Safety Data Sheet Revision Date: 11/22/16 www.restek.com 1. IDENTIFICATION Catalog Number / Product Name: Company: Address: Phone#: Fax#: Emergency#: Email: Revision Number: Intended use: 30726 / DHA Isoparaffins Standard Restek Corporation 110 Benner Circle Bellefonte, Pa. 16823 814-353-1300 814-353-1309 800-424-9300 (CHEMTREC) 703-527-3887 (Outside the US) www.restek.com 2 For Laboratory use only 2. HAZARD(S)IDENTIFICATION Emergency Overview: GHS Hazard Symbols: GHS Classification: Aspiration Hazard Category 1 Flammable Liquid Category 2 Skin Corrosion/Irritation Category 2 Hazardous to the aquatic environment - Chronic Category 2 Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 3 GHS Signal Word: GHS Hazard: Danger Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects. GHS Precautions: Safety Precautions: Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilation and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash hands and skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. First Aid Measures: IF SWALLOWED: Immediately call a POISON CENTER/doctor/.... IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment see section 4. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. 30726 / DHA Isoparaffins Standard Page 1 of 8 In case of fire: Use extinguishing media in section 5 for extinction. Collect spillage. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/container according to section 13 of the SDS. Single No data available. Exposure Target Organs: Repeated No data available. Exposure Target Organs: 3. COMPOSITION / INFORMATION ON INGREDIENT Chemical Name CAS # EINEC # % Composition 3-methylpentane 96-14-0 202-481-4 10.517000 3-methyloctane 2216-33-3 218-686-7 6.995000 2-methylpentane 107-83-5 203-523-4 6.377000 2,4-dimethylpentane 108-08-7 203-548-0 5.931000 3-methylheptane 589-81-1 209-660-6 5.909000 2,5-dimethylhexane 592-13-2 209-745-8 5.854000 3-Methylnonane 5911-04-6 227-631-6 5.272000 2-methylheptane 592-27-8 209-747-9 4.731000 2-methylhexane 591-76-4 209-730-6 4.689000 2,3-dimethylpentane 565-59-3 209-280-0 4.668000 2,5-Dimethylheptane 2216-30-0 2,2,3-trimethylpentane 564-02-3 209-266-4 3.673000 2,2-dimethylpentane 590-35-2 209-680-5 2.438000 3-methylhexane 589-34-4 209-643-3 2.374000 2,3-dimethylbutane 79-29-8 201-193-6 2.352000 3,5-Dimethylheptane 926-82-9 3,3-dimethylpentane 562-49-2 Octane, 2,2-dimethyl- 15869-87-1 2.095000 3,3-Diethylpentane 1067-20-5 1.914000 3,3-Dimethylheptane 4032-86-4 isopentane 78-78-4 201-142-8 1.599000 2-Methylnonane 871-83-0 212-814-5 1.582000 4-Methylheptane 589-53-7 209-650-1 1.508000 2,4-dimethylhexane 589-43-5 209-649-6 1.454000 2-methyloctane 3221-61-2 221-748-6 1.289000 2,3-dimethylheptane 3074-71-3 3-Ethyloctane 5881-17-4 3-Ethylpentane 617-78-7 3,4-Dimethylheptane 922-28-1 0.839000 Octane, 3,3-dimethyl- 4110-44-5 0.804000 2,2-dimethylhexane 590-73-8 209-689-4 0.786000 2,2,3-trimethylbutane 464-06-2 207-346-3 0.660000 3-Ethylhexane 619-99-8 210-621-0 0.307000 3.860000 2.344000 209-230-8 2.305000 1.765000 1.160000 1.068000 210-529-0 0.882000 4. FIRST-AID MEASURES 30726 / DHA Isoparaffins Standard Page 2 of 8 Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention. Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. No data. Eyes: Skin Contact: Ingestion: 5. FIRE- FIGHTING MEASURES Extinguishing Media: Fire and/or Explosion Hazards: Fire Fighting Methods and Protection: Hazardous Combustion Products: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire. Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back Do not enter fire area without proper protection including self-contained toxic breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Use water spray/fog for cooling. Carbon dioxide, Carbon monoxide 6. ACCIDENTAL RELEASE MEASURES Personal Precautions and Equipment: Methods for Clean-up: Exposure to the spilled material may be severely irritating or toxic. Follow personal protective equipment recommendations found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred, and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. 