JOURNAL
OF MOLECULAR
SPECTROSCOPY
55,
229-251
(1975)
Line Positions of H,O in the 1.33 to 1.45 Micron
ROBERT
Jet Prop&ion
Laboratory,
A.
TOTH
California
AND
JACK
S.
Region
MARGOLIS
Znstitlrfe of Technology, Pasadena,
Calijornia 91103
Five bands of Hz0 occurring in the 6950-7500 cm-i region were recorded with a vacuum
infrared spectrometer
with spectral resolution of 0.07 cm-i. Measurements
and quantum assignments are given and upper-state
levels are determined. Two of the bands, (101) and (021),
The three other bands,
are type A with origins at 7249.811 and 6871.51 cm-i, respectively.
(200), (002), and (120), are type B with origins at 7201.540, 7445.07, and 6775.10 cm-i,
respectively.
INTRODUCTION
An experimental investigation
of the line positions and strengths of water vapor in
the region 6900-7500 cm-r was undertaken using a vacuum, grating spectrometer. The
present study involves the determination
of the line center frequencies of the vibrationrotation transitions of the five H,O bands in this spectral interval and the determination
of the rotational levels of the five states: (lOl), (200), (021), (120), and (002). A forthcoming publication will present the results of the Hz0 line strength measurements.
Several of the upper-state levels are perturbed by resonance effects. The interactions
involve either Fermi coupling of the near-resonance
levels of the states: (lOl)-(021),
(120)-(ZOO), (120)-(002), and (200)-(002); or Coriolis coupling of the near-resonance
levels of the states: (lOl)-(200),
(lOl)-(002),
(lOl)-(120),
(021)-(200,) (021)-(120),
and (021)-(002). These effects cause the mixed upper-state levels (line positions) to be
displaced from their respective unperturbed locations and cause mixing of the transition
intensities arising from the common lower-state level to the interacting upper levels.
EXPERIMENT&
The spectra were obtained with a 1.8 m Jarrel-Ash grating spectrometer. The grating
was a 300 line/mm-’ Bausch and Lomb replica having 20 cm of usable width and blazed
at 5.7 pm in first order. The Hz0 line positions were calibrated from lines of the 2~~ + va
and VI + 2~2’ + USbands of N,O (1) by observing the N,O lines in second order and the
Hz0 lines in third order of the grating. Further calibration was done by observing the
2.9 pm HtO lines (2,3) in first and second order and the 1.4 pm Hz0 lines in second and
fourth orders, respectively. The estimated accuracies of the line center measurements
were: 0.007 cm-’ for unblended lines and between 0.01 and 0.015 cm-r for blended,
resolved lines and very weak, observed, and unblended absorptions. The spectral resolution in the 1.4 pm region was -0.07 cm+.
Copyright
0
1975 by Academic
AU rights of reproduction
Press, Inc.
in any form reserved.
1
2
3
3
4
4
5
6
7
a
9
10
11
12
13
14
15
16
17
18
19
20
20
21
21
21
21
22
23
23
24
25
25
26
26
27
20
29
29
30
30
31
32
32
33
34
LINE
NUMBER
6953.108
6954.016
6954.016
6954.437
6954.437
6955.164
6956.320
6957.269
6957.472
6957.867
6950.704
6961.184
6961.313
6962.272
6963.174
6963.751
6965.589
6965.808
6966.695
6967.338
6967.441
6967.441
6969.047
6969.047
6969.047
6969.047
6969.311
6970.150
6970.150
6970.558
6971.319
6971.319
6971.594
6971.594
6971.804
6972.062
6972.760
6972.760
6972,044
6972.844
6973.666
6974.629
6974.629
6975.038
6975.422
6952.322
CM
FREQ
-1
83
5
51
4
86
2
86
3
94
6
41
4
40
4
31
2
22
1
322
43
2
43
1
50
5
32
2
41
4
32
2
32
1
94
6
54
1
72
5
62
4
32
1
85
3
77
0
77
1
76
1
85
4
42
3
60
6
64
3
54
2
51
5
41
4
10 2 9
50
5
81
7
10 1 9
11 0 11
11 1 11
9 0 9
Y 1 9
93
7
84
4
92
7
82
7
51
4
83
51
96
96
104
31
30
21
20
441
54
54
62
30
53
22
44
103
53
72
73
22
95
07
87
77
95
40
63
63
53
41
52
11 2
40
92
11 1
12 0
12 1
10 1
10 0
103
94
102
91
63
6
5
3
4
7
3
3
1
2
1
2
4
3
3
1
0
7
2
6
5
0
4
1
2
0
5
4
3
4
3
4
3
10
4
8
10
12
12
10
10
a
5
a
a
3
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
-1
1006.117
326.626
1631.384
1631.242
1581.337
142.279
136.762
95.176
70,091
488.108
610.342
610.115
602.774
136.762
503.969
134.902
488.135
1538.150
508.812
709.609
816.695
136.164
1477.298
1590.690
1590.692
1394.817
1474.981
222.053
661.549
648.979
503.969
224.838
446.511
1525.136
222.053
1080.386
1524.849
1557.841
1557.852
1114.550
1114.533
1446.129
1360.236
1437.969
1079.080
661.549
CM
E
1
.1291-03
~1184-02
r5797-05
r1934-05
r7400-05
.2910-02
.8971-02
.3663-02
*4141-02
.1532-02
.8499-03
.2836-03
.2921-03
.8978-02
r4731-03
.9063-02
.5112-03
.3070-05
.1484-02
.1832-03
.1037-03
.3004-02
.1232-04
.2362-05
.7085-05
.1854-04
.4153-05
.1976-02
.2211-03
.7496-03
.5069-03
.5851-02
.1893-02
.3253-05
.1977-02
.2866-04
.9772-05
.2773-05
.8320-05
.7280-04
.2427-04
.1435-04
.2182-04
.4978-05
.8658-04
.2198-03
STRENGTH
TEMP=295K
021
021
101
101
101
021
021
021
021
101
200
200
101
021
101
021
101
200
120
021
200
021
101
101
101
200
101
021
200
120
120
021
200
101
021
200
101
101
101
200
200
101
101
101
200
101
BAND
35
36
37
37
37
38
38
39
40
40
41
42
43
43
44
44
44
45
46
47
48
48
49
50
51
52
53
53
54
55
56
57
58
59
60
61
62
63
b3
63
64
65
66
67
68
69
70
71
72
LINE
hUM8EP
6977.587
6977.851
6976.610
6978.610
6978.610
6979.736
6979.736
6979.851
6979.984
6979.984
6980.543
6980.756
6981.119
6981.119
6981.537
6981.537
6981.537
6981.820
6983.308
6983.667
6984.331
6984.331
6984.827
6984.962
6985.065
6985.683
6987.126
6987.126
6900.303
6993.267
6994.904
6995.788
6995.940
6997.524
6997.665
6997.601
6998.007
6998.192
6998.192
6998.192
6998.815
6999.004
6999.500
6999.993
7000.647
7000.809
7001.585
7001.690
7oo1.8bl
FREQ
-1
CM
MEASUREMENTS
_.._ _ _ _ AND ASSIGNMENTS OF WATER VAPOR
IN THE 1.33 TO i.45 MICRON SPECTRAL~REGION
TABLE
5
l1
93 2
85
61
6
9
4
6
6
6
42
2
71
6
62
5
63
3
80
a
91
a
81
8
92
8
10 0 10
10 1 10
75
2
75
3
83
6
43
2
83
6
82
6
b4
5
72
6
72
6
42
2
61
60
75
3
65
2
91
a
42
3
65
1
41
3
52
4
55
0
55
1
10 0 10
63
4
84
5
52
3
76
1
76
2
33
1
33
0
42
3
5
5
2
1
7
2
2
2
5
1
0
9
1
6
4
2
3
0
1
2
32
1
82
7
60
6
65
2
91
9
101
9
90
9
102
9
11 0 11
11 1 11
85
3
85
4
91
9
32
1
93
7
92
7
93
6
a1
7
74
3
53
3
51
50
75
65
82
53
65
31
50
55
55
10 1
65
94
63
86
86
44
44
32
‘P
: ‘Z
l2
75 l l1
3
33
0
22
1
',: : 'Z
85
3
61
HOTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
.1190-02
.3592-02
.6244-02
.2231-03
.6632-03
.2185-03
.6284-04
.1013-04
.1886-03
.3030-04
.2573-04
.8578-05
.1214-04
.3656-04
.6587-04
.6339-02
.1474-04
.4741-04
.3215-04
.7543-04
.1776-03
.4790-03
326.626
325.348
212.156
885.601
446.697
888.599
920.210
1293.019
920.169
1293.635
1327.110
1327.118
1255.912
1255.167
920.210
212.156
1216.232
1201.922
1282.920
882.891
931.238
503.969
STRENGTH
TEMP=295K
.197?-02
.4385-05
.3184-04
.3846-04
.9642-06
.3328-04
.9214-02
.9974-04
.7663-04
.2367-03
.1399-02
.2300-03
.7532-02
.3589-02
.1567-03
.4700-03
.1017-04
.7266-04
.8004-05
.7065-03
.5669-05
.1701-04
.5162-03
.1549-02
.2139-02
-1
447.253
1690.665
1282.920
1255.167
1774.611
1059.647
134.902
1059.836
008.633
885.601
508.812
888.599
173.366
325.348
742.074
742.077
1293.019
888.633
1340.885
648,979
1411.638
1411.612
488.135
488.108
206.302
CM
E
021
200
021
101
200
101
200
101
101
101
101
101
021
120
101
101
200
200
101
200
021
021
021
200
101
021
101
021
120
021
021
120
200
021
021
021
021
021
200
101
101
200
101
101
200
200
021
BAND
8
a
$
%
u
g
!d
3
100
101
102
102
102
103
104
105
lU6
lU7
108
108
109
110
111
112
a4
85
a5
86
a7
68
89
90
90
91
92
92
93
94
95
96
97
97
98
99
72
73
74
75
76
77
78
79
MO
a0
al
a2
83
LINE
NUMbtH
5
9
3
9
3
4
4
6
4
3
2
1
0
1
2
5
a
8
2
4
0
1
3
7
7
3
1
7
7
3
9
9
5
5
5
4
5
5
1
2
83
91
74
90
41
73
96
72
74
53
43
43
68
66
32
61
al
no
76
4u
66
6b
53
70
71
31
32
82
01
52
90
91
72
61
73
63
62
73
65
65
7010.574
7012.108
7012.108
7012.695
7012.835
7013.175
7014.047
7014.475
7014.475
7014.563
7015.85
7015.85
7015.929
7016.176
7017.221
7017.933
7018.817
7018.617
7019.578
7021.823
7022.093
7022.478
7022.719
7022,719
7022.719
7023.207
7023,366
7023.459
7025,055
7025.391
7025.999
7025.999
702b.278
7026.541
7028.147
7028.315
7006.361
7007.033
7007.033
7007.176
7008.300
7008.395
7006.148
6
3
4
0
4
7
7
70
71
71
31
51
22
52
7003.102
7003.730
7004.233
7004.756
1
3
1
0
4
a
8
2
2
a
8
2
10
10
6
4
6
3
4
6
2
3
76
52
66
66
51
al
a0
42
43
92
91
42
10 0
10 1
8;:
51
71
52
52
a3
75
75
a
2
5
3
7
5
2
1
0
1
2
1
6
7
7
2
3
1
3
4
a
4
43
41
10
42
05
92
a4
91
53
a3
96
70
a4
42
33
33
76
76
43
72
71
70
5
6
6
a4
60
61
TRANSITION
UPPER
LOWER
STATE
STATE
7ooL.861
7001.944
CM
-1
FREQ
ROTATIONAL
23.794
300.363
.
