new random set of parameters for the secondary component is generated around the re-scaled values with a standard deviation 2.5 times smaller than the observed error. After running the simulation, the error of each parameter was adopted as the standard deviation of all the solutions obtained. The inverse value of x2min of each solution was used as the weight for computing the standard deviation. Thus, we considered a larger weight when the minimum of the solution was better defined, i.e. the fundamental actual parameters could be more accurately reproduced. For systems close to the limit of the covered region in the (Z, Y) range and with shallow minima, only the inner region of the Gaussian distribution was considered when computing the standard deviation, in order to avoid possible extrapolation biases. The errors adopted are listed, together with the corresponding parameters, in Table 3. The smallest errors in Z and Y are about 0.002 and 0.025, respectively, for the sharpest minima, and they rise to about 0.010 and 0.100, respectively, for the systems with the widest, more poorly-defined minima. The mean errors are ksZ l 0:004 and ksY l 0:04; i.e. around 20 per cent in both cases. 4.4 Biases A biased determination of the best-fitting parameters may result if the x 2 function presents a strong asymmetric shape in the minimum region. In order to study this possibility, we used the results of the Monte Carlo simulation described in the previous section to compare the distribution of the solutions with a Gaussian distribution. A simple way of evaluating the asymmetry of the distribution consists in comparing the best-fitting parameters with the mean values of the 500 simulations. We computed these mean values for the systems in Table 3. The differences between these values and the best-fitting parameters are listed in Table 4. As may be seen, the differences are small in all cases and always smaller than the standard errors listed in Table 3. Additionally, there does not exist any systematic trend either in the form of a zero point (the mean differences are kZ 2 Zl 20:001 ^ 0:002 and kY 2 Yl 0:000 ^ 0:012) or as a functional dependence of Z or Y. Thus, we conclude that no significant statistical bias is present when considering a sample of systems. However, some individual q 2000 RAS, MNRAS 313, 99±111 Eclipsing binaries: He/metal enrichment ratio Table 4. Difference between the best-fitting chemical composition and the mean value obtained from a Monte Carlo simulation n 500: GZ CMa (extrapolated solution), V380 Cyg and HV 2274 (both have chemical composition values computed without using the fitting algorithm) are not included. Name Z 2 Z Y 2 Y Name Z 2 Z Y 2 Y V539 Ara AD Boo EM Car YZ Cas WX Cep CW Cep V442 Cyg V1143 Cyg AI Hya HS Hya KW Hya x 2 Hya TZ Men 0.000 20.004 0.000 20.002 0.001 20.005 20.001 0.002 20.003 20.003 0.000 0.001 0.000 20.002 20.012 0.001 20.007 0.014 20.008 20.004 0.018 20.008 20.024 20.004 0.011 0.001 TV Nor U Oph V451 Oph V1031 Ori EE Peg AI Phe z Phe V1647 Sgr V3903 Sgr V906 Sco CD Tau CV Vel 0.000 0.001 0.001 20.001 0.003 20.001 0.000 0.000 20.001 20.002 20.002 20.002 0.003 0.033 0.012 20.020 0.014 20.011 0.001 20.001 0.000 0.001 20.006 20.009 Figure 6. Histograms showing the distribution of 500 simulated solutions for the chemical composition of the eclipsing binaries V539 Ara and HS Hya. The vertical solid line represents the actual best-fitting solution listed in Table 3, and the vertical dotted line is the mean value of the distribution. Notice the asymmetric behaviour, especially in the case of HS Hya. effects are not discarded, since they may depend on the actual location of the system in the H±R diagram. This possibility is statistically difficult to evaluate, owing to the fact that it is related to a single system. Since the asymmetry that we observe is rather small in all cases, no significant bias should be expected for any of the systems. As an example, Fig. 6 shows histograms for Z and Y computed for two extreme cases: V539 Ara and HS Hya. V539 Ara is a system with a well-defined and deep minimum that presents a very slightly asymmetric distribution with an extended wing towards high Z. Nevertheless, the mean value of the distribution is indistinguishable from the best-fitting values (dotted and solid lines in the figure, respectively), indicating that no significant bias is present. HS Hya is an example of a system with a shallow minimum. In this case, the solution is not so well defined and a clear asymmetric trend is observed in the figure (towards high Z and high Y). Thus, the mean values of the distribution are larger than the best-fitting parameters. Even in an q 2000 