BIOSAFE® HM 4072 - OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM CHLORIDE, 72% in methanol
OCTADECYLDIMETHYL(3TRIMETHOXYSILYLPROPYL)AMMONIUM CHLORIDE, 72% in
methanol
Safety Data Sheet BIOSAFE® HM 4072
Date of issue: 03/19/2014
Revision date: 10/14/2016
Version: 2.0
SECTION 1: Identification
1.1.
Product identifier
Product name
: OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM CHLORIDE, 72% in
methanol
Product code
: BIOSAFE® HM 4072
Product form
: Mixture
Physical state
: Liquid
Formula
: C26H58ClNO3Si
Synonyms
: (TRIMETHOXYSILYLPROPYL)OCTADECYLDIMETHYLAMMONIUM CHLORIDE
DIMETHYLOCTADECYL[3-(TRIMETHOXYSILYL)PROPYL]AMMONIUM CHLORIDE
Chemical family
: ORGANOMETHOXYSILANE
1.2.
Recommended use of the chemical and restrictions on use
Recommended use
1.3.
: Antimicrobial product
For research and industrial use only
Details of the supplier of the safety data sheet
GELEST, INC.
11 East Steel Road
Morrisville, PA 19067
USA
T 215-547-1015 - F 215-547-2484 - (M-F): 8:00 AM - 5:30 PM EST
[email protected] - www.gelest.com
1.4.
Emergency telephone number
Emergency number
: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International)
SECTION 2: Hazard(s) identification
2.1.
Classification of the substance or mixture
GHS-US classification
Flammable liquids Category 2
Acute toxicity (oral) Category 4
Acute toxicity (dermal) Category 4
Acute toxicity (inhalation:vapor) Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Specific target organ toxicity (single exposure) Category 1
H225
H302
H312
H332
H315
H318
H370
Full text of H statements : see section 16
2.2.
Label elements
GHS-US labeling
Hazard pictograms (GHS-US)
:
Signal word (GHS-US)
: Danger
Hazard statements (GHS-US)
: H225 - Highly flammable liquid and vapor
H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled
H315 - Causes skin irritation
H318 - Causes serious eye damage
H370 - Causes damage to organs
Precautionary statements (GHS-US)
: P280 - Wear protective gloves/protective clothing/eye protection/face protection
P307 + P311 - If exposed: Call a poison center/doctor
P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking
P233 - Keep container tightly closed
P240 - Ground/Bond container and receiving equipment
P241 - Use explosion-proof electrical equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P260 - Do not breathe vapors
GHS02
Print date: 10/14/2016
EN (English US)
GHS05
GHS07
GHS08
SDS ID: BIOSAFE® HM 4072
Page 1
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
P264 - Wash hands thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P330 - Rinse mouth
P301 + P312 - If swallowed: Call a POISON CENTER if you feel unwell
P303 + P361 + P353 - If on skin (or hair): take off immediately all contaminated clothing. rinse
skin with water/shower
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P304 + P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER
P321 - Specific treatment (see first aid instructions on this label)
P362 + P364 - Take off contaminated clothing and wash it before reuse
P370 + P378 - In case of fire: Use water spray, foam, carbon dioxide, dry chemical to
extinguish
P403 + P235 - Keep in a cool place
P405 - Store locked up
P501 - Dispose of contents/container to licensed waste disposal facility
2.3.
Hazards not otherwise classified (HNOC)
No additional information available
2.4.
Unknown acute toxicity (GHS US)
No data available
SECTION 3: Composition/Information on ingredients
3.1.
Substance
Not applicable
3.2.
Mixture
Name
Product identifier
%
GHS-US classification
(CAS No) 27668-52-6
67 - 87
Eye Irrit. 2A, H319
Methanol
(CAS No) 67-56-1
15 - 20
Flam. Liq. 2, H225
Acute Tox. 3 (Oral), H301
Acute Tox. 3 (Dermal), H311
Acute Tox. 3 (Inhalation:vapour),
H331
Skin Irrit. 2, H315
Eye Dam. 1, H318
STOT SE 1, H370
STOT SE 3, H336
3-Chloropropyltrimethoxysilane
(CAS No) 2530-87-2
7 - 13
Flam. Liq. 4, H227
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Octadecyldimethyl(3-trimethoxysilyl)ammonium chloride
Full text of hazard classes and H-statements : see section 16
SECTION 4: First aid measures
4.1.