982.912
399.458
704.214
446.511
416.209
1006.117
1059.836
1059.647
1216,194
446.511
1045.058
1045.059
399.458
744.163
744.064
315.780
382.517
lOa0.3R6
1079.080
315.780
;;;,"mo"
1216.186
383.843
709.609
586.480
586.244
1079.080
508.812
1050.158
1631.384
506.244
1122.709
315.780
285.220
285.419
1216.194
1255.167
1080.3I36
1131.776
.4677-04
.1894-02
.107&3-03
.3593-04
.2514-02
.4465-03
.1489-03
.1203-02
.2606-02
.286A-04
.A659-04
.1261-02
.242a-04
.72R4-04
.4616-04
.2516-02
.5690-03
.2029-O?
.7729-03
.1237-03
.9519-O&
.3176-04
.8699-04
.1395-02
.3318-04
.6167-05
.1010-02
.6989-04
.1277-02
.1462-02
.4381-02
.4431-04
.1477-04
.ao22-05
.1760-03
.3363-03
.1010-02
.6638-03
1122.709
382.517
275,497
.1986-02
.6797-04
.25a2-02
.1531-02
.1568_01
.4068-02
.3660-04
.28al-04
.2227-04
STRENGTH
TEMP=295K
446.697
-1
447.253
CM
E
1
021
101
021
021
021
200
200
200
200
10'1
101
021
101
101
101
021
021
120
021
101
101
101
200
101
LO1
021
021
101
120
021
021
101
101
200
200
021
021
021
021
002
101
021
021
021
101
200
101
RAND
1ARLE
113
114
115
115
116
117
118
119
119
120
121
122
123
124
125
126
126
127
128
129
129
130
131
132
133
133
134
134
135
136
137
15a
139
139
140
141
142
143
144
145
146
147
147
148
149
lb0
151
152
153
NUMtXH
LINE
(COIJT.1
7028.433
7028.781
7029.103
7029.103
7031.244
7031.48
7031.646
7032.355
7032.355
7033.529
7034.224
7034.483
7034.d30
7036.519
7036.797
7038.434
7038.434
703d.936
7039.159
7039.281
7039.281
7039.559
7040.011
7040.46
7041.538
7041.538
7042.177
7042.177
7042.418
7045.456
7043.990
7044.26
7044.632
7044.832
7045.229
7045.426
7045.838
7046.398
7046.812
7047.098
7047.320
7047.685
7047.685
7047.996
7048.432
7048.806
7051.570
7051.93u
7053.137
FREO
-1
CM
7
7
9
9
6
0
81
a2
91
90
83
44
73
5
10 0 10
3
4
4
5
7
5
7
1
5
74
61
71
62
70
33
84
52
52
9
9
4
1
0
5
0
91
90
73
55
55
03
33
10 1 10
10 0 10
63
3
54
2
54
1
74
4
22
1
5
6
6
6
6
0
6
6
b
a
a
7
3
4
3
b5
2
11 u 11
1
61
71
60
72
61
22
a3
71
72
a1
80
82
42
62
41
2
1
5
7
2
2
2
3
7
1
1
5
4
20
43
62
a1
43
75
65
74
92
43
65
72
74
33
2
R
8
6
6
9
9
7
31
80
a1
71
02
102
101
a2
1
9
9
5
7
LO 0 10
10 1 10
81
a
32
1
31
2
51
4
a0
R
53
3
74
3
64
3
64
2
Yi
a
53
2
64
2
63
4
64
3
21
2
53
90
91
62
71
LOWER
STATE
ROTATIONAL
TRANSITION
UPPER
STATE
-1
927.745
542.906
586.460
552.912
586.244
285.220
1122.709
882.891
885.601
920.210
920.169
1006.117
488.135
446.511
416.209
816.695
1114.533
920.210
920.169
042.357
742.074
742.077
1050.158
285.419
1293.635
1293.019
885.601
70.091
383.843
552.912
882.891
302.517
1059.836
888.599
931.238
1201.922
383.843
888.633
782.410
927.745
285.220
173.366
744.064
744.163
704.214
982.912
CM
E
002
021
200
021
200
200
200
101
101
101
101
200
101
021
200
021
021
.5899-04
.4177-03
.3223-03
.1193-02
.q6aO-03
.1401-02
.7070-04
.7542-04
.2233-03
.6287-04
.lb87-03
.1249-03
.5174-03
.2006-02
.7401-03
.llOO-03
.2573-04
021
021
101
200
200
200
200
LO1
101
200
021
101
200
200
021
200
200
101
200
021
200
200
101
101
021
021
021
200
002
BAND
.6627-04
.1989-03
.2755-03
.15oa-03
.4524-03
.3356-04
.4198-02
.4799-04
.9067-03
.7374-04
.3714-03
.6053-04
.1391-02
.1785-03
.101a-04
.2243-03
.4186-02
.8588-03
.1137-02
.7579-04
.2737-02
.9594-04
.2212-03
.3044-04
.7583-02
.1562-03
.4684-03
.5431-03
.4499-04
STHENGTH
TEMP=295K
z
r
g
x
"0
2
s
6
2
E
M
153
154
155
156
157
157
157
150
359
160
160
161
161
162
163
164
165
166
167
160
169
169
170
171
171
172
173
174
175
176
176
177
178
179
180
180
180
.181
182
182
183
184
164
185
186
186
187
188
la8
LINE
NUMBEH
7053.137
7053.760
7053.938
7054.232
7055.860
7055.860
7055.860
7056.369
7056.536
7057.362
7057.362
7057.529
7057.529
7058.406
7058.930
7059.244
7061.173
7061.765
7063.135
7063.681
7064.082
7064.082
7064.256
7064.988
7064.988
7065.532
7066.511
7067.154
7067.418
7067.700
7067.700
7068.286
7068.396
7068.510
7068.609
7068.609
7068.609
7069.102
7069.220
7069.220
7070.787
7071.506
7071.506
7071.599
7073.530
7073.530
7073.779
7074.255
7074,255
FREQ
-1
CM
10 1 10
73
5
72
5
53
2
77
0
77
1
33
0
72
6
65
1
65
2
74
4
92
R
61
5
91
8
53
3
73
5
71
6
71
6
72
6
11 0 11
11 1 11
44
1
53
2
64
3
32
1
42
2
54
2
61
6
73
5
44
1
44
0
64
2
42
3
30
3
33
0
64
3
60
6
82
6
71
6
80
8
81
8
72
6
41
3
62
4
63
3
12 1 12
12 0 12
11 1 11
63
4
62
4
51
5
77
1
77
0
21
1
71
7
55
0
55
1
73
5
90
9
52
4
91
9
63
4
60
6
70
7
81
7
82
7
12 0 12
12 1 12
42
2
63
3
63
4
21
2
3U
3
52
3
50
5
72
6
54
2
54
1
54
1
31
2
42
2
44
1
54
2
51
5
81
7
61
5
70
7
71
7
62
5
43
2
72
5
53
2
13 1 13
13 0 13
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
.369a-03
.1405-02
.1967-04
.6558-05
.4177-02
.1770-03
.7344-04
r2204-03
.6109-04
.2882-04
.3993-03
r8704-04
.5061-03
.1016-03
.5457-03
r5720-03
.1857-03
.2741-04
.9135-05
.1556-02
.1484-02
.4225-03
r6020-02
.1203-02
.2862-03
.1913-02
.1052-03
.1643-02
.5474-03
.1393-03
.3916-02
.9117-o?
