Ionization Smoke Detectors in Slovenia – Current Status and Future Challenges Simona Sučić ARAO Celovška cesta 182 SI-1000 Ljubljana, Slovenia [email protected] Kostanjevec Marko, Tomaž Žagar ARAO Celovška cesta 182 SI-1000 Ljubljana, Slovenia [email protected], [email protected] Simon Dekleva Zarja Elektronika Polčeva pot 1 SI- 1241 Kamnik, Slovenia [email protected] ABSTRACT Ionization smoke detectors use an ionization chamber and a radionuclide such as americium-241 to detect smoke. In Slovenia, installation of ionization smoke detectors started at the beginning of the 1970’s. Due to good technical performance, ionization smoke detectors were widely used and can be found in industrial, service and even in general public buildings like hospitals or schools. Significant numbers of ionization smoke detectors are still in use, however during the last 10 years they are increasingly being replaced by new technologies. In practice, major reconstructions and upgrades of the existing fire alarm systems usually occur during the renovation of buildings and in that process old ionization smoke detectors are also being removed. According to the Slovenian legislation removed detectors are collected and transmitted to the ARAO - organization responsible for the public service of institutional radioactive waste management. Due to the large number of ionization smoke detectors, it is becoming a routine practice in their treatment that the device is disassembled and the associated radioactive source is recovered and conditioned for storage. The rest of non-radioactive materials (plastic, metal and electronic components) are treated and prepared for recycling. After such conditioning the radioactive part of smoke detectors is in more appropriate form for storage and requires significantly less space in the storage facility. This paper presents current status and lessons learned related with the conditioning of ionization smoke detectors that were collected in recent years through the public service in field of institutional radioactive waste management in Slovenia. Also, future challenges and positive effects of performed actions related with the conditioning of ionization smoke detectors in Slovenia are discussed. 1006.1 1006.2 1 INTRODUCTION Smoke detectors used as fire alarms are important safety devices, because of their obvious potential to save lives and property. The OECD report [1] indicated that around 40 % of fire related deaths could be prevented by use of smoke detectors. Also, according to [1], the benefits from the use of ionization smoke detectors are at least 500 times greater than the possible harmful effects. Ionization smoke detectors are the most common type of smoke detectors and have been commercially manufactured and used around the world for several decades [2]. Due to the price and their technical characteristics, mainly very good sensitiveness to a wide range of fire conditions, they were much more popular than the other types of smoke detectors. Nowadays, the other types of smoke detectors are improved and it is a common practice that wherever is possible, both users and manufacturers, are moving towards technologies which do not require radioactive sources [3]. However, due to better technical performances, ionization smoke detectors may still be in use in some industrial and service buildings. They are robust and can survive quite severe conditions without damage [4]. Ionization smoke detector contains radioactive source, which produces ions between two charged electrodes. Alpha particles from the radioactive source ionize air molecules, allowing positive and negative ions to flow between charged electrodes in the smoke detector. The smoke alarm triggers when smoke particles disrupt the constant flow of ions [5]. The majority of smoke detectors contain an artificially produced radionuclide Am-241. Am-241 is produced in nuclear reactors and is a decay product of Pu-241. Am-241 is long-lived radionuclide that emits alpha particles and low energy gamma rays [6]. An older versions of ionization smoke detectors contained Ra-226, Pu-239, Kr-85, Eu-152 etc. It is important to emphasize that the ionization smoke detectors actually need a small amount of radioactive material with low activity (a few kBq) to ionize the air around the detector and that the dose rate at the detector housing is usually several times higher than the dose rate due to natural background radiation. However, with the distance, the dose rate decreases rapidly [6]. Being mainly composed of an americium source (< 40 kBq), ionization smoke detectors do not present a health risk for people who are working in buildings or other premises on which