M/s. Veer Chemie & Aromatics (P) Ltd.
LIST OF CONTENTS
S.NO
DESCRIPTION
Enclosures
&
Annexures
PAGE NO
Enclosures
1
2
3
4
Copy of EC
Copy of CFO
TSDF Membership
Plant Lay out
Enclosure Enclosure Enclosure Enclosure -
1
2
3
4
5
6
7
8
9
Annexures
List Of Products
Manufacturing Process
Water Consumption Details
Waste water Details
Solid & Hazardous waste details
Stack Emission Details
Process Emission Details
List of Raw materials
Solvents Details
Annexure - I
Annexure - II
Annexure - III
Annexure - IV
Annexure - V
Annexure - VI
Annexure -VII
Annexure - VIII
Annexure - IX
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
1
2
3
4
1-4
1-6
1-4
1
2
3-46
47
48
49
50-51
52
53-57
58-59
Page 1
Enclosure - 1
Enclosure - 2
Enclosure - 3
Enclosure - 4
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M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - I
LIST OF EXISTING PRODUCTS
S. No
1
2
3
Product Name
Niacinamide
Niacin & its derivatives
Isoniazid
Quantity In
Kg/Month
25000.00
25000.00
6000.00
56000.00
Quantity In
Kg/Day
833.33
833.33
200.00
1866.67
LIST OF PROPOSED PRODUCTS
S. No
1
2
3
1
2
3
4
5
6
7
8
Product Name
Group-A
Isonicotinic acid
Nicotinic acid
Niacinamide
Total (Sum of any one or all products
Group-B
Benzyl Nicotinate
Ethyl Isonicotinate
Ethyl Nicotinate
Hexyl Nicotinate
Methyl Isonicotinic acid
Methyl Nicotinate
Methyl-6-Methyl Nicotinate
Myristyl nicotinate
Total (Sum of any one or all products
Total Sum of (Group-A + Group-B)
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity In
MT/Month
Quantity In
MT/Day
325.00
325.00
325.00
325.00
10.83
10.83
10.83
10.83
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
375.00
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
12.50
Page 2
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - II
Group - A
1. ISONICOTINIC ACID
Process Description
Stage-1
4-cyano pyridine is hydrolysed with Ammnoium hydroxide to yield Ammnoim salt of
Isonicotinic acid which on neutralisation with dilute sulphuric acid gives Isonicotinic
acid.
Prepared By
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Page 3
M/s. Veer Chemie & Aromatics (P) Ltd.
ISONICOTINIC ACID
Route of Synthesis
Stage-1
Step-A
N
N
+
CN
NaOH
+
Sodium Hydroxide
4-cyano-pyridine
C6H4N2
H2O
COONa
Sodium Nicotinate
C6H4NNaO2
18.0
40.00
NH3
+
17.0
145.09
104.11
Step-B
N
N
2
2
+
COONa
Sodium Nicotinate
C6H4NNaO2
Na2SO4
COOH
Sulphuric Acid
98.08
2X145.09=290.18
Prepared By
+
H2SO4
Rightsource Industrial Solutions Pvt. Ltd.,
Isonicotinic acid
C6H5NO2
2X123.11=246.22
Sodium Sulphate
142.04
Page 4
M/s. Veer Chemie & Aromatics (P) Ltd.
ISONICOTINIC ACID
Flow Chart
4-Cyanopyridine
Activated Carbon
Sodium hydroxide
SS REACTOR
(HYDROLYSIS)
SS P.F
Dil. Sulphuric Acid
Niacin for packing
Drying
Candle
Filter
SS Neutralizer
(Neutralization)
Centrifuging
HTDS Effluent
water
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 5
M/s. Veer Chemie & Aromatics (P) Ltd.
ISONICOTINIC ACID
Material Balance:
Name of the input
4-cyano pyridine
Activated carbon
Sodium hydroxide
Sulfuric acid
Water
Total
Prepared By
Material Balance of Isonicotinic Acid
Stage-1
Batch Size: 880.0Kgs
Quantity
Name of the out put
in Kg
Isonicotinic Acid
800.00
8.00
Effluent water
346.00
(Water-2826.7)
Spent
carbon
424.00
Inorganic solid waste
2965.00
(Sodium sulphate)
Process Emission
(Ammonia)
Organic solid waste
4543.00
Total
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
880.00
2826.70
8.00
614.04
130.63
83.63
4543.00
Page 6
M/s. Veer Chemie & Aromatics (P) Ltd.
2. NICOTINIC ACID
Process Description
Stage-1
3-Cyano pyridine is hydrolysed with sodium hydroxide to yield sodium salt of
nicotinate which on neutralisation with dilute sulphuric acid gives Nicotinic acid.
Prepared By
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Page 7
M/s. Veer Chemie & Aromatics (P) Ltd.