.4478-02
.4200-03
.6394-03
.4676-04
.5427-03
.1490-03
.4467-03
.1762-03
.1546-02
.3132-03
.2229-03
.8905-05
.2969-05
782.410
508.812
1394.817
1394.814
285.419
709.609
888.633
888,599
927.745
1080.386
542.906
1079.080
503.969
816.695
704.214
704.214
709.609
1327.110
1327.118
488.108
508.812
756,725
212.156
315.780
610.115
447.253
816.695
488.108
488.135
757.781
300.363
136.762
285.419
756.725
446.697
982.912
704.214
744.064
744.163
709.609
275.497
602.774
661.549
1557.852
1557.841
STRENGTH
TEMP=295K
.7717-04
.1043-03
-1
1114.550
816.695
CM
E
“I*
BAND
TABLE
1
FREP
-1
CM
7074.485
7074.485
7074.62
7074.983
7075.32
7075.44
7075.67
7076.681
7078.857
7079.182
7079.875
7079.875
7080.096
7080.096
7080.21
7080.29
7080.584
7080.747
7081.091
7081.091
7081.245
7082.256
7082.39U
7083.341
7083.58
7063.99
7084.322
7084.642
7084.Y97
7085.263
7085.521
7085.878
7086.901
7088.800
7088.979
7089.35
7089.709
7089.900
7090.471
7091.041
7091.860
7092.30
7092.484
7093.248
7094.069
7094.706
7094.706
7095.445
7095.690
LINE
NUMBEK
189
189
190
191
192
193
194
lY5
196
197
198
198
199
199
200
201
202
203
204
204
205
206
207
2ua
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
230
231
232
fCONT.1
8
3
1
2
4
7
6
4
6
2
2
5
6
3
1
8
3
5
6
4
4
5
3
8
0
3
3
1
6
4
8
3
3
4
3
2
4
2
4
6
6
7
91
52
43
43
51
92
61
62
82
43
53
72
72
53
43
92
63
73
80
41
73
62
64
81
88
74
53
21
60
40
92
42
74
73
64
64
41
75
51
60
61
81
83
92
51
83
63
54
54
50
84
61
70
71
63
73
81
88
71
62
32
61
51
64
93
62
64
84
44
54
74
83
63
44
82
64
63
82
43
74
93
62
41
30
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
6
7
4
6
3
2
1
5
5
5
7
7
4
4
7
1
6
4
2
5
5
3
6
5
3
5
1
1
4
5
4
0
7
2
4
7
1
3
7
4
4
3
-1
1006.117
1201.922
399.458
1006.117
661.549
610.115
610.342
325.348
1122.709
542.906
586.244
586.4aO
648.979
842.357
882.891
1789.045
704.214
602.774
206.302
542.906
326.626
756.725
1282.920
552.912
756.725
1122.709
488.108
610.342
927.745
1050.158
648.979
488.135
885.601
757.781
648.979
885.601
383.843
931.238
1216.232
602.774
224.838
136.762
CM
E
-1249-03
.4801-04
.2423-02
.1256-03
.2357-03
.3029-03
.9079-03
.3479-02
.7117-04
.3987-03
.9682-03
.3224-03
.7167-03
.2790-03
.7583-04
.2888-05
.5820-03
.2994-03
.2071-02
.4010-03
.1152-02
.4094-03
.3251-04
.1144-02
.4206-03
.7056-04
.1570-02
.8648-03
.608a-04
.3263-04
.7116-03
.5233-03
.2367-03
.1404-03
.7508-03
.2244-03
.8647-03
.180A-03
.1489-04
.2969-03
.5938-02
.9256-02
STRENGTH
TEHP=295K
101
101
200
200
021
021
021
200
200
101
101
101
200
200
101
021
120
200
200
200
200
002
200
200
101
101
200
200
101
002
101
200
021
200
021
101
101
200
101
101
021
120
BAND
233
234
235
236
236
236
237
237a
238
239
240
240
241
242
243
244
244
244
245
245
246
247
248
249
250
251
252
253
254
255
256
257
258
259
260
260
261
261
262
263
264
265
266
267
268
269
270
27U
271
LINE
NUMBEH
7095.a6U
7096.643
7097.096
7097.377
7097.377
7097.377
7097.520
7097.708
7098.101
7OY9.708
7100.648
71Ot1.64tl
7100.831
7102.505
7104.616
7105.85
?105,M5
7105.85
7106.835
7106,835
7107.095
7107.844
7108.713
7111.203
?111.45b
7113.179
7113.26
7113.662
7115.020
7115.325
7115.487
?11b,Ua1
7116.1Y9
7116.471
7117,252
7117.252
7117.423
7117.423
?11?.?71
?11&.0?4
7118.657
7119.815
7120.21
7120.362
7121.695
7121.965
7122.515
7122.515
7122.688
FREQ
-1
CM
6
3
6
1
2
1
9
0
4
1
9
6
5
4
6
7';;' 5
4c?
3
33
0
11
0
43
2
30
3
64
2
71
7
32
2
71
6
11 2 10
74
4
72
5
50
5
83
5
31
3
64
2
Y2
7
50
5
51
5
74
3
41
3
65
2
a4
4
32
1
a2
7
42
3
43
2
42
2
93
7
62
4
bl
5
LO 1
44
52
44
102
71
51
11
82
31
83
43
20
52
a2
91
54
53
54
92
72
52
22
05
33
73
53
32
52
72
43
21
22
53
41
73
71
33
73
102
64
73
51
73
40
70
82
60
61
64
51
74
76
33
a2
52
52
43
63
63
62
62
72
ROTATIONAL
TRANSITION
UPPER
LONER
5TATE
STATE
a
1
3
2
8
5
4
0
5
0
5
2
1
3
6
2
1
1
3
4
5
6
1
5
9
3
4
4
4
4
7
6
6
6
2
4
3
1
0
6
4
3
1
6
3
4
5
5
-1
1079.080
610.342
503.969
610.115
1080.386
782.410
416.209
136.164
1050.158
285.419
816.695
508.812
212.156
446.511
709.609
382.517
95.176
134.902
503.969
224.038
816.695
704.214
285.220
816.695
1293.635
756.725
a42.357
399.450
842.357
222.053
586.244
982.912
446.697
447.253
757.781
399.456
931.238
1216.194
285.419
982.912
416.209
446.511
383.843
1006.117
661.549
602.774
552.912
7a2.410
CM
E
.8826-02
.4a30-03
.5693-02
.1058-03
.5459-03
.1414-02
.1051-03
.3249-04
.4460-03
.2803-03
.2431-02
.2937-03
.1926-O?
.1025-02
.4934-04
.6395-03
.1913-02
.1479-03
.2416-02
.1817-03
.449?-04
.4243-02
.4678-04
.7424-03
.1934-02
.8?54-03
.1323-03
.2259-03
.3009-03
.3743-02
.2b37-02
.9233-04
.8612-03
.4a55-03
.20?4-03
.3058-m
.3745-03
.7452-03
.2921-02
.3383-04
.4204-02
.1108-03
.1415-02
.6014-02
.1917-02
.1771-03
~1139-02
.3925-03
STRENGTH
TEMP=295K
021
101
200
101
021
200
200
200
200
101
021
101
101
101
101
200
021
200
101
200
200
101
200
101
021
021
200
200
021
200
021
021
101
101
021
101
200
101
200
101
101
200
200
021
200
200
101
021
BAND
TABLE
269
290
2Yl
292
292
293
2Y4
295
296
297
298
2Y9
300
300
301
302
303
304
305
306
307
308
309
309
310
2h9
272
273
274
275
276
276
277
277
278
279
280
281
281
2Ml
281
262
283
284
285
206
287
268
269
1 (CONT.1
7122.YO9
7123.1139
7124.066
7124.704
7126.057
7126.057
7126.554
7126.554
7127.045
7127.273
7128.014
7126.971
7128.971
7126.971
7126.971
7129.32
7131.Y42
7132.854
7133.007
7133.908
7134.699
7134.983
7135.515
7135.515
7135.515
7135.826
7136.092
7136.843
7136.843
7137.518
?13?.60
7138.304
7139.090
713Y.OU7
7140.097
7140.78
714i1.912
7140.912
7142.38
7142.561
7142.780
7143.41
7144.05
7145.076
7145.219
7147.730
7149.26
7149.260
7150.06
FREQ
-1
CM
2
3
6
4
4
4
4
4
2
3
2
4
0
3
1
a
1
a
5
1
7
1
2
31
2
21
2
13 2 12
75
5
10
1
32
2
50
5
1oa
3
55
1
61
'(I,
41
40
a4
51
21
31
31
51
33
41
33
81
54
102
62
32
93
10
53
a3
5
bl
5
43
1
65
2
63
3
20
2
65
1
60
6
12 1 11
12 2 11
54
2
73
4
52
5.2
3
2
5
5
5
3
3
3
3
2
1
3
1
2
2
5
4
7
4
2
6
t-l
5
41
3
22
1
12 2 11
65
2
21
2
42
3
52
4
LO&
2
64
2
61
50
51
41
74
52
30
32
33
53
43
43
43
72
63
92
73
42
93
22
62
94
6
63
4
31
2
55
1
61
6
31
3
55
0
62
5
11 1 10
11 2 10
65
1
02
7
41
53
HOTAlIONAL
TRANSITION
LOvlFR
UPPER
STATE
-1
200
101
101
101
101
101
200
200
021
002
101
101
101
200
101
101
101
200
021
200
200
101
200
n21
101
200
101
101
101
200
.2084-02
.1409-02
.484?-03
.a7ln-03
.2630-02
.2630-02
.3765-03
.7219-03
.5098-04
.2?19-03
.1214-02
.3256-04
.291?-02
.1154-02
.4012-03
.34?8-02
.1152-02
.1489-02
.1911-03
.1940-02
.R?88-02
.1479-02
.a071-02
.3122-05
.2231-03
.1163-01
.3933-02
.7453-o.?
.9515-O?
