ULTRA Scientific, Inc.
Di-n-butyl Phthalate
Revision nr.2
Dated 15/01/2016
Printed on 15/01/2016
Page n. 1 / 9
Safety data sheet
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Code:
Product name
INDEX number
EC number
CAS number
DMP-015
Di-n-butyl Phthalate
607-318-00-4
201-557-4
84-74-2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use
reference material and/or laboratory reagent
1.3. Details of the supplier of the safety data sheet
Name
Full address
District and Country
ULTRA Scientific, Inc.
250 Smith Street
02852 N. Kingstown
USA
Tel.
401-294-9400
Fax
401-295-2330
e-mail address of the competent person
responsible for the Safety Data Sheet
[email protected]
Product distribution by
ULTRA Scientific, Inc.
(RI)
1.4. Emergency telephone number
For urgent inquiries refer to
US: (800) 424-9300
Outside US: (703) 527-3887
SECTION 2. Hazards identification.
2.1. Classification of the substance or mixture.
The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent
amendments and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation
1907/2006 and subsequent amendments.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.
Hazard classification and indication:
Reproductive toxicity, category 1B
Hazardous to the aquatic environment, acute toxicity,
category 1
H360Df
H400
May damage the unborn child. Suspected of damaging.
Very toxic to aquatic life.
2.2. Label elements.
Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.
Hazard pictograms:
Signal words:
Danger
Hazard statements:
H360Df
H400
May damage the unborn child. Suspected of damaging.
Very toxic to aquatic life.
Restricted to professional users.
EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
SECTION 2. Hazards identification.
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... / >>
Precautionary statements:
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P273
Avoid release to the environment.
P280
Wear protective gloves / clothing and eye / face protection.
P308+P313
IF exposed or concerned: Get medical advice / attention.
P391
Collect spillage.
Contains:
INDEX.
DIBUTYL PHTHALATE
607-318-00-4
2.3. Other hazards.
On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.
SECTION 3. Composition/information on ingredients.
3.1. Substances.
Contains:
Identification.
Conc. %.
DIBUTYL PHTHALATE
CAS.
84-74-2
100
EC.
201-557-4
INDEX. 607-318-00-4
Classification 1272/2008 (CLP).
Repr. 1B H360Df, Aquatic Acute 1 H400 M=1
The full wording of hazard (H) phrases is given in section 16 of the sheet.
3.2. Mixtures.
Information not relevant.
SECTION 4. First aid measures.
4.1. Description of first aid measures.
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If
problem persists, seek medical advice.
SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash
contaminated clothing before using it again.
INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.
INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an
unconscious person, unless authorised by a doctor.
4.2. Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances, see chap. 11.
4.3. Indication of any immediate medical attention and special treatment needed.
Information not available.
SECTION 5. Firefighting measures.
5.1. Extinguishing media.
SUITABLE EXTINGUISHING EQUIPMENT
The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.
5.2. Special hazards arising from the substance or mixture.
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products.
EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
SECTION 5. Firefighting measures.
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5.3. Advice for firefighters.
GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
SECTION 6. Accidental release measures.
6.1. Personal precautions, protective equipment and emergency procedures.
Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to
prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in
emergency procedures.
6.2. Environmental precautions.
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
6.3. Methods and material for containment and cleaning up.
Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10.
Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be
disposed of in compliance with the provisions set forth in point 13.
6.4. Reference to other sections.
Any information on personal protection and disposal is given in sections 8 and 13.
SECTION 7. Handling and storage.
7.1. Precautions for safe handling.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the
environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before
entering places in which people eat.
7.2. Conditions for safe storage, including any incompatibilities.
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers
away from any incompatible materials, see section 10 for details.
7.3. Specific end use(s).
Information not available.
SECTION 8. Exposure controls/personal protection.
8.1. Control parameters.
Regulatory References:
AUS
BEL
DEU
DNK
ESP
FRA
GRB
IRL
Österreich
Belgique
Deutschland
Danmark
España
France
United Kingdom
Éire
TLV-ACGIH
Grenzwerteverordnung 2011 - GKV 2011
AR du 11/3/2002. La liste est mise à jour pour 2010
MAK-und BAT-Werte-Liste 2012
Graensevaerdier per stoffer og materialer
INSHT - Límites de exposición profesional para agentes químicos en España 2015
JORF n°0109 du 10 mai 2012 page 8773 texte n° 102
EH40/2005 Workplace exposure limits
Code of Practice Chemical Agent Regulations 2011
ACGIH 2014
EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
SECTION 8. Exposure controls/personal protection.
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DIBUTYL PHTHALATE
Threshold Limit Value.
Type
Country
MAK
VLEP
AGW
MAK
TLV
VLA
VLEP
WEL
OEL
TLV-ACGIH
AUS
BEL
DEU
DEU
DNK
ESP
FRA
GRB
IRL
TWA/8h
mg/m3
5
5
0.58
0.58
3
5
5
5
5
5
ppm
STEL/15min
mg/m3
ppm
0.05
0.05
1.16
1.16
0.1
0.1
10
10
Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.
8.2. Exposure controls.
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace
is well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with
applicable standards.
Provide an emergency shower with face and eye wash station.
HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time
depends on the duration and type of use.
SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash
body with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a
type B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the
presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.)
combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to
the threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing
apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS.
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.
Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways.
SECTION 9. Physical and chemical properties.
9.1. Information on basic physical and chemical properties.
Appearance
liquid
Colour
colourless
Odour
Not available.
Odour threshold.
