7.7 PRESCRIBED FOCUS AREA Applications and uses of science Radioactivity — a double-edged sword When most people hear the word ‘radioactivity’, they immediately conjure up mental images of scientists in lead suits holding ticking Geiger counters out in front of them, or of the horrible burns or cancers suffered by survivors of atomic bombs or the Chernobyl disaster. But is destruction all that there is to radioactivity, or can it also be a valuable lifesaver? In order to appreciate the doubleedged nature of radioactivity, let’s first look at what it is and where it comes from. Radioisotopes So far, you have learned that all atoms of the same element have the same number of protons — in other words, they all have the same atomic number. However, while the atoms of a particular element have the same number of protons, they may not always the same number of neutrons in their nuclei. For example, the normal version of hydrogen has a single proton in its nucleus but another version of hydrogen (called deuterium) has a proton and a neutron in its nucleus and yet another version (called tritium) has one proton and two neutrons. Atoms that have the same number of protons, but differ in number of neutrons they have, are called isotopes. Most elements have two or three different isotope forms. The isotopes of any element have the same chemical properties — they just differ in atomic mass. The protons and neutrons of the nucleus are held tightly together by something called 204 Core Science | Stage 5 Complete course the strong nuclear force, which overcomes the repulsive force that the positive protons exert on each other. Without the strong nuclear force, the repulsive force between the protons would tear the nucleus apart. In most isotopes, the two forces balance out and the nucleus remains intact and is said to be stable. In some isotopes, however, the presence of extra neutrons in the nucleus makes it much harder for the strong nuclear force to keep them intact and the nuclei start to break apart or decay. When these unstable nuclei break up, energy in the form of radiation is released and smaller, more stable elements are formed. As a result, isotopes whose nuclei have a tendency to decay are said to be radioactive. Some examples of stable and radioactive isotopes Element Symbol Number of protons Number of neutrons Stable or radioactive Carbon-12 C 6 6 Stable Carbon-14 C 6 8 Radioactive Uranium-235 U 92 235 Radioactive Uranium-238 U 92 238 Stable There are approximately 50 isotopes, including Uranium-235 and Carbon-14 that are naturally radioactive. Most radioactive isotopes (about 2000 in total) are made radioactive artificially by bombarding their atoms with sub-atomic particles like protons and neutrons. The radiation energy released by the decay of both naturally and artificially radioactive nuclei can be used for a number of different purposes. Nuclear radiation There are three types of radiation: alpha (α), beta (β) and gamma (γ). Alpha radiation is made up of alpha particles (α particles). Each alpha particle is made up of two neutrons and two protons — essentially the same as the nucleus of a Helium atom. These particles are the largest of the radiation particles and move relatively slowly — at about 20 000 km/s. They cannot travel easily through materials and can be stopped by a sheet of paper or human skin. They do not pose much of a threat outside of the body but they can cause serious damage if breathed in, eaten or injected. Beta radiation is made up of beta particles (β particles) which are fastmoving electrons. Smaller than the alpha particles, beta particles travel at 99% of the speed of light (which travels at 300 000 km/s). Beta particles can penetrate human skin and damage living tissue, but they cannot penetrate thin layers of plastic, wood or aluminium. Gamma radiation is different from the other two because it is made up of electromagnetic waves (as are radio waves and microwaves) rather than particles. These gamma rays, as they are known, have no mass and travel at the speed of light. They have a lot more penetrating power than alpha or beta particles and can be stopped only by a thick shield of lead or concrete. As they pass through the body, they can cause serious and permanent damage to the living tissue and the DNA of the cells themselves. α particles — absorbed in a few centimetres of air, or by a piece of paper or layer of dead skin Paper β rays — barely affected by air; absorbed in many centimetres of lead Wood γ particles — absorbed in about 100 cm of air, or a few centimetres of wood Lead Concrete The different penetrating powers of alpha (α), beta (β) and gamma (γ) radiation Radioisotopes and nuclear power The radioactive properties of uranium are used in the generation of electricity in nuclear