SECTION 1 PRODUCT AND COMPANY INFORMATION Barium Chloride, Dihydrate PRODUCT NAME: PRODUCT NUMBER: 1186 CAS NUMBER: 10326-27-9 SYNONYMS: Barium Dichloride Dihydrate MANUFACTURER: Prochem, Inc. 826 Roosevelt Road Rockford, IL 61109 PHONE: FAX: TOLL FREE: 815-398-1788 815-398-1810 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Danger Signal Word Hazard Statements H301 H332 Toxic if swallowed Harmful if inhaled Precautionary Phrases P261 P301 + P310 P304 +P340 P405 Avoid breathing dust/fume/gas/mist/vapours/spray IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Store locked up. HMIS CLASSIFICATION: Health: 2 Fire: 0 NFPA RATING: Health: 2 Flammability: 0 Physical Hazard: 0 Reactivity Hazard: 0 EYE CONTACT: May cause eye irritation. SKIN CONTACT: May cause skin irritation. May be harmful if absorbed through skin. INHALATION: May cause respiratory tract irritation. Toxic if inhaled. INGESTION: Toxic if swallowed. BARIUM CHLORIDE, DIHYDRATE PAGE 1 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: BaCl2 2H2O Molecular Weight: 244.26 CHEMICAL NAME CAS# Barium Chloride, Dihydrate SECTION 4 % 10326-27-9 100 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention. INHALATION: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. Give oxygen if deemed necessary. If not breathing administer CPR. Get emergency care immediately. INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Product is not flammable AUTO IGNITION TEMPERATURE: No data EXPLOSION LIMITS: No data EXTINGUISHING MEDIUM: Use appropriate media for adjacent fire. Cool containers with water. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen chloride gas and barium oxide. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear appropriate respiratory and protective equipment to avoid all exposure to with the material. ENVIRONMENTAL PRECAUTIONS: Do not let enter drains or allow to be released into environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Pick up and arrange disposal without creating dust. Sweep up and shovel. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear approved personal protective equipment. Ensure adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts. CONDITIONS FOR SAFE STORAGE: Store in a cool, dry, and well-ventilated area. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION OCCUPATIONAL EXPOSURE CONTROLS: Component Barium Exposure Limits 3 0.5 mg/m 3 0.5 mg/m 3 0.5 mg/m Basis TLV PEL REL TLV: Threshold Limit Value over 8 hours of work. PEL: Permissible Exposure Limit Entity ACGIH OSHA NIOSH REL: Recommended Exposure Limit EYE PROTECTION: Always wear approved safety glasses with side shields, or safety goggles, face shield when handling a chemical substance in the laboratory. BARIUM CHLORIDE, DIHYDRATE PAGE 2 SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION (Cont.) SKIN PROTECTION: Wear nitrile or rubber gloves, apron, or lab coat. VENTILATION: Handle in an efficient chemical fume hood. RESPIRATOR: Approved NIOSH dust respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers, and washing facilities accessible to areas of use and handling. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: White solid MOLECULAR WEIGHT: 244.26 BOILING POINT: 1560° C MELTING POINT: 963° C SPECIFIC GRAVITY: 3.86 gm/ml VAPOR PRESSURE: Not applicable SOLUBILITY: Soluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Heat and moisture INCOMPATIBILITY: Strong oxidizing agents DECOMPOSITION PRODUCTS: Hydrogen chloride gas and barium oxide SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: LD50 Intraperitoneal – mouse – 51 mg/kg CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified as a confirmed carcinogen. MUTAGENIC EFFECTS: No data TETRATOGENIC EFFECTS: No data RTECS: CQ88751000 To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA No information available SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. SECTION 14 DOT (US): TRANSPORTATION DATA UN1564 IATA/IMDG: UN1564 Barium compounds, n.o.s. Barium compound, n.o.s. (Barium chloride dehydrate) (Barium chloride dehydrate) Class 6.1 Class 6.1 PG III PG III BARIUM CHLORIDE, DIHYDRATE PAGE 3 SECTION 15 REGULATORY INFORMATION TSCA: Listed in the TSCA SARA (TITLE 313): Barium chloride dehydrate MASSACHUSETTS RIGHT TO KNOW COMPONENTS: No components are subject to the Massachusetts Right to Know Act PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Barium chloride dihydrate NEW JERSEY RIGHT TO KNOW COMPONENTS: Barium chloride dehydrate SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 06/14 BARIUM CHLORIDE, DIHYDRATE PAGE 4
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