Not available.
pH.
Melting point / freezing point.
-35
°C.
Initial boiling point.
340
°C.
Boiling range.
Not available.
Flash point.
>
172
°C.
Evaporation Rate
Not available.
Flammability of solids and gases
Not available.
Lower inflammability limit.
Not available.
Upper inflammability limit.
Not available.
Lower explosive limit.
0.47
% (V/V).
EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
SECTION 9. Physical and chemical properties.
Upper explosive limit.
Vapour pressure.
Vapour density
Relative density.
Solubility
Partition coefficient: n-octanol/water
Auto-ignition temperature.
Decomposition temperature.
Viscosity
Explosive properties
Oxidising properties
9.2. Other information.
VOC (Directive 1999/13/EC) :
VOC (volatile carbon) :
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Not available.
1
mmHg
N/A
1.047 Kg/l
slightly soluble in water
Not available.
405.44 °C.
Not available.
Not available.
Not available.
Not available.
0
0
SECTION 10. Stability and reactivity.
10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.
10.2. Chemical stability.
The product is stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions.
No hazardous reactions are foreseeable in normal conditions of use and storage.
10.4. Conditions to avoid.
None in particular. However the usual precautions used for chemical products should be respected.
10.5. Incompatible materials.
Information not available.
10.6. Hazardous decomposition products.
Information not available.
SECTION 11. Toxicological information.
11.1. Information on toxicological effects.
This product has a teratogenic effect on human beings; it has toxic effects on fetus development. This product must be handled carefully
because of its possible teratogenic effects, which may reduce human fertility.
DIBUTYL PHTHALATE
LD50 (Oral).
LD50 (Dermal).
LC50 (Inhalation).
6300 mg/kg Rat
> 4000 mg/kg Rabbit
15.68 mg/l/4h Rat
SECTION 12. Ecological information.
This product is dangerous for the environment and highly toxic for aquatic organisms.
12.1. Toxicity.
DIBUTYL PHTHALATE
LC50 - for Fish.
EC50 - for Crustacea.
EC50 - for Algae / Aquatic Plants.
1.6 mg/l/96h Oncorhynchus mykiss
3.93 mg/l/48h Daphnia magna
0.21 mg/l/72h Scenedesmus acutus
12.2. Persistence and degradability.
DIBUTYL PHTHALATE
Solubility in water.
Rapidly biodegradable.
12.3. Bioaccumulative potential.
mg/l 0,1 - 100
EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
SECTION 12. Ecological information.
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DIBUTYL PHTHALATE
Partition coefficient: n-octanol/water.
4.46
12.4. Mobility in soil.
Information not available.
12.5. Results of PBT and vPvB assessment.
On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.
12.6. Other adverse effects.
Information not available.
SECTION 13. Disposal considerations.
13.1. Waste treatment methods.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this
product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
Waste transportation may be subject to ADR restrictions.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
SECTION 14. Transport information.
14.1. UN number.
ADR / RID, IMDG, IATA:
3082
14.2. UN proper shipping name.
ADR / RID:
IMDG:
IATA:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DIBUTYL PHTHALATE)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DIBUTYL PHTHALATE)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DIBUTYL PHTHALATE)
14.3. Transport hazard class(es).
ADR / RID:
Class: 9
Label: 9
IMDG:
Class: 9
Label: 9
IATA:
Class: 9
Label: 9
14.4. Packing group.
ADR / RID, IMDG, IATA:
III
EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
SECTION 14. Transport information.
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14.5. Environmental hazards.
ADR / RID:
Environmentally Hazardous.
IMDG:
Marine Pollutant.
IATA:
Environmentally Hazardous.
14.6. Special precautions for user.
ADR / RID:
HIN - Kemler: 90
Special Provision: EMS: F-A, S-F
Cargo:
Pass.:
Special Instructions:
IMDG:
IATA:
Limited Quantities 5 L
Tunnel restriction code (E)
Limited Quantities 5 L
Maximum quantity: 450 L
Maximum quantity: 450 L
A97, A158, A197
Packaging instructions: 964
Packaging instructions: 964
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code.
Information not relevant.
SECTION 15. Regulatory information.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.
Seveso category.
2, 9i
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Product.
Point.
3
Contained substance.
Point.
51-30
DIBUTYL PHTHALATE
Substances in Candidate List (Art. 59 REACH).
DIBUTYL PHTHALATE
Substances subject to authorisarion (Annex XIV REACH).
DIBUTYL PHTHALATE
Sunset Date: 2/21/2015
Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:
None.
Substances subject to the Rotterdam Convention:
None.
Substances subject to the Stockholm Convention:
None.
Healthcare controls.
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the
risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected.
15.2. Chemical safety assessment.
No chemical safety assessment has been processed for the mixture and the substances it contains.
EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
SECTION 16. Other information.
Text of hazard (H) indications mentioned in section 2-3 of the sheet:
Aquatic Acute 1
H360Df
H400
Reproductive toxicity, category 1B
Hazardous to the aquatic environment, acute toxicity, category 1
May damage the unborn child. Suspected of damaging.
Very toxic to aquatic life.
LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).
GENERAL BIBLIOGRAPHY
1. Regulation (EU) 1907/2006 (REACH) of the European Parliament
2. Regulation (EU) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- ECHA website
Note for users:
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Dated 15/01/2016
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EN
ULTRA Scientific, Inc.
Di-n-butyl Phthalate
Revision nr.2
Dated 15/01/2016
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SECTION 16. Other information. ... / >>
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current
health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.
EN