MECHANICAL PROPERTIES II Mechanical Failure Photograph of the fuselage of an airplane whose canopy was fractured during midflight to Hawaii. Investigations showed that the canopy was weakened as a consequence of corrosion and fatigue. [Source: © Robert Nichols, Black Star] S. O. Kasap University of Saskatchewan CANADA An e-Booklet Optimized for laser printing v.1.1 © 1990-2001, S.O. Kasap Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet CONTENTS 1. 2. 3. 4. 5. Crack Propagation and Griffith's Theory of Brittle Fracture Ductile Fracture Phenomenon of Fatigue Creep Impact Energy and Toughness 2 Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 3 MECHANICAL PROPERTIES II Mechanical Failure Safa Kasap Department of Electrical Engineering University of Saskatchewan Canada "Very generally there are always two fracture mechanisms competing to break a material -plastic flow and brittle cracking. The material will succumb to whichever mechanism is the weaker; if it yields before it cracks the material is ductile, if it cracks before it yields it is brittle. The potentiality of both forms of failure is always present in all materials" J. E. Gordon The New Science of Strong Materials or Why You Don't Fall Through the Floor (Penguin Books, London, UK:2nd Ed., 1976; Princeton University Press, Princeton, NJ, USA, 1984) p.84 . 1 Crack Propagation and Griffith's Theory of Brittle Fracture Most fractures one way or another involve crack propagation. Normally these cracks are not even visible to the naked eye though they can be detected under an optical or an electron microscope. Figure 1-1 (a) shows a perfect crystal with no load. There are no surface imperfections. When a tensile load, F, is applied to this crystal as in Figure 1-1 (b) then the load is equally divided between each chain of atoms, AA′, BB′ to EE′. Each bond is strained by an equal amount along the tensile load axis. If we were to view the crystal macroscopically without the atomic details as in Figure 1-1 (c) we would find that the lines of force are straight and evenly spaced. Each line of force represents the same amount of force and when we add all the lines we get the total force F. The same number of lines cross a given area perpendicular to the tensile axis anywhere in the crystal because the lines are uniformly spaced. The stress, force per unit area, is therefore uniform across the crystal and is given by σo = F/Ao where Ao is the face area on which the tensile load acts. Suppose that the surface of the crystal has a crack that penetrates and interrupts the atomic chains AA′and BB′as depicted in Figure 1-1 (d). When a load is applied, the atoms such as C at the tip of the crack now have to bear additional loads arising from missing atoms in the crack as shown in Figure 1-1 (e). If we were to view the crystal macroscopically and draw the lines of force, we observe that the lines that previously passed through the crack region now have to go around the crack as shown in Figure 1-1 (f). In the zone around the crack there are more lines of force per unit area and therefore greater stress. This region around the tip of the crack, shown as hatched in Figure 1-1 (f), has stress concentration. The stress across the crystal where there is a crack is not uniform and the stress is maximum, due to the largest number of force lines per unit are, around the tip of the crack. It is apparent that there has been a stress amplification or concentration at the tip of the crack where the maximum stress is greater than σo . This is caused because the lines of force are closely spaced and there are more lines per unit area. The increase in the stress, or stress amplification, depends on the length of the crack c as well as the radius of curvature r of the crack or its "sharpness". The sharper the crack, the more suddenly the lines of force have to be bent and more closely separated they become. Far away from the crack, as in the lower portion of the crystal in Figure 1-1 (f), the lines of force are again evenly spaced and the stress is the applied stress σo. Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 4 Crack A A B B C C D D E E A C A Force F Force F E C Force F E Ao Stress concentration Force Force Force (a) Perfect crystal with no load. (b) A perfect crystal with an applied load. Each chain of atoms, AA , to EE , carries an equal amount of force. Solid lines between atoms represent strained bonds which are due to forces acting on these bonds. (c) Macroscopic representation of (b) without the atomic details. The lines of force go through the crystal uniformly and in every region the force per unit area is constant. Thus stress is uniform across the crystal. (d). The surface of the crystal has a crack which penetrates and interrupts the atomic chains AA and BB . (e) When a load is applied the atoms such as C at the tip of the crack now have to bear additional loads arising from missing atoms in the crack. Thus there is a stress concentration around the tip of