NICOTINIC ACID
Route of Synthesis
Stage-1
Step-A
N
N
+
CN
NaOH
+
Sodium Hydroxide
3-Cyano pyridine
C6H4N2
H2O
COONa
18.0
Sodium Nicotinate
C6H4NNaO2
40.00
104.11
145.09
+
NH3
17.0
Step-B
N
N
2
COONa
Sodium Nicotinate
C6H4NNaO2
+
H2SO4
COOH
Sulphuric Acid
Nicotinic acid
98.08
C6H5NO2
2X145.09=290.18
Prepared By
2
Rightsource Industrial Solutions Pvt. Ltd.,
+
Na2SO4
Sodium
Sulphate
142.04
2X123.11=246.22
Page 8
M/s. Veer Chemie & Aromatics (P) Ltd.
NICOTINIC ACID
Flow Chart
3-Cyanopyridine
Activated Carbon
Sodium hydroxide
SS REACTOR
(HYDROLYSIS)
SS P.F
Dil. Sulphuric Acid
Niacin for packing
Drying
Candle
Filter
SS Neutralizer
(Neutralization)
Centrifuging
HTDS Effluent
water
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 9
M/s. Veer Chemie & Aromatics (P) Ltd.
NICOTINIC ACID
Material Balance:
Name of the input
3-Cyano pyridine
Activated carbon
Sodium hydroxide
Sulphuric acid (98%)
Water
Total
Prepared By
Material Balance of Nicotinic Acid
Stage-1
Batch Size: 880.0Kgs
Quantity
Name of the out put
in Kg
Nicotinic Acid
800.00
8.00
Effluent water
346.00
(Water-2826.7,water from
Sulphuric acid-8.48)
Spent carbon
424.00
Inorganic solid waste
2965.00
(Sodium sulphate)
Process Emission
(Ammonia)
Organic solid waste
4543.00
Total
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
880.00
2835.18
8.00
614.04
130.63
75.15
4543.00
Page 10
M/s. Veer Chemie & Aromatics (P) Ltd.
3. NIACINAMIDE
Process Description:
Stage-1
3-Cyano pyridine undergoes hydrolysed with dilute sodium hydroxide to give
Niacinamide
Prepared By
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Page 11
M/s. Veer Chemie & Aromatics (P) Ltd.
NIACINAMIDE
Route of Synthesis:
Stage-1:
N
N
+
H2O
18.00
104.11
Prepared By
NH2
O
CN
3-Cyano pyridine
C6H4N2
C
Rightsource Industrial Solutions Pvt. Ltd.,
Niacinamide
C6H6N2O
122.13
Page 12
M/s. Veer Chemie & Aromatics (P) Ltd.
NIACINAMIDE
Flowchart:
3-Cyanopyridine
Activated Carbon
Sodium hydroxide
Sulphuric acid
SS REACTOR
(HYDROLYSIS)
S.S P.F
SS Candle
Filter
3-Cyanopyridine
Niacinamide for packing
DM water Wash
SS Crystallizer
(Crystallization)
Drying
Centrifuging
Wash water & ML
for recycle
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 13
M/s. Veer Chemie & Aromatics (P) Ltd.
NIACINAMIDE
Material Balance:
Name of the input
3-Cyano pyridine
Sodium hydroxide
Sulphuric acid
Activated carbon
Water
Total
Prepared By
Material Balance of Niacinamide
Stage-1
Batch Size: 1070.00
Quantity
Name of the out put
in Kg
Niacinamide
1000.00
Effluent water Recovered
14.00
for Recycle
17.00
(Water-954.8,Generated
water-6.23)
2.00
Spent carbon
1143.00
Inorganic Residue
(Sodium sulphate)
Process Emission
(Ammonia)
Niacin
2176.00
Total
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
1070.00
961.03
2.00
24.60
14.37
104.00
2176.00
Page 14
M/s. Veer Chemie & Aromatics (P) Ltd.
Group - B
1. BENZYL NICOTINATE
Process Description
Stage-1
Nicotinyl chloride hydrochloride reacts with benzyl alcohol in presence of Toluene
and the reaction mass is neutralised with liquor ammonia to liberate Benzyl
Nicotinate
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 15
M/s. Veer Chemie & Aromatics (P) Ltd.
BENZYL NICOTINATE
Route of Synthesis:
Stage-1:
Cl
HO
HCl
O
Toluene
+
+
N
Nicotinyl chloride Hydrochloride
C6H4ClNO.HCl
Benzyl alcohol
C7 H8 O
Ammonium hydroxide
2X35.05=70.10
108.14
178.02
O
2 NH4OH
O
+
N
Benzyl nicotinate
C13H11NO2
2NH4Cl
+
Ammonium chloride
2H2O
2X18=36.0
2X53.49=106.98
213.23
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 16
M/s. Veer Chemie & Aromatics (P) Ltd.
BENZYL NICOTINATE
Flow Chart
Nicotinyl chloride HCl
Liq.Ammonia
Benzyl Alcohol
Toluene
Organic Layer
Toluene for Recycle
SS Rector
GLR
Aq.Solution for
Ammonium
chloride recovery
Prepared By
SS Vacuum
Distillation Vessel
Pure Benzyl Nicotinate
Rightsource Industrial Solutions Pvt. Ltd.,
Page 17
M/s. Veer Chemie & Aromatics (P) Ltd.