.14la-03
206.302
285.220
503.969
383.843
382.517
382.517
782.410
648.979
12n1.922
842.357
315.780
1282.920
136.164
552.912
542.906
325.348
326.626
275.497
931.238
446.511
136.762
275.497
134.902
1774.753
am.599
79.496
300.363
416.209
2254.320
757.781
200
200
BAND
002
101
021
021
021
200
021
101
021
021
002
200
.l-t85-02
.1428-02
STRENGTH
TEMP=295K
.7952-05
.?161-03
.?688-02
.1599-03
.2021-02
.2846-02
.479a-03
.1145-02
.lO54-04
.3509-05
.7225-04
.22?4-03
1340.885
640.979
173.366
742.074
447.253
142.279
742.077
552.912
1524.849
1525.136
888.633
885.601
275.497
508.812
CM
E
311
311
311
312
313
314
315
316
317
317
318
318
319
320
321
322
323
324
325
325
326
326
327
320
329
330
331
331
332
333
334
335
336
337
338
339
340
341
342
342
343
344
345
346
347
348
349
349
350
LINE
NUMBER
7150.258
7150.258
7150.258
7150.510
7150.742
7151.075
7151.992
7152.680
7154.347
7154.347
7156.07
7156.07
7156.73
7156.815
7157.042
7157.172
7157.732
7159.233
7160.205
7160.205
7160.463
7160.463
7161.405
7161.50
7164.072
7164.403
7164.090
7164.898
7165.215
7165.820
7166.058
7166.710
7167.250
7167.33
7168.430
7169.218
7170.272
7172.694
7173.774
7173.774
7173.947
7174.135
7175.492
7175.907
7176.438
7179.106
7179.749
7179.749
7180.400
FREQ
-1
CM
0
2
3
6
2
3
3
1
0
1
2
1
1
2
1
1
6
3
3
2
1
3
0
4
0
0
1
5
0
6
1
4
3
1
7
1
0
2
3
z
6
3
5
2
2
1
1
55
97
97
72
75
75
41
43
88
80
43
22
44
31
21
33
94
30
30
87
87
31
44
40
00
77
77
51
22
03
11
96
96
21
103
22
33
06
06
9:
94
30
62
42
76
76
32
3
3
2
5
1
2
2
4
1
0
3
2
2
1
0
2
5
2
4
i
2
4
3
3
1
1
0
4
1
5
2
3
4
2
6
2
3
3
2
2
1
5
2
4
5
1
2
4
64
97
97
72
65
65
42
52
80
08
31
31
53
32
22
42
84
31
40
a7
07
41
53
42
11
77
77
51
32
83
20
96
96
31
93
32
42
86
86
75
21
94
32
62
51
76
76
41
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
.7528-04
.7371-02
.1925-02
.2426-05
.7279-05
.5697-02
.4899-03
.3943-02
.4778-02
.6312-05
.1894-04
.2432-02
.6065-02
.3392-04
.4070-02
.5974-05
.1993-05
.7331-02
.3450-04
.2081-02
.3974-02
.1747-04
.5822-05
.1025-03
.3605-02
.2245-04
.2083-02
.3013-03
.1166-02
.4535-04
.1512-04
.5750-02
1122.709
173.366
222.053
1590.690
1590.692
224.830
503.969
300.363
37.137
1394.814
1394.817
399.458
212.156
1050.158
70.091
1631.384
1631.242
173.366
1282.920
206.302
300.363
1411.612
1411.638
1059.836
95.176
1360.236
206.302
602.774
326.626
1216.194
1216.186
224.830
STRENGTH
TEMP=295K
.4276-03
.8289-06
.2487-05
.3748-03
.7851-04
.2356-03
.1225-02
.7507-03
.2764-05
.9213-06
.2995-02
.7367-02
.1434-02
.6097-02
.2945-02
.1226-02
-1
756.725
1810.588
1810.590
782.410
BRR.633
888.599
315.780
416.209
1789.045
1789.046
142.279
173.366
508.812
212.156
136.164
315.700
CM
E
021
200
101
101
101
101
200
101
200
101
101
101
101
101
200
101
101
101
021
101
200
101
101
021
200
101
101
101
200
101
101
200
101
101
021
200
200
200
200
200
200
101
101
101
021
021
200
200
BAND
351
352
353
353
354
355
356
357
358
358
358
359
3bO
361
361
362
363
364
365
366
367
367
368
369
370
371
372
372
373
374
375
376
376
377
370
379
380
380
381
382
383
384
305
386
367
388
389
390
391
LINE
NUMBER
TABLE 1 (CONT.)
7185.404
7185.592
7185.592
7185.592
718d.130
7180.345
7189.002
7189.002
7189.18
7189.338
7189.536
7190.280
7190.728
7192.407
7192.407
7194.138
7194.450
7194.555
7194.810
7199.372
7199.372
7202.10
7202.262
7202.YO6
7203.901
7203.901
7204.169
7205.254
7205.688
7207.071
7207.071
7208.912
7209.518
7210.45
7211.066
7211.368
7211.589
7212.137
7212.52
7212.tl9
7212.95
7214.777
7184.L(b
7180.619
7181.138
7182.198
7102.198
7102.93
7183.00
FREQ
-1
CM
3
4
4
3
2
5
84
31
64
61
0
3
5
4
5
2
3
2
6
0
2
1
3
4
1
1
n
4
1
4
2
2
4
3
22
85
73
41
a4
53
75
75
71
11
65
65
31
52
10
55
55
74
11
41
65
75
63
64
74
63
4
0
1
6
4
2
8
6
5
2
5
1
2
2
95
66
66
61
85
76
113
104
95
20
51
10
21
20
31
64
64
04
74
54
31
05
73
41
a4
61
75
75
74
21
65
65
22
52
20
55
55
74
21
32
63
64
63
64
66
103
94
a5
95
66
66
52
95
30
43
11
31
22
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
2
3
2
5
4
1
3
4
4
3
4
5
2
3
3
1
1
2
0
3
2
0
1
3
2
1
3
3
3
2
5
1
0
3
3
1
7
5
4
3
2
0
3
1
E
-1
.7376-02
.4285-03
.1384-03
.7188-04
1122.709
173.366
756.725
757.701
.6201-04
.8808-03
.2871-02
.3755-04
.2813-03
.1489-02
.2286-04
.4042-03
.9744-04
.3251-04
.1777-03
.3591-02
.7492-04
.2248-03
.2963-02
.1943-02
.4063-02
.4597-03
.1532-03
.1827-03
.1165-01
.613?-02
.2396-03
.4582-03
.2271-03
.1420-03
.4282-05
.1046-03
.3487-04
.1952-02
.1247-04
.1104-03
.3321-05
.2373-04
.1269-04
.8779-02
.2648-02
.1401-01
.2849-02
.R861-02
STRENGTH
TEMP=295K
927.745
610.342
142.279
1255.167
842.357
275.497
1131.776
542.906
1059.836
1059.647
931.238
95.176
888.633
fem.599
136.164
446.511
70.091
742.077
742.074
931.238
79.496
212.156
661.549
756.725
661.549
757.781
1474.981
104S.058
1045.059
446.511
1255.912
1045.058
1538.150
1360.236
1477.298
136.762
382.517
42.372
142.279
134.902
CM
101
101
002
101
101
200
101
101
101
101
101
101
002
101
101
101
200
101
101
101
101
101
101
200
021
120
101
101
200
101
101
101
101
200
101
021
021
021
101
101
101
200
101
101
BAND
8
s
$
:
%
g
3
E
I+
FREQ
-1
CM
7214.777
7215.476
7216.1a4
7216.31
7218.196
7219.498
7219.606
7220.752
7220.752
7221.42
7222.28
7223.109
7223.109
7223.40
7224.490
7224.94
7226.017
7227.962
7230.051
7230.315
7230.623
7230.905
7231.350
7231.a68
7232.073
7232.107
7232.107
7232.187
7232.516
7233.183
7233.410
7234.008
7234.405
7235.545
7236.122
7236.436
7236.792
7239.652
7240.408
7241.110
7241.205
7241.382
7241.588
7242.36a
7243.073
7243,922
7244.01
7244.53
7245,562
LINE
WMBER
391
392
393
394
395
396
397
390
398
399
400
401
401
402
403
404
405
406
407
406
409
410
411
412
413
414
414
414
415
416
417
418
419
420
421
422
423
424
425
426
427
428
429
430
431
432
433
434
435
4
1
5
0
2
2
2
6
1
2
1
2
4
2
0
3
2
2
6
3
3
0
1
1
4
0
2
6
1
n
2
4
1
51
21
62
00
43
21
42
a2
43
53
32
33
20
73
31
33
52
32
31
60
63
63
22
11
22
62
22
54
a3
11
22
53
73
32
1
1
2
1
6
0
1
0
3
3
55
54
54
60
11
44
44
42
53
32
22
61
30
61
70
11
22
52
73
10
43
21
41
91
43
53
31
33
11
72
30
33
51
32
22
52
63
62
21
00
53
54
20
53
54
54
63
10
44
44
42
53
ROTATIONAL
TRANSITION
UPPER.
LOWER
STATE
STATE
2
0
5
3
5
7
0
1
3
5
1
3
9
2
3
2
0
1
5
3
1
4
1
1
3
4
4
1
0
1
1
2
1
2
2
1
2
3
1
0
1
2
2
.2103-02
206.302
101
101
200
101
200
120
101
101
200
101
.2959-02
.4097-03
.8853-02
.4097-03
.1058-02
.1403-01
.8936-02
.196a-02
.1071-03
136.164
542.906
136.762
542.906
586.244
42.372
134.902
446.511
816.695
23.794
383.843
95.176
275.497
920.210
382.517
503.969
173.366
285.419
37.137
782.410
136.762
2a5.220
399.458
212.156
134.902
446.511
64A.979
602.774
95.176
.ooo
101
101
101
200
200
101
101
200
101
200
200
200
101
200
101
200
101
101
200
200
200
200
002
200
021
101
101
002
200
101
101
101
101
@AND
.1533-01
.8a25-03
.3609-02
.15oa-02
.6494-04
.2666-02
.4914-03
.7445-02
~4281-02
.4t323-02
.3816-03
.R900-07
.lr29-02
.2471-02
.6122-02
.8984-02
.1952-02
.7271-03
.3057-03
.3636-02
.5785-02
.i44a-02
.8535-03
.4102-02
610.342
70.091
508.812
.1516-O?
