Supporting Information for
Characterization of PM2.5 Source Profiles for Traffic and Dust Sources in
Raipur, India
Jeevan Lal Matawle1,2, Shamsh Pervez1, Shippi Dewangan1, Anjali Shrivastava3, Suresh
Tiwari4, Pallavi Pant5, Manas Kanti Deb1, Yasmeen Pervez6
1
School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur-492010(C.G.), India.
Directorate of Geology and Mining, Chhattisgarh, Regional Laboratory, Jagdalpur-494001 (C.G.), India.
3
National Environmental Engineering Research Institute, Nehru Marg, Nagpur-440020, India
4
Indian Institute of Tropical and Meteorology (IITM), New Delhi, India.
5
Department of Environmental Health, School of Public Health and Health Sciences, University of Massachusetts,
Amherst, MA 01002, USA
6
Department of Engineering Chemistry, Chhatrapati Shivaji Institute of Technology, Kolihapuri, Durg, CG, India,
491010
2
Submitted to Aerosol Air Quality Research
April 2015
* Corresponding author: Dr. Shamsh Pervez, Tel: +91 9425242455
E-mail address: [email protected]; [email protected] S 1. Summary of developed source profiles and comparison with earlier reported profiles.
Source ID
Various studies
Present study
c
(54P25COM)
As, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sb, Se, V, Zn, NO3-
c*
(43M10UC)
Present study
b
PRD
c
(BVPVRD1)
(52P25COM)
b
c
2WVG
HDVD
(53P25COM)
(Comp-2S2WG-All)
Present study
3WVD
4WVD
(BVUNPV2)
Present study
d
d
(Comp-3WD-2)
Present study
d
(Comp-LCVD-all)
Present study
d
As, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, S, Sb, Se, V, F-, Cl, NO3-, SO42-, Na+, NH4+, K+, Mg2+
Al, As, Cd, Co, Cr, Cu, Mg, Mn, Mo, Ni, Pb, Sb, Se, V,
F-, Mg2+
As, Cd, Co, Cu, Hg, Mo, Ni, S, Sb, Se, V, Zn, NO3-,
-
Present study
UPRD
As, Cd, Co, Hg, Mo, Pb, S, Sb, Se, V, F , Mg
(Comp- HCVD-all)
a
b
(MZMVC)
(BVRDMV)
Cr, Cu, Mn, Na, Ni, Zn,
NO3-, Na+, NH4+, K+
SO42-, K+, NH4+, EC,
Na, Mg, Mn
Al, K, Mn, Na, ClNa+, NH4+ ,K+, SO42-,Mg2+
2+
Cl-,NO3-,S,Cl,V,Cr,Co,Ni, Cu, Zn, As, Se, Mo, Cd,
Sb,Hg, Pb
Present study
CD
-
(MZSOILC)
a
Soil
Chemical abundances in percent mass
0.1-1%
<0.1%
Cl , Na, Cl, V, Cr, Mn, Co,
Ni, Cu, As, Se, Mo, Cd, Sb, Hg, Pb
As, Cd, Co, Cu, Hg, Mo, Ni, Sb, Se, V, Zn, NO3-
-
+
Fe, Mg, Na, OC,
Ca
Ca, Fe, SO42-, OC, EC
Ca2+
Fe, Mg, SO42-, Ca2+, EC
Ca, OC
EC, Al, Fe
OC, Ca
SO42-,Ca2+,
Ca, Fe, Mg,
OC,EC
As, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, S, Sb, Se, V,
Zn, F-, NO3-, Na+, NH4+
Cl ,EC,NH4+,Na+,Na,Cl,V,Cr,
Mn, Co, Ni, Cu, Zn, As, Se, Mo, Cd, Sb, Hg, Pb
Al, K, Na, Cl-, SO42-, K+, Mg2+
Mg, Ca2+, OC, EC
NO3-,SO42-,K+,Mg, S, K
OC, Al, Fe
As, Cd, Co, Cu, Hg, Mo, Ni, Sb, Se, V, Zn, NO3-
Al, Cr, K, Mn, Na, Pb, F ,Cl ,Na ,
NH4+, K+, Mg2+
Ca, Fe, Mg, SO4, Ca ,
OC, EC
Al, As, Ca, Cd, Co, Cr, Cu, Hg, K, Mg, Mn, Mo, Ni, Pb,
Sb, V, NO3-, NH4+, K+, Ca2+, Mg2+
Al, As, Cd, Co, Cr,Cu, Fe, K, Mg, Mn, Mo, Ni, Pb, S, Sb,
Se
Al, AS, Cd, Co, Cr, Cu, Hg, K, Mg, Mn, Mo, Ni, Sb, V,
F-, NO3-, K+, Mg2+
Al, As, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni,
Pb, S, Sb, Se, V, Zn, F-, NO3-, Na+, NH4+, Mg2+
Al, As, Ca, Cd, Co, Cr, Cu, Hg, K, Mg, Mn, Mo, Na,
Sb, Se, V, F-, K+, Ca2+, Mg2+
Al, AS, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb,
Sb, Se, V, F-, Cl-, NH4+
Al, As, Ca, Cd, Co, Cr, Cu, Hg, K, Mg, Mn, Mo, Ni, Sb,
V, F-,NO3-, K+, Ca2+, Mg2+
Al, As, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb,
Sb, Se, V, Zn, F-, Cl-, NH4+
NO3-, K+, NH4+,Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni,
Cu, As, Se, Mo, Zn, Cd, Sb, Hg, Pb
NH4+, Al, K, V, Cr, Mn, Co. Ni, Cu, As, Se, Mo, Cd, Sb,
Hg. Pb
Fe, Na, Se, Zn, F-, Cl-, SO42-, Na+
S
-
+
Ca, Fe
Ca
2+
OC, EC
2-
V, Zn, F-, NO3-, NH4+, Mg2+
2-
-
Ca, Fe, Na, Pb, Se, Zn, Cl , SO4 ,
Na+, NH4+, Ca2+
EC, Ca, Na, Cl-, SO4 ,
Na+, K+, Ca+
OC
S, EC
OC
SO42-, K+, Ca2+
Fe, Na, Pb, Zn,Cl-, NO3-,
NH4+
Ca, S, Zn, NO3-, SO42-,
2+
2+
OC, EC
2-
+
SO4 , Na ,
+
S
+
Na , K ,
OC, EC
OC, EC
Ca , Mg
-
OC
Ca, Fe, Mg, F-,Ca, OC,EC
Mg, Na, K, Zn, Cl , NO3 , Na ,
NH4+, K+
Al, Cr, K, Mn, Na, Pb, F-, Cl-, Na+,
NH4+, K+,Mg2+
NO3 ,SO42-,NH4+,Na, K+,
Mg, S, K, Zn
Al, Cr, K, Mn, Na, Pb, F-, Cl-,
Na+,NH4+,K+, Mg2+
-
>10%
OC, Al, K, Ca, Fe
Al, K, Mn, Zn, Ca2+, EC
-
1-10%
Al, Ca, Fe, K, Mg, Cl-,
SO42-, Ca2+, EC
Fe, Pb, Se, Zn, Na+
Na, S, Cl-, SO42-, NH4+
OC. EC
Ca, S, NO3-, Na+,Mg2+
SO42-, K+, Ca2+
OC, EC
SO42-, Na, S,
Cl-,
OC, EC
SO42-, Na, S
OC, EC
-
+
+
2+
Cl , NO3 , Na , K , Mg , Ca, Fe,
Zn,
*Represents PM10 Profile a Watson et al., 2001 b Chow et al., 2004 c CPCB, 2008a d CPCB 2008b