Fungicides Fungicide Categories • Contact – work on leaf & stem surface to prevent penetration by fungus • Systemic – are absorbed into plant tissue and are translocated (primarily in xylem) • Local systemic – absorbed but only move a short distance, don’t move in vascular tissue • Mesostemic – new category strongly attracted to plant surface and are absorbed by waxy layers Comparison of fungicide categories Contact Systemic • Protective • Not translocated • New growth is not protected • Typically for foliar diseases only • Broad spectrum • Little possibility of resistance developing • Typically not used for root pathogens • Protective & curative • Translocated • New growth is protected • For foliar and root diseases • Specific mode of action • More possibility of resistance developing • Effective on root pathogens Fungicide Families • • • • • • Aromatic hydrocarbons Benzimidazole Dicarboximide DMI (demethylation inhibitors) Ethylenebisdithiocarbamate (EBDC) Strobilurins Fungicide families • Aromatic hydrocarbon – Contact, protective – Destroy fungal membranes – High volitility • Examples – Chloroneb (Terraneb) – Ethazol (Koban, Terrazole) – PCNB pentachloronitrobenzene (Terrachlor, Turcide) • Benzimidazole – – – – Systemic, curative, protective Inhibit cell wall formation Primarily xylem movement Translocates in xylem • Examples – Benomyl (Tersan 1991, Benelate – Thiophanate methyl (Fungo) Fungicide families • Dicarboximide – Contact/local systemic – Interfere with DNA synthesis – Don’t move in xylem or phloem • Examples – Iprodione (Chipco 26019) – Vinclozolin (Vorlan) • DMI (demethylation inhibitors) – Systemic, curative & protective – Inhibits ergosterol biosynthesis – DON’T APPLY ON BENT OR BERMUDA GREENS ABOVE 90 degrees F • Examples – – – – Fenarimol (Rubigan) Propiconazol (Banner) Triadimefon (Bayleton) Others :Eagle, Tourney, Trinity, and Triton Fungicide families • EBDC Ethylene bisdithiocarbamate – Contact, protective – Multiple site mode of action – Broad spectrum • Examples – Maneb (Stoller) – Maneb+zinc (Diathane M‐45) – Mancozeb (Tersan LSR) • Strobilurins – Systemic, curative – Quinone inside inhibitor (QiI) – Moves in xylem • Examples – – – – – Flutolanil (Prostar) Azoxystrobin (Heritage) Trifloxystrobin (Compass) Tebucanozol (Torque) Fluoxastrobin (Disarm) Fungicide Families • Triazine – Contact,protective – Broad spectrum – Inhibits spores • Example – Anilazine (Dyrene) • Benzonitrile – Contact, protective – Broad spectrum – Inhibits glutathione • Example – Chlorothalonil (Daconil) • Mixtures – A number of products are available that are mixtures of two chemistries • Examples – Azoxystrobin + propiconazole (Headway) – Chlorothalonil + fluoxastrobin (Disarm C) Pythium fungicides • Aromatic hydrocarbons – Discussed on previous slide – Contact, protective • Ones that work on pythium – Chloroneb (Terraneb) – Ethazol (Koban, Terrazole) • Carbamate – Local systemic, degrades quickly in plant, some curative effect – Inhibits sporulation – Moves short distance in xylem • Examples – Propamocarb (Banol, Proplant ) – Stellar (home lawns, propamocarb + fluopicolide Pythium fungicides • Phenylamide – Systemic, curative – Inhibit nucleic acid systhesis – Kills hyphae inside plant thus often used with contact fungicide – Moves in xylem • Examples – Metalaxyl (Subdue, Apron ‐ seed treatment) • Phosphonate – Systemic, protective, weak curative – Moves in xylem & phloem – Fosetyl‐Al Common seed treatment • Examples – Fosetyl‐Al (Aliette, Autogragh, Prodigy, Signature) – Phosphoric acid (Alude, Magellan, Vital)
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