.8755-03
.2922-03
.2214-03
.1541-01
.5300-03
.1590-02
.1229-02
.1438-07
STRENGTH
TEMP=295K
508.812
610.342
610.115
661.549
23.794
488.135
488.108
315.780
50R.812
-1
C'J
E
TABLt
1
1
466
467
46R
469
470
471
472
473
474
475
476
477
477
478
479
4BO
rib5
436
437
438
439
440
441
442
443
444
4115
4W6
447
448
448
449
450
451
452
453
454
455
456
457
45a
458
459
459
460
461
462
463
464
LINE
lUMtiEH
ICON.
7245.708
7246.118
724a.158
7249.911
7250.121
7252.000
7252.273
7252.841
7253.105
7253.455
7253.882
7254.049
7254.227
725r.227
7255.400
7256.117
7259.42
7260.904
7261.040
7261.459
7261.54
7262.047
7262.298
7264.51a
7264.518
7266.189
7260.189
7266.370
7266.654
7267.842
7267.95
726a.lb4
7268.43u
7268.605
7268.772
7271.19
7271.33
7271.74
7272.442
7273.000
1273.316
7273.972
7274.681
7274.813
7275.btla
7275.6&b
7275.78b
7276.n99
7277.609
FREQ
-1
CY
0
3
3
4
1
3
1
S
6
2
1
2
6
3
6
7
4
6
3
1
4
5
4
2
5
1
2
4
5
51
21
42
32
61
93
64
53
43
a2
31
71
70
63
a2
53
10
40
62
52
64
73
54
31
74
64
3
3
5
1
3
2
4
0
1
5
2
3
5
3
5
2
33
52
41
41
30
51,
2;:
52
42
40
11
43
72
21
30
a3
74
03
32
1
52
00
31
71
51
65
72
53
31
73
83
4
0
3
6
5
1
6
2
3
5
6
3
5
2
4
2
2
7
3
2
3
7
2
3
8
5
50
21
41
43
53
93
63
32
42
a1
20
63
al
62
74
1
4
2
2
6
4
6
3
4
0
2
2
2
3
1
1
2
6
32
52
32
40
22
42
21
43
42
32
11
42
71
10
21
71
73
03
31
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
-1
200
101
101
200
200
101
101
101
200
200
200
200
021
200
101
200
.1961-O?
~2961-02
.1233-02
.ilao-01
.2691-02
.3991-02
.6138_02
.4805-02
.1243-02
.5605-03
.1549-01
.11RO-01
.5874-03
.2a57-03
.1277-03
.2a98-02
.1a44-03
.7633-03
.5775-02
.2904-02
.5437-03
.1182-02
.7372-04
.la25-03
.145a-02
.2aa6-02
.loa3-05
.1290-03
300.363
a02.891
70.091
661.549
744.163
552.912
931.238
416.209
,000
142.279
704.214
326.626
888.633
709.609
508.812
142.279
816.695
1006.117
200
101
200
002
200
002
200
200
101
200
200
101
.3562-02
.1174-01
.5818-02
.2608-02
.1447-02
.1530-04
.2305-03
.2123-02
.4027-02
.7830-04
.4127-02
.2290-03
.4471-03
.1175-02
325.340
79.496
224.a3a
382.517
508.812
1216.232
661.549
206.302
200
101
200
002
101
101
200
200
200
200
200
101
002
200
.61a6-02
.7571-03
.2122-02
200
101
200
BPND
STRENGTH
TEMP=295K
212.156
416.209
206.302
222.053
136.164
315.780
79.496
382.517
300.363
212.156
37.137
315.780
704.214
23.794
79.496
704.214
842.357
1006.117
142.279
cM
E
503
504
505
506
507
508
509
510
511
512
513
514
515
516
517
518
519
520
521
522
523
524
525
526
527
520
400
409
490
491
492
493
494
495
496
497
490
499
500
500
501
502
405
406
407
40.1
482
403
484
LINE
NUMBEK
7270.025
7278.557
7270.751
7200.306
7280.490
7201.075
7201.21
7201.720
7201.00
7202..706
7283.015
7203.732
7283.900
7284.710
7285.048
7205.776
7205.075
7286.040
7286.712
7207.030
7267.030
7287.50
7200.094
7209.06
7290.111
7290.929
7291.404
7291.609
7291.720
7292.302
7292.607
7293.063
7294.123
7294.260
7295.632
7296.654
7296,857
7297.534
7297.995
7290.354
7290.606
7299.426
7301.890
7302.590
7302.760
7303.224
7304.536
7305.065
7306.345
CM
-1
FREld
5
6
6
1
3
2
5
2
6
7
0
1
6
5
7
1
2
3
2
7
6
60
61
65
41
65
51
20
71
02
55
55
72
72
103
21
06
96
32
71
60
5
0
4
1
6
2
62
22
51
22
94
21
50
0
9
7
1
4
6
2
1
3
3
6
5
2
4
4
44
134
92
44
62
03
75
22
64
64
105
61
54
51
41
6
1
3
O
7
1
61
33
42
11
93
11
95
94
21
72
51
71
72
103
11
71
70
64
41
64
40
10
70
83
54
54
5
6
1
6
5
7
6
8
0
7
7
2
4
3
4
1
7
6
1
2
4
4
52
41
1
10
0
2
5
7
3
O
4
7
6
3
5
3
43
13 4
91
43
62
82
74
33
63
104
60
53
62
30
TRANSITION
UPPER
LOhER
STATE
STATE
HOTATIONAL
-1
200
002
002
200
101
200
200
101
200
002
200
200
200
101
101
101
002
021
200
002
200
.5030-02
.3226-03
.9690-03
.1446-03
.5001-02
.4362-03
.1974-02
.1547-01
.1002-02
.1251-03
.8912-03
.2974-03
.3330-03
.1819-03
.1502-04
.1414-01
.4237-05
.8030-05
.3670-02
.1773-03
.1187-02
586.480
586.244
757.781
224.036
756.725
222.053
23.794
586.244
1006.117
610.342
610.115
506.480
709.609
1446.129
42.372
1474.981
1340.885
95.176
709.609
326.626
200
002
200
200
200
101
.1972-02
.1402-02
.4037-02
.1421-01
.1544-04
.4828-02
447.253
285.220
300.363
42.372
1216.232
37.137
224.030
101
200
200
101
200
200
002
021
200
200
002
200
200
200
200
BAND
.0950-03
.1412-07
.9040-04
.2703-02
.1170-02
.2323-03
.1860-03
.4200-02
.8014-03
.7363-03
.7796-05
.6584-03
.4980-03
.1138-02
.8961-02
STRENGTH
TEMP=295K
383.843
2874.437
1079.080
302.517
552.912
885.601
931.238
205.419
416.209
640.979
1501.337
446.697
503.969
552.912
136.762
CM
E
TABLE
1
i
563
564
565
566
567
560
560
569
570
562
563
550
551
552
553
554
555
556
557
550
559
560
560
561
529
530
530
531
531
532
533
534
534
555
536
537
530
539
540
541
542
543
544
545
546
547
547
540
549
LINE
NUMBER
(CONT.)
7331.247
7330.265
7330.495
7326.591
7327.602
7327.602
7320.000
7320.430
7329.451
7330.103
7330.265
7306.483
7306.730
7306.738
7307.191
7307.191
7308.13
7300.69
7308.811
7308.811
7309.245
7309.949
7310.10
7310.336
7310.43
7310.666
7312.193
7312.069
7313.059
7313.53
7313.70
7314.206
7314.512
7314.512
7315.703
7315.985
7316.971
7310.60
7310.724
7319.440
7319.08
7320.70
7322.711
7322.065
7323.425
7323.961
7325.710
7325.710
7325.013
CM
FRkQ
-1
53
211
42
00
80
3
0
8
3
2
4
4
1
2
4
2
6
4
1
5
31
52
41
32
65
52
43
71
40
43
73
5
5
3
5
1
3
6
72
51
42
Y4
32
42
82
7
7
7
0
2
3
5
2
32
30
50
31
70
71
114
91
1
3
6
0
1
7
5
2
2
5
7
4
4
22
31
61
66
66
01
72
32
21
61
82
63
51
4
6
0
2
7
40
02
22
31
02
4
2
2
0
7
51
32
32
00
71
1
5
3
2
5
3
1
5
3
0
6
50
31
21
61
41
33
62
30
33
71
6
6
9
21.
60
105
90
6
4
6
73
60
61
1
2
6
3
2
2
5
1
2
0
4
3
1
4
8
3
5
22
20
61
42
20
21
50
65
65
00
63
30
32
52
81
64
51
TRANSITION
UPPER
LONER
STATE
STATE
KOTATIONAL
.2707-03
.6400-03
.1966-02
.5070-04
.2990-02
.7531-02
.2318-03
842.357
446.697
206.302
.ooo
586.480
399.450
206.302
136.762
205.419
704.214
205.220
552.912
95.176
325.34A
142.279
79.496
542.906
275.497
447.253
446.697
1710.720
920.169
222.053
982.912
136.164
173.366
885.601
.2488-02
.2072-02
.2120-02
.5669-02
.3353-03
.3655-02
.3568-02
.2905-02
.1192-01
.4343-03
.1527-02
.1447-02
.1104-02
.8958-02
.4338-02
.5625-03
.1981-02
.6621-03
.4012-05
.1973-03
.9019-02
.4125-02
.1914-02
.3920-02
416.209
744.163
756.725
326.626
134.902
70.091
447.253
300.363
.4122-02
.1181-01
l3584-02
.7655-04
.2297-03
.1550-03
.7394-03
.8935-02
.6024-02
.7672-03
.4648-03
.4229-03
.1100-02
70.091
79.496
325.340
880.633
000.5Y9
744.064
640.979
136.762
212.156
STRENGTH
TEMP=295K
-1
IX
E
101
002
101
000
200
101
101
101
200
021
200
101
200
101
101
101
200
200
200
200
002
002
101
021
101
200
101
101
101
002
002
101
101
200
200
200
200
200
101
002
200
200
002
101
BAND
s
r
g
$
kz
5
g
;;
.
