Bonding A chemical bond is a force that holds two or more atoms together. Compound – two or more elements chemically combined by gaining, losing, or sharing electrons. Molecule – a particle made of 2 or more atoms covalently bonded together. Electrons closest to the nucleus -least amount of energy and lowest energy level. farthest from the nucleus have the greatest amount of energy and are in the highest energy level. Outermost electrons are easily attracted to the positively charged nucleus of other atoms. This forms a chemical bond. These outermost electrons are called valence electrons. Using the Periodic table to determine the number of valence electrons. Groups 1,2, 13 – 18 have the same number of valence electrons as the ones digit of the group number,except helium which only has 2. Groups 3- 12 vary in numbers of valence electrons. Lewis Electron Dot Diagram p. 271 • Lewis Electron Dot diagram is a model that represents valence electrons in an atom as dots around the element’s chemical symbol. (See handout for steps to do this.) • Elements with unpaired dot are reactive or chemically unstable. • Atoms will bond to other atoms to become chemically stable. Isotopes Isotopes : are atoms of the same element with different numbers of neutrons. Example: Isotopes of the element, carbon. Carbon - 12 6 protons 6 neutrons Carbon - 14 6 protons 8 neutrons The same element, same number of protons, different number of neutrons. (If proton number changes, element changes) Covalent Bond (nonmetal to nonmetal) Covalent Bonding – A type of bonding in which two or more atoms share one or more pairs of valance electrons. When covalent bonding occurs, molecules are formed. Covalent Bond • Single covalent bond – atoms share one pair of valence electrons. • Double covalent bond – atoms share two pairs of valence electrons. • Triple covalent bond – atoms share three pairs of valence electrons. Covalent bond examples • The more valence electrons that two atoms share, the stronger the covalent bond is between the atoms. • Examples : H20 CO2 N2 C6H12O6 H2 Valence number – The number of electrons an atom needs to gain, lose, or share to become stable. (Gain electrons – negative valence) (Lose electrons – positive valence.) Chemical formulas – a group of chemical symbols and numbers that represent the number of atoms of each element that make up a compound . ( H2O) In a chemical formula, the element with the positive charge is always written first. Subscript – the number that shows how many atoms of an element are in the compound. Examples H20, CO2 The number 2 is the subscript in each. How to Write Formulas • 1. Write the symbol correctly for both elements. • 2. Write the valence number above each symbol. Make sure you have a positive first, and then a negative. • 3. Criss-cross valences to make a subscript. • 4. NEVER write 1 as a subscript. (It is understood to be 1 if there is no number.) • 5. Reduce to lowest terms. Examples • Sodium Chloride • Copper (I) Sulfide Aluminum Oxide Iron (III) Iodide 1. Calcium Sulfide 2. Copper (I)Iodide 3. Potassium Chloride 4. Iron(III) Bromide 5. Sodium Nitride 6. Antimony (V) Oxide Problem check 1. Calcium Sulfide 2. Copper (I)Iodide CaS CuI 3. Potassium Chloride 4. Iron(III) Bromide KCl FeBr 3 5. Sodium Nitride Na3N 6. Antimony (V) Oxide Sb2O5 Practice Problems • Aluminum Bromide • Calcium Iodide Magnesium Nitride Potassium Sulfide • Copper (I) Chloride Barium Fluoride • Hydrogen Oxide Lead Bromide Practice Problems Aluminum Bromide Magnesium Nitride AlBr3 Mg3N2 Calcium Iodide Potassium Sulfide CaI2 K2S Copper (I) Chloride Barium Fluoride CuCl Ba F2 Hydrogen Oxide Lead Bromide H 2O PbBr2 Practice Problems 1. Lead Iodide 2. Barium Fluoride 3. Tin (II) Nitride 4. Lithium Chloride 5. Sodium Bromide 6. Iron (II) Oxide 7. Potassium Fluoride 8. Silver Bromide 9. Calcium Chloride 10. Copper (I) Iodide 11. Aluminum Nitride 12. Cobalt (II) Sulfide Practice Problems • • • • • • 1. PbI2 3. Sn3N2 5. NaBr 7. KF 9. CaCl2 11. AlN 