RAS, MNRAS 313, 99±111 107 extreme case, such as HS Hya, a possible bias is a factor of two smaller than the standard error listed in Table 3. Despite the asymmetric distribution displayed by a small number of systems, we adopted the criterion of quoting the standard deviation of a normal distribution as the error of our determination. In our examples, such a criterion includes 82 per cent and 57 per cent (Z and Y) of the simulated solutions for V539 Ara, and 82 per cent and 75 per cent (Z and Y) for HS Hya. 5 R E S U LT S O N M E TA L C O N T E N T Although it has been clearly stated that the metal abundance that we derive has an intrinsic character, a comparison with the atmospheric determinations should provide compatible results in most cases. Only systems with atmospheric anomalies (e.g. metallic line spectra), are expected to exhibit large differences, whereas the best agreement should be for stars with deep outer convection zones, i.e. mid-F and cooler. Unfortunately, very few systems have spectroscopic determinations of the atmospheric metal content. The only systems with published spectroscopic [Fe/H] are UX Men (Andersen, Clausen & Magain 1989), EE Peg (Linnell et al. 1996), AI Phe (Andersen et al. 1988) and CD Tau (Ribas et al. 1999a). A metallicity estimation can be also obtained from the StroÈmgren photometric index d m8 for A3±G2 stars. For those systems in this spectral type range, we computed the metallicity following the calibrations of Smalley (1993) and Nissen (1988). All the available empirical metal abundance determinations and the comparison with the isochrone fitting results are listed in Table 5. The extrapolated solution for UX Men listed in Table 3 has been not included, since it was considered to be unreliable. Some remarks must certainly be made concerning the systems with atmospheric metallic anomalies: GZ CMa, AI Hya, KW Hya and EE Peg. For three of them, the metal abundance deduced from the atmospheric parameters is considerably larger than the intrinsic metallicity deduced from the models. This is a clear indication of the presence of physical processes (diffusion) that lead to an enhancement of the metal abundance in the external layers of the star (Michaud 1980). The remaining system, GZ CMa, also with a metallic line spectrum, presents an atmospheric metallicity in good agreement with the results of the isochrone fitting. The metallic character that leads to its classification is probably related to a real, intrinsic high metal abundance rather than to atmospheric anomalies. Regarding those systems with non-metallic spectra, the agreement between observational metallicity determinations and the results of our fitting algorithm is excellent. Indeed, all the differences in Z are within ^0:005: An interesting possibility of the results is the analysis of the metal abundance as a function of the mass or the age of the system. The mean values of the chemical composition of all 27 galactic systems listed in Table 3 are kZl 0:016 ^ 0:006 kYl 0:260 ^ 0:028: However, it may be illustrative to split these systems into those composed of O- and B-type stars and those composed of A- and Ftype stars. This means that, for the first group, which includes 11 OB-type systems, kZl 0:014 ^ 0:005 kYl 0:265 ^ 0:029; and for the remaining 15 systems with A- and F-type components (AI Phe, with a K-type component, has not been included): kZl 0:018 ^ 0:006 kYl 0:257 ^ 0:029: 108 I. Ribas et al. Table 5. Observational metallicity determination, and comparison with the best-fitting solution from the algorithm. Z( 0:0188 (Schaller et al. 1992). Name GZ CMa YZ Cas WX Cep V380 Cyg AI Hya HS Hya KW Hya TZ Men UX Men V1031 Ori EE Peg AI Phe CD Tau HV 2274 (LMC) [Fe/H]obs Zobs 0.22 0.03 20.03 20.03 0.5 20.17 0.5 20.03 0:04 ^ 0:10 20.25 0.5 20:14 ^ 0:10 0:08 ^ 0:15 20:45 ^ 0:06 0.032 0.020 0.017 0.018 0.07 0.013 0.06 0.018 0:021 ^ 0:005 0.011 0.06 0:014 ^ 0:003 0:023 ^ 0:008 0:007 ^ 0:001 Therefore, the mean metallicity of the OB-type systems comes out to be marginally smaller than that of the systems with AF-type components. This result supports the indications of a low metal content for the early-B type system GG Lup found by Andersen, Clausen & GimeÂnez (1993). This system, which was not considered in our analysis owing to its unevolved stage, actually falls below the solar metallicity ZAMS in Fig. 3. Another interesting study carried out by Kilian (1992), based on atmospheric abundance determinations, also revealed a substantially sub-solar metallicity (by almost a factor of two) for a sample of early-type stars in OB associations. A very thorough study on the chemical evolution of the galactic disc was published