they are installed. Operational practice confirmed that there was no health threat from ionization smoke detectors as long as the detector was installed and used properly. However, dealing with a large number of ionization smoke detectors like maintenance or management of disused detectors can represent a significant risk and thus require safe management [3]. Ionization smoke detector is considered as sealed radioactive source. The Radiation Protection Safety and Safety of Radiation Sources: International Basic Safety Standards [2] defines a sealed source as “radioactive source in which the radioactive material is (a) permanently sealed in a capsule or (b) closely bounded and in a solid form”. When a source is no longer needed or becomes unfit for use in its application, it is considered disused. Disused sources, if they are deemed unusable, are conditioned and disposed of at a waste disposal facility, if such a facility is available. If a disposal option is not in place the conditioned disused source should be stored under proper conditions [3]. In many countries individual smoke detectors are exempted from regulatory control due to the extremely small amount of radioactive material, therefore, disposal in municipal landfills is often considered as appropriate and allowed. However, due to the large number of these devices and the long half-life of the sources, it is becoming a routine practice worldwide to collect them, remove and consolidate the sources, and condition for long term storage. The rest of non-radioactive materials (plastic, metal and electronic components) are treated and prepared for recycling. This is a typical activity that is performed in many countries in order to minimize the volume of waste stored in the storage facility. Additionally, in many countries there is a Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016 1006.3 limiting concentration of 4,000 Bq/g for alpha emitters in individual radioactive waste packages for disposal into shallow ground repositories. Also, many countries have opted for removing the old and unused ionization smoke detectors from the public domain and have treated, and stored them in centralized facilities [7]. Conditioning, according to the IAEA Safety Glossary [8], includes operations that produce a waste package suitable for handling, transport, storage and/or disposal. Retrievability for further processing and disposal is recommended by international recommendations [3]. Governmental bodies are preforming many activities in order to minimize possibilities that ionization smoke detectors will be lost, stolen, or improperly discarded. A specific concern in management of ionization smoke detectors is to ensure that devices are properly treated and stored after they are no longer in use. This requires tracking of a device during its entire life cycle. The Code of Conduct [9] calls national regulatory bodies for establishing and maintaining a national register of certain sealed radioactive sources. This register should include the category of radioactive source, the serial number, manufacturer’s type number, radionuclide, activity, physical form, location of source, the purpose of use, the licence holder or user, details of receipt or transfer or disposal of the source. “CRADLE-TO-GRAVE” CONTROL OVER IONIZATION SMOKE DETECTORS IN SLOVENIA 2 In Slovenia, installation of ionization smoke detectors started at the beginning of the 1970’s. Due to good technical performance, ionization smoke detectors were widely used and can be found in industrial, service and even in general public buildings like hospitals or schools. According to Slovenian regulations, special permits for the use of ionization smoke detectors are not required. However, the users or owners of smoke detectors have certain obligations and must fulfill prescribed requirements. For example, registration or notification of the Slovenian Nuclear Safety Administration (SNSA) who keeps the national register of radioactive sources is required. The notifications for any further changes in the number of smoke detectors, changes of their locations or changes of ownership are also required. Users of smoke detectors shall ensure reviews of smoke detectors by an authorized radiation protection expert every five years. Companies engaged in servicing and maintenance of ionization smoke detectors must be authorized for dealing with radioactive sources. At the end of the smoke detector’s lifetime, the user have three months to ensure the transfer to the Central Storage Facility. By the national strategy and regulations there is also an option to transfer disused smoke detectors abroad for recycling or to return them to the manufacturer/supplier. Within the eight days after the ionization smoke detectors were transferred, the new owner must inform the SNSA and prove ownership and responsibility. Described notification system is designed in order to control the usage of ionization smoke detectors and to prevent any undesired situations or loses. 