E
a
571
572
573
573
574
575
576
577
570
578
579
5MO
560
581
582
582
563
584
584
585
586
587
588
569
590
591
592
593
594
594
595
595
596
597
598
599
600
600
601
602
603
604
605
606
607
60.7
608
609
610
LINE
kUWEh
7331.717
7332.237
7332.71
7332.71
7332.86
7333.06
7333.31
7333.665
7333.044
7333.644
7334.153
7334.523
7334.523
7336.314
7336.811
7336.811
7337.712
7338.172
7330.172
7339.037
7340.216
7340.71
7341.08
7341.570
7341.904
7342.586
7342.865
7343.241
7343.395
7343.395
7343.519
7343.519
7343.856
7344.142
7345.31
7345.40
7345.908
7345,YUil
7346.683
7346.840
7347.046
7348.410
7349.907
7350.040
7350.890
7350.890
7351.484
7353.137
7353.60
FRtQ
-1
CM
6
4
6
5
6
1
5
2
1
4
2
0
1
5
2
7
1
6
5
7
9
9
6
6
1
3
1
8
2
1
6
1
3
4
7
0
2
1
83
40
94
62
82
54
62
43
33
41
54
33
54
51
42
93
55
72
50
81
90
91
71
71
11
41
33
102
65
65
72
43
53
52
HZ
11
76
76
532
30
3
u
7
6
6
3
81
92
Y3
83
42
102
55
55
70
40
43
42
71
22
66
66
43
41
81
80
72
71
22
31
31
01
51
92
51
73
40
60
41
22
50
44
22
44
41
32
91
43
61
40
72
70
92
94
71
51
ROTATIONAL
TRAN5ITION
UPPER
LOWER
STATE
STATE
9
1
0
7
4
2
3
6
1
1
0
1
4
A
A
5
7
0
2
2
7
5
7
4
5
4
6
3
0
5
1
1
0
4
1
8
2
5
4
6
7
0
5
7
4
1293.635
742.074
742.077
SRh.244
222.053
382.517
300.363
704.214
134,902
1045.058
1045.059
383.843
224.030
744.163
744.064
782.410
586.480
136.164
173.366
17S.366
.3180-04
.1563-03
.4688-03
.1003-07
.1988-02
.2709-02
.4045-02
.5679-03
.8830-02
.1070-03
.3567-04
.8976-03
~5697-02
.4669-03
.1557-03
.374fJ-03
.3337-03
.2923-02
.7510-02
.7510-02
.7848-04
.1153-02
.4967-04
.2506-02
.1091-03
.2080-02
.6590-03
.1520-02
.3019-02
.3481-02
.1616-02
.9113-02
.5387-03
.5839-02
.6212-02
.9051-04
.2855-02
.4153-03
.1974-02
.1842-03
882.891
326.626
1201.922
399.458
816.695
222.053
446.697
275.497
136.164
325.348
46B.108
134.902
458.135
224.030
212.156
1079.080
382.517
542.906
222.053
709.609
STRENGTH
TEMP=295K
.1007-02
.2995-04
.2234-04
.3515-03
.2424-02
506.244
-1
1080.386
1360.236
5R6.480
399.458
CM
E
101
101
101
101
200
101
101
200
002
101
101
101
002
200
200
002
101
002
101
101
101
002
101
200
200
021
101
101
200
002
101
200
101
101
101
101
021
200
101
200
200
101
002
021
002
BAND
TABLE
FREQ
-1
CM
7353.726
7353.726
7353.92
7354.180
7354.361
7354,573
7355.256
7355.570
7356.045
7356.630
7357.02
7357.183
7357.626
7358.06
7358.96
735b.Y6
7359.05
7359.320
7359.97
7361.475
7361.475
7362.16
7362.27
7362.438
7362.59
7363.232
7364.22
7364.22
7364.35
7364.643
7365.000
7365.373
7365.464
7366.31
7366,405
7368.405
7366.54
7368.652
7369.093
7369.206
7369.206
7370.35
7370.35
7371.14
7371.46M
7372.07
7372.805
7372.805
7372.805
LINE
NUMBEH
611
611
612
613
614
615
616
617
618
619
620
621
622
623
624
624
625
626
627
628
628
629
630
631
632
633
634
634
635
636
637
638
639
640
641
642
643
644
645
646
646
647
647
648
649
650
651
651
65;
1 (CONT.)
120
120
101
101
002
101
101
002
200
200
200
021
101
101
101
101
101
101
002
101
101
101
101
002
101
790
TOO
200
.4975-04
.1658-04
.1550-03
.8930-03
.1927-02
.1253-02
.1525-02
.2903-03
.2151-02
.7689-04
.2563-04
.5280-03
.7679-03
.2300-03
.7665-04
.5006-03
.19Cil-02
.6621-03
.4264-03
.4655-04
.1552-04
.7493-05
.2498-05
.2847-02
.1973-03
.9097-C'
.2729-04
.1263-C?
1216.194
1216.186
744.064
610.342
222.053
315.780
275.497
4
7
7
6
2
3
3
2
2
8
63
71
70
71
86
86
97
97
20
Y2
35
3
12 0 12
12
__ 1 12
_
2
5
3
2
65
62
75
75
11 0 11
11 1 11
5
1
61
43
610.115
206.302
1114.550
1114.533
503.969
416.209
880.599
880.633
503.969
447.253
446.697
756.725
1214.194
1216.186
1590.692
1590.690
142.279
920.169
1327.118
1327.110
315.780
6
3
1
2
2
1
3
9
11 1 11
11 0 11
42
2
2
3
60
64
76
76
a7
07
31
90
53
61
53
52
65
65
3
6
3
4
2
1
10 1 10
LO 0 10
54
32
1
2
8
1
4
2
3
2
1
7
2
3
3
4
87
07
R2
64
31
52
51
76
76
80
54
40
42
41
101
101
.2979-03
.4648-03
61fl.115
744.163
2
8
3
7
64
01
54
81
101
200
101
200
101
200
200
.1560-01
.1982-03
.1187-02
.2346-03
.3584-02
.6267-02
.7926-04
23.794
920.169
326.626
885.601
325.348
212.156
802.091
1
9
5
7
5
1
7
10
90
51
82
50
32
81
22
0
10 1 10
61
6
91
8
60
6
43
2
92
8
120
120
.1145-03
.3818-04
1045.058
1045.059
1
0
66
66
0
1
77
77
-1
BAND
E
CM
STRENGTH
TEMP=295K
ROTATIONAL
TRANSITION
UPPER
LONER
STATE
STATE
y
-I
g
x
"0
e
m
0
cr:
g
cn
=j
z
M
668
669
670
671
672
673
674
675
676
677
677
678
679
680
681‘
662
682
603
604
685
685
686
687
68.3
609
690
691
692
693
694
694
660
666
667
b68
665
664
663
658
659
660
661
662
657
652
653
654
655
656
LINE
iUMf3EH
7373.918
7375.181
7375.547
7375.722
7376.323
7377.38
7377.623
7378.672
7379.302
7380.006
7380.108
7380.343
7381,022
7381.415
7381.604
7381.770
7382.19
7382.19
7302.19
7382.34
7362.503
7382.71
7303.660
7304.176
7384.399
7364.497
7304.873
7385.036
7365.036
7305.24
7386.04
7366.53
7306.74
7307.085
7387.085
7360.593
7308.846
7390.133
7390.133
7390.709
7391.264
73Y1.45
7392.22
7392.390
7392.78
7393.13
7393.516
7393.837
7393.537
FREQ
-1
CM
6
4
5
3
2
6
6
1
1
2
4
3
8
3
3
21
a3
71
43
10
53
62
75
103
a5
74
11 2 10
a2
7
90
9
91
9
5
2
4
7
3
1
2
73
21
05
93
05
54
64
64
2
50
5
74
4
54
2
72
6
44
1
44
0
74
3
al
a
a0
R
32
1
102
9
13 0 13
13 1 13
101
9
73
5
63
63
61
60
.7420-03
.R791-02
.3337-04
.4921-03
.ltJOO-03
.2523-02
.417R-03
.aa73-02
.389a-03
.4151-03
.587a-02
.1163-01
.409S-02
.1994-02
.7836-03
.5039-04
.3051-03
.5712-03
.2719-04
.1a43-03
.155f3-03
.4671_03
648.979
136.762
lOS9.647
744.163
1059.836
399.458
542.906
134.902
782.410
542.906
224.838
79.496
300.363
446.511
648,979
1201.922
842.357
704.214
1327.110
709.609
744.064
744.163
4
3
3
a
2
4
5
I
6
5
5
4
2
3
3
4
7
4
586.480
586.244
70.091
1114.533
1557.852
1557.841
1114.550
602.774
5
2
3
3
5
0
1
2
7
7
2
10
12
12
10
4
.3792-02
.2649-02
.4384-03
.1991-02
.1185-02
.4398-02
.1468-02
.1454-03
.3354-03
.1007-02
.4164-02
.2552-04
.8867-05
.2956-05
.7657-04
.311Q-03
STRENGTH
TEMP=295K
325.348
382.517
756.725
446.511
552.912
285.419
285.220
757.781
-i
.4880-03
.2003-02
.2503-02
.1469-02
CM
E
101
101
101
101
200
200
101
101
002
200
101
021
200
021
002
101
002
101
021
101
200
200
021
002
101
101
IO1
200
200
101
101
101
101
101
200
200
101
200
002
200
101
101
BAND
ThiLi
503.969
446.511
399.458
508.812
3
3
4.
2
11 0 11
72
6
a0
8
81
a
71
72
61
41
22
42
52
63
92
73
22
63
30
75
al
75
51
61
50
43
64
52
62
33
33
64
71
70
20
10 0
12 1
12 0
10 1
62
53
52
51
53
ROTATIONAL
TRANSITION
UPPER
LOkER
STATE
STATE
1
695
696
697
698
699
700
701
701
702
703
704
705
706
707
708
709
705,
7fJ9
710
711
712
713
714
715
716
717
718
719
720
720
721
722
723
723
724
724
725
726
727
728
729
729
730
7.51
732
733
734
734
735
LINE
NUMBER
(CONT.)