BENZYL NICOTINATE
Material Balance:
Material Balance of Benzyl Nicotinate
Stage-1
Batch Size: 100.0 Kg’s
Name of the input
Quantity
Name of the out put
in Kg
Nicotinyl chloride
Benzyl Nicotinate
112.00
Hydrochloride
Benzyl alcohol
68.00
Toluene Recovery
Toluene
119.00
Toluene Loss
Methanol
234.00
Methanol Recovery
Nitric acid 60%
55.00
Methanol Loss
Ammonium hydroxide
166.00
Effluent water
(Water-840,Nitric acid-33,
Water from Nitric acid-22,
Water
840.00
Generated water-22.64,
Ammonium hydroxide-121.9,
Toluene-2,Methanol-2)
Inorganic solid waste
(Ammonium chloride)
Organic Solid waste
(Organic impurities-34.16,
Toluene-5,Methanol-5)
Total
1594.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
100.00
106.05
5.95
215.30
11.70
1043.54
67.30
44.16
1594.00
Page 18
M/s. Veer Chemie & Aromatics (P) Ltd.
2. ETHYL ISONICOTINATE
Process Description
Stage-1
Isonicotinic acid reacts with Ethyl alcohol in presence of Sulphuric acid as a catalyst
to give Ethyl Isonicotinate sulphate which one neutralisation with liquor ammonia
liberates Ethyl Isonicotinate which is extraction with Toluene. Toluene is distilled out
from the extract. The crude ester is subjected for vacuum distillation to give pure
Ethyl Isonicotinate.
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 19
M/s. Veer Chemie & Aromatics (P) Ltd.
ETHYL ISONICOTINATE
Route of Synthesis:
Stage-1:
CH3
HO
N
+
C2H5OH
O
Isonicotinic acid
C6H5NO2
123.11
Prepared By
Toluene
O
N
+
H2SO4
Ethanol
C2H6O
46.07
Rightsource Industrial Solutions Pvt. Ltd.,
H2O
O
Ethyl Isonicotinate
C8H9NO2
18.00
151.16
Page 20
M/s. Veer Chemie & Aromatics (P) Ltd.
ETHYL ISONICOTINIC ACID
Flow Chart
Ethanol
Liq.Ammonia
Toluene
H2SO4
Isonicotinic acid
G.L.R (Reactor)
Neutralisation
Toluene for Recycle
Distillation
Extractor (S.S)
Esterification
(S.S)
Vessel (S.S)
Aqueous solution for
ammonium sulphate
recovery
Deep Vacuum
Distillation Vessel
Pure Ethyl ester of
Isonicotinic acid
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 21
M/s. Veer Chemie & Aromatics (P) Ltd.
ETHYL ISONICOTINATE
Material Balance:
Material Balance of Ethyl Isonicotinate
Stage-1
Batch Size: 450.0 Kg’s
Name of the input
Quantity
Name of the out put
in Kg
Ethyl Isonicotinate
Isonicotinic acid
500.00
Ethanol
500.00
Toluene Recovery
Toluene
500.00
Toluene Loss
Sulphuric acid
700.00
Ethanol Recovery
Ammonia
238.00
Effluent water
Water
1190.00
(Water-1190,Generated
water-53.58,Toluene-2)
Inorganic solid waste
(Ammonium sulphate)
Isonicotinic acid Recovery
Organic Residue
(Organic impurities-14.74,
Toluene-5)
Total
3628.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
450.00
468.00
25.00
362.85
1245.58
923.33
133.50
19.74
3628.00
Page 22
M/s. Veer Chemie & Aromatics (P) Ltd.
3. ETHYL NICOTINATE
Process Description
Stage-1
Nicotinic acid reacts with Ethyl alcohol in presence of Sulphuric acid as a catalyst to
give Ethyl nicotinate sulphate which one neutralisation with liquor ammonia liberates
Ethyl nicotinate which is extraction with Toluene. Toluene is distilled out from the
extract. The crude ester is subjected for vacuum distillation to give pure Ethyl
Nicotinate.
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 23
M/s. Veer Chemie & Aromatics (P) Ltd.
ETHYL NICOTINATE
Route of Synthesis:
Stage-1:
C2H5O
HO
+
O
C2H5OH
N
Nicotinic acid
C6H5NO2
Ethanol
C2H6O
123.11
46.07
Prepared By
Toluene
H2SO4
Rightsource Industrial Solutions Pvt. Ltd.,
+
O
H2O
N
Ethyl Nicotinate
18.00
C8H9NO2
151.16
Page 24
M/s. Veer Chemie & Aromatics (P) Ltd.
ETHYL NICOTINATE
Flow Chart
Nicotinic Acid
Methanol
H2SO4
G.L.R
Esterification
Reactor
Liq.Ammonia
Neutralisation
(S.S)
Toluene
Extractor (S.S)
Aqueous Solution for
Ammonium Sulphate
recovery
Toluene for recycle
Distillation
Vessel
Deep Vacuum
Distillation
Cooling
Packing
Testing
Release
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 25
M/s. Veer Chemie & Aromatics (P) Ltd.
