Safety Data Sheet

Safety Data Sheet
Revision Date: 11/22/16
www.restek.com
1. IDENTIFICATION
Catalog Number / Product Name:
Company:
Address:
Phone#:
Fax#:
Emergency#:
Email:
Revision Number:
Intended use:
30726 / DHA Isoparaffins Standard
Restek Corporation
110 Benner Circle
Bellefonte, Pa. 16823
814-353-1300
814-353-1309
800-424-9300 (CHEMTREC)
703-527-3887 (Outside the US)
www.restek.com
2
For Laboratory use only
2. HAZARD(S)IDENTIFICATION
Emergency Overview:
GHS Hazard
Symbols:
GHS
Classification:
Aspiration Hazard Category 1
Flammable Liquid Category 2
Skin Corrosion/Irritation Category 2
Hazardous to the aquatic environment - Chronic Category 2
Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 3
GHS Signal
Word:
GHS Hazard:
Danger
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause drowsiness or dizziness.
Toxic to aquatic life with long lasting effects.
GHS
Precautions:
Safety
Precautions:
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilation and lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash hands and skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
First Aid
Measures:
IF SWALLOWED: Immediately call a POISON CENTER/doctor/....
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment see section 4.
Do NOT induce vomiting.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
30726 / DHA Isoparaffins Standard
Page 1 of 8
In case of fire: Use extinguishing media in section 5 for extinction.
Collect spillage.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposal:
Dispose of contents/container according to section 13 of the SDS.
Single
No data available.
Exposure
Target Organs:
Repeated
No data available.
Exposure
Target Organs:
3. COMPOSITION / INFORMATION ON INGREDIENT
Chemical Name
CAS #
EINEC #
% Composition
3-methylpentane
96-14-0
202-481-4
10.517000
3-methyloctane
2216-33-3
218-686-7
6.995000
2-methylpentane
107-83-5
203-523-4
6.377000
2,4-dimethylpentane
108-08-7
203-548-0
5.931000
3-methylheptane
589-81-1
209-660-6
5.909000
2,5-dimethylhexane
592-13-2
209-745-8
5.854000
3-Methylnonane
5911-04-6
227-631-6
5.272000
2-methylheptane
592-27-8
209-747-9
4.731000
2-methylhexane
591-76-4
209-730-6
4.689000
2,3-dimethylpentane
565-59-3
209-280-0
4.668000
2,5-Dimethylheptane
2216-30-0
2,2,3-trimethylpentane
564-02-3
209-266-4
3.673000
2,2-dimethylpentane
590-35-2
209-680-5
2.438000
3-methylhexane
589-34-4
209-643-3
2.374000
2,3-dimethylbutane
79-29-8
201-193-6
2.352000
3,5-Dimethylheptane
926-82-9
3,3-dimethylpentane
562-49-2
Octane, 2,2-dimethyl-
15869-87-1
2.095000
3,3-Diethylpentane
1067-20-5
1.914000
3,3-Dimethylheptane
4032-86-4
isopentane
78-78-4
201-142-8
1.599000
2-Methylnonane
871-83-0
212-814-5
1.582000
4-Methylheptane
589-53-7
209-650-1
1.508000
2,4-dimethylhexane
589-43-5
209-649-6
1.454000
2-methyloctane
3221-61-2
221-748-6
1.289000
2,3-dimethylheptane
3074-71-3
3-Ethyloctane
5881-17-4
3-Ethylpentane
617-78-7
3,4-Dimethylheptane
922-28-1
0.839000
Octane, 3,3-dimethyl-
4110-44-5
0.804000
2,2-dimethylhexane
590-73-8
209-689-4
0.786000
2,2,3-trimethylbutane
464-06-2
207-346-3
0.660000
3-Ethylhexane
619-99-8
210-621-0
0.307000
3.860000
2.344000
209-230-8
2.305000
1.765000
1.160000
1.068000
210-529-0
0.882000
4. FIRST-AID MEASURES
30726 / DHA Isoparaffins Standard
Page 2 of 8
Inhalation:
Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not
breathing, give artificial respiration and have a trained individual administer oxygen. Get
medical attention immediately
Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to
prevent chemical from transferring to the uncontaminated eye. Get immediate medical
attention.
Wash with soap and water. Remove contaminated clothing and launder. Get medical
attention if irritation develops or persists.
No data.
Eyes:
Skin Contact:
Ingestion:
5. FIRE- FIGHTING MEASURES
Extinguishing Media:
Fire and/or Explosion Hazards:
Fire Fighting Methods and Protection:
Hazardous Combustion Products:
Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing
agents. Water spray or fog may also be effective for extinguishing if
swept across the base of the fire. Water can also be used to absorb heat
and keep exposed material from being damaged by fire.