by Edvardsson et al. (1993). The authors collected high-accuracy spectroscopic and photometric data for a sample of 189 field stars. Their results show that, for the ages of our DDLEBs, no correlation between the age and the metallicity is present. Indeed, the age±metallicity relation is quite flat, even for ages close to 10 Gyr, and with a large scatter in metallicity. Studies based on open-cluster data also confirm the presence of a large metallicity scatter and do not support the existence of an age±metallicity relation (Friel 1995, and references therein). Thus, our result is not in contradiction with these studies. In addition, the age-span of our DDLEBs is small (the oldest system, AI Phe, is only 5 Gyr old) and we are only sampling a restricted spatial area around the Sun, mostly within 1 kpc. 6 C H E M I C A L E N R I C H M E N T R AT I O A N D PRIMORD IA L H ELIUM A BUN DAN CE The initial metal and helium abundances (Z, Y) are independent output parameters provided by our fitting algorithm. Thus, the data listed in Table 3 allow us to establish an empirical determination of the enrichment law and, as a consequence, an estimation of the primordial helium abundance. Since the chemical enrichment law is thought to be universal, the results for the LMC system HV 2274 and for the remaining Galactic systems can be treated together. The determined helium abundance of these 28 systems is plotted versus the metallicity in Fig. 7. Error bars have not been represented for each point, but an illustration of the typical errors is provided in the bottom-right part of the figure. As can be seen, a quite well-defined linear dependence is present in the figure, in spite of the rather large scatter and the error bars associated with each point. Even though both axes are Z obs 2 Z 0.000 0.004 0.003 0.05 0.002 0.05 0.004 20.005 0.03 0.004 20.003 Comments Photometric, primary Am star Photometric, based on the B comp. Photometric Spectrophotometric Photometric, primary Fm star Photometric Photometric, primary Am star Photometric, based on B comp. Spectroscopic Photometric Spectroscopic, primary Am star Spectroscopic Spectroscopic Spectrophotometric Figure 7. The initial helium abundance (Y) versus the initial metallicity (Z) for a sample of 28 DDLEBs (Table 3). Typical error bars are shown in the bottom-right part of the panel. The solid line represents a weighted linear regression, the result of which is in the top part of the panel. affected by observational errors, we decided to compute a weighted linear regression of Y as a function of Z, since the mean relative error of the former is more than three times larger than that of the latter. The adopted relationship was expressed in the form Y Y p DY=DZZ; 4 where Yp can be assimilated to the value of the primordial helium and DY/DZ is the enrichment ratio. We tested different weight systems leading to very similar results, and we finally adopted relative weights proportional to the inverse of the quadratic sum of the errors in Y and Z. The resulting values of the least-squares fit and their uncertainties are Y p 0:225 ^ 0:013 DY=DZ 2:2 ^ 0:8; with a correlation coefficient r 0:5 and an rms residual in Y of 0.024. The scatter of the relation is therefore rather large, but in agreement with what is expected from the mean uncertainty of the measurements ksY l 0:04: The large dispersion is probably caused by the random errors of the fundamental parameters, q 2000 RAS, MNRAS 313, 99±111 Eclipsing binaries: He/metal enrichment ratio especially the effective temperature. However, the influence of these errors is already included in the uncertainties quoted for the fitted abundances. The main concern is not the effect of the random errors but the presence of a systematic trend. No systematic errors are expected in the mass and surface gravity determination of the DDLEB components, since the analysis of different systems are completely independent and possible sources of systematic effects are always studied in detail. The most likely source of systematic errors is the effective temperature determination, since it is a scale-dependent quantity and any zero-point offset would have a direct influence on the determined initial helium abundance. The atmospheric parameters of a star (the effective temperature is included) are affected by its rotation rate (Figueras & Blasi 1998). As we showed in Section 3, the effective temperature of most of the systems in the sample was obtained through photometric indices and calibrations, which can both be influenced by rotation. This influence depends on two parameters: the fractional angular velocity (the ratio between the observed and the critical