ETHYL NICOTINATE
Material Balance:
Material Balance of Ethyl nicotinate
Stage-1
Batch Size: 450.0 Kgs
Name of the input
Quantity
Name of the out put
in Kg
Ethyl nicotinate
Nicotinic acid
500.00
Ethanol
500.00
Toluene Recovery
Toluene
500.00
Toluene Loss
Sulphuric acid
700.00
Ethanol Recovery
Ammonia
238.00
Effluent water
Water
(Water-1190,Generated
1190.00
water-73.10,Toluene-2)
Inorganic solid waste
(Ammonium sulphate)
Nicotinic acid Recovery
Organic Residue
(Organic impurities-45.16,
Toluene-5)
Total
3628.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
450.00
468.00
25.00
312.89
1265.10
923.35
133.50
50.16
3628.00
Page 26
M/s. Veer Chemie & Aromatics (P) Ltd.
4. HEXYL NICOTINATE
Process Description
Stage-1
Nicotinyl chloride hydrochloride reacts with Hexyl alcohol in presence of Toluene and
the reaction mass is neutralised with liquor ammonia to liberate Hexyl Nicotinate
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 27
M/s. Veer Chemie & Aromatics (P) Ltd.
HEXYL NICOTINATE
Route of Synthesis:
Stage-1:
Cl
HCl
O
+
HO
CH3
2NH4OH
+
Toluene
N
Nicotinoyl chloride
Hexyl alcohol
Ammonium hydroxide
C6H4ClNO.HCl
C6H14O
2X35.05=70.10
178.02
102.17
O
O
CH3
+
N
2NH4Cl
Hexyl Nicotinate
Ammonium chloride
C12H17NO2
2X53.49=106.98
+
2H2O
2X18=36.0
207.27
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 28
M/s. Veer Chemie & Aromatics (P) Ltd.
HEXYL NICOTINATE
Flow Chart
Nicotinyl chloride HCl
Liq.Ammonia
Hexyl Alcohol
Toluene
Organic Layer
Toluene for Recycle
SS Rector
GLR
Aq.Solution for
Ammonium
chloride recovery
Prepared By
SS Vacuum
Distillation Vessel
Pure Hexyl Nicotinate
Rightsource Industrial Solutions Pvt. Ltd.,
Page 29
M/s. Veer Chemie & Aromatics (P) Ltd.
HEXYL NICOTINATE
Material Balance:
Material Balance of Hexyl Nicotinate
Stage-1
Batch Size: 100.0 Kgs
Name of the input
Quantity
Name of the out put
in Kg
Hexyl Nicotinate
Nicotinyl chloride
112.00
Hydrochloride
Toluene Recovery
Hexyl alcohol
60.00
Nitric acid60%
115.00
Toluene Loss
Ammonium hydroxide 20%
166.00
Methanol Recovery
Toluene
Methanol Loss
115.00
Methanol
225.00
Effluent water
Water
800.00
(Water-800,Generated water22.65,Nitric acid-69,water
from Nitric acid-46,Water from
Ammonium hyroxide-132.8,
Toluene-2,Methanol-1)
Inorganic Residue
(Ammonium chloride)
Organic Solid waste
(Organic impurities-31.88,
Toluene-7,Methanol-2)
Total
1593.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
100.00
100.25
5.75
210.75
11.25
1073.45
50.67
40.88
1593.00
Page 30
M/s. Veer Chemie & Aromatics (P) Ltd.
5. METHYL ISONICOTINIC ACID
Process Description
Stage-1:
Isonicotinic acid undergoes esterification with Methanol in presence of Sulphuric acid
neutralisation with Liquor ammonia and extraction with Toluene .Toluene is distilled
off to obtain crude ester which on vacuum distillation pure product is obtained
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 31
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL ISONICOTINIC ACID
Route of Synthesis:
Stage-1:
H 3C
HO
Toluene
N
+
CH3OH
O
Isonicotinic acid
Methanol
C6H5NO2
32.04
+
N
H2SO4
H2O
O
Methyl Isonicotinate
C7H7NO2
18.00
137.14
123.11
Prepared By
O
Rightsource Industrial Solutions Pvt. Ltd.,
Page 32
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL ISONICOTINIC ACID
Flow Chart
Methanol
Liq.Ammonia
Toluene
H2SO4
Isonicotinic acid
G.L.R (Reactor)
Neutralisation
Toluene for Recycle
Distillation
Extractor (S.S)
Esterification
(S.S)
Vessel (S.S)
Aqueous solution for
ammonium sulphate
recovery
Deep Vacuum
Distillation Vessel
Pure Ethyl ester of
Isonicotinic acid
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 33
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL ISONICOTINIC ACID
Material Balance:
Material Balance of Methyl Isonicotinic acid
Stage-1
Batch Size: 450.0 Kg’s
Name of the input
Quantity
Name of the out put
in Kg
Methyl Isonicotinic acid
Isonicotinic acid
500.00
Methanol
500.00
Methanol Recovery
Sulphuric acid
700.00
Methanol Loss
Ammonia
238.00
Toluene Recovery
Toluene
500.00
Toluene Loss
Water
1190.00
Isonicotinic acid Recovery
Effluent water
(Water-1190,Generated
water-59.06,Toluene-2,
Methanol-1)
Inorganic Solid waste
(Ammonium sulphate)
Organic Residue
(Organic impurities-18.59
Methanol-4,Toluene-10)
Total
3628.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
450.00
370.25
19.75
463.00
25.00
96.00
1252.06
923.35
28.59
3628.00
Page 34
M/s. Veer Chemie & Aromatics (P) Ltd.