the crack. (f) Macroscopic representation of (e) without the atomic details. Lines of force have to go around the crack. In the zone around the crack there are more lines of force per unit area and therefore greater stress. Figure 1-1 The local variation of the stress across a specimen containing a surface crack is shown in Figure 1-2 (highly exaggerated).The ratio of the maximum stress σm at the crack tip to the applies stress σo is called the stress concentration factor, Kt, and represents the amount of stress amplification. Kt depends on the crack length c and the radius of curvature r of the crack tip. The maximum stress σm at the tip of an elliptical (or circular) crack is given by c σ m = σ 0 1 + = Ktσ 0 r Maximum stress at cracks (1−1) Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 5 For a sharp crack which has a length much longer than its radius of curvature , c >> r, c Maximum stress at cracks (1−2) r Stress concentrations can also occur at the tips of internal cracks just as they do at the tip of a surface crack. The same equations apply with the same c and r, but the crack length is now 2c. σ m ≈ 2σ 0 o = F / Ao c r C X Crack X' m o C x The variation of stress across a specimen that has a surface crack of length c and radius of curvature r. The stress is maximum at the tip C of a crack. Figure 1-2 Stress amplifications can be appreciable if the cracks are sharp as r would then be small as shown in Equation (1−2). Suppose that a surface crack is about 0.2 micron long (200 nm). If the crack terminates sharply at an atomic point ,then its radius of curvature will be of the order of an atomic bond length, say 0.1nm. Such a crack would hardly be visible even under an optical microscope as it is even shorter than the wavelength of visible light, though it can be probably viewed under an electron microscope. Then the stress amplification from Equation (1−1), Kt, is about 90. Thus even if the applied stress σo may not very high, the stress amplification at the tip of this crack may be sufficiently large to rupture the most strained bond at the tip and hence enlarge the crack. The crack then penetrates or propagates into the bulk by a bond length. Of course, things get worse when c gets larger and stress amplification becomes greater which causes more ruptured bonds at the crack tip and a further penetration or propagation of the crack. At each step of crack propagation the stress amplification ruptures the bond at the crack tip which allows the crack to spontaneously propagate across the specimen. This is how fracture occurs in such brittle solids as glasses and ceramics as schematically illustrated in Figure 1-3 (a) and (b). Spontaneous crack propagation inevitably leads to a dramatic fracture that is typical of brittle solids. Such crack propagation events almost certainly occur in all brittle materials that do not exhibit any plastic deformation. The amplified stresses at the crack tip do not plastically deform this region but instead rupture bonds and spontaneously propagate the crack. By manufacturing crystal whiskers, thin filaments of single crystals, that are free of any surface cracks, engineers have been able to produce whiskers that approach the theoretical fracture limit in which nearly all the bonds are ruptured at the fracture plane. Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 6 In ductile metals, if the amplified stresses around the crack tip are sufficiently large then, these stresses will plastically deform this region as shown in Figure 1-3 (c) which then becomes strain hardened and more difficult to further deform. If the crack is to propagate spontaneously into the bulk of the material, then it has to do much work in plastically deform the material that is progressively hardening. Crack propagation in ductile materials is therefore much more difficult and consequently failure by crack propagation across the whole component occurs less frequently. It does nonetheless occur given the right conditions as discussed below. Brittle material Ductile material Plastic work has hardened this region When the applified stress o is below the critical stress cb required for crack propagation, the crack is stable. (b) When o, exceeds cb, then the crack propagates across a brittle material. (c) In a ductile material the crack cannot propagate easily because it needs to do plastic work, plastically deform the tip region, which requires substantial energy. Figure 1-3 It is clear that the crack propagation in brittle and ductile materials have different origins. The propagation of a crack in a brittle material involves no appreciable plastic work at the tip of the crack. For brittle materials such as glasses and ceramics, the critical applied stress needed to break the bonds at the crack tip and thereby spontaneously propagate the crack depends not only on the elastic modulus E but also on the surface tension of the material, γ, which is the surface energy per unit surface area because new