Vapors may be ignited by heat, sparks, flames or other sources of
ignition at or above the low flash point giving rise to a Class B fire.
Vapors are heavier than air and may travel to a source of ignition and
flash back
Do not enter fire area without proper protection including self-contained
toxic breathing apparatus and full protective equipment. Fight fire from a
safe distance and a protected location due to the potential of hazardous
vapors and decomposition products. Flammable component(s) of this
material may be lighter than water and burn while floating on the surface.
Use water spray/fog for cooling.
Carbon dioxide, Carbon monoxide
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions and Equipment:
Methods for Clean-up:
Exposure to the spilled material may be severely irritating or toxic. Follow
personal protective equipment recommendations found in Section 8 of
this SDS. Personal protective equipment needs must be evaluated based
on information provided on this sheet and the special circumstances
created by the spill including; the material spilled, the quantity of the spill,
the area in which the spill occurred, and the expertise of employees in the
area responding to the spill. Never exceed any occupational exposure
limits.
Prevent the spread of any spill to minimize harm to human health and the
environment if safe to do so. Wear complete and proper personal
protective equipment following the recommendation of Section 8 at a
minimum. Dike with suitable absorbent material like granulated clay.
Gather and store in a sealed container pending a waste disposal
evaluation.
7. HANDLING AND STORAGE
Handling Technical Measures and Precautions:
Storage Technical Measures and Conditions:
Toxic or severely irritating material. Avoid contacting and avoid
breathing the material. Use only in a well ventilated area.
Store in a cool dry ventilated location. Isolate from
incompatible materials and conditions. Keep container(s)
closed. Keep away from sources of ignition
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
United States:
Chemical Name
CAS No.
IDLH
ACGIH STEL
ACGIH TLV-TWA
3-methylpentane
96-14-0
ND
1000 ppm
STEL (listed
under Hexane
isomers other
than nhexane)
500 ppm TWA (listed
under Hexane isomers
other than n-hexane)
3-methyloctane
2-methylpentane
2216-33-3
107-83-5
ND
ND
30726 / DHA Isoparaffins Standard
1000 ppm
STEL (listed
under Hexane
isomers other
No TLV
500 ppm TWA (listed
under Hexane isomers
other than n-hexane)
OSHA Exposure
Limit
No data available.
No data available.
No data available.
Page 3 of 8
2,4-dimethylpentane
108-08-7
ND
3-methylheptane
2,5-dimethylhexane
3-Methylnonane
2-methylheptane
2-methylhexane
589-81-1
592-13-2
5911-04-6
592-27-8
591-76-4
ND
ND
ND
ND
ND
2,3-dimethylpentane
565-59-3
ND
2,5-Dimethylheptane
2,2,3trimethylpentane
2,2-dimethylpentane
2216-30-0
564-02-3
ND
ND
590-35-2
ND
3-methylhexane
589-34-4
ND
2,3-dimethylbutane
79-29-8
ND
3,5-Dimethylheptane
3,3-dimethylpentane
Octane, 2,2-dimethyl3,3-Diethylpentane
3,3-Dimethylheptane
isopentane
926-82-9
562-49-2
15869-87-1
1067-20-5
4032-86-4
78-78-4
ND
ND
ND
ND
ND
ND
2-Methylnonane
4-Methylheptane
2,4-dimethylhexane
2-methyloctane
2,3-dimethylheptane
3-Ethyloctane
3-Ethylpentane
3,4-Dimethylheptane
Octane, 3,3-dimethyl2,2-dimethylhexane
2,2,3-trimethylbutane
3-Ethylhexane
871-83-0
589-53-7
589-43-5
3221-61-2
3074-71-3
5881-17-4
617-78-7
922-28-1
4110-44-5
590-73-8
464-06-2
619-99-8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Personal Protection:
Engineering Measures:
Respiratory Protection:
30726 / DHA Isoparaffins Standard
than nhexane)
500 ppm
STEL (listed
under
Heptane, all
isomers)
500 ppm
STEL (listed
under
Heptane, all
isomers)
500 ppm
STEL (listed
under
Heptane, all
isomers)
500 ppm
STEL (listed
under
Heptane, all
isomers)
500 ppm
STEL (listed
under
Heptane, all
isomers)
1000 ppm
STEL (listed
under Hexane
isomers other
than nhexane)
400 ppm TWA (listed
under Heptane, all
isomers)
No data available.
No TLV
No TLV
No TLV
No TLV
400 ppm TWA (listed
under Heptane, all
isomers)
No data available.
No data available.
No data available.
No data available.
No data available.
400 ppm TWA (listed
under Heptane, all
isomers)
No data available.
No TLV
No TLV
No data available.
No data available.
400 ppm TWA (listed
under Heptane, all
isomers)
No data available.