6. METHYL NICOTINATE
Process Description
Stage-1
Nicotinic acid undergoes etherification with Methanol in presence of Sulphuric acid
neutralisation with Liquor ammonia and extraction with toluene .Toluene is distilled
off to obtain crude ester which on vacuum distillation pure product is obtained
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 35
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL NICOTINATE
Route of Synthesis:
Stage-1:
HO
+
O
CH3OH
N
Nicotinic acid
C6H5NO2
Toluene
H3CO
H2SO4
O
H 2O
N
Methanol
Methyl Nicotinate
32.04
C7H7NO2
18.00
137.14
123.11
Prepared By
+
Rightsource Industrial Solutions Pvt. Ltd.,
Page 36
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL NICOTINATE
Flow Chart
Nicotinic Acid
Methanol
H2SO4
G.L.R
Esterification
Reactor
Liq.Ammonia
Neutralisation
(S.S)
Toluene
Extractor (S.S)
Aqueous Solution for
Ammonium Sulphate
recovery
Toluene for recycle
Distillation
Vessel
Deep Vacuum
Distillation
Cooling
Packing
Testing
Release
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 37
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL NICOTINATE
Material Balance:
Material Balance of Methyl Nicotinate
Stage-1
Batch Size: 450.0 Kgs
Name of the input
Quantity
Name of the out put
in Kg
Methyl Nicotinate
Nicotinic acid
500.00
Methanol
500.00
Methanol Recovery
Sulphuric acid
700.00
Methanol Loss
Ammonia
238.00
Toluene Recovery
Toluene
500.00
Toluene Loss
Water
1190.00
Effluent water
(Water-1190,Generated
water-59.06,Toluene2,Methanol-2)
Nicotinic acid Recovery
Inorganic Residue
(Ammonium sulphate)
Organic Residue
(Organic impurities-39.59,
Toluene-10,Methanol-2)
Total
3628.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
450.00
347.50
18.50
463.00
25.00
1253.06
96.00
923.35
51.59
3628.00
Page 38
M/s. Veer Chemie & Aromatics (P) Ltd.
7. METHYL-6-METHYL NICOTINATE
Process Description
Stage-1
6-methyl nicotinic acid sulphate undergoes esterification in presence of Methanol
followed by neutralization in with Ammonium hydroxide and extraction with
Chloroform. Crude ester is obtained after distilled off Chloroform which on Vacuum
distillation pure product is obtained.
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 39
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL-6-METHYL NICOTINATE
Route of Synthesis:
Stage-1:
H3C
N
H2SO4
COOH
+
6-Methyl Nicotinic acid sulfate
CH3OH
Methanol
32.04
C7H9NO6S
2 NH4OH
+
Methanol
Ammonium hydroxide
2X35.05=70.10
235.21
H3 C
N
COOCH3
Methyl-6-Methyl Nicotinate
C8H9NO2
+
(NH4)2SO4
Ammonium sulphate
+
3 H2O
54.00
132.14
151.16
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 40
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL-6-METHYL NICOTINATE
Flow Chart
6-Methyl Nicotinic acid sulphate
Esterification
Neutralisation
Extraction
Purification
Packing
Pure Methyl 6-Methyl Nicotinate
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 41
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL-6-METHYL NICOTINATE
Material Balance:
Material Balance of Methyl-6-Methyl Nicotinate
Stage-1
Batch Size: 214.0Kg’s
Name of the input
Quantity
Name of the out put
in Kg
6-Methyl Nicotinic acid
Methyl-6-Methyl Nicotinate
975.00
Sulphate in sulphuric acid
Methanol
870.00
Methanol Recovery
Chloroform
975.00
Methanol Loss
Chloroform Recovery
Sulphuric acid
180.00
Chloroform Loss
Ammonium hydroxide 20%
1600.00
Effluent water
Water
1000.00
(Water-1000,Generated
water-223.84,Water from
Ammonium hydroxide1280,Methanol-2)
Inorganic Residue
(Ammonium sulphate)
Organic Residue
(Organic impurities-687.96,
Methanol-3)
Total
5600.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
214.00
580.20
30.80
926.25
48.75
2505.84
603.20
690.96
5600.00
Page 42
M/s. Veer Chemie & Aromatics (P) Ltd.