2.1 Types and Quantities of Ionization Smoke Detectors in Slovenia The users and maintainers of ionizing smoke detectors in Slovenia are usually well informed about the necessary steps that must be performed when old ionizing smoke detectors are being replaced or removed. Removed units are usually stored in bags or boxes before being sent to the ARAO. According to the register [10] of accepted ionization smoke detectors into Central Storage Facility, the most commonly used radioactive source in Slovenian ionization smoke detectors is Am-241. Rarely ionization smoke detectors contained Ra-226 and just few detectors contained Pu-239. As presented in Table 1, waste management practice revealed that 36 models of ionization smoke detectors, produced by 16 different manufacturers are present in Slovenia. Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016 1006.4 Table 1: Types of ionization smoke detectors discovered in Slovenia [10] Manufacturer Model APOLLO S60, S30, S90, XP-95 Radionuclide Activity Origin Country United Kingdom Am-241 33 kBq Am-241 30 kBq Am-241 Am-241 Am-241, Ra-226 30 kBq 555 kBq 2.7 MBq, 1.3 MBq ST-I-DA Am-241 33 kBq IJD-5 LKM-1978, LKM-1979 I-716, F 716 Am-241 Am-241 Am-241 74 kBq 5 kBq* 30 kBq United Kingdom USA Germany Slovenia JD-1S Am-241 207 kBq Serbia MORLEY IAE MI-ISE Am-241 18.5 kBq PASTOR SIEMENS STATITROL SYSTEM SENSOR SLAVIJAELEKTRO TAL (TEHNO ALARM) IOJ-1 BR 910 301G7 1412 SV-1 Am-241 Am-241 Am-241 Am-241 Am-241 33 kBq 30 kBq 33 kBq 37 kBq 207 kBq United Kingdom Croatia Germany USA USA Serbia IDD-801, IDD-801N Am-241 74 kBq Croatia TDZ DELČEVO IDD 801, IDD 801S, IDD 802, IDD 803 RID-1 Am-241 74 kBq Macedonia 37 MBq USSR CERBERUS F 716, F 716I, F 715V, F 716VI, F 712 F 910, F 906, F 911 F 600, F 6A Ex FES 5B, FES 5.220B CALECTRO, NITTAN ERA ESSER ISKRA INSTITUT “BORIS KIDRIČ” - VINČA Unknown 238 Pu, 239Pu Switzerland *The activity does not exceed regulatory limits for exemption levels in Slovenia From year 2009 until the end of 2015 more than 18,000 of ionization smoke detectors were accepted for conditioning and storage. Before that around 10,000 of ionization smoke detectors were stored in the Central Storage Facility. The most frequent models that were accepted in Central Storage Facility are F 716, FES 5B (Cerberus) and IDD 801 (TZD Delčevo). The diversity and share of major producers in total amount of detectors that were in use in Slovenia are given in Figure 1. In addition to ionizing smoke detectors already accepted in the Central Storage Facility, it is expected that in the scope of the public service at least 2,000 detectors annually will be collected within next 10 years. According to the national registry of radiation sources [11], at the end of 2015 24,330 ionisation smoke detectors are still being used by 285 organisations around Slovenia. Unfortunately, it is assumed that there is also a certain amount of detectors in use which is not yet registered in national registry of radiation sources Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016 1006.5 operated by SNSA. One of the reasons is that the application of smoke detectors started many years before the regulatory framework and national register were established. 8% 2% 1% 8% Cerberus Delčevo Apollo 26% 55% Iskra Statitrol Other Figure 1: Diversity and share of major producers in total amount of ionization smoke detectors that were in use in Slovenia [10] 2.2 Management of Disused Ionization Smoke Detectors During major reconstructions or upgrades of the existing fire alarm systems old ionization smoke detectors are being removed. These activities are usual linked with the renovation or major adaptation of buildings. According to Slovenian regulations, only licenced organisation for dealing with radioactive sources can perform these activities. Collection Once being in possession of removed ionization smoke detectors the user/owner notifies ARAO for further steps in the process of waste management. ARAO provides collecting, transportation, handling, conditioning and storage services for disused sources from various applications in Slovenia (Figure 2). Also, after the change of ownership ARAO is legally responsible for the safe and secure conditioning and storage of the sources under its ownership, and operates under license conditions defined by a regulatory body. Figure 2: Removed ionization