400 ppm TWA (listed
under Heptane, all
isomers)
No data available.
500 ppm TWA (listed
under Hexane isomers
other than n-hexane)
No data available.
No TLV
No TLV
No TLV
No TLV
No TLV
600 ppm TWA (listed
under Pentane, all
isomers)
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
Local exhaust ventilation is recommended when generating excessive levels of
vapors from handling or thermal processing.
Respiratory protection may be required to avoid overexposure when handling this
product. General or local exhaust ventilation is the preferred means of protection.
Use a respirator if general room ventilation is not available or sufficient to
Page 4 of 8
eliminate symptoms.
Wear chemically resistant safety glasses with side shields when handling this
product. Wear additional eye protection such as chemical splash goggles and/or
face shield when the possibility exists for eye contact with splashing or spraying
liquid, or airborne material. Do not wear contact lenses. Have an eye wash
station available.
Avoid skin contact by wearing chemically resistant gloves, an apron and other
protective equipment depending upon conditions of use. Inspect gloves for
chemical break-through and replace at regular intervals. Clean protective
equipment regularly. Wash hands and other exposed areas with mild soap and
water before eating, drinking, and when leaving work.
Eye Protection:
Skin Protection:
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance, color:
Odor:
Physical State:
pH:
Vapor Pressure:
Boiling Point:
Flash Point:
Flammability:
Upper Flammable/Explosive Limit, % in air:
Lower Flammable/Explosive Limit, % in air:
Autoignition Temperature:
Decomposition Temperature:
Evaporation Rate:
Odor Threshold:
Solubility:
Partition Coefficient: n-octanol in water:
VOC % by weight:
Molecular Weight:
No data available.
None
No data available.
No data available.
No data available.
No data available.
-60
Extremely Flammable
No data available.
No data available.
No data available. deg C
No data available.
No data available.
No data available.
Not determined
No data available.
0
No data available.
10. STABILITY AND REACTIVITY
Stability:
Conditions to Avoid:
Materials to Avoid / Chemical Incompatiability:
Hazardous Decomposition Products:
Stable under normal conditions.
No data available.
Strong oxidizing agents
No data available.
11. TOXICOLOGICAL INFORMATION
Routes of Entry:
Inhalation, Skin Contact, Eye Contact, Ingestion
Target Organs Potentially Affected By Exposure: No data available.
Chemical Interactions That Change Toxicity:
None Known
Immediate (Acute) Health Effects by Route of Exposure:
Inhalation Irritation:
Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea
and headache.
Skin Contact:
Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause
permanent damage.
Eye Contact:
Contact with the eyes may cause moderate to severe eye injury. Eye contact
may result in tearing and reddening, but not likely to permanently injure eye
tissue. Temporary vision impairment (cloudy or blurred vision) is possible.
Ingestion Irritation:
May be harmful if swallowed.
Long-Term (Chronic) Health Effects:
Carcinogenicity:
Reproductive and Developmental Toxicity:
Inhalation:
Skin Contact:
No data.
No data available to indicate product or any components
present at greater than 0.1% may cause birth defects.
Upon prolonged and/or repeated exposure, can cause
moderate respiratory irritation, dizziness, weakness, fatigue,
nausea and headache.
Upon prolonged or repeated contact, can cause
moderate skin irritation, defatting, and dermatitis. Not
likely to cause permanent damage.
Component Toxicological Data:
NIOSH:
30726 / DHA Isoparaffins Standard
Page 5 of 8
Chemical Name
No data available.
CAS No.
Component Carcinogenic Data:
OSHA:
Chemical Name
No data available.
CAS No.
ACGIH:
Chemical Name
No data available.
CAS No.
NIOSH:
Chemical Name
No data available.
CAS No.
NTP:
Chemical Name
No data available.
CAS No.
IARC:
Chemical Name
No data.
No data.
No data.
LD50/LC50
CAS No.
Group No.
Group 1
Group 2A
Group 2B
12. ECOLOGICAL INFORMATION
Overview:
Mobility:
Persistence:
Bioaccumulation:
Degradability:
Ecological Toxicity Data:
This material is not expected to be harmful to the ecology.
No data
No data
No data
No data
No data available.
13. DISPOSAL CONSIDERATIONS
Waste Description of Spent Product:
Disposal Methods:
Waste Disposal of Packaging:
Spent or discarded material is a hazardous waste.
Dispose of by incineration following Federal, State, Local,
or Provincial regulations.
Comply with all Local, State, Federal, and Provincial
Environmental Regulations.
