Mighty Molecule Models Upper-elementary students build molecule models to learn about important molecules and their properties. Y By Tom Brown, Greg Rushton, and Marie Bencomo ou don’t expect to see fifth graders busily puzzling out the chemical formulas of propane, methanol, and other important molecules. While it might seem unusual for students to be exploring these concepts in their fifth-grade class, the purpose was not to teach high school chemistry but rather to explore properties that characterize certain molecules. The students used their newly acquired knowledge of atoms’ bonding requirements to help them build three-dimensional molecular models. This engaging lesson was one of several developed as part of the SMATHematics Project: The Wonder of Science, The Power of Mathematics—a collaborative partnership between Kennesaw State University and two local school districts that aims to provide elementary teachers with accurate science and math classroom activities designed to kindle curiosity while building understanding (see Internet Resources). The effort is succeeding—as you can see by the fifth-grade classroom experience described here. January 2008 33 January 2008 33 For several lessons leading up to the molecule-building inquiry, Clarkdale Elementary students had been learning about the basic structure of atoms, including the form and behavior of protons, neutrons, and electrons. This introduction to the subatomic structure of the atom is part of the fifth-grade science curriculum that deals with the nature of matter. At the start of the exploration, the fifth-grade teacher Ms. Bencomo reviewed these concepts with a role-play. Two students stood in front of the class and pretended they were the parts of a hydrogen atom. One student acted as the nucleus and the other as the electron. While one student sat staunchly in the center, the other student buzzed Students explored molecule configurations with ball-and-stick atomic models. around in an imaginary orbit. Then two needs to gain stability. They can also bond with anmore students assumed the role of a second atom, with other atom of the same kind. In order to keep things a nucleus and one orbiting electron. Ms. Bencomo relatively simple at the elementary level, Ms. Bencomo explained that each of these atoms could bond with chose not to initiate a deeper discussion of how this each other in order to become more stable as a unit. bonding relates to stable (noble gas) electron conShe said that by sharing their only electron with each figurations (a discussion more appropriate for middle other, the two atoms could form an attractive bond school students). She then reminded students that that would help each atom to become more steady and when atoms bond with one another, they form subsettled. This was important because groups of steady stances that we call compounds or molecules. and stable atoms are needed in nature in order to form But the notion of atoms joining with each other the fundamental building blocks of matter. To remedy can get complicated quickly if we consider that the the situation, she encouraged one of the students to 92 natural elements can combine to form an almost suggest that the two atoms share electrons so that both limitless number of compounds. Fortunately, we can of them could gain stability. The two “electrons” then simplify things by focusing our efforts on the chemstarted circling both atoms, moving in a figure-eight istry of living things. Of the 92 naturally occurring pattern around both nuclei while trying to show that elements, only about 25% of them are important to they were attracted to both at the same time. The stuliving things, and only four elements (carbon, nitrodents were clearly pleased with this simple solution to gen, oxygen, and hydrogen) make up 95% of all living the problem. things. If Ms. Bencomo’s students can understand how those four elements bond to become stable, they Bonding Rules can comprehend a great deal about the chemistry of Ms. Bencomo told the students that they were going life. For example, the most important molecule on to learn about some of the patterns that atoms follow the planet, water, is formed by a combination of two when they are together. She explained that elements hydrogen atoms and one oxygen atom (H 2O). and the atoms that make them up follow patterns that To start simply, Ms. Bencomo focused student atstudents can understand. For example, most atoms tention on a poster that showed the name, symbol, have less stable configurations when by themselves, so designated color, and number of bonds needed for they bond with other atoms in ways that make them each of the “fabulous four” elements (see the Fabulous more stable. In addition, each different type of atom Four table in Figure 1) to be stable. (She explained (element) has to form a certain number of bonds to the colors were arbitrarily assigned as an easy way of become more steady and settled. She explained that representing the different elements in the models and two atoms can form one bond (single) or two bonds drawings the students created.) She briefly explained (double) and sometimes even three bonds (triple) and used ball-and-stick atomic models to demonstrate between them—depending on the total number each 34 Science and Children Photographs courtesy of the authors Atoms Role-Play Mighty Molecule Models Figure 1. Mighty Molecule lab sheet. The