8. MYRISTYL NICOTINATE
Process Description
Stage-1
Nicotinyl chloride hydrochloride reacts with Myristyl alcohol in presence of Toluene
and the reaction mass is neutralised with liquor ammonia to liberate Myristyl
Nicotinate
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 43
M/s. Veer Chemie & Aromatics (P) Ltd.
MYRISTYL NICOTINATE
Route of Synthesis:
Stage-1:
Cl
HCl
O
+
HO
CH3
+
2NH4OH
Toluene
N
C6H4ClNO.HCl
2X35.05=70.10
214.39
178.02
CH3
O
O
Ammonium hydroxide
Myristyl alcohol
C14H30O
Nicotinoyl chloride Hydrochloride
+
N
Myristyl Nicotinate
C20H33NO2
2NH4Cl
Ammonium chloride
2X53.49=106.98
+
2H2O
2X18=36.0
319.48
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 44
M/s. Veer Chemie & Aromatics (P) Ltd.
MYRISTYL NICOTINATE
Flow Chart
Nicotinyl chloride HCl
Liq.Ammonia
Myristyl Alcohol
Toluene
Organic Layer
Toluene for Recycle
SS Rector
GLR
Aq.Solution for
Ammonium
chloride recovery
Prepared By
SS Vacuum
Distillation Vessel
Pure Myristyl Nicotinate
Rightsource Industrial Solutions Pvt. Ltd.,
Page 45
M/s. Veer Chemie & Aromatics (P) Ltd.
MYRISTYL NICOTINATE
Material Balance:
Material Balance of Myristyl Nicotinate
Stage-1
Batch Size: 150.0 Kgs
Name of the input
Quantity
Name of the out put
in Kg
Nicotinyl chloride
Myristyl Nicotinate
112.00
Hydrochloride
Myristyl alcohol
136.00
Toluene Recovery
Nitric acid 60%
55.00
Toluene Loss
Ammonium hydroxide20%
166.00
Methanol Recovery
Toluene
125.00
Methanol Loss
Methanol
250.00
Effluent water
Water
850.00
(Water-850,Generated water22.65,Nitric acid-33,Water
from Nitric acid-22,Water
from Ammonium hydroxide132.8)
Inorganic Residue
(Ammonium chloride)
Organic Residue
(Organic impurities-57.88,
Toluene-10,Methanol-10)
Total
1694.00
Total
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Quantity
in Kg
150.00
108.75
6.25
227.50
12.50
1060.45
50.67
77.88
1694.00
Page 46
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - III
WATER CONSUMPTION DETAILS
S. No.
1
2
3
4
5
6
Prepared By
Purpose
Process & washings-50.5 +DM water
Regeneration-5.05
Boiler make up
Cooling tower make up
Domestic
Scrubbing system
Gardening
Total
Rightsource Industrial Solutions Pvt. Ltd.,
Water Input
In KLD
55.55
12.00
64.00
5.00
6.00
5.00
147.55
Page 47
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - IV
WASTE WATER DETAILS
S. No
Purpose
1
Process & washings-72.31 + DM water
Regeneration-5.05
Boiler Blow down
Cooling tower Blow down
Domestic
Scrubbing system
Total
2
3
4
5
Effluent In KLD
77.36
2.00
13.00
4.00
6.00
102.36
HTDS & LTDS DETAILS
S. No
Purpose
1
Process &
Washings-(72.31)
+DM water
regeneration-(5.05)
Boiler Blow down
Cooling towers
Blow down
Scrubbing system
Domestic
2
3
4
5
Total
Prepared By
HTDS
In KLD
22.94
2.00
13.00
6.00
0.00
43.94
LTDS
Effluent
Disposal Method
In KLD
In KLD
54.42
77.36 HTDS Effluent sent to
ETP with MEE system.