14. TRANSPORTATION INFORMATION
United States:
DOT Proper Shipping Name:
Flammable liquids, n.o.s. (3-Methylpentane, 3Methyloctane)
UN1993
3
II
UN Number:
Hazard Class:
Packing Group:
International:
IATA Proper Shipping Name:
Flammable liquids, n.o.s. (3-Methylpentane, 3Methyloctane)
UN1993
3
II
UN Number:
Hazard Class:
Packing Group:
Marine Pollutant: No
Chemical Name
CAS#
Marine Pollutant
Severe Marine
Pollutant
No data available.
15. REGULATORY INFORMATION
United States:
30726 / DHA Isoparaffins Standard
Page 6 of 8
Chemical Name
CAS#
CERCLA
SARA 313
3-methylpentane
3-methyloctane
2-methylpentane
2,4-dimethylpentane
3-methylheptane
2,5-dimethylhexane
3-Methylnonane
2-methylheptane
2-methylhexane
2,3-dimethylpentane
2,5-Dimethylheptane
2,2,3-trimethylpentane
2,2-dimethylpentane
3-methylhexane
2,3-dimethylbutane
3,5-Dimethylheptane
3,3-dimethylpentane
Octane, 2,2-dimethyl3,3-Diethylpentane
3,3-Dimethylheptane
isopentane
2-Methylnonane
4-Methylheptane
2,4-dimethylhexane
2-methyloctane
2,3-dimethylheptane
3-Ethyloctane
3-Ethylpentane
3,4-Dimethylheptane
Octane, 3,3-dimethyl2,2-dimethylhexane
2,2,3-trimethylbutane
3-Ethylhexane
96-14-0
2216-33-3
107-83-5
108-08-7
589-81-1
592-13-2
5911-04-6
592-27-8
591-76-4
565-59-3
2216-30-0
564-02-3
590-35-2
589-34-4
79-29-8
926-82-9
562-49-2
15869-87-1
1067-20-5
4032-86-4
78-78-4
871-83-0
589-53-7
589-43-5
3221-61-2
3074-71-3
5881-17-4
617-78-7
922-28-1
4110-44-5
590-73-8
464-06-2
619-99-8
-
-
The following chemicals are listed on CA Prop 65:
Chemical Name
CAS #
State Right To Know Listing:
Chemical Name
CAS#
3-methylpentane
96-14-0
3-methyloctane
2216-33-3
2-methylpentane
107-83-5
2,4-dimethylpentane
108-08-7
3-methylheptane
589-81-1
2,5-dimethylhexane
592-13-2
3-Methylnonane
5911-04-6
2-methylheptane
592-27-8
2-methylhexane
591-76-4
2,3-dimethylpentane
565-59-3
2,5-Dimethylheptane
2216-30-0
2,2,3-trimethylpentane
564-02-3
2,2-dimethylpentane
590-35-2
3-methylhexane
589-34-4
2,3-dimethylbutane
79-29-8
3,5-Dimethylheptane
926-82-9
3,3-dimethylpentane
562-49-2
Octane, 2,2-dimethyl15869-87-1
3,3-Diethylpentane
1067-20-5
3,3-Dimethylheptane
4032-86-4
isopentane
78-78-4
2-Methylnonane
871-83-0
4-Methylheptane
589-53-7
2,4-dimethylhexane
589-43-5
2-methyloctane
3221-61-2
30726 / DHA Isoparaffins Standard
New Jersey
X
X
X
X
X
X
-
SARA EHS
313
-
TSCA
Pennsylvania
X
X
X
X
X
X
X
X
X
X
X
X
X
X
California
-
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Regulation
Massachusetts
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Page 7 of 8
2,3-dimethylheptane
3-Ethyloctane
3-Ethylpentane
3,4-Dimethylheptane
Octane, 3,3-dimethyl2,2-dimethylhexane
2,2,3-trimethylbutane
3-Ethylhexane
3074-71-3
5881-17-4
617-78-7
922-28-1
4110-44-5
590-73-8
464-06-2
619-99-8
-
X
-
X
-
-
16. OTHER INFORMATION
Prior Version Date:
Other Information:
References:
Disclaimer:
04/24/14
Any changes to the SDS compared to previous versions are marked by a vertical
line in front of the concerned paragraph.
No data available.
Restek Corporation provides the descriptions, data and information contained
herein in good faith but makes no representation as to its comprehensiveness or
accuracy. It is provided for your guidance only. Because many factors may affect
processing or application/use, Restek Corporation recommends you perform an
assessment to determine the suitability of a product for your particular purpose
prior to use. No warranties of any kind, either expressed or implied, including
fitness for a particular purpose, are made regarding prodcuts described, data or
information set forth. In no case shall the descriptions, information, or data provided
be considered a part of our terms and conditions of sale. Further, the descriptions,
data and information furnished hereunder are given gratis. No obligation or liability
for the description, data and information given are assumed. All such being given
and accepted at your risk.
30726 / DHA Isoparaffins Standard
Page 8 of 8