7426.449
7396.362
7396.464
7397.11
7397.585
7399.168
7399.528
7400.456
7400.456
7401.291
7401.993
7402.753
7402.875
7403.6213
74b4.482
7404.619
7405.158
7405.158
7405.158
7406.037
7407.36
74o7.7Yb
7407.Y3
7408.70
7409.552
7411.376
7413.015
7413.674
7415.604
7416.048
7416.046
7416.353
7417.826
7418.250
74la.25b
7418.070
7418.670
7419.177
7419.84
7419.965
7420.159
7421.25
7421.25
7421.40
7422.56Y
7424.692
7425.Y7r
742b.121
7426.121
FREb
-1
CM
6
5
1
7
4
6
1
2
2
1
5
1
4
4
3
10
5
10
a
0
a
0
2
1
7
6
7
2
11
11
9
9
3
2
1
n
5
6
6
13
13
6
0
5
1
12
12
10
Y4
84
22
81
73
a3
21
54
31
54
95
33
a4
95
30
10 0
72
10 1
92
.44
91
00
53
11
71
94
Y3
42
11 1
11 0
102
101
64
20
55
55
83
105
82
14 1
14 5
116
33
105
10
12 1
12 u
11 1
95
72
14 1
14 0
106
21
95
11
11 1
11 0
101
5
5
14
14
5
1
4
0
11
11
9
a2
7
74
4
31
2
71
6
63
3
73
5
22
0
43
1
32
1
43
2
a5
4
20
2
74
3
a5
3
31
2
90
9
62
4
91
9
a2
7
42
3
al
7
11
1
51
5
20
2
62
4
a4
5
a3
6
30
3
10 1 10
10 0 10
92
a
91
0
53
2
21
1
44
0
44
1
73
4
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
-1
1474.9Rl
78?.410
2073.521
2073.510
1874.974
95.176
1477.298
42.372
1327.110
1327.110
1293.019
Has.601
927.745
173.366
704.214
661.549
816.695
136.164
383.843
212.156
382.517
1255.167
70.091
931.238
1255.912
173.366
920.169
602.774
920.210
885.601
300.363
882.891
37.137
326.626
70.091
602.774
1122.709
1006.117
136.762
1114.550
1114.533
1080.3ab
1079.089
508.812
95.176
488.135
4a8.108
842.357
CM
E
_I..
.4421-05
.38B9-03
.7157-06
.2386-Qb
.1885-05
.3705-02
.1312-04
.1401-01
.9102-05
.2731-04
.1075-04
.2472-03
.6360-04
.7366-02
.5678-03
.2331-03
.1094-03
.2945-02
.9096-03
.6100-02
.2747-02
.3867-04
.4204-02
.la70-03
.1285-04
.7374-02
.1982-03
.31OP-03
.6606-O&
.2347-03
.4077-02
.7928-04
.4779-O;?
.1196-02
.4070-02
.3029-03
.73aa-04
.1305-03
.9066-02
.7691-04
.2564-04
.3029-04
.9147-04
.1487-02
.3606-02
.5483-03
.1645-02
.2903-O:!
101
101
101
101
101
101
101
002
101
101
101
021
101
002
101
101
101
002
200
002
200
101
200
101
101
002
101
101
101
101
101
101
002
101
002
002
101
101
101
101
101
101
101
200
002
200
200
101
STRENGTH
IEF*P=295K BAND
_
769
770
771
772
773
774
775
7b8
757
758
750
759
760
761
762
763
764
7b4
764
765
766
767
76.7
756
737
730
739
740
741
742
743
744
744
745
745
746
747
748
740
749
750
751
751
752
753
754
755
736
735
LIlvE
dJMBEh
7426.449
7426.593
7427.950
7428.34
7429.706
7431.34
7431.432
7432.04
7432.304
7435.602
7435.602
7435.735
7435.735
7435.939
7436.903
7437.177
7437.177
7437.991
7438.22
7438.973
7438.973
7439.361
7440.056
7441.145
7441.354
7444.353
7444.54
7444.686
7444.686
7445.52
7445.67
7446.310
7447.477
7450.931
7452.396
7452.396
7452.396
7452.627
7453.564
7453.717
7453.717
7454.45
7455.206
7459.23
7459.364
7459.826
7460.14
7461.138
7461.887
FREO
-1
CM
11
103
Ii
7
7
10
6
10
13
15
15
9
6
1
0
11
3
1u
93
1
6
4
9
5
9
12
14
14
8
5
0
1
10
4
113
94
112
13 1
14 1
14 0
114
83
55
55
12 3
40
h43
73
413
6
3
3
3
5
12
12
6
10
10
A
2
7
2
3
9
6
12 3
104
12 2
14 1
15 1
15 0
124
94
bb
66
13 3
52
752
82
532
63
102
94
707
82
52
30
63
83
12 1
12 0
10 5
11 2
11 1
10 3
53
92
21
541
63
4
54
2
31
2
10 4 7
73
4
12 2 11
12 1 11
717
102
a
10 5 5
7
6
2
4
6
13
13
7
11
11
9
1
8
1
2
10
7
657
65
1
65
1
43
1
11 4
8
04
5
13 2 12
13 1 12
b24
112
9
11 5 6
65
11 2
104
734
92
61
43
74
93
13 1
13 0
11 5
12 2
12 1
11 3
55
102
33
ROTATIONAL
TRANSITION
UPPER
LOWER
STATE
STATE
-1
22.794
12R2.920
1695.069
1360.236
1690.665
2042.312
2073.521
2073.510
1843.029
1050.158
742.077
742.074
1962.508
222.053
756.725
842.357
275.497
610.342
640.979
610.115
173.366
1581.337
842.357
1774.753
1774.611
586.480
1437.969
1724.706
661.549
1293.635
1340.885
586.244
982.912
446.511
136.762
661.549
1050.158
1557.052
1557.841
1718.720
1525.136
152U.849
1446.129
508.812
1201.922
79.496
CU
E
.1541-01
.3404-04
.1517-05
.2330-04
.4651-05
.8369-06
.?la8-06
.2396-06
.7375-06
.3551-04
.4788-03
.1596-03
.1236-05
.2004-02
.4461-03
.2a42-03
.1545-02
.90.56-03
.?4?6-03
.3032-03
.?bOE-02
.?918-05
.2931-03
.3083-05
.1029-05
.3294-03
.5314-05
.1312-05
.2340-03
.3215-04
.asi3-05
.1021-02
.4aa2-04
.1953-02
.9146-02
.235?-03
+35la-04
.aa72-05
.2958-OS
.4048-05
.3469-05
.1042-04
.1530-04
.1481-02
.5037-04
.1202-01
STRENGTH
TEMP=295K
002
101
101
101
101
101
101
101
101
200
200
200
101
101
200
002
101
200
101
200
101
101
200
101
101
002
101
101
101
101
101
200
101
002
200
200
101
101
101
101
101
101
101
101
101
101
BAND
TABLE
776
777
778
779
7hO
781
702
783
784
705
786
787
768
789
789
789
790
791
791
792
793
794
795
796
796
797
797
798
799
RbO
no0
601
eo2
au3
all4
805
a06
a07
808
809
610
811
612
a12
812
813
a14
LINE
IWFiBEK
1 (CONT.1
7466.503
7466.724
7460.84
7469.532
74bY.690
7470.00
7473.703
7473.95Y
7475.193
7476.26
747b.t.20
7476.71
7476.90
7478.641
7470.641
7478.641
7479.09
7479.5Yl
?479.>91
7464.320
7485.074
7405.329
7486.19
7490.975
7490.Y75
7491.285
7491.2M5
7492.17
7492.59
7495.563
74Y5.563
7496.342
7497.140
7497.7YZ
7498.121
7498.489
7499.55
7501.34
7501.61
7504.73
750*.97
7507.49
7508.04
7506.04
7508.04
7508.42
7509.19
FREQ
-1
CM
2
3
2
1
1
3
4
1
7
9
0
4
3
4
3
5
2
7
4
2
2
4
2
1
5
1
1
3
2
2
6
4
3
4
5
1
2
4
2
31
41
65
11
22
fl
21
74
a5
4
52
3
51
22
31
2
114
124
a
123
13 3 10
00
11
1
62
63
3
52
53
2
51
b3
3
74
03
b
62
4
61
21
22
1
92
93
6
40
41
3
43
1
42
31
44
1
73
74
3
52
3
43
44
n
32
63
4
50
10
21
2
33
(!
32
31
32
2
21
30
3
32
71
41
42
41
50
76
76
52
53
44
72
53
43
42
51
87
87
53
54
1
5
3
2
3
4
2
1
3
1
1
2
1
2
76
20
42
32
2
6
3
3
7
1
7
b
2
R
21
114
72
43
113
20
104
63
31
103
HOTATIONAL
TRANSITION
UPPf_R
LOWER
STATE
STATE
E
.21?7-02
.5607-03
.5970-02
.4022-02
.5816-02
.3562-02
.4?74-04
.1592-04
.7624-03
.1456-02
206.302
704.214
224.838
300.363
224.030
325.348
1216.194
416.209
508.812
1216.186
.3634-02
.19oq-03
.2472-02
.8984-02
.1690-05
.2053-06
.5784-02
.3057-03
.1966-02
.2541-02
.1649_03
.4098-03
.11?9-01
.4940-04
.1961-02
.1241-02
.7713-02
.2b55-03
.?bVl-02
.6344-02
.3677-02
.1549-01
.6179-02
.2897-02
.1180-01
95.176
931.238
399.458
134.902
1fl99,ooa
2105.867
,000
602.774
446.511
399.458
931.238
542.906
79.496
1201.922
222.053
315.780
173.366
842.357
382.517
212.156
325.348
23.794
212.156
143.279
70.496
101
002
101
002
002
002
200
200
002
002
002
200
002
002
101
101
002
002
002
101
002
002
002
002
002
002
200
002
002
101
200
002
002
002
002
002
002
200
002
.?443-02
.150?-02
.2350-03
.4823-02
173.366
275.497
888.599
37.137
BAND
002
101
002
101
101
STRFNGTti
IEMP=295t'
.4102-02
.2231-fl5
.2291-03
.2963-02
.3271-05
-1
70.091
1616.453
661.549
142.279
1538.150
CY
TOTH AND MARGOLIS
240
Sample pressures ranged from 1 to 9 mm of Hg, and paths, from 8 to 32 m. A multitransversal cell of 2 m base length was used for all measurements. The foreoptics, source,
and PbS detector were housed in a vacuum box that was connected to the vacuum
spectrometer’and
the absorption cell. All measurements
were obtained for the Hz0
sample at room temperature.