Description of first aid measures
First-aid measures general
: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible). If possible show this sheet; if not
available show packaging or label.
First-aid measures after inhalation
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel
unwell, seek medical advice.
First-aid measures after skin contact
: Remove/take off immediately all contaminated clothing. Wash with plenty of soap and water. If
skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact
: Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion
: Never give anything by mouth to an unconscious person. Immediately call a poison center or
doctor/physician.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries
: Causes damage to organs.
Symptoms/injuries after inhalation
: Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation. Overexposure may cause: Cough. Headache. Nausea. Visual disturbances.
Symptoms/injuries after skin contact
: Harmful in contact with skin. Causes skin irritation. Repeated exposure to this material can
result in absorption through skin causing significant health hazard.
Symptoms/injuries after eye contact
: Causes serious eye damage.
Print date: 10/14/2016
EN (English US)
SDS ID: BIOSAFE® HM 4072
2/9
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
Symptoms/injuries after ingestion
: Harmful if swallowed. Swallowing a small quantity of this material will result in serious health
hazard. Oral toxicity is associated with methanol, the solvent and a hydrolysis product which
causes nausea, vomiting, headache, visual effects including blindness. Onset of symptoms
may be delayed up to 48 hours.
Chronic symptoms
: Methanol may effect the central nervous system resulting in persistent or recurring headaches
or impaired vision.
4.3.
Indication of any immediate medical attention and special treatment needed
NOTE TO PHYSICIAN: The combination of visual disturbances, metabolic acidosis and formic acid in urine is evidence of methanol poisoning. The
therapeutic intravenous administration of ethanol (10 mls/hour) allows methanol to be preferentially oxidized and reduces production of methanol
metabolites. Acidosis must be treated with intravenous administration of sodium bicarbonate and methanol elimination may be increased by
hemodialysis, as indicated. Treatment should be based on blood methanol levels and acid-base balance.
SECTION 5: Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media
: Water spray. Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media
: Do not use straight streams.
5.2.
Special hazards arising from the substance or mixture
Fire hazard
: Highly flammable liquid and vapor. Irritating fumes and organic acid vapors may develop when
material is exposed to elevated temperatures or open flame.
Explosion hazard
: May form flammable/explosive vapor-air mixture.
5.3.
Advice for firefighters
Firefighting instructions
: Exercise caution when fighting any chemical fire. Use water spray to cool exposed surfaces.
Protection during firefighting
: Do not enter fire area without proper protective equipment, including respiratory protection.
Avoid all eye and skin contact and do not breathe vapor and mist.
SECTION 6: Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
General measures
6.1.1.
: Eliminate every possible source of ignition. Use special care to avoid static electric charges.
For non-emergency personnel
Protective equipment
: Wear protective equipment as described in Section 8.
Emergency procedures
: Evacuate unnecessary personnel.
6.1.2.
For emergency responders
Protective equipment
6.2.
: Avoid breathing vapors. Do not attempt to take action without suitable protective equipment.
Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure
controls/personal protection".
Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3.
Methods and material for containment and cleaning up
For containment
: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or
streams.
Methods for cleaning up
: Clean up any spills as soon as possible, using an absorbent material to collect it. Use only nonsparking tools.
6.4.
Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1.
Precautions for safe handling
Additional hazards when processed
: Handle empty containers with care because residual vapors are flammable. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking.
Precautions for safe handling
: Avoid all eye and skin contact and do not breathe vapor and mist. Ground/bond container and
receiving equipment. Take precautionary measures against static discharge. Use only outdoors
or in a well-ventilated area. Use only non-sparking tools.
Hygiene measures
: Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse.
Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work.
7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof
electrical equipment.
Storage conditions
: Keep container tightly closed. Keep in a cool place. Store locked up.