2. BaF2 4. LiCl 6. FeO 8. AgBr 10. CuI 12. CoS Binary Compound – a compound composed of ONLY 2 elements. Polyatomic Ion- a group of positively or negatively charged covalently bonded atoms. Calcium Phosphate Tin (IV) Chromate Ammonium Oxide Magnesium Sulfate Homework Check 1. K2O 6. Ca3(PO4)2 2. NaC2H3O2 7. FeBr2 3. Ag2SO4 8. HClO3 4. ZnCO3 9. MgSO3 5. CrS 10. (NH4)3PO4 Homework Check Cd CrO4 Al2O3 FePO4 AgNO3 NaClO2 ZnI2 Cu(ClO3)2 PbC2O4 KClO3 SnS2 SbCl5 Li3PO4 Naming compounds – change the ending of the second element to – “ide”. (Do not change the names of polyatomic ions.) Check to see if Roman numeral is needed. Ex: NaCl - Sodium Chloride Fe2O3 – Iron (III) Oxide Examples • Zn3N2 ______________________ • K2SO3 ______________________ • CuO ______________________ • Ba(C2H3O2)2 _____________________ Ion – an atom or group of atoms that has become electrically charged. It is a charged particle. When an atom loses an electron, it loses a negative charge and becomes a positive ion. When an atom gains an electron, it gains a negative charge and becomes a negative ion. Ionic Bond (Metal to Nonmetal) 1. Ionic Bond – the attraction between two oppositely charged ions. An ionic bond is formed when atoms gain or lose electrons. Ionic bonds form compounds. Ionic bond Homework Check 1.Ammonium Phosphate 2. Iron (ll) Bromide 3. Hydrogen Chlorate 4. Sodium Acetate 5. Silver Sulfate 6. Chromium (lll) Sulfide 7. Potassium Oxide 8. Tin (ll) Oxide 9. Hydrogen Oxide 10. Antimony (III) Phosphate Predicting Reactions between Elements To form an ionic bond, a metal bonds to a non-metal. Metals to the left of stair-step line except H. Non-metals to the right of stair-step line, except H Metalloids along stair-step except Al which is a metal. Predicting ionic bonds • Metals react with non-metals to form ionic compounds. • Will Na react with Br? _____ • Will Ca react with Ag _____ • Will S react with Cl? _______ Metallic Bonds (metal to metal) • Metallic Bond – Bond formed when many metal atoms share their pooled valence electrons. • Valence electrons are not bonded to one atom but positive ions are surrounded by a “sea of electrons” Ex: Aluminum Properties of compounds. • See handout and p. 288 in textbook. Homework check 1.Iron (ll) Hydroxide 2. Aluminum Perchlorate 3. Chromium (ll) Acetate 4. Tin (lV) Chloride 5. Lead Chromate 6. Copper (ll) Sulfide 7. Potassium Hypochlorite 8. Mercury (ll) Dichromate 9. Calcium Hydroxide 10. Tin (ll) Sulfite Homework check 11. Zinc Phosphate 12. Barium Fluoride 13. Sodium Nitrate 14. Cadmium Carbonate 15. Mercury (ll) Peroxide 16. Iron (lll) Sulfite 17. Antimony (V) Oxide 18. Copper(l) Permanganate 19. Chromium (lll) Oxalate 20. Ammonium Sulfate Homework check Chlorine - nonmetal Aluminum - metal Boron - metalloid Calcium - metal Zinc - metal Hydrogen - nonmetal Neon - nonmetal Nickel - metal Sodium - metal Magnesium - metal Silver - metal Fluorine - nonmetal Silicon - metalloid Potassium - metal Helium - nonmetal Uranium - metal Bromine - nonmetal Carbon - nonmetal Francium - metal Argon - nonmetal Homework Check Sodium & Calcium - no -two metals metallic Hydrogen & Oxygen -no two nonmetal covalent Potassium & Bromine yes -metal +nonmetal Francium & Fluorine - yes metal + nonmetal Helium & Carbon - no two nonmetals covalent Magnesium & Chlorine - yes metal+ nonmetal Neon & Argon - no - two nonmetals covalent Nickel & Copper - no two metals metallic Phosphorus & Oxygen - no two nonmetals cov Calcium& Uranium - no two metals metallic Homework Check 1.Ammonium Phosphate 11. Manganese(ll) Oxide 2. Iron (ll) Bromide 12. Tin (lV) Iodide 3. Hydrogen Chlorate 13. Calcium Oxide 4. Sodium Acetate 14. Potassium Chloride 5. Silver Sulfate 15. Copper (l) Hydroxide 6. Chromium (lll) Sulfide 16. Ammonium Sulfide 7. Potassium Oxide 17. Aluminum Carbonate 8. Tin (ll) Oxide 18. Hydrogen Sulfite 9. Copper (ll) Phosphate 19. Iron (lll) Sulfate 10. Zinc Sulfate 20. Aluminum Nitride
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