Radioactive Decay II Syllabus Reference: –6.2 – Radioactive Decay –12.2 – Nuclear Physics Isotope Stability Small nuclei when N = Z Larger nuclei need more neutrons Too many or too few = unstable radioactive decay Decay Series When an isotope decays into another that is also radioactive, a series can occur. Allows us to find some isotopes in nature that ordinarily wouldn’t be there. HalfHalf-life, rate of decay Radioactive decay is random – Can’t predict individually, can as a whole. The number of parent nuclei in a sample and the number of decays per second (activity) decreases exponentially with time. HalfHalf-life = the time it takes for half the parent isotope in a given sample to decay. – Or the time in which there is a 50% chance of decay. – Or the time for activity to decrease by 50% 1 Practice Iodine 131 decays with a halfhalf-life of approximately 8 days. If a sample of Iodine 131 has an initial mass of 100 g, how much of the isotope will remain after 24 days? – 12.5 g A sample of phosphorousphosphorous-90 (T1/2 = 14 days) has a mass of 7.5 g. Some time later, only 1.88 g of the original isotope remains. How many days have passed? – 28 days Decay Constant The Decay Constant (λ (λ) is the ratio between the number of nuclei decaying per unit time and the total number of nuclei of the original isotope (ΔN/Δ N/Δt)/N =λ =λ Activity of a sample = (Δ (ΔN/Δ N/Δt) = -λN Determined by λ and N Radioactive Decay Law N = N0e-λt – Using calculus from activity definition – N = activity remaining – N0 = original activity – t = time over which decay has occurred 1 Becquerel (Bq (Bq)) = 1 event/s T1/2 = ln2/λ ln2/λ – From above equation Practice 24 Na 11 undergoes β decay with a halfhalf-life of about 15 hours. A) What is the decay constant for sodiumsodium-24? B) If the initial activity of a sample is 3.6 x 103 Bq, Bq, what will its activity be after 6 hours? A) 1.28 x 10-5 s-1 B) 2.73 x 103 Bq Radioactive Dating 14C dating – T1/2 of 5730 years – Useful up to ~60,000 years – Other isotopes for older dating, 238U (4.5 x 109 T1/2) for rocks 2 Detection of Radiation Schematic drawing of a photomultiplier tube (from scintillator) Geiger counter or GeigerGeiger-Muller tube Scintillation counter Cloud chamber Bubble chamber Photocathode Photons eject electrons via photoelectric effect Each incident electron ejects about 4 new electrons at each dynode stage “Multiplied” signal comes out here Vacuum inside tube An applied voltage difference between dynodes makes electrons accelerate from stage to stage 3
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