crystal surfaces are created when the crack penetrates into the bulk. This critical stress σcb for brittle materials was derived by Griffith1 and is given by 2 Eγ Critical applied stress in brittle materials (1−3) πc When the applied stress exceeds σcb, as shown in Figure 1-3 (b), the amplified stress at the crack tip is able to rupture the bonds at the tip and thereby create new fracture surfaces. The crack extends further into the bulk. Its length c becomes longer. This increases the amplified stress σm in Equation (1−1) but lowers the critical stress σcb in Equation (1−3), that is the applied stress exceeds σcb even more. Greater amplified stress at the crack tip ruptures even more bonds and the crack propagation becomes even faster. Hence once crack propagation starts it accelerates and dramatically fractures the specimen. Inasmuch as crack propagation in brittle materials does not involve plastic work it is said to propagate elastically. σ cb = 1 Alan Arnold Griffith (1893-1963) was a British engineer who developed our present understanding of brittle fracture. According to Professor J.E. Gordon, some of the practical work at the time had to be done somewhat discretely by Griffith and his co-worker Sir Ben Lockspeiser as working on such non-engineering materials as glass was not considered a serious research activity at the Royal Aircraft Establishment in 1920s. In those days, as one might have guessed, primary engineering materials were wood and steel. By the way, the derivation of this equation was published by Griffith in the Philosophical Transactions of the Royal Society of London, A221, 163, 1921. Undoubtedly Griffith's crack theory caused as much revolution in mechanical engineering as vacuum tubes did in electrical engineering around the same time. Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 7 In ductile materials, the crack propagation inevitably involves plastic deformation around the tip. The critical applied stress σcd for crack propagation in a ductile metal then depends also on the amount of plastic work that has to be done to "fracture" the region around the tip for the tip to extend further. The plastic work done per unit volume to fracture a ductile material in a tensile test is known as toughness which should therefore influence the critical stress σcd for crack propagation. In general, σcd is given by 2 EGc Critical applied stress in ductile materials (1−4) πc Where Gc is a material property called the toughness of the material2. Qualitatively it is the plastic work done per unit surface area of the crack. Effectively it is plastic work done to create a crack with a unit σ cd = 2 Not to be confused with the modulus of toughness for tensile fractu Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 8 surface area. For ductile materials Gc is quite large, 10 − 100 kJ m−2, whereas for brittle materials it is small; for glass it is 0.01 kJ m−2. Thus the critical stress for ductile materials is much greater than that for brittle materials and therefore ductile materials posses a greater fracture toughness given comparable elastic moduli. Example 1-1: Critical stresses for crack propagation Consider an invisible surface crack on one side (edge) of a thin glass plate and also on one side of a thin aluminum−alloy plate. Suppose that the crack length is 0.2 µm, and the radius of curvature of the crack is 0.1 nm. Find the stress concentration factor and the critical applied tensile stress for crack propagation in each plate. What is the maximum stress at the crack tip at the onset of fracture for the thin glass plate? From materials data books, for glass, E = 70 GPa, γ ≈ 0.51 J m−2 and for the aluminum alloy E = 70 GPa and Gc = 20 kJ m−2. Solution The stress amplification factor Kt is given by c 0.2 × 10 −6 =2 = 89.4 r 0.1 × 10 −9 For the glass fiber, the critical applied stress σcb is Kt = 2 σ cb = 2 Eγ = πc 2(70 × 10 9 Pa )(0.5 J m -2 ) π (0.2 × 10 -6 m ) = 3.34 × 108 Pa or 334 MPa The maximum stress at the crack tip for fracture is σm = Ktσcb = (89.4)(334 MPa) = 29.8 GPa. We note that the magnified stress at the crack tip is about ~E/3. For the aluminum alloy, any crack propagation involves plastic work. The critical stress is σ cd = 2 EGc = πc 2(70 × 10 9 Pa )(20 × 10 3 J m -2 ) π (0.2 × 10 -6 m ) = 6.68 × 1010 Pa, 66.8 GPa The applied stress needed to propagate this crack is 66.8 GPa. This is, in fact, grater than typical tensile strengths of aluminum alloys, typically below 400−500 MPa. Thus, the fracture is unlikely to proceed by the propagation of this crack in the case of the aluminum plate. 