RESULTS AND DISCUSSION
Table 1 is a listing of the measured line center frequencies, upper- and lower-state
rotational quantum numbers (J K-r Kr), ground-state energy levels, line strengths, and
band assignments. The line numbers given in the first column in Table 1 pertain to the
numbering of the Hz0 absorptions shown in Fig. 1. Values of the ground-state
energy
levels were taken from the work of Flaud and Camy-Peyret
(3), The line strengths, S’,
given in Table 1 were calculated from the expression
S’ = g*v.exp (-E”/kT)/(Q.vo),
(1)
00
0
7245.Hll
10
1
1
0
7273.000
7284.745
7289.982
'fr24.j7?
7r36.Roo
'(?Ll,oi?3
E895.147
6913.72
6919.570
2
2
13li.902
7325.230
7341.794
7376.:73
7377.573
'1?69.319
7277.682
1293.203
7329.408
733l.tl6
6041.168
7382.287
7386.244
7418.061
7445.574
7451.868
7333.5%
7338.252
7368.971
7398.401
7405.236
7472.96%
7473.064
7007.41:
7016.740
'051.41:
;09a.o,4
7103.618
7"01.791
7201.961
7415.600
',417.83a
'14C7.768
7489.354
7505.811
7568.203
K6R.889
7665.530
'(iG5.j63
iO91.9?6
'1096.72
ilj4.482
7191.366
7205.416
7514.951
7515.918
75e7.395
7601.310
7632.644
'(688.654
7193.65
719G.lj7
11
11
20
21
211
22
22
1
0
30
3
31
3'1
3
2
32
32
33
33
2
1
1
0
40
41
4
4
41
42
42
3
3
2
43
2
:2:
44
0
50
5
;:
52
52
53
53
t
4
3
3
2
::::
7517.497
7517.744
7464.438
7466.234
'1517.220
7536.568
7552.368
7611.810
7613.426
7707.634
7707.717
7563.945
7564.673
7636.972
7648.772
7677.259
7729.563
7735.324
7825.820
7826.299
7690.435
7784.287
77a4.500
5:
5:
1
0
7945.970
7945.985
7906.97
7Mi.00
60
61
6
6
61
62
62
6:
5
5
4
4
7680.923
7681.203
7775.003
$781.212
7836.643
',370.4;a
63
64
3
3
7884.534
'($7.300
7631.701
7632.086
7725.455
Y'i33.302
w34.02;
,?,?1.692
7838.902
79ni.003
6955.0%
6972.747
;0?7.3'>
7028.5:P
7298.395
7g.:g4
743'h
7275.735
7306.511
7338.989
7419.036
7423.005
7556.394
'1556.535
7723.590
7723.61
731?.47
7313.75
7424.844
744p.486
749?.3?0
>iC3.210
'7:73.900
; .(Ol.782
LINE
64
65
2
2
"6::
66 0
70
71
-IL
72
72
'73
73
POSITIONS
;;g.;G&2
808;:98
pm;;
2 A
74
75
7
7
G
G
5
5
4
4
3
3
7815.55
7815.664
7929.98-f
7932.923
8007.962
8032.649
0oco.720
8135.403
8138.808
8253.977
;i
76
77
E
1
1
88;$:09947
8395.95
8559.73
80
81
81
82
a2
a3
8
8
7
7
6
G
z
84
85
85
86
E6
87
37
88
;
4
4
3
3
2
2
1
0
7967.854
7967.891
8101.798
8103.123
8202.572
6a6.221
8?61.525
3324.200
8334.854
3444.044
8444.7oG
05e5.40
8585.40
3751.13
90
91
91
92
v
9
8
8
;5:
03
94
94
95
95
96
96
97
97
7'
6
G
5
5
4
4
3
3
2
14
OF HsO
7927.923
Ro4Y.316
8049.49
8195.79
8195.81
7702.715
7868.625
7869.352
8063.68
rn63.88
7765.981
7766.148
7380.508
7004.476
7oy.674
7985.276
8014.571
8093.604
5C96.61
7448.56
7449.197
7587.738
7598.338
7676.304
7730.2X?
7‘152.575
7871.745
7875.197
8039.684
8039.380
8233.409
8215.953
10 0 10
10 110
101 9
102 9
102 a
103 8
103 7
104 7
104 6
105 6
105 5
241
8363.79
7917.72-l
7917.965
8052.192
8054.116
8150.838
8169.501
7602.173
m2.33
7767.349
7773.290
7879.253
7919.207
7958.439
8283.722
8072.01
8408.14
8233.780
g::';
3
8137.900
8138.004
tP90.685
8291.637
8412.&O
8419.793
t482.464
8535.716
8558.25
8657.917
8660.389
6198.63
8087.380
8087.419
'7772.845
7773.266
.2
-IpI:",
88224309.t57
8361.782
8128.646
8503.730
8s31.953
8325.28
8325.3'1
a$.;;
2;::9703a
8445.91
7961.71
7961.75
8176.46
8178.09
g:;z
8961.04
e639.105
8642.29
%%’
8807:720
8894.97
8901.99
8167.67
8167.69
11 0 11
u 111
11110
11 2 10
112 9
8407.30
::;z
12 0 12
1e 1 12
It*111
12 2 11
12 2 10
8753.23
8753.24
;;gfh;;
13 0 13
13 11:
13 1 12
13 2 12
8993.46
8993.47
9219.15
Y2L9.11
8700.00
8700.00
8391.19
8391.M
9141.60
8632.10
8632.11
242
where g is the statistical weighting factor for the ground-state level, v is the line center
frequency, E” is the ground-state energy level, k is Boltzmann’s constant, Q is the rotational partition function (173.7 at 295 K), and vO is the band center frequency. The
expression for the line strength, S, measured from spectra involves additional terms in
Eq. (1) such as S,, the vibrational band strength; L, the rigid-rotor transitionintensity;
and F, a factor which accounts for the nonrigidity behavior of the molecule and is a
function of the rotational transition.
S = S,o.S’.F-L.
(2)
LINE POSITIONSOF Ha0
___._-_
.__
-..__.___-._-_-._
._--A--.-.
____
mc
bW
em
.I-__---_.-
243
~__~~~~__.~
4
Q
M
L___
A_._.
dOQ
-_._.__-.._I._---..-_
__.___
_i_
244
TOTH
AND MARGOLIS
LINE
POSITIONS
OF Hz0
245
246
TOTH
AND MARGOLIS
I
i
I
t
LINE
POSITIONS
OF Hz0
247
248
TOTH AND MARGOLIS
-
1
LINE
POSITIONS
OF Hz0
249
FIG. 1. Scan of the 6950-7500 cm+ region of HzO. The sample pressure was 9 mm of Hg and the path
length was 16 m.
The rotational
and assignments
analysis
of the five bands was aided with a listing of the line positions
of H,O in the 1.4bm
region
from
the unpublished
work
of Benedict
(4). Also a similar
and more complete listing is given by Garing and McClatchey (5).
The values of the line positions for several lines given in this work differ from those
given in Refs. (4) and (5) and the maximum difference is 2.4 cm-l for ground-state
transitions to the 918 level of the (200) state.
Tables 2 and 3 list values of the energy levels of the (lOl), (200), (021), and the (002),
(120) states, respectively. The wavelength coverage of this work did not extend far
enough to observe the 000-101 transition of the (021) band or several transitions of the
(120) and (002) bands. Values of the energy levels given in Tables 2 and 3 were determined from the measured line positions and values of the ground-state levels (3).
Several of the lines appear much stronger
than would be expected considering
only
their respective unperturbed
line strengths. For example, the strength of the transition,
652-735 of the (021) band (line No. 152) is enhanced by a factor of -800 because of a
strong Fermi interaction of the (021) level with the 634 level of the (101) state (line
No. 154). An example of Coriolis interactions is shown in Fig. 1 for line No. 631 given
as the transition, 615-542 of the (002) band which is enhanced by a factor of -200
because its upper level is located only 5.25 cm-’ from the position of the 643 level of the
(101) state (line No. 621). The transition strengths of both (101) lines given above are
deenhanced such that the sum of the observed line strengths
equals the sum of the calculated, unperturbed line strengths.
of the interacting
levels
LlNE
POSITIONS
OF Hz0
251
ACKNOWLEDGMENT
The authors thank Susan Walp and Raja Gangadharan
for their assistance in carrying out the research.
Also the authors thank Dr. William Benedict for the use of the unpublished
values of line positions and
quantum assignments
cited in Ref. (I).
This paper presents the results of one phase of research carried out at the Jet Propulsion
Laboratory,
California
Institute
of Technology,
under Contract
Number NAS 7-100, sponsored hy the National
Aeronautics
and Space Administration.
RECEIVED:
September
23, 1974
REFERENCES
1.
2.
3.
J.
5.
J. PL~VA, J. Mol. Spectrosc. 25, 62 (1968).
L. A. PUGH, Ph.D. Dissertation,
The Ohio State University,
1972.
J. M. FLAW AND C. CAMY-PEYRET, J. Mol. Spectrosc. 26, 811 (1973)
W. S. BENEDICT, private communication.
J. S. GARING AND R. A. MCCLATCHEY, .4pp/. Opt. 12, 254.5 (1973).