Print date: 10/14/2016
EN (English US)
SDS ID: BIOSAFE® HM 4072
3/9
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
Incompatible materials
: Acids. Alcohols. Oxidizing agent. Peroxides.
Storage area
: Store in a well-ventilated place. Store away from heat.
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
Methanol (67-56-1)
ACGIH
ACGIH TWA (ppm)
200 ppm
ACGIH
ACGIH STEL (ppm)
250 ppm
OSHA
OSHA PEL (TWA) (mg/m³)
260 mg/m³
OSHA
OSHA PEL (TWA) (ppm)
200 ppm
IDLH
US IDLH (ppm)
6000 ppm
NIOSH
NIOSH REL (TWA) (mg/m³)
260 mg/m³
NIOSH
NIOSH REL (TWA) (ppm)
200 ppm
NIOSH
NIOSH REL (STEL) (mg/m³)
325 mg/m³
NIOSH
NIOSH REL (STEL) (ppm)
250 ppm
8.2.
Exposure controls
Appropriate engineering controls
: Provide local exhaust or general room ventilation.
Personal protective equipment
: Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure.
Hand protection
: Neoprene or nitrile rubber gloves.
Eye protection
: Chemical goggles or face shield. Contact lenses should not be worn.
Skin and body protection
: Wear suitable protective clothing.
Respiratory protection
: Where exposure through inhalation may occur from use, respiratory protection equipment is
recommended. NIOSH-certified combination organic vapor - amine gas (brown cartridge)
respirator.
SECTION 9: Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Appearance
: Clear liquid.
Molecular mass
: 496.29 g/mol
Color
: Straw.
Odor
: Amine-like.
Odor threshold
: No data available
Refractive index
: No data available
pH
: No data available
Relative evaporation rate (butyl acetate=1)
: No data available
Melting point
: No data available
Freezing point
: No data available
Boiling point
: 68 °C (initial, methanol)
Flash point
: 15 °C
Auto-ignition temperature
: 230 °C
Decomposition temperature
: No data available
Flammability (solid, gas)
: Highly flammable liquid and vapor
Vapor pressure
: 50 mm Hg @ 25°C
Relative vapor density at 20 °C
: No data available
Relative density
: 0.89
VOC content
: 28 %
Solubility
: Reacts with water. Dissolves.
Log Pow
: No data available
Log Kow
: No data available
Viscosity, kinematic
: No data available
Print date: 10/14/2016
EN (English US)
SDS ID: BIOSAFE® HM 4072
4/9
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
Viscosity, dynamic
: No data available
Explosive properties
: No data available
Oxidizing properties
: No data available
Explosion limits
: 6 - 36.5 vol % (lower; upper)
9.2.
Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.
Reactivity
No additional information available
10.2.
Chemical stability
Stable when stored in sealed containers.
10.3.
Possibility of hazardous reactions
No additional information available
10.4.
Conditions to avoid
Heat. Sparks. Open flame.
10.5.
Incompatible materials
Acids. Alcohols. Oxidizing agent. Peroxides.
10.6.
Hazardous decomposition products
Organic acid vapors.
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Acute toxicity
: Oral: Harmful if swallowed. Dermal: Harmful in contact with skin. Inhalation:vapour: Harmful if
inhaled.
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM CHLORIDE, 72% in methanol (27668-52-6)
ATE US (oral)
500.000 mg/kg body weight
ATE US (dermal)
1500.000 mg/kg body weight
ATE US (vapors)
15.000 mg/l/4h
Methanol (67-56-1)
LC50 inhalation rat (ppm)
ATE US (oral)
ATE US (dermal)
ATE US (vapors)
22500 ppm (Exposure time: 8 h)
100.000 mg/kg body weight
300.000 mg/kg body weight
3.000 mg/l/4h
3-Chloropropyltrimethoxysilane (2530-87-2)
LD50 oral rat
LD50 dermal rabbit
5628 mg/kg
2830 µl/kg
Skin corrosion/irritation
: Causes skin irritation.
Serious eye damage/irritation
: Causes serious eye damage.