reactors. Uranium is an element that occurs naturally in most rocks, although usually in very small amounts. Australia is one of several countries that have large high-grade deposits of uranium. Uranium is converted to uranium dioxide and then sealed in rods, called fuel rods. The uranium undergoes a fission reaction in the reactor when neutrons are fired at the radioactive uranium. This causes the uranium nuclei to split and form two new elements, releasing neutrons, Nuclear equation: 235 U 92 + 1 n 0 radiation and heat in the process. This heat energy is used to heat water to produce steam, which is used to turn the turbines that generate the electricity. Radiotherapy in the treatment of cancer Radiotherapy is the use of radioisotopes, or other radiation such as X-rays, to kill cancer cells or prevent them from multiplying. It can be targeted at a small area so that surrounding tissue is not damaged. Radiotherapy is often used along with other treatments such as surgery or chemotherapy. Radiation can be directed at the cancer by a machine like the one 141 Ba 56 + 92 Kr 36 + French physicist Henri Becquerel accidentally discovered radioactivity while investigating the fluorescence of uranium salts in 1896. When he developed a photographic plate that had been in a drawer near his bench top, he found that it had been fogged up by radiation from the uranium salts. This effect of radioactivity is now used in a protective device worn by people who work with radioactive materials. The ‘fogging’ of the film in this device measures the amount of radioactivity they have been exposed to. Becquerel was the first scientist to report the effects of radioactivity on living tissue. He suffered from burns on his skin as a result of carrying a small quantity of the element radium in his pocket. below. This method is known as external radiotherapy. The other method, known as internal radiotherapy or brachytherapy, involves placing radioisotopes inside the body at or near the site of the cancer. In some cases both methods are used. The type of treatment depends on the type of cancer, its size and location as well as the general health of the patient. Radioisotopes in the diagnosis of disease Radioactive substances may be inserted into the body to detect or identify the cause of disease. The radiation produced by the 1 3 0n Gamma rays 141 Ba 56 235 U 92 Barium nucleus Nuclear reaction Slow neutron Uranium nucleus An example of a nuclear fission reaction ENERGY 92 Kr 36 Krypton nucleus Fast neutrons 7 Chemistry — the inside story 205 substance while it is in the part of the body under investigation is measured to diagnose the problem. Some radioisotopes can be used to obtain images of parts of the body. The gamma rays emitted by these radioisotopes are used to produce the images. PET (positron emission tomography) scans use cameras surrounding the patient to detect gamma rays coming from radioisotopes injected into the body. spoiling. Food in sealed containers can be preserved by exposing it to gamma radiation. The radiation kills the micro-organisms in the food and keeps it from spoiling. However, there has been much controversy about the safety of food that has been treated in this way. Some of the radioisotopes used in the treatment and diagnosis of disease. Radioactive material makes its way into air, water, soil, food, animals and human tissue. Uranium releases radioactive radon gas into the atmosphere when it is mined and milled. The radioactive gas returns to Earth as rain, contaminating soil and water. The solid radioactive wastes from mining, called tailings, can infiltrate through the soil and into the ground water or is dispersed into the environment by wind. Radioisotope Use Half-life Phosphorus-32 Used to treat leukaemia 14.3 days Cobalt-60 Used in radiotherapy for treating cancer 5 years Barium-137 Diagnosis of digestive illnesses 2.6 minutes Iodine-123 Monitoring of thyroid and adrenal glands, and assessment of damage caused by strokes 13 hours Iodine-131 Diagnosis and treatment of thyroid problems 8 days Iron-59 Measurement of blood flow and volume 46 days Thallium-201 Detection of damaged heart muscles 3 days Preserving food If you’ve ever suffered from food poisoning you will understand why it is necessary to keep food from Impacts of nuclear waste Management of nuclear waste The management of nuclear waste depends on the amount, type, and period of time the waste remains hazardous. For example: • Low-level waste generated from hospitals and industry is buried in shallow landfill sites. • Intermediate-level waste in resins and chemical sludge is buried in concrete or bitumen. • High-level waste in spent fuel rods is transported in thick containers to prevent leaking. radioactive iodine (iodine-131) moves from the ground to a cow. The radioactive iodine enters the cow’s milk (in a concentrated form) . . . Fallout enters the food chain when solid radioactive contaminants fall into bodies of water and onto the soil. The contaminants are taken in by plants and animals, becoming more concentrated as and travels to the thyroid they move up the food gland of a human, where chain. In humans, the it increases the risk of contaminants move cancer. to target organs, delivering large, close-range doses of radiation. For example . . . 