CHAPTER 10.3 REVIEW KEY 10.3 Worksheet 1. Percent composition 2. 100 3. Molar mass 4. Empirical 5. Whole-number 6. Molecular 7. ST (You can use experimental data too) 8. AT 9. AT 10. NT 11. C 12. B 13. A (It is CH2O) 14. The first problem will be worked out in detail a. Step 1: Calculate the molar mass of the elements in the compound and the molar mass of the compound. Cr2 = 52.0 x 2 = 104 g O3 = 16.0 x 3 = + 48.0 g Cr2O3 c. % of Hg = 86.3% % of S = 13.7% = 152 g (molar mass) Step 2: Divide the molar mass of each element in the compound by the molar mass of the compound, then multiply by 100 to convert to percent. % of Cr in Cr2O3 = 104 g Cr X 100 = 152 g Cr2O3 68.4% % Comp of O = 48 g O X 100 = 152 g Cr2O3 31.6% CHAPTER 10.3 REVIEW KEY b. % of Mn = 38.7% d. % of Ca = 24.5% % of P = 21.8% % of N = 17.1% % of O = 39.4% % of O = 58.5% 15. Step 1: Assume 100 g of the compound, so 29.1% Na will become 29.1 g Na, 40.5% S will become 40.5 g S, and 30.4% O will become 30.4 g O. Step 2: Calculate the number of moles of each element in 100 g of the compound. 29.1 g Na 1.00 mol Na = X 1 23.0 g Na 1.27 mol Na 40.5 g S 1 X 1.00 mol S 32.1 g S = 1.27 mol S 30.4 g O 1 X 1.00 mol O 16.0 g O = 1.90 mol O Smallest mole number Step 3: Divide the moles of each element by the smallest number of moles to determine the mole ratio of each element in the compound. Na 1.27 mol 1.27 mol : 1 : : S 1.27 mol 1.27 mol : 1 : : O 1.90 mol 1.27 mol 1.5 Na1S1O1.5 Step 4: You can’t have the fraction 1.5, so multiply each number in the ratio by 2. 2 x Na1S1O1.5 = Na2S2O3 16. Step 1: Calculate the molar mass of iron and the molar mass of Fe2O3. Fe2 O3 = 55.8 x 2 = 112 g = 16.0 x 3 = + 48 g Fe2O3 = 160 g (molar mass) Step 2: Calculate the percent composition of iron in Fe2O3. % Comp of Fe = 112 g Fe 160 g Fe2O3 X 100 = 70 % Step 3: Determine number of kg of iron that makes up 639 kg of Fe2O3. 639 kg Fe2O3 x 70% = 447 kg Fe
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