Respiratory or skin sensitization
: Not classified
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
None of the components in this product at concentrations >0.1% are listed by IARC, NTP,
OSHA or ACGIH as a carcinogen
Reproductive toxicity
: Not classified
Specific target organ toxicity (single exposure)
: Causes damage to organs.
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard
: Not classified
Symptoms/injuries after inhalation
: Harmful if inhaled. Danger of serious damage to health by prolonged exposure through
inhalation. Overexposure may cause: Cough. Headache. Nausea. Visual disturbances.
Symptoms/injuries after skin contact
: Harmful in contact with skin. Causes skin irritation. Repeated exposure to this material can
result in absorption through skin causing significant health hazard.
Symptoms/injuries after eye contact
: Causes serious eye damage.
Print date: 10/14/2016
EN (English US)
SDS ID: BIOSAFE® HM 4072
5/9
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
Symptoms/injuries after ingestion
: Harmful if swallowed. Swallowing a small quantity of this material will result in serious health
hazard. Oral toxicity is associated with methanol, the solvent and a hydrolysis product which
causes nausea, vomiting, headache, visual effects including blindness. Onset of symptoms
may be delayed up to 48 hours.
Chronic symptoms
: Methanol may effect the central nervous system resulting in persistent or recurring headaches
or impaired vision.
SECTION 12: Ecological information
12.1.
Toxicity
Ecology - general
: Toxic to aquatic organisms.
Methanol (67-56-1)
LC50 fish 1
LC50 fish 2
12.2.
28200 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
> 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Persistence and degradability
No additional information available
12.3.
Bioaccumulative potential
Methanol (67-56-1)
BCF fish 1
Log Pow
12.4.
< 10
-0.77
Mobility in soil
No additional information available
12.5.
Other adverse effects
Other adverse effects
: This substance may be hazardous to the environment.
Effect on ozone layer
: No additional information available
Effect on the global warming
: No known effects from this product.
GWPmix comment
: No known effects from this product.
SECTION 13: Disposal considerations
13.1.
Waste treatment methods
Sewage disposal recommendations
: Do not dispose of waste into sewer.
Waste disposal recommendations
: Incinerate. Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to licensed waste disposal facility.
Additional information
: Handle empty containers with care because residual vapors are flammable. Improper disposal
of pesticides or pesticide residues is a violation of US Federal law. Preferred option for
disposal of waste pesticides is incineration at a licensed and permitted facility.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information
14.1.
UN number
UN-No.(DOT)
DOT NA no.
14.2.
: 1230
UN1230
UN proper shipping name
Transport document description
: UN1230 Methanol (METHANOL SOLUTION), 3 (6.1), II
Proper Shipping Name (DOT)
: Methanol
Class (DOT)
: 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT)
: II - Medium Danger
Hazard labels (DOT)
: 3 - Flammable liquid
6.1 - Poison
DOT Packaging Non Bulk (49 CFR 173.xxx)
: 202
DOT Packaging Bulk (49 CFR 173.xxx)
: 242
DOT Packaging Exceptions (49 CFR 173.xxx)
: 150
(METHANOL SOLUTION)
Print date: 10/14/2016
EN (English US)
SDS ID: BIOSAFE® HM 4072
6/9
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
DOT Symbols
14.3.
: + - Fixes (cannot be altered) proper shipping name, hazard class, and packing group,I - Proper
shipping name appropriate for international and domestic transportation
Additional information
Emergency Response Guide (ERG) Number
: 131
Other information
: No supplementary information available.
