D J. Chem. Chem. Eng. 10 (2016) 301-304 doi: 10.17265/1934-7375/2016.06.007 DAVID PUBLISHING Magnetic Isotope Theory of the Origin of Life on Earth Aibassov Yerkin1, Nakisbekov Narymzhan1, Yemelyanova Valentina1 and Savizky Ruben2 1. Research Institute of New Chemical Technologies and Materials, Kazakh National University Al-Farabi, Almaty 005012, Kazakhstan 2. Columbia University, 3000 Broadway, New York, NY, 10027, USA Abstract: The authors have proposed a new of magnetic isotope theory of life on Earth. According to this theory the initial impetus for the beginning of the synthesis of organic compounds is the impact of electromagnetic radiation from the sun and energy radioactive isotopes. Key words: Theory of the origin of life on earth, magnetic field, radioactive isotope, synthesis organic compounds. 1. Introduction Life is one of the most complex phenomena of nature. The problem of the origin of life on Earth has long been haunted by many scientists [1-6]. Ever since man began to wonder, where was all alive, all this time been considered a set of hypotheses and assumptions about the origin of life. In this work, an opportunity to review and modify the theory of Oparin-Haldane as the most likely, is to make it further effect of the magnetic radiation and radioactive isotopes of energy. The authors first time offered to consider the effect of the magnetic field and the radioactivity to the first organic compounds in the origin of life on Earth. 2. Theory At various times regarding the origin of life on Earth put forward the following three theories: the steady state of life, spontaneous and Oparin-Haldane’s “primordial soup”. Oparin suggested that solutions of high molecular compounds can be formed spontaneously increased concentration zone that is relatively separated from the external environment and may support communication with it. He called them coacervates. Corresponding author: Aibassov Erkin Zhakenovich, professor, research field: metal organic chemistry of uranium and thorium, As, Sb and Bi. According to his theory, the process to the origin of life can be divided into three stages: the emergence of organic substances; occurrence of protein; occurrence of protein bodies. Planetary systems arose from the gas-dust material. Along with metals and metal oxides contained in it, hydrogen, ammonia, water and simple hydrocarbon—methane. Conditions for the start of the formation of protein structures have been established since the introduction of the primary ocean (broth). In the aquatic environment derivatives of hydrocarbons could be subjected to complex chemical changes and transformations. As a result of the complexity of the molecules could form more complex organic materials, namely carbohydrates. Science has shown that the application of ultraviolet rays can be artificially synthesized not only amino acids and other organic substances. According to the theory, a further step towards the emergence of proteins could be the formation of coacervate drops. Molecules of water surrounded by a shell, joined together to form multimolecular complexes—coacervates. They also can occur by simply mixing a variety of polymers. Thus there is a self-assembly of polymer molecules in the formation of multimolecular. Drops were able to absorb substances from the outside on the type of open systems. Thus, coacervates can grow, multiply, exercise metabolism. 302 Magnetiic Isotope Th heory of the Origin O of Life on Earth In 1953, in i an experim ment Miller— —Urey placedd the mixture of H2O, NH3, CH H4, CO2, CO in i a closed veessel and began to t pass throuugh her elecctric shocks at a temperature of 80 °C. It was w found thaat the amino acids a are formed. Later also suugar nucleotiddes were obtaained under varioous conditioons. Miller concluded that evolution caan occur wheen fazovooboosoblennom state s of solution (coacervates) ( . However, suuch a system m can not reproducce itself. 3. Results and Discusssion Electromaagnetic wavees as a geneeral phenomeenon were predictted by the claassical laws of o electricity and magnetism, known as Maxwell’s equuations. Howeever, to date, the magnetic efffects in chem mistry have been b little studiedd. Therefore, the authors have h attempteed to investigate the effect of o magnetic effects on the physicochem mical and thhermodynam mic functionss in chemistry. Figs. 1 annd 2 show thee electromagnnetic waves. Not only is the wave of o electric andd magnetic fiields travel at thee speed of liight, but theyy have a lim mited orieentation and a proportionnate amountt, E = coBo, whiich can be immediately i seen from the t Poyntingg vector. The eleectric field, magnetic fiield and thee direection of wavve propagatioon are all ortthogonal andd the wave propaagation in thhe same direection as thee vector E × B. Then T we obtaiin the followiing equation:: ΔE/ΔB = c wheere, c is the sppeed of light.. From F the viewpoint v off electromag gnetic wavee mov ving rectilineearly, the elecctric field can n fluctuate upp and d down, whilee the