LTDS effluents treated in
ETP-RO Rejects to MEE
0.00
2.00 system and RO permeate
0.00
13.00 to reuse, Condensate
from MEE to reuse and
0.00
6.00 MEE residue to AFTD.
4.00
4.00 Septic tank followed by
Soak pit
58.42
102.36
Rightsource Industrial Solutions Pvt. Ltd.,
Page 48
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - V
SOLID WASTE DETAILS
S. No
Description
1
2
3
4
5
6
Organic Solid Waste
Inorganic solid waste
Spent Carbon
ETP Sludge
MEE salts
Solvent distillation Residue
Quantity
In
Kg/Day
6306.00
12257.00
98.00
200.00
2872.00
204.00
Method Of Disposal
Sent to Cement Industries
Sent to TSDF
Sent to Cement Industries
Sent to TSDF
Sent to TSDF
Sent to Cement Industries
HAZARDOUS WASTE DETAILS
S. No
Description
1
Waste Oils & Grease
2
Detoxified Containers
3
Used Lead Acid
Batteries
Prepared By
Quantity
Mode of Disposal
1000
Ltrs/Annum
500No’s/Month
SPPCB Authorized Agencies for
Reprocessing/Recycling
After Detoxification sent back to
suppliers/SPPCB Authorized Parties
Send back to suppliers for buyback
of New Batteries
10No’s/Year
Rightsource Industrial Solutions Pvt. Ltd.,
Page 49
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - VI
STACK EMISSION DETAILS FOR BOILER
Particulars
Type of Fuel
Coal Consumption
Ash Content
Sulphur Content
Nitrogen Content
No. of Stacks
Height of stack
Diameter of Stack
Temperature of Flue Gas
Velocity of Flue Gas
Particulate Matter at outlet of Bag
filter (Based on 115 mg/Nm3 at
outlet)
Sulphur dioxide emission
Oxides of Nitrogen emission
Units
2.0 TPH Coal
fired Boiler
-TPD
%
%
%
No
M
M
o
C
m/s
gm/sec
Indian Coal
5.0
47
0.8
1.07
1
32
0.60
95
6.5
0.21
gm/sec
gm/sec
0.46
0.57
STACK EMISSIONS FOR THERMOPACK BOILER
Particulars
Thermo pack Boiler Capacity
Type of Fuel
Stack Temperature Before
Air preheater
Stack
Temperature
After
preheater
Combination Air Temperature
Efficiency Increased By
Stack Height
Fuel Consumption per Day
Prepared By
Units
Kcal/hr.
-o
C
Air
2,00,000 kcal/hr.
Thermo pack Boiler
2,00,000
Coal
350
o
150
o
110
5.0
13.56
0.43
C
C
%
m
TPD
Rightsource Industrial Solutions Pvt. Ltd.,
Page 50
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - VI
STACK EMISSION DETAILS FOR D.G.SETS
Capacity
In KVA
Emission
of SPM in
Mg/Nm3
125 KVA
(Existing)
62.5 KVA
(Existing)
200 KVA
(Proposed)
Prepared By
60.0
Emission Emission
Of SO2 in
of NOx
3
Mg/Nm
in
Mg/Nm3
85.0
110.0
Stack
dia.
In m
Flue Gas
Temp. in
O
C
Stack
Height
in (m)
Flue gas
Velocity
In m/sec.
0.30
290
10
16.10
26.0
13.0
17.0
0.10
80
5
3.75
65.0
110.0
135.0
0.30
220
10
18.50
Rightsource Industrial Solutions Pvt. Ltd.,
Page 51
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - VII
PROCESS EMISSION DETAILS
S. No
1
Name of the Gas
Ammonia
Prepared By
Quantity
Treatment Method
In
Kg/Day
3362.00 Scrubbed by using chilled water media
Rightsource Industrial Solutions Pvt. Ltd.,
Page 52
M/s. Veer Chemie & Aromatics (P) Ltd.
Annexure - VIII
Group-A
ISONICOTINIC ACID
LIST OF RAW MATERIALS
S.No.
1
2
3
4
Raw Material
4-Isocyano pyridine
Activated carbon
Sodium hydroxide
Sulfuric acid
Used in
Kg’s/Month
800.00
8.00
346.00
424.00
Used in
Kg’s/Day
9848.53
98.49
4259.49
5219.72
NICOTINIC ACID
LIST OF RAW MATERIALS
S.No.
1
2
3
4
Raw Material
3-Cyano pyridine
Activated carbon
Sodium hydroxide
Sulfuric acid (98%)
Prepared By
Used in
Kg’s/Month
800.00
8.00
346.00
424.00
Rightsource Industrial Solutions Pvt. Ltd.,
Used in
Kg’s/Day
9848.53
98.49
4259.49
5219.72
Page 53
M/s. Veer Chemie & Aromatics (P) Ltd.
NIACINAMIDE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
Raw Material
3-Cyano pyridine
Sodium hydroxide
Sulphuric acid
Activated carbon
Used in
Kg’s/Month
1000.00
14.00
17.00
2.00
Used in
Kg’s/Day
10124.67
141.75
172.12
20.25
Group-B
BENZYL NICOTINATE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
6
Raw Material
Nicotinyl chloride Hydrochloride
Benzyl alcohol
Toluene
Methanol
Nitric acid 60%
Ammonium hydroxide
Prepared By
Used in
Kg’s/Month
112.00
68.00
119.00
234.00
55.00
166.00
Rightsource Industrial Solutions Pvt. Ltd.,
Used in
Kg’s/Day
1866.67
1133.33
1983.33
3900.00
916.67
2766.67
Page 54
M/s. Veer Chemie & Aromatics (P) Ltd.
ETHYL ISONICOTINATE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
Raw Material
Isonicotinic acid
Ethanol
Toluene
Sulphuric acid
Sodium hydroxide
Used in
Kg’s/Month
500.00
500.00
500.00
700.00
560.00
Used in
Kg’s/Day
1851.83
1851.83
1851.83
2592.57
2074.05
ETHYL NICOTINATE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
Raw Material
Nicotinic acid
Ethanol
Toluene
Sulphuric acid
Sodium hydroxide
Used in
Kg’s/Month
500.00
500.00
500.00
700.00
560.00
Used in
Kg’s/Day
1851.83
1851.83
1851.83
2592.57
2074.05
HEXYL NICOTINATE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
7
Raw Material
Nicotinyl chloride Hydrochloride
Hexyl alcohol
Nitric acid60%
Ammonium hydroxide 20%
Toluene
Methanol
Prepared By
Used in
Kg’s/Month
112.00
60.00
115.00
166.00
115.00
225.00
Rightsource Industrial Solutions Pvt. Ltd.,
Used in
Kg’s/Day
1866.67
1000.00
1916.67
2766.67
1916.67
3750.00
Page 55
M/s. Veer Chemie & Aromatics (P) Ltd.
