Technical Information www.addivant.com Effective: April 2013 LOWINOX® 22M46-45D dispersion Aqueous preparation of an antioxidant Description LOWINOX® 22M46-45D dispersion is a 45% by weight water-based dispersion of the hindered phenolic antioxidant LOWINOX® 22M46 stabilizer. Active Ingredient LOWINOX® 22M46 stabilizer Chemical Name Phenol, 2,2'-methylenebis[6-(1,1-dimethylethyl)-4-methyl- Synonym 2,2’-Methylenebis(6-t-butyl-4-methylphenol) CAS-Number: 119-47-1 EINECS-Number: 204-327-1 Formula LOWINOX® 22M46 stabilizer Typical physical properties of LOWINOX® 22M46-45D dispersion Appearance White liquid Antioxidant content (% weight) 45 Particle Size ( D50) [µm] <4 0 pH @ 25 C 9,5-10,5 TM The information contained herein relates to a specific Addivant product and its use, and is based on information available as of the date hereof. Additional information relating to the product can be obtained from the pertinent Material Safety Data Sheets. Nothing in this Technical Data Sheet TM TM shall be construed to modify any of Addivant standard terms and conditions of sale under which the product is sold by Addivant . NOTHING IN THIS TECHNICAL DATA SHEET SHALL BE CONSTRUED TO CONSTITUTE A REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING THE PRODUCT’S CHARACTERISTICS, USE, QUALITY, SAFETY, MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND ANY AND ALL SUCH REPRESENTATIONS AND WARRANTIES ARE HEREBY EXPRESSLY DISCLAIMED. Nothing contained herein shall constitute permission or recommendation to practice any intellectual property without the permission of the owner. Addivant TM and the Addivant Copyright © 2013 Addivant TM TM logo are trademarks of Addivant Corporation. All rights reserved. TM Corporation or one of its subsidiaries. Technical Information www.addivant.com Effective: April 2013 Application LOWINOX® 22M46-45D dispersion provides the highly efficient antioxidant LOWINOX® 22M46 stabilizer in an easy-to-handle water-based liquid form. LOWINOX® 22M46 stabilizer is one of the most widely used antioxidants for white, light colored and transparent vulcanates that are based on natural or synthetic rubbers. In light colored vulcanates, LOWINOX® 22M46 stabilizer retards the crazing effect caused by exposure to light. LOWINOX® 22M46 stabilizer does not influence processing and vulcanizing properties. It exhibits low volatility and migration which makes it suitable for use in POM and ABS. For more detailed advice on applications please contact your local AddivantTM sales representative. General Advantages Liquid form of a highly efficient antioxidant suited for emulsion and dispersion manufacture of polymers Excellent storage stability Adjusted viscosity to assure accurate and easy dosage Water based system with no dust and no VOC (volatile organic compounds) exposure of the workforce All ingredients have broad food contact approvals TM The information contained herein relates to a specific Addivant product and its use, and is based on information available as of the date hereof. Additional information relating to the product can be obtained from the pertinent Material Safety Data Sheets. Nothing in this Technical Data Sheet TM TM shall be construed to modify any of Addivant standard terms and conditions of sale under which the product is sold by Addivant . NOTHING IN THIS TECHNICAL DATA SHEET SHALL BE CONSTRUED TO CONSTITUTE A REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING THE PRODUCT’S CHARACTERISTICS, USE, QUALITY, SAFETY, MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND ANY AND ALL SUCH REPRESENTATIONS AND WARRANTIES ARE HEREBY EXPRESSLY DISCLAIMED. Nothing contained herein shall constitute permission or recommendation to practice any intellectual property without the permission of the owner. Addivant TM and the Addivant Copyright © 2013 Addivant TM TM logo are trademarks of Addivant Corporation. All rights reserved. TM Corporation or one of its subsidiaries. Technical Information www.addivant.com Effective: April 2013 Food Contact Approval The components of LOWINOX® 22M46-45D dispersion can be used in applications that come into contact with food according to the following regulations: LOWINOX® 22M46 stabilizer: This compound has broad food contact approvals; for details please contact AddivantTM Regulatory Affairs Polymer Additives. EEC: The substance is listed under Reference No. 66480 in the 6th amendment of the plastic material directive amending Directive 90/128/EEC (relating to plastic materials and articles intended to come into contact with foodstuffs) with a SML (specific migration limit) of 1.5 mg/kg. USA: - FDA 21 CFR 178.2010 FDA 21 CFR 175.300 FDA 21 CFR 177.1520(c) FDA 21 CFR 177.2470 FDA 21 CFR 177.2480 FDA 21 CFR 177.2600 Antioxidants and/or