206 Core Science | Stage 5 Complete course The diagram below shows parts of the body targeted by specific radioactive isotopes likely to be present in the fallout from Chernobyl. The risk, in all cases, is that of cancer in the targeted organ or in related tissue. Thyroid: iodine-131* Lungs: krypton 85 Bone: strontium 90 and yttrium 90 Kidneys: ruthenium 106 Ovaries: iodine-131*, ruthenium 106 and caesium 137* Muscle: caesium 137* *These isotopes were detected by Swedish monitors early in the week after the Chernobyl disaster. Other methods of managing waste include vitrification, where liquid radioactive waste is mixed with glass and poured into steel drums. The steel drums are then dug deep into the ground or under the sea floor. Another possible option is to send nuclear waste into space. With 150 000 tonnes of used nuclear fuel in the world, which is increasing daily, individuals, groups and governments are concerned about the lack of a satisfactory disposal system. Activities 14 The use of barium-137 in the diagnosis of digestive illnesses involves the patient drinking it in a syrup. What property of barium-137 makes its use quite safe? REMEMBER 15 Is cobalt-60, used in the treatment of cancer, more likely to be used in external radiotherapy or internal radiotherapy? Use the information in the table to explain your answer. 1 Recall how isotopes of the same element are different from each other. 2 Explain why the isotopes of some elements are radioactive. 3 Identify the type of nuclear radiation described by the following statements. (a) A radioactive particle that has the same size and mass as an electron (b) A radioactive particle that is made up of two protons and two neutrons (c) The type of radiation that can penetrate the human body and can be stopped only by a thick shield of lead or concrete (d) A radioactive particle that can travel almost at the speed of light 4 Recall the name of the nuclear reaction that takes place in nuclear power stations. 16 Discuss the positive and negative impacts of uranium on people and the environment. USING DATA 17 A scientist wished to determine the type of radiation emitted by a radioisotope. She had three materials (paper, plastic and lead) and an instrument called a Geiger counter, which detects nuclear radiation. She covered the radioisotope with each of the three materials and measured the radiation that passed through each material. The results of her experiment are shown in the table below. Results of radioactivity experiment 5 Describe three uses of radioactive elements. Material 6 Describe what radiotherapy is and how it prevents the spread of cancer through the body. Paper No effect on readings Plastic Readings fell by two-thirds Lead Large fall in readings 7 Distinguish between internal radiotherapy and external radiotherapy. 8 Explain how radioisotopes used in food preservation stop food from spoiling. Effect on Geiger counter readings What type of nuclear radiation does this radioisotope emit? Explain your answer. 9 Describe the nature of nuclear waste. 10 Explain how radioactive waste can affect people via its effect on the environment 11 Describe some technological sloutions to the disposal of nuclear wastes THINK 12 About 0.01 per cent of the potassium in your body is the 40 radioisotope 19K . (a) How many protons and neutrons are in each atom of this radioisotope? (b) The stable nuclei of potassium atoms have one less neutron than the nuclei of potassium’s unstable radioisotope. Write down the complete symbol for the stable isotope of potassium. 13 Is iodine-131 a more stable radioisotope than barium-137? Explain. INVESTIGATE 18 On a cold spring morning in April 1986, a nuclear reactor at Chernobyl, in what is now Ukraine, exploded and released radioactive gases into the atmosphere. Create a report on: (a) how the disaster happened (b) how it affected the workers at the power plant and the surrounding towns and villages (c) the attempts to reduce or control the damage caused by the radiation (d) the long-term effects of the explosion. 19 Describe radioactive fallout? 20 Radiotherapy is an effective method of treating cancer. However, it has a number of side effects. Research what the side effects are. 7 Chemistry — the inside story 207
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