magnetic field may vary v right andd left, but this patttern can be aalternated witth an electricc field oscillating right and leeft, and a magnetic m fieldd oscillating up and a down. T This arbitrarriness in thee orieentation withh a preferennce to the propagationn direection is know wn as polarizaation (Fig. 3)). Thus, T the polaarization of electromagnettic waves hass a grreat influencee on the coursse of chemicaal reactions. If the magneetic field andd enables to o change thee direection of the magnetic pooles, whereass the reactionn can n go in the oppposite direction. Fig. 1 The electromagneti e ic oscillations can be represeented in the fo orm of self-proopagating tran nsverse vibratiions of electricc and magneticc fields. The fiigure—plane-p polarized wavee propagating from right to left. Fluctuattions in the eleectric field aree shown in a veertical plane, and the fluctuattions of the maagnetic field - in i the horizonttal. Fig. 2 The figure—planef -polarized wavve propagatingg from right to t left. Fluctuaations in the eelectric field are shown in a vertical planee, and the flucttuations of the magnetic field d—in the horizzontal. Magnetiic Isotope Th heory of the Origin O of Life on Earth Fig. 3 3033 The polarization p off electromagnettic waves. Fig. 4 Chan nging the direction of motion n of the electron ns as a function of the direction of o the magneticc field. The theorry has been unnable to offerr a solution too the problem of o accurate reproductioon—within the coacervate and the geenerations—ssingle, randoomly appeared efffective proteiin structures. However, it was shown thatt the first coacervatess were forrmed spontaneoussly from the liipid synthesizzed abiogeniccally, and they may m enter into i symbiossis with “livving solutions”— —colonies selff-replicating RNA molecuules, among whiich were thhe ribozymees catalyze the synthesis of lipids, and a community can c already caalled organism. The impettus for the devvelopment off the theory of the RNA worldd was the disscovery of riibozymes—R RNA molecules with w enzymattic activity, and a thereforee are ablee to combinee the functionns that these cells mostlyy opeerate separatelly proteins annd DNA, that is to catalyzee biocchemical reeactions and storage of geneticc info ormation. Thhus, it is assuumed that the first livingg creaatures were RNA-organis R sms without proteins andd DN NA, and theey could bee the protottype of thee auto ocatalytic cyycle formed by the very y ribozymess capable of catalyyzing the syntthesis of theirr own copies.. The T authors afffirm, in the ffollowing exp periment, it iss possible for the authors a to gett organic com mpounds. (1) In a 10 mL m test tubee for NMR spectroscopyy anaalysis is neceessary to pouur an aqueous solution off NaN NO3, KHCO O3, NaHPO O4, UO2(NO3)2. Changee mag gnetic spectrooscopy of the following op ptions: (a) thee tem mperature from m 20 to 300 °C; (b) X-raay irradiationn dose (from 5 min m to 60 m min); (c) conccentration off uran nium salts; (dd) pressure (11 to 150 atm (weld vial));; (e) the concentraation of d- annd f-elements.. Itt is possible to t flow the Eqq. (1): N 4H2PO4 + H NH HCOOH + NaCl + KJ + ATP P → NH2COO ONa (1)) (2 2) The waterr soluble inorrganic salts of Na, K, Mg,, Fe, Cu, and otheers. The authoors introducee the uranium m saltt solution. Thhen the solutiion was passed through a mix xture of gasess: CO2, CO, C CH4, H2 and N2. 304 Magnetic Isotope Theory of the Origin of Life on Earth It is possible to flow the Eq. (2): (2) nCO2 + nH2O + hv → n(C6H12O6) As a result of these experiments is necessary to pay attention to formation of an organic phase (NMR, IR and UV spectroscopy, etc.). 3. Conclusions The authors affirm that the total dependence on the factors influencing the emergence of life on Earth, is described by the equation: Life = f (T, P, E, B, R), where, T is temperature, P is pressure, E is electrical field, B is magnetic fields, R is radiation. Thus, the authors have proposed a new of magnetic isotope theory of life on Earth. According to this theory the initial impetus for the beginning of the synthesis of organic compounds is the impact of electromagnetic radiation from the sun and energy radioactive isotopes. References [1] [2] [3] [4] [5] [6] Lurquin, P. F. 2003. The Origins of Life and the Universe. Columbia University. Rauchfuss, H. 2008. “Chemical Evolution and the Origin of Life.” Springer 85-110. Mulkidjanian, A. Y., and Galperin, M. Y. 2009. 1. On the Origin of Life in the Zinc World. 2. Validation of the Hypothesis on the Photosynthesizing Zinc Sulfide Edifices as Cradles of Life on Earth. Biology Direct. Sugawara, T. 2011. “Self-Reproduction of Supramolecular Giant Vesicles Combined with the Amplification of Encapsulated DNA.” Nature Chemistry 1127. Pons, M. L. 2011. “Early Archean Serpentine Mud Volcanoes at Isua, Greenland, as a Niche for Early Life.” PNAS, Sept. 15. Crick, F. “Life Itself: Its Origin and Nature.” Simon and Schuster 1981: 192.
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