stabilizers for polymers. Resinous and Polymeric Coatings Olefin Polymers Polyoxymethylene copolymer Polyoxymethylene homopolymer Rubber articles intended for repeated use. Other Components – Emulsifier: USA: - FDA 21 CFR 175.105 FDA 21 CFR 175.300 FDA 21 CFR 176.170 - FDA 21 CFR 176.180 - FDA 21 CFR 176.210 - FDA 21 CFR 177.1200 FDA 21 CFR 177.1210 - FDA 21 CFR 177.1390 adhesives resinous & polymeric coatings components of paper and paperboard in contact with aqueous and fatty foods components of paper and paperboard in contact with dry food defoaming agents used in the manufacture of paper and paperboard cellophane closures with sealing gaskets for food containers laminate structures for use at temperatures of 250°F and above TM The information contained herein relates to a specific Addivant product and its use, and is based on information available as of the date hereof. Additional information relating to the product can be obtained from the pertinent Material Safety Data Sheets. Nothing in this Technical Data Sheet TM TM shall be construed to modify any of Addivant standard terms and conditions of sale under which the product is sold by Addivant . NOTHING IN THIS TECHNICAL DATA SHEET SHALL BE CONSTRUED TO CONSTITUTE A REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING THE PRODUCT’S CHARACTERISTICS, USE, QUALITY, SAFETY, MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND ANY AND ALL SUCH REPRESENTATIONS AND WARRANTIES ARE HEREBY EXPRESSLY DISCLAIMED. Nothing contained herein shall constitute permission or recommendation to practice any intellectual property without the permission of the owner. Addivant TM and the Addivant Copyright © 2013 Addivant TM TM logo are trademarks of Addivant Corporation. All rights reserved. TM Corporation or one of its subsidiaries. Technical Information www.addivant.com Effective: April 2013 - FDA 21 CFR 177.1400 FDA 21 CFR 177.2600 FDA 21 CFR 178.3120 hydroxyethyl cellulose film, water-insoluble rubber articles intended for repeated use animal glue Other Components – Thickener: The respective compound is used as direct food additive/food ingredient and is generally recognized as safe (GRAS). It can therefore be used in food contact applications as well. Other Components – Biocide: EEC: The compound is listed on the draft positive list of additives used in the manufacture of plastic articles and materials intended to come into contact with foodstuffs (the Synoptic Document). A complete dossier for the compound was submitted before the 31/12/2006 for inclusion into the “transitional list”. It is expected that the substance will be restricted to a specific migration limit of 1.2 mg/kg. Therefore the biocide can continue to be used in accordance with the Framework Regulation and National Legislation and in accordance with Directive 2002/72/EEC once the transitional list is published: Germany BGA XIV for use in plastic dispersions used in food packaging for use in articles prepared from natural or synthetic rubber for use in paper, cardboard and pasteboard used in food packaging BGA XXI BGA XXXVI Spain Resolución de 4.XI.82 modificada por Orden de 3.VII.85 listed on Annex 1 of Royal Decree 1125/1982 Warenwet CAT 33 listed on HFDST 2, para 1. (Paper and board for general use) as a slimicide for use only in industrial process waters listed on HFDST 2, para 1. (Paper and board for general use) as a preservative for preservation of coatings only. The Netherlands Warenwet CAT 39 TM The information contained herein relates to a specific Addivant product and its use, and is based on information available as of the date hereof. Additional information relating to the product can be obtained from the pertinent Material Safety Data Sheets. Nothing in this Technical Data Sheet TM TM shall be construed to modify any of Addivant standard terms and conditions of sale under which the product is sold by Addivant . NOTHING IN THIS TECHNICAL DATA SHEET SHALL BE CONSTRUED TO CONSTITUTE A REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING THE PRODUCT’S CHARACTERISTICS, USE, QUALITY, SAFETY, MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND ANY AND ALL SUCH REPRESENTATIONS AND WARRANTIES ARE HEREBY EXPRESSLY DISCLAIMED. Nothing contained herein shall constitute permission or recommendation to practice any intellectual property without the permission of the owner. Addivant TM and the Addivant Copyright © 2013 Addivant TM TM logo are trademarks of Addivant Corporation. All rights reserved. TM Corporation or one of its subsidiaries. Technical Information www.addivant.com Effective: April 2013 USA FDA 21 CFR 175.105 FDA 21 CFR 176.170 FDA 21 CFR 176.180 FDA 21 CRF 176.300 FDA 21 CFR 177.2600 adhesives components of paper and paperboard in contact with