value) and the inclination of the rotation axis with respect to the visual, which can be adopted to be close to 908 for DDLEBs. A rotating star is therefore similar to a non-rotating one with smaller effective temperature. We collected the linear rotational velocities for most of the systems in our sample and interpolated in the tables of Collins & Sonneborn (1977) to obtain the critical angular velocity and the StroÈmgren indices for both the rotating and the non-rotating cases. Then we computed a correction to our photometry as the difference between the StroÈmgren indices that include rotation and those of an identical non-rotating star. All the components of the systems in our sample have fractional angular velocities below 0.3 and most of them (65 per cent) are below 0.2. Therefore, the rotation correction is expected to be very small. Actually, we found that the temperature difference was in all cases around or below 100 K. Moreover, differences of at most 50 K were found between the components in the same binary system. Therefore, the influence of stellar rotation on the temperature difference between the system components can be neglected, and, thus, the metallicity determination is not affected, since it is only determined by the relative location of the components. However, the derived initial helium abundance may be systematically influenced by the change in the effective temperature (see Fig. 2). Since rotation has only significant influence on Y and not on Z, Yp and DY/DZ are not equally affected. Actually, the slope of the relation remains unchanged when an offset in the y-axis is considered, and so DY/DZ can be considered free of systematics caused by the effective temperature. However, the zero point (Yp) is directly influenced by a systematic trend on the helium abundance determination. As an illustration of the order of magnitude of the effect, a systematic increment of the effective temperature of only about 2 per cent would produce a change of Yp from 0.225 to 0.24. Further discussion on this point is provided at the end of this section. 6.1 Comparison with previous results Once the presence of systematic errors in our DY/DZ determination has been ruled out, we can compare the result with the recent values described in Section 1, either coming from the analysis of H ii regions, ZAMS structure or Galactic Bulge stars. We find a good general agreement, with our estimate lying around the `mean' value deduced from all determinations. Also, the agreement with the most accurate value of Izotov & Thuan (1998) is very good. However, it has to be pointed out that the q 2000 RAS, MNRAS 313, 99±111 109 uncertainty associated with our determination is the smallest one when compared with all the previous results. The enrichment law that we have obtained can also be compared with what several authors adopt when building their stellar evolutionary models for a range of metallicities. In contrast with the models of CG, some of the most widely-used models adopt a fixed law Y(Z) to compute the initial helium content as a function of the metallicity. In summary, the Geneva group (Schaller et al. 1992; Shaerer et al. 1993a,b; Charbonnel et al. 1993) adopts Y 0:24 3Z; the Padova group (Bressan et al. 1993; Fagotto et al. 1994a,b) uses Y 0:23 2:5Z; and the Cambridge group (Pols et al. 1998) employs Y 0:24 2Z: We see that the slope of the enrichment law considered by all these current models lies within the error bars of our empirical determination, the Padova-group and Cambridge-group adoptions being the closest to our estimate. Regarding the primordial helium abundance, hundreds of papers in the literature are devoted to the study of this important parameter. Actually, most of the studies obtain primordial helium abundances that fall in the range between 0.23 and 0.24. Therefore, this is a quite well-established quantity and the main concern is now the determination of the third decimal place. We shall only review here some of the most recent results. A thorough work on the observational determination of the primordial helium abundance was published by Pagel et al. (1992). The authors measured the abundance of helium, nitrogen and oxygen for a sample of 33 extragalactic H ii regions and evaluated the possible statistical and systematic errors. They obtained a value of Y p 0:228 ^ 0:005 stat: ^ 0:005 syst:; that was subsequently modified by Olive & Steigman (1995) to Y p 0:232 ^ 0:003 after excluding some discrepant objects. Peimbert (1996) collected all the available Yp determinations from 1979 to 1995, and obtained a weighted average of Y p 0:234 ^ 0:005; very close to the previously-mentioned value. An update of the