2 Ductile Fracture Ductile fracture characteristically involves substantial plastic deformation. As a ductile specimen is loaded in a tension test and beyond the yield point, dislocation motions give rise to homogeneous plastic strain. The specimen extends and becomes narrower as shown in Figure 2-1(a). A neck forms when the engineering stress reaches the tensile strength where local stresses give rise to more plastic deformation in the neck than other regions as shown in Figure 2-1(b). The true stress in the neck is actually greater than any other region because the neck is narrower. Large stresses in the neck nucleate microcavities or microvoids as pictured in Figure 2-1(c). These tiny cavities usually form around particulate inclusions. In essence they serve as tiny internal cracks. The tips of these cavities experience substantial stress amplification and therefore propagate the cracks. As the cavities enlarge in directions perpendicular to the tensile stress axis they gradually coalesce and eventually form an elliptical cavity or crack as in Figure 2-1 (d). In the final stages, the elliptical crack simply propagates to the surfaces by shearing at the maximum shear stress angle 45° as shown in Figure 2-1(e). The fracture surfaces therefore have a cup and cone type appearance as indicates in Figure 2-1(f). Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet Nucleation of microvoids 45° Cavity due to Coalesced microvoids 45° Necked region 45° 9 Cone Shearing at 45° Fibrous structure 45° 45° Cup 45° Ductile fracture. (a) dislocation motions cause plastic flow. (b) Necking begins. (d) Microvoids are formed due to high stresses in the neck region. (e) Microvoids coelesce and give a cavity, and internal crack, within the neck (e) The material around the crack experiences excessive shear stresses at 45° (maximum shear stress angle) which propagates the internal crack to the surfaces and causes fracture. Figure 2-1 3 Phenomenon of Fatigue Many engineering components experience time varying stresses rather than static loads. Figure 3-1(a) and (b) show two examples of time dependent stresses. In Figure 3-1(a), the time variation of the stress is a periodic function of time analogous to an alternating voltage at a power outlet. In Figure 3-1(b), the stress variation has no periodicity but nonetheless it still exhibits variations and puts a component under a varying stress. Time varying loads whether periodic cycles or aperiodic fluctuations occur naturally in engineering. One can think of many examples, for example, the shaft of the electric motor that is carrying a load, as shown in Figure 3-2, experiences cyclic stresses as the material endures tension and compression during the rotation. It may be thought that as long as the tensile stress in the shaft does not exceed the tensile strength, the shaft will not fracture but this is not true. Failure under time varying stresses is different than that occurring under static tensile loading. A component that can withstand loads up to its tensile strength under static loading can easily fail under cyclic conditions with a stress magnitude that is a fraction of its tensile strength. It was thought (long time ago) that the "specimen got tired of carrying the load and gave up" and the failure was inappropriately named fatigue. Under a cyclic stress, components usually fail by the nucleation of a surface crack and its subsequent propagation through the component. Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet (t) 10 (t) max t t min a b Aperiodic stress variations Alternating stress cycles Time varying stress can lead to failure even if the maximum stress is below the tensile strength of the metal. Figure 3-1 Tension Compression Shaft Electric motor Load Cyclic loads and hence cyclic stresses occur frequently as in this example of an electric motor driving a load. The shaft experiences cyclic stresses. Figure 3-2 Fatigue therefore invariably involves failure by crack propagation. The crack however is induced during load cycling by the changes in the stress direction and the resulting changes in the slip formations on the surface. The exact details are not treated in this book. Fatigue tests normally employ cyclic stresses with a well defined period as in Figure 3-1(a). Fatigue is typically characterized by plotting the amplitude of the cyclic stress, denoted by S, against the number of cycles to failure, N as shown in Figure 3-3. The results are called S − N plots. If the stress amplitude, S, is equal to the tensile strength, σTS, then obviously the specimen fractures within quarter of a cycle, time needed to reach σTS. When S is less than σTS it may take many cycles for the material to fail. The lower the stress amplitude, the greater the number of cycles N to failure as shown in Figure 3-3. An interesting feature of fatigue is that even when S is less than the yield strength, the material, nonetheless, still fails provided that it is cycled long enough. Ferrous alloys such as steels show an endurance limit as identified in Figure 3-3. Endurance limit is the maximum amplitude of stress that can be cycled infinitely without fracturing the specimen. As long as the stress amplitude is less than the endurance limit steel components can be cycled by an infinite number of times. Stresses below the endurance limit therefore identify a safe zone. No such endurance limits exist for aluminum and copper alloys. They tend to show eventual failure if cycled long enough. Figure 3-4 compares the S-N behavior of various metals, those that exhibit endurance limit and those that do not. Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet Stress Amplitude, S ( max) TS 11 Time varying stress can lead to failure even if the maximum stress is below the tensile strength of the metal. Ferrous alloy YS Endurance limit Safe zone 1/ N 4 1 104 102 106 108 N, number of cycles to failure (logarithmic scale) Figure 3-3 Stress (MPa) 450 400 Al alloy (7075-T6) 350 Structural steel rod Al-4.5%Cu alloy 300 250 200 150 Mild steel (0.2%C) Copper 100 50 0 104 105 106 107 Cycles to Failure 108 109 Fatigue in ferrous (solid lines) and non-ferrous (dashed lines) metals [From: Al alloy (7075-T6) from G.M. Sinnclair and T.J. Dolan, Trans. ASME, 75, p.867, 1953; Mild steel (0.3%C) , Al-4.5%Cu alloy (fully heat treated) and Cu from O.H. Wyatt and D. Dew-Hughes, Metals, Ceramics and Polymers (Cambridge University Press, 1974), Fig. 5.29, p. 173 and Fig. 5.28, p. 172 repectively; Structural steel rod from 1990 Guide to Selecting Engineering Materials, Vol. 137, Issue 6, June 1990, American Society of Metals (ASM International, 1990), p.40.] Figure 3-4 4 Creep When a permanent load is applied to a component, elastic deformation occurs almost instantaneously. At elevated temperatures, typically above 0.3Tm, where Tm is the melting temperature (in Kelvin), the component also exhibits slow permanent deformation with time which is called creep. The specimen is said to creep under a constant load. Figure 4-1 shows what happens when at time t = 0, a constant tensile stress is applied to a component. It first exhibits instantaneous elastic deformation at t = 0 but then it deforms plastically and permanently with time. The strain increases with time and shows three characteristic regions in the ε vs. t behavior as indicated in Figure 4-1. Eventually the specimen fractures after a duration of time called the rupture time. In the primary creep region, the creep rate continuously slows with time. The decrease in the creep rate is due the strain hardening of the material. As dislocations become entangled they cannot move freely and plastic deformation becomes more difficult. Eventually the creep rate reaches a steady state value which marks the secondary region as shown in Figure 4-1. In this region the creep continues at a constant but slow rate. Indeed the creep rate is the lowest during this time. The creep process Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 12 during this time normally involves slow atomic and vacancy diffusions to and from dislocations which disentangles and unpins some of the dislocations. The creep rate, dε /dt, in this regime is therefore thermally activated. Eventually microvoids or microcracks are formed at grain boundaries by various processes such as dislocation pileups at grain boundaries or by the relative sliding of neighboring grain boundaries to name a few. Even vacancies diffusing to grain boundaries can coalesce to form a microvoid. Formations of microvoids lead to crack propagation across grains and hence to rapid creep rates which identify the tertiary region in Figure 4-1. Crack propagation eventually lead to failure or rupture. Stress, Time Strain, Tertiary Primary Rupture Secondary d = Creep rate dt Instantaneous elastic strain Time 0 Rupture time, tr The phenomenon of creep and rupture Figure 4-1 Strain, Higher stress or temperature B A C T < 0.3Tm 0 Time Creep at a given temperatureT1 and 1 is the curve A. If temperature or stress is increased then the curve becomes B. Below 0.3Tm there is significant creep Figure 4-2 At a higher temperature or greater stress, the creep rate becomes accelerated and the rupture occurs sooner. Creep is typically characterized by examining the steady state creep rate, the strain rate in the secondary region, and the rupture time for a given set of variables such as stress and temperature. The dependences of the rupture time and the creep rate on the stress are shown Figure 4-3 and Figure 4-4. Conventionally the Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 13 stress is plotted along the y−axis and the plots are log−log plots. Temperature has a pronounced effect of the creep characteristics. Below about 0.3Tm the creep effects are considered negligible. log(Stress) T = T1 T2 > T1 T3 > T2 0 log(Rupture time) Stress and temperature dependence of rupture time tr Figure 4-3 log(Stress) T = T1 T2 > T1 T3 > T2 log(Creep time) 0 Stress and temperature dependence of creep rate Figure 4-4 5 Impact Energy and Toughness Many materials when in use fail or fracture as a result of impact. Further, some ductile metals, notable BCC and HCP metals such as iron and all steels, exhibit a change from ductile to brittle failure under fast strain rates at low temperatures. This behavior is more pronounced if there is a sharp crack or a notch in the component. It