Transport by sea
DOT Vessel Stowage Location
: B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded
DOT Vessel Stowage Other
: 40 - Stow ‘‘clear of living quarters’’
Air transport
DOT Quantity Limitations Passenger aircraft/rail : 1 L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 60 L
CFR 175.75)
SECTION 15: Regulatory information
15.1. US Federal regulations
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM CHLORIDE, 72% in methanol (27668-52-6)
EPA FIFRA Registration
HM 4072 is a Federal Insecticide, Fungicide, Rodenticide Act (FIFRA)
regulated antimicrobial, EPA registration number 83019-4
Methanol (67-56-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
SARA Section 313 - Emission Reporting
1.0 %
Octadecyldimethyl(3-trimethoxysilyl)ammonium chloride (27668-52-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
3-Chloropropyltrimethoxysilane (2530-87-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
Methanol (67-56-1)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification
Class B Division 2 - Flammable Liquid
Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Octadecyldimethyl(3-trimethoxysilyl)ammonium chloride (27668-52-6)
Listed on the Canadian DSL (Domestic Substances List)
3-Chloropropyltrimethoxysilane (2530-87-2)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
Methanol (67-56-1)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Octadecyldimethyl(3-trimethoxysilyl)ammonium chloride (27668-52-6)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
3-Chloropropyltrimethoxysilane (2530-87-2)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Print date: 10/14/2016
EN (English US)
SDS ID: BIOSAFE® HM 4072
7/9
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
National regulations
Methanol (67-56-1)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Poisonous and Deleterious Substances Control Law
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Octadecyldimethyl(3-trimethoxysilyl)ammonium chloride (27668-52-6)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
3-Chloropropyltrimethoxysilane (2530-87-2)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
15.3. US State regulations
Methanol (67-56-1)
U.S. - California Proposition 65 Carcinogens List
U.S. - California Proposition 65 Developmental Toxicity
No
Yes
U.S. - California Proposition 65 Reproductive Toxicity Female
No
U.S. - California Proposition 65 Reproductive Toxicity Male
No
Non-significant
risk level (NSRL)
Methanol (67-56-1)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
Full text of H-phrases::
-----H225
-----H227
-----H301
-----H302
-----H311
-----H312
-----H315
-----H318
-----H319
-----H331
-----H332
-----H336
-----H370
Print date: 10/14/2016
Highly flammable liquid and vapor
Combustible liquid
Toxic if swallowed
Harmful if swallowed
Toxic in contact with skin
Harmful in contact with skin
Causes skin irritation
Causes serious eye damage
Causes serious eye irritation
Toxic if inhaled
Harmful if inhaled
May cause drowsiness or dizziness
Causes damage to organs
EN (English US)
SDS ID: BIOSAFE® HM 4072
8/9
OCTADECYLDIMETHYL(3-TRIMETHOXYSILYLPROPYL)AMMONIUM
CHLORIDE, 72% in methanol
Safety Data Sheet
Abbreviations and acronyms
: Abbreviations: ND: Not Determined, No Data; NA: Not Applicable; LD: Lethal Dose; LC: Lethal
Concentration; ATE: Acute Toxicity Estimates; H: hour; °: °C unless otherwise stated; mm:
millimeters Hg, torr; PEL: permissible exposure level; TWA: time weighted average; TLV:
threshold limit value; TG: Test Guideline; NIOSH: National Institute for Occupational Safety and
Health; IARC: International Agency for Research on Cancer; NTP: National Toxicology
Program; HMIS: Hazardous Material Information System; CAS No.: Chemcial Abstract Service
Registration Number; EC No.: European Commission Registration Number; EC Index No.:
European Commission Index Number; OECD: The Organisation for Economic Co-operation
and Development; GHS: The Globally Harmonized System of Classification and Labelling.
HMIS III Rating
Health
: 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability
: 4 Severe Hazard - Flammable gases, or very volatile flammable liquids with flash points below
73 F, and boiling points below 100 F. Materials may ignite spontaneously with air. (Class IA)
Physical
: 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Prepared by safety and environmental affairs.
Date of issue: 03/19/2014
Revision date: 10/14/2016
Version: 2.0
SDS US (GHS HazCom 2012) - Custom
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
The information contained in this document has been gathered from reference materials and/or Gelest, Inc. test data and is to the best knowledge and belief of Gelest, Inc. accurate and reliable.
Such information is offered solely for your consideration, investigation and verification. It is not suggested or guaranteed that the hazard precautions or procedures described are the only ones which
exist. Gelest, Inc. makes no warranties, express or implied, with respect to the use of such information and assumes no responsibility therefore. Information on this safety data sheet is not intended
to constitute a basis for product specifications.
© 2016 Gelest Inc. Morrisville, PA 19067
Print date: 10/14/2016
EN (English US)
SDS ID: BIOSAFE® HM 4072
9/9