primordial helium determination was presented by Olive, Steigman & Skillman (1997). They obtained and analysed new data on low-metallicity extragalactic H ii regions and derived a primordial helium abundance of Y p 0:234 ^ 0:002 stat:; again in very good agreement with the determinations of Olive & Steigman and Peimbert. Olive et al. also obtain an upper bound to Yp of 0.237, at the 95 per cent confidence level. This value seems to be in contradiction to the recent result published by Izotov & Thuan (1998), who obtain Y p 0:244 ^ 0:002 and claim that a value as low as Y p 0:234 can be excluded. Thus, the determination of the primordial helium abundance is still an open question, although in the region of 3±4 per cent. We have to remark that all these works are based on the observation and modelling of spectral features of H ii regions. Therefore, the results are subject to possible systematic errors related, e.g., to the values of the helium emissivity adopted or to the amount of undetected neutral helium. As we earlier pointed out, our primordial helium abundance determination is not as reliable as the helium enrichment value, since it may be affected by systematic errors in the determination of the effective temperature. Thus, we cannot contribute to the discussion about the accurate estimation of Yp. However, the argument can be reversed and we can adopt a quite accurate primordial helium abundance of Y p 0:24: Then, when comparing with our estimation Y p 0:225; we deduce that the possible systematics present in the effective temperature determination can be constrained to be around 2 per cent as a mean, although this figure may change as a function of the photometric region. This is the reflection of an increment of the helium abundance by 0.015. In conclusion, large systematics or zero-point offsets in the 110 I. Ribas et al. effective temperature determination can be ruled out, thus reinforcing our confidence in the whole analysis and in the resulting parameters. 7 CONCLUSIONS The chemical composition of a sample of 50 eclipsing binaries with accurate fundamental parameters was studied by comparison of evolutionary-model predictions with observations. This was done through an algorithm founded on the assumption that evolutionary models should be able to fit an isochrone to both components of the system for a certain chemical composition. We made use of the evolutionary models of CG that constitute a grid with several (Z, Y) values. Thus, both Z (metallicity) and Y (initial helium abundance) were treated as free parameters. The fitting algorithm is based on the interpolation of the evolutionary models and the minimization of a x 2 function that depends on the chemical composition and the fundamental parameters of the components. The best-fitting model parameters are those that predict the smallest value of x 2. The algorithm yields the bestfitting values for the age and the chemical composition (Z, Y) of the system (among other parameters) for those cases where a minimum is found. The errors associated with the chemical composition determination were evaluated by means of Monte Carlo simulations. We collected all the available empirical metal abundance determinations (photometric, spectroscopic and spectrophotometric) for the systems in our sample and we compared them with the resulting values of the fitting algorithm. All the differences in Z were found to be within ^0.005, except for those systems with atmospheric anomalies. When studying the correlation between the metal abundance and the spectral type, we found that the mean metallicity of systems with OB-type components is marginally smaller than that of the systems with AF-type components. Since both the values of Z and Y are output parameters of our fitting algorithm, we were able to undertake a determination of the chemical enrichment law. We obtained DY=DZ 2:2 ^ 0:8; in good agreement with the most recent results, but with a smaller formal error. Moreover, possible systematic effects were discussed and ruled out. Also, an estimation of the primordial helium abundance was derived by extrapolation of the linear enrichment relationship. Our result, Y p 0:225 ^ 0:013 is less accurate than that obtained through other methods and appears to be slightly lower than current estimations. This may be justified by the presence of small systematic deviations of the effective temperature determination (rotation effects or a zero-point offset). It should be emphasized that this is the first time that the helium-to-metal enrichment ratio and the primordial helium have been obtained through the analysis of DDLEBs. 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