smoke detectors Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016 1006.6 Storage and Disposal The first step in the waste management process is characterization of waste or disused sealed sources where the activity, the radionuclide content and other important characteristics of waste are being determined. The disused ionization smoke detectors are sorted and grouped based on the management option (conditioned, unconditioned), and by characteristics of the source (radionuclides). ARAO temporary store disused smoke detectors in the Central Storage Facility and prepare them for further conditioning. As required by the regulatory body, ARAO maintains an up to date inventory of all radioactive sources in its possession. If it will not be possible to send disused sources abroad for recycling the only sustainable and long term option will be disposal which is the final phase in the life cycle of radioactive sources. Prior to final disposal safety analysis needs to be performed. However, since the final disposal facility in Slovenia is not available conditioned radioactive sources from ionization smoke detectors for certain amount of time will be stored in the Central Storage Facility. When the disposal facility will be available radioactive sources will be once again conditioned to meet waste acceptance disposal criteria and finally disposed. Conditioning Up to now ARAO accepted more than 28,000 units of disused ionization smoke detectors into Central Storage Facility. This large number of unconditioned smoke detectors represents a volume of approximately 30 m3 which could be problematic from the aspect of fire safety (plastic material), occupancy of storage space, source leaking, degradation of source housings etc. Before starting the detectors dismantling and radioactive source recovery activities detail inventory of smoke detectors stored in the facility was revised and updated. The next step is the removal of the sources from the original devices (Figure 3). Figure 3: Removal of the radioactive sources from the original devices (dismantling) Performed activities resulted in a huge reduction of the volume of packages intended for storage or disposal. According to the ARAO experiences during conditioning of smoke detectors in last four years the original volume of waste packages was reduced by factor 25. Over 12,000 units of ionisation smoke detectors with the radionuclide Am-241 were conditioned. As seen in Figure 4 the sources removed from smoke detectors have been packed in polyethylene bags, which are then transferred into the standard steel 210 liter drums. Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016 1006.7 Figure 4: The sources removed from smoke detectors packaged in polyethylene bags and loaded in the standard steel 210 liter drum Operational experienced confirmed that more than 6,000 sources can be stored in one drum and that for storage purposes additional shielding of drums is not necessary. Contaminated equipment (smear, gloves, etc.) represents a very small proportion of the secondary radioactive waste, which is practically negligible. Operations of removing sources from devices involves the manipulation of bare sources, which needs special procedure, shielded and ventilated workplace and tools to protect the operators and prevent the spread of contamination. Ionization smoke detectors were handled manually by trained and skilled operators (Figure 5). The radioactive sources and contaminated housing of smoke detectors packed in steel drums have been safely stored in the Central Storage Facility. The rest of non-radioactive materials (plastic, metal and electronic components) are treated and prepared for recycling. After such conditioning the radioactive sources from smoke detectors are in more appropriate and safe form for storage and require significantly less space in the storage facility. After the storage in the Central Storage Facility, it is likely that the internal bags and drums will be retrieved for further conditioning and repackaging prior to disposal. All handling operations were carefully planned, tested and implemented in coordination with the radiation protection staff. Figure 5: The radioactive sources of smoke detectors safely store in the Central Storage Facility 3 BENEFITS AND LESSONS LEARNED Operational experiences confirmed that conditioning of ionization smoke detectors and separation of radioactive from non-radioactive part is an effective method for volume reduction. During conditioning activities a lot of plastic materials related with the ionization smoke detectors were removed from the storage facility. This represents an additional operational safety benefit and reduction of potential fire hazard. The IAEA technical manual [7] and international catalogue of sealed radioactive sources and devices [12] and many other manually obtained data (design data, photos, illustrations etc.) Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016 1006.8 from manufactures/maintainers of devices were very helpful during the preparation of dismantling operations. However, dealing with disused ionization smoke detectors requires different types of precaution measures to be taken in order to prevent mechanical damages of the radioactive source (e.g. dropping from a height). Damaged devices must be separately collected and treated to avoid cross contamination. Dismantling of smoke detectors must be carried out slowly and carefully to preserve the radioactive source intact and to protect spreading of contamination to non-radioactive part of device. Sources may also be leaking, which would require specific radiation safety measures. Conditioning of smoke detectors has become a regular activity and an integral part of the core mission of ARAO. Operations were carefully planned and carried out by ARAO staff exclusively. During the performed activities existing knowledge is upgraded and ARAO staff is now able to dismantle all types of detectors that are in use in Slovenia. 4 CONCLUSION The paper provides a review of management practices related with the treatment of ionization smoke detectors in Slovenia. Presented management practices are fully in line with the sustainability policy and the mission of ARAO. Operational experiences confirmed that performed activities were the most cost effective way to improve the safety and security of the long lived sources and minimize the volume of waste in the Central Storage Facility. All activities were performed according to national requirements and international standards. Although the special attention was given to the international recommendations for reuse or recycling of disused sources [3], it is very unlikely that anyone would want to take radioactive sources from smoke detectors for any further use. The obtained results clearly confirmed the importance of well trained and skilled staff with a potential to cope with the most demanding aspects of waste management. In this sense additional efforts in the near future should be designated for the conditioning of sources to meet the waste acceptance criteria of the future disposal facility. REFERENCES [1] Organisation for Economic Co-operation and Development, Nuclear Energy Agency, “Recommendations for Ionization Chamber Smoke Detectors in Implementation of Radiation Protection Standards”, OECD NEA, 1977. [2] International Atomic Energy Agency, Radiation Protection and Safety of Radiation Sources: International Basic Safety Standards - Interim Edition General Safety Requirements Part 3, IAEA Safety Standards Series No. GSR Part 3 (Interim), IAEA, Vienna, 2011. [3] International Atomic Energy Agency, Management of Disused Sealed Radioactive Sources, IAEA Nuclear Energy Series No. NW-T-1.3, Vienna, 2014. [4] M. W. Carter, “Domestic Smoke Detectors – A Radioactive waste problem?”, International Congresses IRPA 9 Vienna, Austria, April 1996, International Radiation Protection Association, 1996, V3-119. [5] IQ8Quad, ESSER by Honeywell, “Pravi senzor za vsako okolje - Principi zaznavanja javljalnika IQ8Quad”, Dunaj, 2009. Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016 1006.9 [6] World Nuclear Association, “Smoke Detectors and Americium”, Retrieved from URL: http://www.world-nuclear.org/information-library/non-power-nuclearapplications/radioisotopes-research/smoke-detectors-and-americium.aspx, 9. August 2016. [7] International Atomic Energy Agency, “Draft Technical Manual on: Dismantling of Ionic Smoke Detectors and Conditioning of associated radioactive sources”, IAEA, 2006. [8] International Atomic Energy Agency, “IAEA Safety Glossary: Terminology Used in Nuclear Safety and Radiation”, Protection, 2007 Edition, IAEA, Vienna, 2007. [9] International Atomic Energy Agency, Code of Conduct on the Safety and Security of Radioactive Sources, IAEA, Vienna, 2004. [10] ARAO, “Evidence of radiation sources in Central Storage Facility” (Internal material), Ljubljana, 2016. [11] Slovenian Nuclear Safety Administration, Annual Report 2015 on Radiation and Nuclear Safety in the Republic of Slovenia 2015, SNSA, Ljubljana, 2016. [12] International Atomic Energy Agency, “International Catalogue of Sealed Radioactive Sources and Devices”, IAEA, Vienna, 2004. Proceedings of the International Conference Nuclear Energy for New Europe, Portorož, Slovenia, September 5-8, 2016
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