Maleckar 2016-2017 Exam 1 Review Sheet CHS Chemistry Chapter 1: Matter, Measurement, and Problem Solving how many significant digits are present in a number report an answer with the correct number of significant digits write numbers in scientific notation Chapter 2: Atoms, Molecules, and Ions Dalton’s Atomic Theory know what Dalton thought about the structure of an atom understand Thomson’s model for an atom understand Rutherford’s model for an atom and how his experiments showed this know what contribution Milliken made know the structure of an atom and where the most mass is, where most volume is, where the charges are know how to abbreviate the symbol for an atom using nuclide notation and hyphen notation ex: 126C Carbon-12 superscript = mass number = protons + neutrons subscript = atomic number = # protons know how to calculate #protons/neutrons/electrons given the symbol & numbers know what an isotope is (differ in # of neutrons, not electrons or protons) be able to calculate average atomic masses when given their % abundances; do other similar problems regarding isotopes understand the layout of the periodic table Alkali Metals, Alkaline Earth Metals, Halogens, Noble Gases, Transition Metals, Lanthanides, Actinides, Metals, Nonmetals, Metalloids be able to convert between grams/moles/atoms; understand the mole and be proficient with Avogadro’s number know what an ion is know the difference between a cation and an anion be able to predict the charges of ions: Group 1A atoms form +1 cations; Group 2A atoms form +2 cations; Al forms a +3 cation; N forms a -3 anion; Group 6A atoms form -2 anions; Group 7A atoms form -1 anions; charges on transition metals - there are too many possibilities be able to tell the difference between ionic and covalent compounds by looking at their formulas be able to determine the oxidation number of an atom from a formula (ex: Cu in CuSO4 is +2) be able to create a neutral ionic compound from cations and anions, using the appropriate subscripts be able to name compounds Ionic Compounds - metal/nonmetal where metal has a fixed & predictable charge: ex: LiCl lithium chloride - metal/nonmetal where metal is a transition metal: ex: FeCl2 iron(II) chloride Molecular Compounds - nonmetal/nonmetal use prefixes (know 1-10) ; no “mono” in front of the first element ex: SO3 sulfur trioxide Acids - oxyanions/oxyacids/ternary acids -ate ending on the anion becomes an –ic ending on the acid Ex: NO3- nitrate HNO3 nitric acid -ite ending on the anion becomes an –ous ending on the acid Ex: NO2- nitrite HNO2 nitrous acid Hydrates - Name the ionic compound, then use the prefix + hydrate to indicate the quantity of water molecules Ex: Magnesium Sulfate Heptahydrate MgSO4 H2O Chapter 3: Calculations with Chemical Formulas and Chemical Equations be able to balance reactions (except for redox reactions) understand what a redox reaction is (some atoms are changing their charges, gaining and losing electrons) be able to calculate molecular weights for compounds from their formulas be able to calculate % composition (by mass or by mole) of individual elements in a compound be able to apply Avogadro’s number to get # of atoms be able to determine empirical formulas & molecular formulas, given %s or amounts in grams moles in = moles out and mass in = mass out (Law of Conservation of Mass) be able to do combustion analysis problems Chapter 4: Chemical Reactions know what an electrolyte is; know what a nonelectrolyte is know the difference between a strong and weak electrolyte Substance that breaks apart completely to make ions is a strong electrolyte Substance that breaks apart a little bit to make ions is weak electrolyte Substance that doesn’t generate ions at all is a non-electrolyte be able to recognize/complete the following types of reactions: combustion: hydrocarbon (C, H, maybe O) + O 2 CO2 + H2O oxygen is a reactant metathesis/Double displacement: AB + CD AD + CB 2 ionic compounds single replacement AB + C A + CB element +compound combination/synthesis/composition: A + B C 1 product decomposition: C A + B 1 reactant Special Double Displacement Reactions neutralization: HX + YOH YX + H2O acid + base = salt + water precipitation reaction Metathesis reactions can be driven to completion by the formation of a pure substance the formation of a gas product (H2S, CO2, N2, O2, H2, H2CO3, SO2, or NH3)( Further decompose H2CO3 H2O + CO2 H2SO3 H2O + SO2 NH4OH H2O + NH3 the formation of a precipitate (ppt, s or ↓) a difference in activities of metals use provided activity series – the higher the metal is on the list, the stronger reactant that metal will be redox reactions can be spotted by assigning oxidation numbers to all of the atoms in the reaction; if something changes oxidation numbers from one side of the reaction to the other, then it has gained/lost electrons; OIL RIG; both an oxidation and a reduction must take place in the same reaction be able to write complete and net ionic equations: the ions that cancel out are the spectator ions the remaining “stuff” is the net ionic equation be able to calculate molarity (moles/liter) be able to do dilution problems using molarity M1V1 = M2V2
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