is therefore highly desirable to characterize, in a standard fashion, the failure of materials under impact and in the presence of a surface notch. Impact energy is the energy absorbed by a metal specimen to fracture in a standard impact test. The most common impact test is the Charpy test which involves fracturing a specially shaped metal specimen by releasing a pendulum hammer from a certain height h as shown in Figure 5-1. After fracturing the specimen, the hammer rises to a height h′ so that the impact energy absorbed by the specimen in fracturing is the change in the potential energy of the pendulum, i.e. Mg(h − h′), where M is the mass of the hammer. The scale can be calibrated to read the impact energy directly. It may be surmised that the impact energy from the Charpy test correlates to the toughness of the material. Higher impact energies are recorded for tougher metals. Figure 5-1 illustrates the Charpy test and also shows the special shape of the test specimen. Notice that the sample is V−notched to ensure that the fracture begins at this point. The absolute value of the impact energy from Charpy tests depends on the shape and exact dimensions of the Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 14 notch, so that Charpy test results are often useful for comparison purposes only, for example, for the comparison of impact energy at different temperatures. Scale Impact energy, Eimpact 0J Start End Hammer M h h' V-notch Notched specimen Specimen anvil A schematic illustration of the Charpy impact test Figure 5-1 Charpy tests are often carried out as a function of temperature to show the ductile-to-brittle transition exhibited by certain metals, those with BCC and HCP crystal structures, as illustrated in Figure 5-2 for two carbon steels (steels with 0.11%C and 0.53%C) which have the BCC crystal structure. Impact Energy (J) 250 200 Steel: 0.11%C (BCC) 150 100 Stainless steeel (FCC) 50 0 -150 -100 Impact energy vs temperature for two BCC metals, steels with 0.11%C and 0.53%C and one FCC metal, stainless steel. Steel: 0.53%C (BCC) -50 0 50 100 150 200 250 Temperature ( C) Figure 5-2 An example for an FCC metal, stainless steel, is also shown. Both carbon steels exhibit a ductile to brittle transition in their fracture behavior which is typical of these BCC structures whereas the stainless steel exhibits no such transition which exemplifies FCC metals. Comparison of the two steels shows that the addition of carbon to steel reduces the impact energy and increases the transition temperature in Figure 5-2. Such changes are extremely important in engineering design. For example, a component using Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 15 0.53%C steel will fracture in a brittle fashion and hence dramatically under a high strain rate if it experiences impact whereas 0.11%C steel can easily absorb large amounts of impact energy and not fracture. Even 0.11%C steel becomes brittle against impacts at temperatures below –50 °C which, by the way, are not unusual in northern latitudes (and during some winter days and nights in the author's country). The different ductile transition behavior of BCC and FCC metals can be intuitively explained by the temperature dependence of the critical shear stress τcss (see Mechanical Properties I) that is needed to move dislocations in the crystal and thereby do plastic (ductile) work. In the case of FCC metals τcss is already smaller than that for BCC crystals and, further, τcss increases more rapidly with decreasing temperature for BCC metals. Thus, plastic work becomes more difficult in BCC metals at lower temperatures which leads to the observed brittle impact−fracture. NOTATION A BCC c E ε F FCC Gc g γ HCP h Kt area (m2) body centered cubic crystal structure crack length (m) elastic modulus (Pa or N m-2) strain (no units) force (N) face centered cubic crystal structure toughness of the material (J m-2) acceleration due to gravity (9.81 m s-2) surface tension, surface energy per unit surface area (J m-2) hexagonal close-packed crystal structure height (m) stress concentration factor (no units) M N r S σ σcd σcb σm σo σTS Tm t τcss mass (kg) number of cycles to failure radius of curvature of the crack tip (m) amplitude of the cyclic stress stress (Pa or N m-2) critical stress for ductile materials (Pa or N m-2) critical stress for brittle materials (Pa or N m-2) maximum stress at the crack tip (Pa or N m-2) applied stress (Pa or N m-2) tensile strength (Pa or N m-2) melting temperature (K) time critical shear stress (Pa or N m-2) Defining Terms BCC stands for body centered cubic crystal structure. Brittle materials do not exhibit any marked plastic deformation and their fracture strains are less than a few percent. They exhibit very limited toughness. Ceramics and glasses are examples of brittle materials. Dislocation is a line imperfection within a crystal that extends over many atomic distances. Ductile materials exhibit an ultimate tensile strength point and