aqueous and fatty food components of paper and paperboard in contact with dry food slimicides in manufacturing paper and paperboard rubber articles intended for repeated use General Instruction for Transport, Storage and Handling of Dispersions/ Emulsions AddivantTM dispersions and emulsions represent a special physical form of AddivantTM polymer additives tailor made for applications where a liquid water based form of polymer stabilizers is needed. The dispersions/emulsions consist of two phases: a finely dispersed polymer stabilizer phase and a continuous aqueous phase. These phases tend to separate and occasionally to discolor if the dispersion/emulsion is exposed to adverse conditions, e.g. excessive heat, frost, light and emulsion breaking or heavily oxidizing chemicals. Therefore the constant quality of AddivantTM dispersions/emulsions can only be guaranteed if the advice given below is thoroughly followed. For additional handling and toxicological information consult the AddivantTM Material Safety Data Sheet. Transport The containers (in general 1000L IBCs) should be placed during transportation in a place where they are protected against: Heat and frost: Direct sunlight: Evaporation: Aggressive chemicals: avoid temperatures below +5°C and above +35°C long distance transport only in covered trucks close container thoroughly close container thoroughly (exhaust gases) Storage For storage the containers should be kept in a place where they are protected against: Heat and frost: Direct sunlight: Evaporation: Aggressive chemicals: avoid temperatures below +5°C and above +35°C long term storage only in warehouses close container thoroughly close container thoroughly (exhaust gases) TM The information contained herein relates to a specific Addivant product and its use, and is based on information available as of the date hereof. Additional information relating to the product can be obtained from the pertinent Material Safety Data Sheets. Nothing in this Technical Data Sheet TM TM shall be construed to modify any of Addivant standard terms and conditions of sale under which the product is sold by Addivant . NOTHING IN THIS TECHNICAL DATA SHEET SHALL BE CONSTRUED TO CONSTITUTE A REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING THE PRODUCT’S CHARACTERISTICS, USE, QUALITY, SAFETY, MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND ANY AND ALL SUCH REPRESENTATIONS AND WARRANTIES ARE HEREBY EXPRESSLY DISCLAIMED. Nothing contained herein shall constitute permission or recommendation to practice any intellectual property without the permission of the owner. Addivant TM and the Addivant Copyright © 2013 Addivant TM TM logo are trademarks of Addivant Corporation. All rights reserved. TM Corporation or one of its subsidiaries. Technical Information www.addivant.com Effective: April 2013 Handling No phase separation or solidification should occur during the recommended shelf life of the product (6 months) if the above storage measures are taken. Prior to use it is recommended that the dispersion/emulsion is mixed in order to destroy inhomogeneities and to redisperse occasionally separated water appearing at the bottom or the top of the container as a thin layer (according to the density of the dispersed material). If the dispersion is only partly used, the remaining quantities should be stored under the conditions described above. If a single container of product is to be used over a long period of time, care should be taken to avoid exposure to heat, frost and light and conditions promoting evaporation. Repeated opening and improper closing could result in bacterial contamination. TM The information contained herein relates to a specific Addivant product and its use, and is based on information available as of the date hereof. Additional information relating to the product can be obtained from the pertinent Material Safety Data Sheets. Nothing in this Technical Data Sheet TM TM shall be construed to modify any of Addivant standard terms and conditions of sale under which the product is sold by Addivant . NOTHING IN THIS TECHNICAL DATA SHEET SHALL BE CONSTRUED TO CONSTITUTE A REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING THE PRODUCT’S CHARACTERISTICS, USE, QUALITY, SAFETY, MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND ANY AND ALL SUCH REPRESENTATIONS AND WARRANTIES ARE HEREBY EXPRESSLY DISCLAIMED. Nothing contained herein shall constitute permission or recommendation to practice any intellectual property without the permission of the owner. Addivant TM and the Addivant Copyright © 2013 Addivant TM TM logo are trademarks of Addivant Corporation. All rights reserved. TM Corporation or one of its subsidiaries.
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