Fabulous Four Element Hydrogen Oxygen Nitrogen Carbon Symbol H O N C Color Yellow Red Light Blue Black Bonds to Get Stable 1 2 3 4 For each molecule, you will be given its common name and the number and type of each atom in the molecule. Your job as a group is to put the atoms together in a way that will form a stable molecule. When you think you have constructed a stable molecule, predict what you think the formula of the molecule should be, and draw a sketch of the molecule. The formula should include the symbol of each element and the number of atoms of each element in your molecule. You are now ready to build some of the most important molecules on our planet. Remember, for the molecule to be stable, it must form the proper number of bonds. When you build the molecules, use sticks or springs to represent the bonds. You can form one bond (single) between two atoms or two bonds (double) and sometimes even three bonds (triple). Procedure: Build the following molecules using the ball-and-stick models and then predict the formula for the molecule and draw a sketch of the molecule. Name of Molecule Atoms in Molecule Actual Formula Sketch of Molecule water 2 hydrogen 1 oxygen H2O O ammonia carbon dioxide methane (natural gas) H H H 1 nitrogen 3 hydrogen NH3 1 carbon 2 oxygen CO2 O=C=O 1 carbon 4 hydrogen CH4 H N H H H H C H oxygen (as found in air) 2 oxygen nitrogen (as found in air) 2 nitrogen methanol (wood alcohol) 1 carbon 4 hydrogen 1 oxygen O2 O O= N2 N N= CH3OH H H C O H H propane 3 carbon 8 hydrogen C3H8 H H C H H C H H C H H January 2008 35 Water was the first molecule on the sheet, and each group of three students built the molecule together with the rest of the class. After doing so, they were asked to predict the formula for this molecule. One student suggested that HOH could be the formula, and a second suggested the more familiar H 2O. Ms. Bencomo indicated that both of these formulas were correct (HOH being the structural formula and H 2O the molecular formula) and encouraged students to begin working within their groups to build and sketch the remaining molecules. Without any explicit instrucStudents tried different configurations to decide if their molecules were stable. tion, each group worked toward the correct structure for each how each of the fabulous four needed to bond to gain molecule by trying different configurations and stability. For example, to make water a water molecule, deciding if their molecule was stable. For example, she used tiny sticks to show how the oxygen atom when constructing a molecule of carbon dioxide (needing two bonds) forms a bond with two hydrogen (CO 2), a common approach was to first model its atoms (each needing one bond) in order to become a structure on the structure of water by making a single stable molecule. bond from the carbon to each oxygen as shown in Figure 2. This only results in one bond for each oxyPutting It Together gen and two bonds for carbon (which needs four), After the discussion of bonding, Ms. Bencomo anand students soon realized that therefore none of nounced that they were ready to build some of the most the atoms were stable. The teacher asked students important molecules on our planet. She distributed who didn’t observe this to defend their choice and a bag to each group of three students that contained was able to lead them to the conclusion that this an assortment of each type of atom—hydrogen (yelstructure was unstable because it lacked the number low), oxygen (red), nitrogen (light blue), and carbon of bonds it needed. Some groups chose to address (black)—and some sticks and springs to represent this shortcoming in their model by simply adding bonds. She then challenged the students to build eight another single bond between the two oxygen atoms common molecules, providing students with the name (Figure 2, second attempt), but this configuration of each molecule, the number of each atom in the molonly obeys the stability rules for oxygen—not carecule, and the number of bonds each atom needs. She bon, so their model needed to be revised. A few distributed a blank lab sheet (see NSTA Connection) minutes later, excited hands waved frantically in the that included the common name, a space to write the air as the students motioned for the teacher to come predicted formula, and a space to sketch a model of the look at their structure. Now the central carbon had molecule. (See a completed lab sheet in Figure 1.) two bonds to each oxygen and no bonds between the Figure 2. Progression of student attempts at sketching the structure of carbon dioxide. C O C O 1st attempt 36 Science and Children O O 2nd attempt O C O 3rd attempt Mighty Molecule Models Figure 3. Student sketching molecular structure. Connecting to the Standards This article relates to the following National Science Education Standards (NRC 1996): Content Standards Grades 5–8 Standard B: Physical Science •Properties and changes of properties in matter two oxygen atoms (Figure 2, third attempt). “Look!” they exclaimed. “Is this right?” Ms. Bencomo asked them to explain their design, and after the students defended their structure, she smiled broadly and congratulated them and their persistence and creativity. Then she directed them to predict the correct chemical formula using water’s formula (H 2O) as an example and then to draw the structure using their colored pencils (Figure 3). Some of the groups were able to