RHS Chemistry Review December 2014 Give a definition and example of each of the following: This section you should have been able to do without help. Major Topics 1. Atomic Theory: Describe what each scientist contributed to the atomic theory: a. Dalton-Created the atomic theory, know the points from your notes and that he thought atoms were indivisible, which is wrong. b. Thompson-Discovered the electron and had the plum pudding model c. Rutherford-gold foil experiment, discovered the nucleus d. Bohr-Planetary Model (Saturn) showing how electrons are arranged around the nucleus 2. The atom: Give the charge, location and mass of the following subatomic particles: a. Proton-Positive, inside the nucleus, 1 a.m.u b. Neutron-Neutral, inside the nucleus, 1 a.m.u c. Electron-Negative, outside the nucleus, 0 a.m.u 3. Periodic trends: Explain the general trends of the following: a. Electronegativity-. It is how strong an atom can pull electrons away from another atom. (Does not include noble gases). Increases as you go from left to right across the periodic table and bottom to top b. Atomic Radius- How big the atom is. Increases as you from right to left across the periodic table and top to bottom, Francium is largest atomic radius. c. Ionic Radius-When an atom loses/gains electrons, it changes the size of the atom. If it gains, it gets bigger, if it loses, it gets smaller. There are different trends for each type of ion. Anions get larger as you go from right to left and down the periodic table. Cations get smaller as you go from right to left and down the periodic table. d. Ionization Energy- How easily an atom ionizes. follows the same pattern as electronegativity. 4. Radioactivity: Give the symbol of each and an example equation for each a. Alpha; + b. Beta- ; + c. Gamma ; + + 5. Radioactivity: List these in order of increasing penetrating power: Beta, Gamma, Alpha Alpha, Beta, Gamma Skills: 1. Sig Figs: a. How many sig figs are in the following numbers: i. 0.000023 2 ii. 5690 3 iii. 451.005 6 iv. 0.001020 4 3 v. 4.20 x 10 3 b. Answer the following in correct sig figs: i. 332.968 cm + 894.85 cm 1227.82 cm ii. 87.50 cm – 10 cm 78 cm iii. 2.30 L x 6.1 L 14 L iv. 89.5 g/783.1 g 0.114 g c. Put these in correct scientific notation: i. 509000000000 5.9 x 1011 ii. 0.000000040 4.0 x 10-8 iii. 0.003 3 x 10-3 iv. 10000000 1 x 107 d. Put these in correct decimal form: i. 6.02 x 108 602000000 -5 ii. 5.6 x 10 0.000056 2. Metric Conversions a. 1000L = ________mL 1000000 mL b. 723 km = _______cm 73200000 cm c. 67.0 mm = _______m 0.067 m d. 9 m = ________nm 9 x 109 nm 3. Density: a. Use the Density equation in the following (in correct sig figs): i. Mass = 15 g; Volume = 5 L = 3 g/mL ii. Mass = 100g; Density = 2.15 g/mL = 47 mL iii. Volume = 54 mL; Density = 1.56 g/mL = 84 g 4. Average Atomic Mass Isotopes of Magnesium Percent abundance Mg - 24 78.99% =18.9576 Mg – 25 10.00% =2.5 Mg - 26 11.01% =2.8626 a. Calculate the average atomic mass using the table above Add the three numbers together to get 24.32 5. Radioactive Decay: Fill in the missing particle in the nuclear equation. a. __________ + b. 6. Wave Problems: + _________ a. A light wave has a frequency of 8.75 x 1015 Hz. What is its wavelength? C = f x λ; Rearrange to λ = C/f 3.00 x 108 / 8.75 x 1015 = 3.4 x 10-8 m. b. A light wave has a frequency of 6.35 x 1015 Hz. What is its energy? E = h x f (no rearranging needed) h = is given to you on formula chart 6.63 x 10-34 x 6.35 x 1015 =4.21 x 10-18 J c. A red light is found to have a wavelength of 674 nm. Calculate its frequency. Convert 674 nm to meters 6.74 x 10-7 m C = f x λ; Rearrange to f = C/ λ 3.00 x 108 / 6.74 x 10-7 m = 4.45 x 1014 hz 7. Electron Configurations: a. Write out the electrons configuration for the following elements: i. Magnesium 1s22s22p63s2 ii. Indium 1s22s22p63s23p64s23d104p65s24d105p1 iii. Strontium 1s22s22p63s23p64s23d104p65s2 b. Name the element for the following electron configurations i. 1s22s22p63s23p64s23d5 Mn, Manganese ii. 1s22s22p63s23p4 S, Sulfur iii. 1s22s22p63s23p64s23d104p65s24d105p3 Sb, Antimony c. Write out the ion electron configuration of the following elements i. Fluorine 1s22s22p6 ii. Calcium 1s22s22p63s23p6 8. Ionic Bonding and Compounds: a. Binary (Give the opposite): i. BaS Barium Sulfide ii. Li3N Lithium Nitride iii. Magnesium phosphide, Mg3P2 iv. Cesium chloride CsCl b. Polyatomics (Give the opposite): i. NaOH Sodium Hydroxide ii. Fe2(SO4)3 Iron (III) Sulfate iii. Potassium dichromate K2Cr2O7 iv. Ammonium Carbonate (NH4)2CO3 c. Transition Metals i. CuO Copper (II) Oxide ii. MnS2 Manganese (IV) Sulfide iii. Nickel (II) Arsenide Ni3As2 iv. Cobalt (III) Acetate Co(C2H3O2)3 d. Mixed: i. Ca(OH)2 Calcium Hydroxide ii. K2Cr2O7 Potassium Dichromate iii. Ag3P Silver Phosphide iv. (NH4)2SO4 Ammonium Sulfate v. Chromium (II) Borate Cr3(BO3)2 vi. Sodium Chlorite NaClO2 vii. Ammonium Sulfite viii. Lead (II) Carbonate (NH4)2SO3 PbCO3 9. Lewis Structures: a. Single Element Dot Diagrams-Draw the dot diagrams for these elements i. Nitrogen ii. Oxygen iii. He iv. Mg b. Bonding Diagrams (Draw the dot diagrams of each compound): i. NaCl ii. Aluminum Sulfide iii. BeCl2 iv. Lithium Nitride
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