METHYL ISONICOTINIC ACID
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
Raw Material
Isonicotinic acid
Methanol
Sulphuric acid
Sodium hydroxide
Toluene
Used in
Kg’s/Month
500.00
500.00
700.00
560.00
500.00
Used in
Kg’s/Day
1851.83
1851.83
2592.57
2074.05
1851.83
METHYL NICOTINATE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
Raw Material
Nicotinic acid
Methanol
Sulphuric acid
Sodium hydroxide
Toluene
Used in
Kg’s/Month
500.00
500.00
700.00
560.00
500.00
Used in
Kg’s/Day
1851.83
1851.83
2592.57
2074.05
1851.83
METHYL-6-METHYL NICOTINATE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
Raw Material
6-Methyl Nicotinic acid Sulphate in
sulphuric acid
Methanol
Chloroform
Sulphuric acid
Ammonium hydroxide 20%
Prepared By
Used in
Kg’s/Month
975.00
Used in
Kg’s/Day
7593.30
870.00
975.00
180.00
1600.00
6775.56
7593.30
1401.84
12460.80
Rightsource Industrial Solutions Pvt. Ltd.,
Page 56
M/s. Veer Chemie & Aromatics (P) Ltd.
MYRISTYL NICOTINATE
LIST OF RAW MATERIALS
S.No.
1
2
3
4
5
6
Raw Material
Nicotinyl chloride Hydrochloride
Myristyl alcohol
Nitric acid 60%
Ammonium hydroxide20%
Toluene
Methanol
Prepared By
Used in
Kg’s/Month
112.00
136.00
55.00
166.00
125.00
250.00
Rightsource Industrial Solutions Pvt. Ltd.,
Used in
Kg’s/Day
1244.43
1511.10
611.11
1844.43
1388.88
2777.75
Page 57
M/s. Veer Chemie & Aromatics (P) Ltd.
Solvents Details
Annexure - IX
Quantity in Kgs/Day
S. No
Product Name
Production
Kgs/Day
Solvent
Name
1
Isonicotinic acid
Total
10833.33
Group-A
No
2
Nicotinic acid
Total
10833.33
3
Niacinamide
Total
10833.33
4
Benzyl Nicotinate
Solvent
Input
Solvent
Recovery
Solvent
Loss
Solvent
to
waste
water
Solvent
to
Residue
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
No
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
No
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3900.00
1983.33
5883.33
3588.33
1767.50
5355.83
195.00
99.17
294.17
33.33
33.33
66.67
83.33
83.33
166.67
1666.67
Group-B
Methanol
Toluene
Total
5
Ethyl isonicotinate
Total
1666.67
Toluene
1851.85
1851.85
1733.33
1733.33
92.59
92.59
7.41
7.41
18.52
18.52
6
Ethyl nicotinate
Total
1666.67
Toluene
1851.85
1851.85
1733.33
1733.33
92.59
92.59
7.41
7.41
18.52
18.52
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 58
M/s. Veer Chemie & Aromatics (P) Ltd.
7
Hexyl Nicotinate
1666.67
Methanol
Toluene
3750.00
1916.67
5666.67
3512.50
1670.83
5183.33
187.50
95.83
283.33
16.67
33.33
50.00
33.33
116.67
150.00
1666.67
Methanol
Toluene
1851.85
1851.83
3703.69
1371.30
1714.80
3086.09
73.15
92.59
165.74
3.70
7.41
11.11
14.81
37.04
51.85
1666.67
Methanol
Toluene
1851.85
1851.83
3703.69
1287.04
1714.80
3001.83
68.52
92.59
161.11
7.41
7.41
14.81
7.41
37.04
44.44
1666.67
Methanol
Chloroform
6775.70
7593.30
14369.00
4518.69
7213.64
11732.33
234.27
379.67
613.93
15.58
0.00
15.58
23.36
0.00
23.36
Myristyl Nicotinate
1666.67
Methanol
Toluene
Total
Solvents Grand Total of all
products
12500.00
2777.78
1388.88
4166.65
2527.78
1208.32
3736.10
138.89
69.44
208.33
0.00
0.00
0.00
111.11
111.11
222.22
9587.04
8822.50
479.35
81.48
203.70
Total
8
Methyl Isonicotinic acid
Total
9
Methyl Nicotinate
Total
10
Methyl-6-Methyl Nicotinate
Total
11
Prepared By
Rightsource Industrial Solutions Pvt. Ltd.,
Page 59