work independently throughout the activity, even when faced with the ultimate task of constructing a model of methanol (CH 3 OH), which contains three different types of atoms and six atoms to bond together. Other groups required occasional support, encouragement, or clarification during the 30-minute lesson, but none became overwhelmed to the point of giving up. In predicting the formulas for each molecule, students frequently wrote them in an unconventional manner, such as writing O 2 C rather than the commonly accepted CO 2 . Yet such attempts represent thoughtful inquiries, and Ms. Bencomo did not correct their responses. The structure of the instructional sequence also allowed for open discourse of ideas within and between groups of students and for groups to work at their own pace. As a consequence, there was no need for any corrective or disciplinary action even though the classroom was noisy and bustling with activity. Excitement for Future Science In reflecting on the lesson, Ms. Bencomo felt that students were very excited about the opportunity to build molecules. While she was encouraged at how well they did overall throughout the activity as well as on the unit test, she recognized that several students were confused by the fact that an atom can form multiple bonds with another atom. She suggested that next time she would probably do a little more introduction into why atoms may have two bonds with the same atom and why they may only have one, as this was one area where students struggled. An analysis of student journals revealed that students recognized the importance of these molecules, as indicated by Julie, who wrote that “oxygen is a very important molecule, and carbon dioxide is too, because oxygen is something you need to breathe, and carbon dioxide is a gas given off in breathing.” Perhaps more importantly, the students expressed their enthusiasm for the lesson, as echoed by Anna, who reflected, “I had lots of fun learning about molecules and atoms, and I can’t wait to learn more.” It is only through such active engagement that we can hope to inspire more students to pursue opportunities in the fields of science, technology, engineering, and mathematics. n Tom Brown ([email protected]) is an associate professor of science education at Kennesaw State University in Kennesaw, Georgia. Greg Rushton is an assistant professor of chemistry at Kennesaw State University in Kennesaw, Georgia. Marie Bencomo is a fifth-grade teacher at Clarkdale Elementary School in Austell, Georgia. Resources National Research Council (NRC). 1996. National science education standards. Washington, DC: National Academy Press. Internet The SMATHematics Project: The Wonder of Science, The Power of Mathematics http://webtech.kennesaw.edu/tbrown/SMATH/ SMATH.htm NSTA Connection Download a blank student lab sheet at www.nsta.org/SC0801. January 2008 37 Mighty molecule student lab sheet. Mighty Molecule Building Name _______________ Most atoms are unstable by themselves, so they bond with other atoms in certain patterns to become stable. Of the 92 natural elements, only about 25% are important to living things and only four elements make up about 95% of living things. If you can understand how these fabulous four elements bond in order to get stable, then you can comprehend a great deal about the chemistry of all living things. The Fabulous Four Element Hydrogen Oxygen Nitrogen Carbon Symbol H O N C Color Yellow Red Light Blue Black Bonds to Get Stable 1 2 3 4 For each molecule, you will be given its common name and the number and type of each atom in the molecule. Your job as a group is to put the atoms together in a way that will form a stable molecule. When you think you have constructed a stable molecule, predict what you think the formula of the molecule should be, and draw a sketch of the molecule. The formula should include the symbol of each element and the number of atoms of each element in your molecule. You are now ready to build some of the most important molecules on our planet. Remember, for the molecule to be stable, it must form the proper number of bonds. When you build the molecules, use sticks or springs to represent the bonds. You can form one bond (single) between two atoms or two bonds (double) and sometimes even three bonds (triple). Procedure: Build the following molecules using the ball-and-stick models and then predict the formula for the molecule and draw a sketch of the molecule. Name of Molecule Atoms in Molecule 2 hydrogen water 1 oxygen 1 nitrogen ammonia carbon dioxide 3 hydrogen 1 carbon Predicted Formula Sketch of Molecule 2 oxygen methane (natural gas) 1 carbon 4 hydrogen oxygen (as found in air) 2 oxygen nitrogen (as found in air) 2 nitrogen 1 carbon methanol (wood alcohol) 4 hydrogen 1 oxygen 3 carbon propane 8 hydrogen Guiding Questions: 1. Do all the molecules contain only single bonds? Why do you think this is the case? 2. Do all the molecules have the same shape? Why do you think this is the case? 3. Because carbon (black) is the only element that can form long chains by bonding to itself over and over, it is the backbone element of all living things. What is unique about carbon that allows it form these big chains? 4. Two of the molecules (methane and propane) that you made are used by people to as a fuel (for energy). What do each of these molecules have in common?
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