considerable plastic deformation before fracture. They also tend to have a high toughness. Ductile work is the work done during plastic deformation. Ductile work is the work done during plastic deformation. Elastic Modulus or Young's modulus (E) is axial stress needed per unit elastic axial strain, and is defined by σ = Eε where σ is the applied stress and ε is the strain all along the same direction (axis). It gauges the extent to which a body can be reversibly (and hence elastically) deformed by an applied load in terms of the material properties. Endurance limit is the maximum amplitude of stress that can be cycled infinitely without fracturing the specimen. FCC stands for face centered cubic crystal structure. HCP stands for hexagonal close−packed crystal structure. Plastic deformation is permanent deformation by material flow as a result of the motion of dislocations. Plastic deformation is permanent deformation by material flow as a result of the motion of dislocations. Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet 16 Strain is a measure of the deformation a material exhibits under an applied stress. It is expressed in normalized units. Under an applied tensile stress, strain (ε) is the change in the length per unit original length, ∆L/Lo. When a shear stress is applied, the resulting deformation involves a shear angle. Shear strain is defined as the tangent of the shear angle that is developed by the application of the shearing force. Strain is a measure of the deformation a material exhibits under an applied stress. It is expressed in normalized units. Under an applied tensile stress, strain (ε) is the change in the length per unit original length, ∆L / Lo. When a shear stress is applied, the resulting deformation involves a shear angle. Shear strain is defined as the tangent of the shear angle that is developed by the application of the shearing force. Volume strain ∆ is the change in the volume per unit original volume; ∆ = ∆V / V. Stress is force per unit area, F / A . When the applied force is perpendicular to the area it leads either to a tensile or compressive stress, σ = F / A. If the applied force is tangential to the area, then it leads to a shear stress, τ = F / A. Stress is force per unit area, F/A. When the applied force is perpendicular to the area it leads either to a tensile or compressive stress, σ = F/A. If the applied force is tangential to the area then it leads to a shear stress, τ = F/A. Surface tension ( γ ) represents the energy required to increase the surface of a body by some unit area keeping the total number of atoms the same. An atom on the surface of a liquid or a solid has less bonds than an atom within the bulk of the substance. Thus, if we were to increase the surface area of the body, e.g. changing it from a sphere to a cube, which has higher surface area, we need to work because we would have less bonds per atom (effectively we have broken bonds). If energy dE is required to increase the surface area by dA then γ = dE / dA. A hypothetical line on the surface of a liquid or a body experiences a force per unit length that is equal in magnitude to the surface tension. Surface tension in a crystal depends on the crystal structure and the surface plane (because the energy difference per atom on the surface and within the bulk depends on the arrangements of atoms on the crystal surface and in the crystal bulk). Toughness is the amount of plastic work done per unit volume to fracture. Yield Strength is the resistance of the material against plastic deformation. 1. QUESTIONS AND PROBLEMS Consider an invisible surface crack on one side (edge) of a thin glass plate. Suppose that the crack length is 1 µm, and the radius of curvature of the crack is 1 nm. Find the stress concentration factor and the critical applied tensile stress for crack propagation in this glass plate. What is the maximum stress at the crack tip at the onset of fracture for the thin glass plate? From materials data books, for glass, E = 70 GPa, γ ≈ 0.51 J m−2 and for the aluminum alloy E = 70 GPa and Gc = 20 kJ m−2. [Ans:] Mechanical properties II: Mechanical Failure (© S.O. Kasap, 1990 - 2001: v.1.1) An e-Booklet All material in this publication is copyrighted. © All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the author. Permission is granted to individuals for downloading this document from the author’s website or his CD-ROM for self-study only. Permission is hereby granted to instructors to use this publication as a classhandout if the author’s McGraw-Hill textbook Principles of Electronic Materials and Devices, Second Edition, has been adopted as a requisite course textbook. The permission is valid only while the book remains in adoption. SPECIAL CUSTOM PUBLISHED e-BOOKLET S.O. Kasap, 1990-2001 The author reserves all rights Last Updated: 6 January 2002 (v.1.1) First published in Web-Materials (Established 1996) http://Materials.Usask.Ca 17
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