7. HANDLING AND STORAGE Handling Technical Measures and Precautions: Storage Technical Measures and Conditions: Toxic or severely irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Keep away from sources of ignition 8. EXPOSURE CONTROLS / PERSONAL PROTECTION United States: Chemical Name CAS No. IDLH ACGIH STEL ACGIH TLV-TWA 3-methylpentane 96-14-0 ND 1000 ppm STEL (listed under Hexane isomers other than nhexane) 500 ppm TWA (listed under Hexane isomers other than n-hexane) 3-methyloctane 2-methylpentane 2216-33-3 107-83-5 ND ND 30726 / DHA Isoparaffins Standard 1000 ppm STEL (listed under Hexane isomers other No TLV 500 ppm TWA (listed under Hexane isomers other than n-hexane) OSHA Exposure Limit No data available. No data available. No data available. Page 3 of 8 2,4-dimethylpentane 108-08-7 ND 3-methylheptane 2,5-dimethylhexane 3-Methylnonane 2-methylheptane 2-methylhexane 589-81-1 592-13-2 5911-04-6 592-27-8 591-76-4 ND ND ND ND ND 2,3-dimethylpentane 565-59-3 ND 2,5-Dimethylheptane 2,2,3trimethylpentane 2,2-dimethylpentane 2216-30-0 564-02-3 ND ND 590-35-2 ND 3-methylhexane 589-34-4 ND 2,3-dimethylbutane 79-29-8 ND 3,5-Dimethylheptane 3,3-dimethylpentane Octane, 2,2-dimethyl3,3-Diethylpentane 3,3-Dimethylheptane isopentane 926-82-9 562-49-2 15869-87-1 1067-20-5 4032-86-4 78-78-4 ND ND ND ND ND ND 2-Methylnonane 4-Methylheptane 2,4-dimethylhexane 2-methyloctane 2,3-dimethylheptane 3-Ethyloctane 3-Ethylpentane 3,4-Dimethylheptane Octane, 3,3-dimethyl2,2-dimethylhexane 2,2,3-trimethylbutane 3-Ethylhexane 871-83-0 589-53-7 589-43-5 3221-61-2 3074-71-3 5881-17-4 617-78-7 922-28-1 4110-44-5 590-73-8 464-06-2 619-99-8 ND ND ND ND ND ND ND ND ND ND ND ND Personal Protection: Engineering Measures: Respiratory Protection: 30726 / DHA Isoparaffins Standard than nhexane) 500 ppm STEL (listed under Heptane, all isomers) 500 ppm STEL (listed under Heptane, all isomers) 500 ppm STEL (listed under Heptane, all isomers) 500 ppm STEL (listed under Heptane, all isomers) 500 ppm STEL (listed under Heptane, all isomers) 1000 ppm STEL (listed under Hexane isomers other than nhexane) 400 ppm TWA (listed under Heptane, all isomers) No data available. No TLV No TLV No TLV No TLV 400 ppm TWA (listed under Heptane, all isomers) No data available. No data available. No data available. No data available. No data available. 400 ppm TWA (listed under Heptane, all isomers) No data available. No TLV No TLV No data available. No data available. 400 ppm TWA (listed under Heptane, all isomers) No data available. 400 ppm TWA (listed under Heptane, all isomers) No data available. 500 ppm TWA (listed under Hexane isomers other than n-hexane) No data available. No TLV No TLV No TLV No TLV No TLV 600 ppm TWA (listed under Pentane, all isomers) No TLV No TLV No TLV No TLV No TLV No TLV No TLV No TLV No TLV No TLV No TLV No TLV No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. No data available. Local exhaust ventilation is recommended when generating excessive levels of vapors from handling or thermal processing. Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to Page 4 of 8 eliminate symptoms. Wear chemically resistant safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material. Do not wear contact lenses. Have an eye wash station available. Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Eye Protection: Skin Protection: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance, color: Odor: Physical State: pH: Vapor Pressure: Boiling Point: Flash Point: Flammability: Upper Flammable/Explosive Limit, % in air: Lower Flammable/Explosive Limit, % in air: Autoignition Temperature: Decomposition Temperature: Evaporation Rate: Odor Threshold: Solubility: Partition Coefficient: n-octanol in water: VOC % by weight: Molecular Weight: No data available. None No data available. No data available. No data available. No data available. -60 Extremely Flammable No data available. No data available. No data available. deg C No data available. No data available. No data available. Not determined No data available. 0 No data available. 10. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Materials to Avoid / Chemical Incompatiability: Hazardous Decomposition Products: Stable under normal conditions. No data available. Strong oxidizing agents No data available. 11. TOXICOLOGICAL INFORMATION Routes of Entry: Inhalation, Skin Contact, Eye Contact, Ingestion Target Organs Potentially Affected By Exposure: No data available. Chemical Interactions That Change Toxicity: None Known Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. Skin Contact: Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Eye Contact: Contact with the eyes may cause moderate to severe eye injury. Eye contact may result in tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Ingestion Irritation: May be harmful if swallowed. Long-Term (Chronic) Health Effects: Carcinogenicity: Reproductive and Developmental Toxicity: Inhalation: Skin Contact: No data. No data available to indicate product or any components present at greater than 0.1% may cause birth defects. Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Component Toxicological Data: NIOSH: 30726 / DHA Isoparaffins Standard Page 5 of 8 Chemical Name No data available. CAS No. Component Carcinogenic Data: OSHA: Chemical Name No data available. CAS No. ACGIH: Chemical Name No data available. CAS No. NIOSH: Chemical Name No data available. CAS No. NTP: Chemical Name No data available. CAS No. IARC: Chemical Name No data. No data. No data. LD50/LC50 CAS No. Group No. Group 1 Group 2A Group 2B 12. ECOLOGICAL INFORMATION Overview: Mobility: Persistence: Bioaccumulation: Degradability: Ecological Toxicity Data: This material is not expected to be harmful to the ecology. No data No data No data No data No data available. 13. DISPOSAL CONSIDERATIONS Waste Description of Spent Product: Disposal Methods: Waste Disposal of Packaging: Spent or discarded material is a hazardous waste. Dispose of by incineration following Federal, State, Local, or Provincial regulations. Comply with all Local, State, Federal, and Provincial Environmental Regulations. 14. TRANSPORTATION INFORMATION United States: DOT Proper Shipping Name: Flammable liquids, n.o.s. (3-Methylpentane, 3Methyloctane) UN1993 3 II UN Number: Hazard Class: Packing Group: International: IATA Proper Shipping Name: Flammable liquids, n.o.s. (3-Methylpentane, 3Methyloctane) UN1993 3 II UN Number: Hazard Class: Packing Group: Marine Pollutant: No Chemical Name CAS# Marine Pollutant Severe Marine Pollutant No data available. 15. REGULATORY INFORMATION United States: 30726 / DHA Isoparaffins Standard Page 6 of 8 Chemical Name CAS# CERCLA SARA 313 3-methylpentane 3-methyloctane 2-methylpentane 2,4-dimethylpentane 3-methylheptane 2,5-dimethylhexane 3-Methylnonane 2-methylheptane 2-methylhexane 2,3-dimethylpentane 2,5-Dimethylheptane 2,2,3-trimethylpentane 2,2-dimethylpentane 3-methylhexane 2,3-dimethylbutane 3,5-Dimethylheptane 3,3-dimethylpentane Octane, 2,2-dimethyl3,3-Diethylpentane 3,3-Dimethylheptane isopentane 2-Methylnonane 4-Methylheptane 2,4-dimethylhexane 2-methyloctane 2,3-dimethylheptane 3-Ethyloctane 3-Ethylpentane 3,4-Dimethylheptane Octane, 3,3-dimethyl2,2-dimethylhexane 2,2,3-trimethylbutane 3-Ethylhexane 96-14-0 2216-33-3 107-83-5 108-08-7 589-81-1 592-13-2 5911-04-6 592-27-8 591-76-4 565-59-3 2216-30-0 564-02-3 590-35-2 589-34-4 79-29-8 926-82-9 562-49-2 15869-87-1 1067-20-5 4032-86-4 78-78-4 871-83-0 589-53-7 589-43-5 3221-61-2 3074-71-3 5881-17-4 617-78-7 922-28-1 4110-44-5 590-73-8 464-06-2 619-99-8 - - The following chemicals are listed on CA Prop 65: Chemical Name CAS # State Right To Know Listing: Chemical Name CAS# 3-methylpentane 96-14-0 3-methyloctane 2216-33-3 2-methylpentane 107-83-5 2,4-dimethylpentane 108-08-7 3-methylheptane 589-81-1 2,5-dimethylhexane 592-13-2 3-Methylnonane 5911-04-6 2-methylheptane 592-27-8 2-methylhexane 591-76-4 2,3-dimethylpentane 565-59-3 2,5-Dimethylheptane 2216-30-0 2,2,3-trimethylpentane 564-02-3 2,2-dimethylpentane 590-35-2 3-methylhexane 589-34-4 2,3-dimethylbutane 79-29-8 3,5-Dimethylheptane 926-82-9 3,3-dimethylpentane 562-49-2 Octane, 2,2-dimethyl15869-87-1 3,3-Diethylpentane 1067-20-5 3,3-Dimethylheptane 4032-86-4 isopentane 78-78-4 2-Methylnonane 871-83-0 4-Methylheptane 589-53-7 2,4-dimethylhexane 589-43-5 2-methyloctane 3221-61-2 30726 / DHA Isoparaffins Standard New Jersey X X X X X X - SARA EHS 313 - TSCA Pennsylvania X X X X X X X X X X X X X X California - X X X X X X X X X X X X X X X Regulation Massachusetts X X X X X X X X X X X X X X Page 7 of 8 2,3-dimethylheptane 3-Ethyloctane 3-Ethylpentane 3,4-Dimethylheptane Octane, 3,3-dimethyl2,2-dimethylhexane 2,2,3-trimethylbutane 3-Ethylhexane 3074-71-3 5881-17-4 617-78-7 922-28-1 4110-44-5 590-73-8 464-06-2 619-99-8 - X - X - - 16. OTHER INFORMATION Prior Version Date: Other Information: References: Disclaimer: 04/24/14 Any changes to the SDS compared to previous versions are marked by a vertical line in front of the concerned paragraph. No data available. Restek Corporation provides the descriptions, data and information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. It is provided for your guidance only. Because many factors may affect processing or application/use, Restek Corporation recommends you perform an assessment to determine the suitability of a product for your particular purpose prior to use. No warranties of any kind, either expressed or implied, including fitness for a particular purpose, are made regarding prodcuts described, data or information set forth. In no case shall the descriptions, information, or data provided be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk. 30726 / DHA Isoparaffins Standard Page 8 of 8
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